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At least 901 records · Page 50
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Miniature triaxial metastable ionization detector for gas chromatographic trace analysis of extraterrestrial volatiles

The present investigation is concerned with a miniature metastable ionization detector featuring an unconventional electrode configuration, whose performance characteristics parallel those of traditional design. The ionization detector is to be incorporated in a flight gas chromatograph (GC) for use in the Space Shuttle. The design of the detector is discussed, taking into account studies which verified the sensitivity of the detector. The triaxial design of the detector is compared with a flat-plate style. The obtained results show that the principal goal of developing a miniature, highly sensitive ionization detector for flight applications was achieved. Improved fabrication techniques will utilize glass-to-metal seals and brazing procedures.

Woeller, F. H.↗
NASA NTRS1984

Dynamic compression and volatile release of carbonates

Particle velocity profiles upon shock compression and isentropic releases were measured for polycrystalline calcite. The Solenhofen limestone release paths lie, close to the Hugoniot. Calcite 3 to 2 transition, upon release, was observed, but rarefaction shocks were not detected. The equation of state is used to predict the fraction of material devolatilized upon isentropic release as a function of shock pressure. The effect of ambient partial pressure of CO2 on the calculations is demonstrated and considered in models of atmospheric evolution by impact induced mineral devolatilization. The radiative characteristics of shocked calcite indicate that localization of thermal energy occurs under shock compression. Shock entropy calculations result in a minimum estimate of 90% devolatilization upon complete release from 10 GPa. Isentropic release paths from calculated continuum Hugoniot temperatures cross into the CaO (solid) + CO2 (vapor) field at improbably low pressures. It is found that release paths from measured shock temperatures cross into the melt plus vapor field at pressures greater than .5 GPa, which suggests that devolatilization is initiated at the shear banding sites.

Tyburczy, J. A.↗
NASA NTRS1985

Biologically produced volatile compounds: N2O emissions from soils

Tropospheric nitrous concentration has increased by 0.2 0.4% per year over the period 1975 to 1982, amounting to net addition to the atmosphere of 2.8 - 5.6 Tg N2O-N per year. This perturbation, if continued into the future, will affect stratospheric chemical cycles, and the thermal balance of the Earth. In turn it will have direct and indirect global effects on the biosphere. Though the budget and cycles of N2O on Earth are not yet fully resolved, accumulating information and recent modelling efforts permit a more complete evaluation and better definition of gaps in our knowledge.

Banin, A.↗
NASA NTRS1985

The partial volatilization of Mercury

During recent years research on the primitive solar nebula has followed two main themes: (1) Very early in the development of the nebula conditions probably favored the occurrence of major gaseous instabilities leading to the formation of giant gaseous protoplanets, but the rapid rise of the external temperature soon evaporated the envelopes of these protoplanets, possibly leaving behind precipitated solids which formed the cores and mantles of the terrestrial planets. (2) Models of the nebula indicate a later stage when conditions in the inner Solar System became very hot; at the position of Mercury the temperature was probably in the range 2500-3500 K. This leads to the hypothesis that the original protomercury was a body substantially more massive than the present planet and of normal composition, but that when it was immersed in the high-temperature field of the dissipating solar nebula, most of the rocky mantle was vaporized and mixed into the solar nebula gases and carried away by them. This hypothesis is investigated in the present paper. For simplicity the vaporization of a mantle composed of enstatite, MgSiO3, was computed for a planet with 2.25 the mass of Mercury at a temperature of 3000 K. It is argued that the mantle could probably be largely removed in the available time of 30,000 yrs. Subsequent accretion would restore some magnesium silicates to the mantle of the planet.

Cameron, A. G. W.↗
NASA NTRS1986

Dynamic compression and volatile release of carbonates

Particle velocity profiles upon shock compression and isentropic releases were measured for polycrystalline calcite. The Solenhofen limestone release paths lie close to the Hugoniot. Calcite 3 to 2 transition, upon release was observed, but rarefaction shocks were not detected. The equation of state is used to predict the fraction of material devolatilized upon isentropic release as a function of shock pressure. The effect of ambient partial pressure of CO2 on the calculations is demonstrated and considered in models of atmospheric evolution by impact induced mineral devolatilization. The radiative characteristics of shocked calcite indicate that localization of thermal energy occurs under shock compression. Shock entropy calculations result in a minimum estimate of 90 percent devolatilization upon complete release from 10 GPa. Isentropic release paths from calculated continuum Hugoniot temperatures cross into the CaO (solid) + CO2 (vapor) field at improbably low pressures. It is found that release paths from measured shock temperatures cross into the melt plus vapor field at pressures greater than .5 GPa, which suggests that devolatilization is initiated at the shear banding sites.

