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NASA NTRS1986

Steranes and triterpanes generated from kerogen pyrolysis in the absence and presence of minerals

Changes in the degree of isomerization of steranes and triterpanes during kerogen pyrolysis in the absence or presence of minerals are described. Kerogen from a Monterey Formation diatomite core sample was pyrolyzed under reduced pressure at 300 C for 2-1000 hrs in the presence or absence of calcite, illite, and montmorillonite. It is observed that the extent of isomerization of biomakers in C-20 in 14 alpha(H), 17 alpha(H)-steranes, at C-22 in 17 alpha(H), 21 beta(H)-hopanes and of 17 beta(H), 21 beta(H)-hopanes correlates to early diagenetic stages in rock extracts from sedimentary basins, and faster isomerization for steranes and triterpanes in the bitumen then for those in the kerogen structure are detected. The effects of the minerals on the isomerization reactions are examined; calcite inhibits, and illite and montmorillonite catalyze the reactions.

Tannenbaum, E.↗
NASA NTRS1986

Determination of cloud microphysical properties by laser backscattering and extinction measurements

The extinction and backscattering of 514 nm laser radiation in polydisperse water droplet clouds was studied in the laboratory. Three cloud size distributions with modal diameters of 0.02, 5.0, and 12.0 microns were investigated. The relationships between the cloud optical parameters (attentuation coefficient, sigma and volume backscattering coefficient, Beta (sub pi)) and the cloud water content, C, were measured for each size distribution. It was found that a linear relationship exists between sigma and C and between beta (sub pi) and C for cloud water content values up to 3gm/cubic m. The linear relationships obtained, however, have slopes which depend on the droplet size distribution. For a given water content both sigma and beta (sub pi) increase as the modal diameter decreases. The measured data are compared with existing theoretical analyses and discussed in terms of thie application to lidar measurements of atmospheric clouds. It is concluded that the empirical information obtained can serve as a basis for quantitative lidar measurements.

Dubinsky, R. N.↗
NASA NTRS1986

Non-LTE hydrogen-line formation in moving prominences

The behavior of hydrogen-line brightness variations, depending on the prominence-velocity changes were investigated. By solving the NON-Local thermodynamic equilibrium (LTE) problem for hydrogen researchers determine quantitatively the effect of Doppler brightening and/or Doppler dimming (DBE, DDE) in the lines of Lyman and Balmer series. It is demonstrated that in low-density prominence plasmas, DBE in H alpha and H beta lines can reach a factor of three for velocities around 160 km/sec, while the L alpha line exhibits typical DDE. L beta brightness variations follow from a combined DBE in the H alpha and DDE in L alpha and L beta itself, providing that all relevant multilevel interlocking processes are taken into account.

Heinzel, P.↗
NASA NTRS1987

Nonlinear force-free magnetic fields: Calculation and applicatin to astrophysics

The problem concerned in this work is that of calculating magnetic field configurations in which the Lorentz force (vector)j x (vector)B is everywhere zero, subject to specified boundary conditions. The magnetic field is represented in terms of Clebsch variables in the form (vector)B = del alpha x del beta. These variables are constant on any field line. The most appropriate choice of boundary conditions is to specify the values of alpha and beta on the bounding surface. It is proposed that the field lines move in the direction of local Lorentz force and relax towards a force-free field configuration. This concept leads to an iteration procedure for modifying the variables alpha and beta that tends asymptotically towards the force-free state. This method is first applied to a simple problem in two rectangular dimensions; the calculation shows that the convergence of magnetic field energy to a minimum state (force-free) is close to exponential. This method is then applied to study some astrophysical force-free magnetic fields, such as the structures and evolution of magnetic fields of rotating sunspots and accretion disks. The implication of the results, as related to the mechanisms of solar flares, extragalactic radio sources and radio jets, are discussed.

Yang, Wei-Hong↗
NASA NTRS1987

Structural models for nickel electrode active mass

Raman spectroscopic data allow one to distinguish nickel electrode active mass, alpha and beta phase materials. Discharges active mass is not isostructural with beta-Ni(OH)2. This is contrary to the generally accepted model for the discharged beta phase of active mass. It is concluded that charged active mass displays a disordered and nonstoichiometric, nonclose packed structure of the R3 bar m, NiOOH structure type. Raman spectral data and x ray diffraction data are analyzed and shown to be consistent with this structural model.

Cornilsen, Bahne C.↗
NASA NTRS1986

Variability of Markarian 1018 - Seyfert 1.9 to Seyfert 1

Simultaneous IUE and optical spectrophotometry of the Seyfert 1.9 galaxy Markarian 1018 is presented. The strength of H-beta(broad) has increased by a factor of 6.6 in 4 yr, and the galaxy now shows strong broad UV and optical line emission similar to that seen in normal Seyfert 1 galaxies, but with markedly asymmetric line profiles. As in other variable Seyfert galaxies, H-alpha emission has also increased but by a lesser amount than H-beta. Furthermore, Ly-alpha (not observed during the first epoch) is now quite strong relative to H-beta and H-alpha. Inspection of the line profiles reveals nearly identical blue asymmetric line profiles in all permitted lines; these show evidence of significant profile evolution over a 1 yr time scale. The present line ratios and the nature of their variability suggest that the enhancement in the broad-line emission is not caused by the removal of obscuring dust but by the 'lighting up' of the broad-line region.

