SEARCH · Engineering Papers
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Solid, linear chain hydrocarbons with molecular weight ranging from about 300 to 2000 can serve as long-lived recording medium in optical memory system. Suitable recording hydrocarbons include microcrystalline waxes and low molecular weight polymers or ethylene.
In many biological research efforts, long chain organic molecules are studied by breaking large molecules into smaller components. Cleavage technique of recent interest is the use of solvated electrons. These are formed when aqueous solutions are bombarded with gamma radiation. Solvated electron is very reactive and can reduce most any species present, even to form free radicals.
Whether any significant increment to accuracy could be transferred from a super-control continental net (continental satellite net or super-transcontinental traverse) to the fundamental geodetic net (first-order triangulation) is discussed. This objective was accomplished by evaluating the positional accuracy improvement for a triangulation station, which is near the middle of the investigated geodetic triangulation net, by using various station constraints over its geodetic position. This investigation on a 1858 kilometer long triangulation chain shows that the super-control net can provide a useful constraint to the investigated geodetic triangulation net, and thus can improve it only when the accuracy of super-control net is at least 1 part in 500,000.
Attempts to prepare low molecular weight, curable poly-(fluoroalkoxyphosphazenes) have been successful. Derivatization of /Cl2PN/n polymer with alkoxides gave functionally reactive terpolymers. These terpolymers could be crosslinked with polyisocyanates at room temperature. Attempts to control molecular weight have not been as successful. The effects of (Cl2PN)3 monomer purity, use of (Cl2PN)3,4 mixture, and early termination of the bulk polymerization of (Cl2PN)3 were studied briefly. Both low and high molecular weight polymers were obtained. Reaction of NH4Cl with PCl5 with subsequent heating to give chain extension gave either gels of oils with molecular weights of several thousand. The stabilization of poly-(fluoroalkoxyphosphazene) was investigated. The results generally were inconclusive, but acids were found to be deleterious while bases had little discernible effect. Improvements in stability by modification of end groups was inconclusive.
Reactions of various polymers, such as polystyrene and its stereo-specific isomers, butylrubber, nylon, etc., with nitrogen dioxide and sulfur-dioxide were studied over the past few years. More recently, work has been initiated on the influence of polymer morphology on degradation of polymers in presence of these gases, near UV radiation and oxygen. Unexpected effects have been observed during chain scission near room temperature. Thus, for instance, isotactic polystyrene of various crystallinities, as far as extent and type are concerned, show marked differences in their degradation characteristics. Thus, for instance, crystalline polymers show faster degradation than amorphous ones, which seems to be contrary to expectations. However, this phenomenon can be explained in quite a consistent manner. The importance of all these reactions in connection with air pollution is briefly discussed.
A computer program is described that performs a statistical multiple-decision procedure called chain pooling. It uses a number of mean squares assigned to error variance that is conditioned on the relative magnitudes of the mean squares. The model selection is done according to user-specified levels of type 1 or type 2 error probabilities.
Apollo 16 metric photographs taken at low to high sun angles provided the first stereographic coverage of the distinctive landforms collectively referred to as Imbrium sculpture. The sculpture consists of a series of nearly linear ridges and troughs extending radially outward for more than 1000 km from the rim of the Imbrium Basin. The origin of the ridges and troughs, whether by deposition and impact scoring by fluidized clouds of ejecta from the Imbrium Basin or by faulting and volcanism during and subsequent to basin formation, is controversial. Evidence indicative of the mode of origin of Imbrium sculpture is summarized as follows. Evidence of volcano-tectonic mode of origin is favored by: (1) wide variation in relative age of parts of the sculpture; (2) furrows without rims; (3) absence of ballistic shielding; (4) asymmetry of sculpture; (5) absence of randomly oriented clusters; and (6) association with other features of structural origin. An origin by ejecta scoring and deposition is favored by the gradational ejecta with a Fra Mauro-type texture. Features that are ambiguous as to mode or origin are furrows made of coalesced crater chains and prominent rims on furrows.