Tyburczy, J. A.↗
NASA NTRS1987

Measurements of the dielectric constants for planetary volatiles

The model of Titan at present has the surface temperature, pressure, and composition such that there is a possibility of a binary ethane-methane ocean. Proposed experiments for future Titan flybys include microwave mappers. Very little has been measured of the dielectric properties of the small hydrocarbons at these radar frequencies. An experiment was conducted utilizing a slotted line to measure the dielectric properties of the hydrocarbons, methane to heptane, from room temperature to -180 C. Measurements of the real part of the dielectric constants are accurate to + or - 0.006 and the imaginary part (the loss tangent) of the liquids studied is less than or equal to 0.001. In order to verify this low loss tangent, the real part of the dielectric constant of hexane at 25 C was studied as a function of the frequency range of the slotted line system used. The dielectric constant of hexane at room temperature, between 500 MHz and 3 MHz, is constant within experimental error.

Anicich, Vincent G.↗
NASA NTRS1987

Lava fountain heights at Pu'u 'O'o, Kilauea, Hawaii - Indicators of amount and variations of exsolved magma volatiles

Factors most important in determining fountain height in Hawaiian-type basaltic eruptions were assessed on the basis of theoretical calculations and observations at Pu'u 'O'o vent, east rift zone of Kilauea, Hawaii. It is shown that fountain height is very sensitive to changes in exsolved gas content (and, thus, can be used to estimate variability in exsolved gas content) and relatively insensitive to large variations in volume flux. Volume flux was found to be the most important parameter determining the equilibrium vent diameter. The results of calculations also indicate that there was a general increase in magma gas content over the first 20 episodes of the Pu'u 'O'o eruption and that gas depletion took place in the conduit beneath the vent during repose periods.

Head, James W., III↗
NASA NTRS1988

Search for volatiles on icy satellites. I - Europa

NASA IRTF reflectance spectra of unprecedented precision, obtained for the leading and trailing sides of Europa, are presently noted to no longer show the apparent absorptions seen in 1980 and 1985. It is presently suggested that if the weak absorptions seen in the 1980 and 1985 data are real, they may indicate the transient spectroscopic presence of a molecular component on Europa's trailing side that differs from the water ice known to be the dominant constituent of the surface.

Brown, Robert Hamilton↗
NASA NTRS1988

Volatiles on Triton - The infrared spectral evidence, 2.0-2.5 microns

The new IR spectra presented for Triton exhibit the 2.3-micron methane band as well as Cruikshank et al.'s (1984) 2.15-micron spectral band. It is found on the basis of comparisons with methane ice spectra, and laboratory spectra of methane dissolved in liquid nitrogen, that the former band cannot be exclusively due to methane's presence. Also, the strength of the 2.3-micron band does not allow any obvious correlation with the satellite's orbital position in the new data set.

Cruikshank, Dale P.↗
NASA NTRS1987

Photochemical weathering and contemporary volatile loss on Mars

In an earlier series of papers by the author it was proposed that photochemical weathering of Fe(2+) in magnetite and in mafic silicates may be occurring in the contemporary surface environment with a resultant loss of O2 from the atmosphere. Morris and Lauer challenged the photochemical weathering model, proposing that oxidation by radiant heating rather than UV photoelectron emission induced oxidation may have dominated in the authors experiments. Subsequent laboratory studies of photochemical weathering of magnetite described here support the authors original proposal that UV illunimation can indeed drive the oxidation of magnetite under contemporary Martian surface conditions. The negative results of the Morris and Lauer study can now be explained.

Huguenin, R. L.↗
NASA NTRS1989

Cosmogenic helium and volatile-rich fluid in Sierra Leone alluvial diamonds

Noble gas measurements were carried out on two identical splits of a finely powdered harshly acid-washed sample derived from fragments of a single alluvial diamond from Sierra Leone, with essentially identical results obtained for both splits. Isotopic ratios for Ar, Kr, and Xe were found to be atmospheric. Their elemental abundances were high relative to published data, owing to the effect of shock implantation in the crushing step, as was verified in a supplementary experiment. No Ne was detected above the blank level. The He-3 was exceptionally abundant, while He-4 was exceptionally depleted, possibly due to the acid wash. The He-3/He-4 ratio was anomalously high at an R/Ra value of 246 + or - 16. The results support the hypothesis that the He-3 excess in diamonds is cosmogenic.