Cohen, Ross D.↗
NASA NTRS1986

Solar cycle variations in the solar wind

The solar cycle variations of various solar wind parameters are reviewed. It is shown that there is a gradual decrease in the duration of high-speed streams from the declining phase of solar cycle 20 through the ascending phase of cycle 21 and a corresponding decrease in the annual average of the proton speed toward solar maximum. Beta, the ratio of the proton thermal pressure to magnetic pressure, undergoes a significant solar cycle variation, as expected from the variation in the IMF. Individual hourly averages of beta often exceed unity with 20 cases exceeding 10 and one case as high as 25. The Alfven Mach number shows a solar cycle variation similar to beta, lower aboard solar maximum. High-speed streams can be seen clearly in epsilon and the y component of the interplanetary magnetic field.

Freeman, John W.↗
NASA NTRS1988

Monte Carlo renormalization-group investigation of the two-dimensional O(4) sigma model

An improved Monte Carlo renormalization-group method is used to determine the beta function of the two-dimensional O(4) sigma model. While for (inverse) couplings beta = greater than about 2.2 agreement is obtained with asymptotic scaling according to asymptotic freedom, deviations from it are obtained at smaller couplings. They are, however, consistent with the behavior of the correlation length, indicating 'scaling' according to the full beta function. These results contradict recent claims that the model has a critical point at finite coupling.

Heller, Urs M.↗
NASA NTRS1988

Nuclear emission-line intensities and profiles in NGC 3783

High-resolution optical spectrophotometry is presented for the nucleus of the Seyfert 1 galaxy NGC 3783. The data suggest that the broadest components of the forbidden lines have blueshifts relative to systemic velocity which are correlated primarily with ionization potential, and FWHMs which are correlated primarily with criticl density. Similar trends also exist in the line components responsible for the larger part of the line emission, but are not as strong as for the broadest line components. Comparison of the profiles of the Balmer lines indicates that the Balmer decrement measured from the H-beta/H-alpha ratio flattens in the line wings. However, the H-gamma and H-delta line profiles are more similar to the H-alpha line profile than to the H-beta line profile, suggesting that the H-beta profile may be anomalous.

Evans, I. N.↗
NASA NTRS1987

Linear and nonlinear mechanical properties of a series of epoxy resins

The linear viscoelastic properties have been measured for a series of bisphenol-A-based epoxy resins cured with the diamine DDS. The linear viscoelastic master curves were constructed via time-temperature superposition of frequency dependent G-prime and G-double-prime isotherms. The G-double-prime master curves exhibited two sub-Tg transitions. Superposition of isotherms in the glass-to-rubber transition (i.e., alpha) and the beta transition at -60 C was achieved by simple horizontal shifts in the log frequency axis; however, in the region between alpha and beta, superposition could not be effected by simple horizontal shifts along the log frequency axis. The different temperature dependency of the alpha and beta relaxation mechanisms causes a complex response of G-double-prime in the so called alpha-prime region. A novel numerical procedure has been developed to extract the complete relaxation spectra and its temperature dependence from the G-prime and G-double-prime isothermal data in the alpha-prime region.

Curliss, D. B.↗
NASA NTRS1988

Universality classes for deterministic surface growth

A scaling theory for the generalized deterministic Kardar-Parisi-Zhang (1986) equation with beta greater than 1, is developed to study the growth of a surface through deterministic local rules. A one-dimensional surface model corresponding to beta = 1 is presented and solved exactly. The model can be studied as a limiting case of ballistic deposition, or as the deterministic limit of the Eden (1961) model. The scaling exponents, the correlation functions, and the skewness of the surface are determined. The results are compared with those of Burgers' (1974) equation for the case of beta = 2.

Krug, J.↗
NASA NTRS1988

Structural models for nickel electrode active mass

Raman spectroscopic data allow one to distinguish nickel electrode active mass, alpha and beta phase materials. Discharges active mass is not isostructural with beta-Ni(OH)2. This is contrary to the generally accepted model for the discharged beta phase of active mass. It is concluded that charged active mass displays a disordered and nonstoichiometric, nonclose packed structure of the R3 bar m, NiOOH structure type. Raman spectral data and X ray diffraction data are analyzed and shown to be consistent with this structural model.

Cornilsen, B. C.↗
NASA NTRS1990

Silicon carbide semiconductor device fabrication and characterization

A number of basic building blocks i.e., rectifying and ohmic contacts, implanted junctions, MOS capacitors, pnpn diodes and devices, such as, MESFETs on both alpha and beta SiC films were fabricated and characterized. Gold forms a rectifying contact on beta SiC. Since Au contacts degrade at high temperatures, these are not considered to be suitable for high temperature device applications. However, it was possible to utilize Au contact diodes for electrically characterizing SiC films. Preliminary work indicates that sputtered Pt or Pt/Si contacts on beta SiC films are someways superior to Au contacts. Sputtered Pt layers on alpha SiC films form excellent rectifying contacts, whereas Ni layers following anneal at approximately 1050 C provide an ohmic contact. It has demonstrated that ion implantation of Al in substrates held at 550 C can be successfully employed for the fabrication of rectifying junction diodes. Feasibility of fabricating pnpn diodes and platinum gated MESFETs on alpha SiC films was also demonstrated.