Superb photographs of King Crater were returned by the Apollo 16 crew. The metric and panoramic cameras provided stereoscopic coverage with which high quality topographic maps may be made. King crater, approximately 75 km in diameter and, on the average, 3.8 km deep, is among the most significant features photographed and visually studied from lunar orbit on the Apollo 16 mission. It is the freshest crater on the far side in its size range and has several unique characteristics. (1) Although its ejecta blanket displays very sharp features, the crater does not appear to have extensive ray systems and secondary crater chains. (2) As depicted for the first time by Apollo 16 photographs, the ejecta blanket is strewn with numerous flow fronts and scarps. (3) A flat and smooth, dark, lavalike deposit 15 km across is on the northern rim of the crater. (4) The central peak of the crater is a Y-shaped structure that begins at the southern rim. (5) Bright units that are aligned with the central peak on the northern wall and rim suggest that a preexisting tabular body was excavated by the cratering process.
Mariner 6 and 7 photographs were used to investigate the nature and importance of linear surface trends on Mars. Cross correlations of frequency-azimuth distributions of linear trends from different Mariner frames indicate that lineations not recognized as topographic features have a component of pseudoforms, probably introduced during digital reconstruction of the pictures. Similar statistical tests may aid in the analysis of surface trends from future satellites and space probes. The most reliable data were separated into photometrically defined provinces. Meridiani Sinus and Margaritifer Sinus display five major trends in common, which are interpreted as extensions of crustal weaknesses related to the enormous equatorial canyon revealed in Mariner 6 and 9 pictures. Alignments of crater wall segments generally match these trends and suggest structural control of crater plan. Crater chains, however, do not match these trends and are interpreted as secondary impacts. Rose diagrams of lineations in Deucalionis Regio exhibit much more complexity and are believed to reflect a better preserved or more complex geologic history.
The author has identified the following significant results. Color composites and diazachrome transparencies of ERTS-1 imagery have greatly increased interpretation capabilities. Vegetation green-up and flooding due to late summer precipitation has been identified on such imagery. MSS imagery in all bands has not proven as valuable for similar determinations. Snow cover has been found to be valuable in the identification of fire scars, pinyon/juniper chainings, and subtle ecotones not previously identified with any other type of imagery. It is felt that a greater understanding of the effects of snow cover on vegetation remote sensing will enable investigators to extend capabilities relating to the mapping and identification of these resources. Highly reflective phreatophytic vegetation has been mapped and quantified using the MSS 5 and 7 bands and diazachrome color composites. Approximately 10 man-hours were required to complete the entire state. Native meadow and hay meadow vegetation has been mapped in Elko County, Nevada, using ERTS-1 imagery. Future plans include a statewide inventory of this resource.
The task of correlating in situ spectral reflectance measurements with ERTS imagery has commenced. A method of additive color analysis of a single multispectral band taken on different dates indicates that ERTS-1 bulk images have sufficient spatial and spectral fidelity to show indications of the presence of soil moisture in desert playas and changes in soil moisture with time. The chain of causality between soil moisture, in situ spectral reflectance, and ERTS multispectral scanner image density remains to be established during the subsequent phases of this study.
A series of DEAB initiated isoprene polymerizations were run in the 5-gallon stirred autoclave reactor. Polymerization run parameters such as initiator concentration and feed rate were correlated with the molecular weight to provide a basis for molecular weight control in future runs. Synthetic methods were developed for the preparation of n-1,3-alkadienes. By these methods, 1,3-nonadiene was polymerized using DEAB initiator to give an ester-telechelic polynonadiene. This was subsequently hydrogenated with copper chromite catalyst to give a hydroxyl terminated saturated liquid hydrocarbon prepolymer having greatly improved viscosity characteristics and a Tg 18 degrees lower than that of the hydrogenated polyisoprenes. The hydroxyl-telechelic saturated polymers prepared by the hydrogenolysis of ester-telechelic polyisoprene were reached with diisocyanates under conditions favoring linear chain extension gel permeation chromatography was used to monitor this condensation polymerization. Fractions having molecular weights above one million were produced.