Mcconville, P.↗
NASA NTRS1991

Coproduction of volatiles and metals from extraterrestrial materials

Two main efforts in support of the general goals of SERC/culpr are presented. Investigations of processes for the coproduction of metals from extra-terrestrial materials in conjunction with plausible schemes for oxygen extraction continue. The principal emphasis was on the extraction and purification of iron from the ilmenite reduction process for oxygen, from the cathode metal deposits made in the magma electrolysis process for oxygen, and from native ferrous metal alloys on the moon and asteroids. All work on the separation and purification of ferrous metals was focussed upon the gaseous carbonyl process, a scheme that involves only temperatures attainable by passive thermal control. The exploration of a variety of schemes was initiated, involving the use of several different propulsion options and both propulsive and aerobraking capture at earth, for return of extraterrestrial resources to earth orbits. In addition, the search for new opportunities in space resource utilization continues. Examples include the continuation of work underway on: (1) the feasibility of locating solar power satellites in highly eccentric earth orbit; (2) the energetics of extracting the potential clean fusion fuel He-3 from the atmosphere for return to earth; and (3) the utility of a nuclear steam rocket (using non-terrestrial water as the working fluid) for transportation in the inner solar system.

Lewis, John S.↗
NASA NTRS1989

Extraction of volatiles and metals from extraterrestrial ores

Extraterrestrial materials, processes, and products were identified which are associated with the production of propellants in space, including the most complete possible conversion of the feedstocks for propellant production into useful products with the minimum feasible expenditure of energy. Laboratory research was identified and begun on several processes that promise very large increases in the mass of useful products at the cost of only modest increases in energy consumption. Processes for manufacturing propellants then become processes for making propellants plus metals and refractories. It is the overall yield of useful materials per unit expended energy that matters, not simply the yield of propellants. Three tasks have been undertaken to date: (1) Literature search and compilation of a dBase 3 data base on space materials processing; (2) Gaseous carbonyl extraction and purification of ferrous metals; and (3) Characterization of lunar ilmenite and its simulants.

Lewis, John S.↗
NASA NTRS1990

Extraction of volatile and metals from extraterrestrial materials

Since March 1, 1989, attention was concentrated on the extraction of ilmenite from extraterrestrial materials and on the planning and development of laboratory facilities for carbonyl extraction of ferrous metal alloys. Work under three subcontracts was administered by this project: (1) electrolytic production of oxygen from molten lunar materials; (2) microwave processing of lunar materials; and (3) production of a resource-oriented space science data base.

Lewis, John S.↗
NASA NTRS1991

Infrared remote sensing of cometary parent volatiles from the ground, air, and space

A balanced view of the present generation of infrared instruments for cometary compositional studies is presented. Ground-based instruments are compared with airborne and spaceborne capabilities. An attempt to give examples of the unique science achievable with each is made, and particular emphasis is on the unique aspects of a dedicated Cometary Composition Telescope in earth orbit for investigating the chemical and structural heterogeneity of the cometary nucleus.

Mumma, Michael J.↗
NASA NTRS1991

Water on Mars: Volatile history and resource availability

The existence of water on Mars is undisputed today. Measurements of atmospheric water vapor have shown that the abundance varies with location and season in a systematic way which depends on processes of exchange with the polar caps, regolith, and atmosphere. Channels, which give the appearance of having been carved by water or of having had water involved in their formation, appear in various locations on the surface; some were formed by catastrophic outflow of water from beneath the surface, while others form valley networks which give the appearance of having formed over long periods of time primarily early in the planet's history. The north polar residual cap consists of water ice, possibly containing an amount of water equivalent to a global layer several tens of meters thick. Finally, water is observed within the regolith, as adsorbed water or as water of hydration.

Jakosky, Bruce M.↗
NASA NTRS1990

Water on Mars - Volatile history and resource availability

An attempt is made to define the available deposits of water in the near-surface region of Mars which will be available to human exploration missions. The Martian seasonal water cycle is reviewed, and geochemical and geological constraints on the availability of water are examined. It is concluded that the only sure source of water in amounts significant as a resource are in the polar ice deposits.

Jakosky, Bruce M.↗