Davis, R. F.↗
NASA NTRS1990

Preliminary plume characteristics of an arcjet thruster

An experimental investigation of a low power arcjet plume was conducted using emission spectroscopy. A laboratory model arcjet incorporating a segmented anode was run on simulated hydrazine at a flow rate of 5 x 10(exp -5) kg/s. The complete visible spectrum measured in the exit plane of the arcjet showed the presence of N2, N2(+), NH, and H. Radial intensity profiles for the H alpha, H sub beta, and the NH A(sup 3)Pi yields X(sup 3)Sigma(0,0) transitions at four different axial locations were measured. These line of sight intensity measurements, spaced 0.05 mm apart, were deconvoluted to give the radial intensity distribution using an inverse Abel transformation. The ratio between the intensities from the H sub alpha and H sub beta transitions indicated a non-Boltzmann energy distribution between excited states in the plume. Axial intensity profiles taken on center line indicated the decay rate of excited states in the plume. An electron number density of 2 x 10(exp 13)/cu cm at the exit plane was determined based on Stark broadening of the H sub beta line. Rotational temperatures of 750 K, 1750 K, and 2500 K were determined for N2, N2(+), and NH respectively. The results demonstrate that the location of the current attachment on the anode has a measurable effect on the electronically excited species in the plume and that dissociation is the dominant frozen flow loss mechanism in low power arcjets.

Manzella, David H.↗
NASA NTRS1989

Styles of volcanism on Venus - New Arecibo high resolution radar data

Arecibo high-resolution (1.5 to 2 km) radar data of Venus for the area extending from Beta Regio to western Eisila Regio provide strong evidence that the mountains in Beta and Eisila Regiones and plains in and adjacent to Guinevere Planitia are of volcanic origin. Recognized styles of volcanism include large volcanic edifices on the Beta and Eisila rises related to regional structural trends, plains with multiple source vents and a mottled appearance due to the ponding of volcanic flows, and plains with bright features surrounded by extensive quasi-circular radar-dark halos. The high density of volcanic vents in the plains suggests that heat loss by abundant and widely distributed plains volcanism may be more significant than previously recognized. The low density of impact craters greater than 15 km in diameter in this region compared to the average density for the higher northern latitudes suggests that the plains have a younger age.

Campbell, Donald B.↗
NASA NTRS1989

The Uranian magnetopause - Lessons from earth

Magnetic field measurements by Voyager 2 reveal differences between the Uranian magnetopause and the typical terrestrial magnetopause. In particular there are pulsations in the magnetic field at Uranus which may represent partial crossings of the magnetopause, the entry into magnetic flux ropes or the passage through mirror mode waves. Examination of terrestrial data, especially those obtained under conditions of very high plasma beta, suggests that the last possibility is the more likely. The magnetopause crossing itself is also different than those typically observed at 1 AU. It contains a magnetic field rotation of over 270 deg. While this is rare at 1 AU, an example has been found at earth where the field rotation is also greater than 270 deg. In some aspects these crossings resemble slow shocks. This also occurred at a time of high plasma beta. Thus it is concluded that plasma beta is very important in determining the structure of the magnetopause.

Russell, C. T.↗
NASA NTRS1990

Emission-line variations and broad-line region kinematics of NGC 5548

Sixteen spectroscopic observations of the Seyfert galaxy NGC 5548 were made between March 1979 and June 1984 at Palomar and Steward Observatories. Broad-line flux variations correlated with nonstellar continuum changes were measured. H-beta, H-gamma, and He II 4686A all respond rapidly to continuum variations providing strong evidence for photoionization by a central continuum source. Additionally, H-beta profile variations have occurred during the 1900 day monitoring period. These profile variations also correlate with changes in the continuum, but lag behind by about 90 days or less. A kinematic model that incorporates radial outflow and an internal line opacity source is proposed to explain qualitatively the observed H-beta profile variations.

Rosenblatt, Edward I.↗
NASA NTRS1990

Coordinated optical and ultraviolet observations of DH Leo

Results are reported from contemporaneous KPNO optical spectroscopy, IUE UV spectroscopy, and KPNO R photometry of the DH Leo triple system in spring 1987. The data are presented in tables, graphs, and spectral phase images and discussed in detail. The H-alpha, H-beta, H-gamma, H-delta, and Ca II H and IRT lines are found to have excess emission, and the phase modulation in H-alpha, H-beta, and Ca II is well correlated with the photometric modulation. This result is attributed to the combination of (1) a small amount of global chromospheric emission and (2) emission from plagelike regions associated with cool starspots. The (H-alpha)/(H-beta) ratio is found to be significantly lower than that in longer-period RS CVn systems.

Newmark, Jeffrey S.↗