Adhesion experiments with polytetra-fluoroethylene (PTFE) and polyimide contacting tungsten indicate that the polymers bond chemically to the clean metal surface. Polymer chain fragments which transfer to the surface of tungsten in field ion microscopy adhesion studies are highly oriented. Auger emission spectroscopy of PTFE transfer films to various metal surfaces indicates that the PTFE is bonded to the metal surface via the carbon atom. With PTFE in sliding contact with different orientations of aluminum, metal orientation is found to influence surfaces in sliding. The lowest friction and least amount of surface damage is detected on the highest atomic density (111) plane. The friction process itself can initiate polymer film formation from simple organic molecules.
Review of the present state of experimentally based concepts of organic evolution from amino acids. Earlier studies of the synthesis of amino acid precursors from meteoritic material, lunar dust, and terrestrial lava are briefly summarized, and laboratory experiments in which polymers of amino acids were obtained either by direct heating of dry amino acids or by heating aqueous solutions of mixtures of amino acids are described. In particular, a process is described by which alpha-amino acids were made to react to form linear chains of proteinoids. It is concluded that a proteinoid microsystem was a common ancestor of all life on earth.
Discussion of NDT techniques and instrumentation developed to demonstrate the quality and normal behavior of 1-W/1-A no-fire electroexplosive devices (EEDs) without firing or degrading the units. Application of these techniques is limited to the bridgewire/explosive/header interface which is considered to be the most critical link in the electroexplosive chain. A certain amount of destructive testing required to determine the sensitivity and output of the EEDs can be accomplished by additional instrumentation that initiates and delivers energy in an impulsive manner with control of pulse width and amplitude.
A stochastic model is applied to the divergence of the horse-pig lineage from a common ansestor in terms of the alpha and beta chains of hemoglobin and fibrinopeptides. The results are compared with those based on the minimum mutation distance model of Fitch (1972). Buckwheat and cauliflower cytochrome c sequences are analyzed to demonstrate their ambiguities. A comparative analysis of evolutionary rates for various proteins of horses and pigs shows that errors of considerable magnitude are introduced by Glx and Asx ambiguities into evolutionary conclusions drawn from sequences of incompletely analyzed proteins.
Apollo 14 obtained 950 photographs from lunar orbit using the Hasselblad and Hycon cameras. The photographs reveal a number of new geologic features as well as previously unrecognized details of the morphology, structure, and stratigraphy of lunar surface units. The primary result is the verification of the extensive role of volcanism in the formation and modification of the lunar highlands, especially on the far side. Terra volcanism appears to be manifest in the formation of (1) constructional units of hilly and furrowed materials of regional extent as in the Kant Plateau in the central near-side highlands and northwest of the crater Pasteur near the eastern limb of the moon; (2) somewhat viscous lava flows and pools associated with fracture systems and/or what appear to be volcanic craters; (3) craters, crater chains, and irregular depressions, particularly on the lunar far side. The first photographs of a flow channel, a leveed sinuous rille that apparently originated by lava flowage on the surface, were obtained by Apollo 14. Another first is a high-resolution photograph of the interior of what appears to be the youngest lunar crater yet photographed in the 20- 40-km size range.
Small ballistic ranges were used to perform controlled laboratory shock experiments on 12 selected silicates. Debye-Scherrer investigations of shocked materials revealed a gradual lattice breakdown of crystalline matter under shock. Individual mineral species behave selectively. Sheet silicates break down very easily, followed by tecto-silicates. Chain-, ino- and ortho-silicates are of considerably higher shock resistance. Depending on the mineral species, the first sign of shock damage is evidenced in the long range order at 20-70 kb. At intermediate pressures (100-200 kb) the long range order is essentially destroyed with the short range order heavily disturbed. At pressures exceeding 300 kb tecto-silicates are completely collapsed.