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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 901 records · Page 50

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NASA NTRS2018

Analysis of Cislunar Transfers from a Near Rectilinear Halo Orbit with High Power Solar Electric Propulsion

As government and commercial interest in the exploration of the Moon and cislunar space has grown, Near Rectilinear Halo Orbits (NRHOs) have shown to be of particular interest as staging orbits for human exploration of the Moon. Once in such staging orbits, low thrust solar electric propulsion (SEP) can enable efficient transfer to other orbits in cislunar space. This paper captures ongoing analysis to design efficient transfers of a massive spacecraft from a L2 Southern NRHO to a Distant Retrograde Orbit, L1 Northern NRHO, and Flat L2 Halo Orbit using low thrust SEP. For each transfer type, reference transfer is designed for an assumed 39 t spacecraft with 26.6 kW SEP system. For each reference transfer, analysis is completed to understand the sensitivity of the transfer to changes in initial mass and SEP power and identify the optimal number of thrusters to use for a given combination of mass and power.

Near Rectilinear Halo Orbits (NRHO)↗

NASA NTRS2020

Missed Thrust Analysis and Design for Low Thrust Cislunar Transfers

This paper details the analysis of the missed thrust problem for low thrust cislunar transfers. Missed thrust analysis is completed for a reference NRHO to DRO transfer that is designed to maximize the final mass without consideration of robustness to unexpected loss of thrust. A new missed thrust design method is presented to include the robustness of the transfer as part of the optimization problem by including a minimal number of branching trajectories tied to the start of thrust arcs in the reference transfer and optimizing them all simultaneously. Results from variations of this approach are presented for and compared to the reference transfer designed without consideration for missed thrust. The results show that this new method can reduce the additional propellant required for recovery from an unexpected 7-day outage by up to 90% without significant increase to the propellant required to complete the reference transfer.

Grebow, Daniel J.↗

NASA NTRS2022

Cryogenic Spray Quenching of A Simulated Propellant Storage Tank Wall With Heat Transfer Enhancement By A Thin-Film Coating and Flow Pulsing in Microgravity

Human space exploration to the Moon, Mars, and possibly asteroids is NASA’s biggest challenge for the new millennium. One of the critical elements to this mission is the effective, sufficient, and reliable supply of cryogenic propellant fluids. Future lower-earth-orbiting (LEO) propellant fuel depots and human-carrying orbital transfer spacecraft flying to the moon and Mars will have to utilize the high thrust and high efficiency of liquid cryogenic chemical propulsion or nuclear thermal propulsion. Efficient in-space tank-to-tank propellant transfer (propellant fuel depot to orbital transfer spacecraft) of cryogenic propellants is an enabling technology for the planned Crewed Mars Surface Mission. The transfer of cryogenic propellants in space, however, has yet to be accomplished, solely due to the unavailability of cryogenic quenching heat transfer data during chilldown (quenching) and filling of the propellant receiver tank in reduced gravity and microgravity as liquid propellant cannot be stored in a required liquid state until the tank is quenched down to the liquid temperature. Therefore, highly energy efficient thermal-fluid management breakthrough concepts to conserve and minimize the cryogen consumption during propellant transfer have become the focus of research and engineering development, especially for the deep-space mission to Mars. In this paper, we introduce such concepts and demonstrate their feasibility for cryogenic storage tank chilldown in parabolic flights under a simulated space microgravity condition. In order to maximize the storage tank chilldown efficiency for the least amount of cryogen consumption, the technology adopted included cryogenic spray cooling, Teflon thin-film coating of the simulated tank surface, and spray flow pulsing. The completed flight experiments successfully demonstrated that spray cooling is the most efficient cooling method for the tank chilldown in microgravity. In microgravity, Teflon coating alone can improve the efficiency up to 72% and the efficiency can be improved up to 59% by flow pulsing alone. However, Teflon coating together with flow pulsing was found to substantially enhance the chilldown efficiency in microgravity for up to 113%.

spray↗

DOE OSTI2015

Self-pacing direct memory access data transfer operations for compute nodes in a parallel computer

Methods, apparatus, and products are disclosed for self-pacing DMA data transfer operations for nodes in a parallel computer that include: transferring, by an origin DMA on an origin node, a RTS message to a target node, the RTS message specifying an message on the origin node for transfer to the target node; receiving, in an origin injection FIFO for the origin DMA from a target DMA on the target node in response to transferring the RTS message, a target RGET descriptor followed by a DMA transfer operation descriptor, the DMA descriptor for transmitting a message portion to the target node, the target RGET descriptor specifying an origin RGET descriptor on the origin node that specifies an additional DMA descriptor for transmitting an additional message portion to the target node; processing, by the origin DMA, the target RGET descriptor; and processing, by the origin DMA, the DMA transfer operation descriptor.

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2015

Changes to the Transfer Line Collimation System for the High-Luminosity LHC Beams

The current LHC transfer line collimation system will not be able to provide enough protection for the high brightness beams in the high-luminosity LHC era. The new collimation system will have to attenuate more and be more robust than its predecessor. The active jaw length of the new transfer line collimators will therefore be 2.1 m instead of currently 1.2 m. The transfer line optics will have to be adjusted for the new collimator locations and larger beta functions at the collimators for absorber robustness reasons. In this paper the new design of the transfer line collimation system will be presented with its implications on transfer line optics and powering, maintainability, protection of transfer line magnets in case of beam loss on a collimator and protection of the LHC aperture.

43 PARTICLE ACCELERATORS↗

DOE OSTI2017

Data Transfer Advisor with Transport Profiling Optimization

The network infrastructures have been rapidly upgraded in many high-performance networks (HPNs). However, such infrastructure investment has not led to corresponding performance improvement in big data transfer, especially at the application layer, largely due to the complexity of optimizing transport control on end hosts. We design and implement ProbData, a PRofiling Optimization Based DAta Transfer Advisor, to help users determine the most effective data transfer method with the most appropriate control parameter values to achieve the best data transfer performance. ProbData employs a profiling optimization based approach to exploit the optimal operational zone of various data transfer methods in support of big data transfer in extreme scale scientific applications. We present a theoretical framework of the optimized profiling approach employed in ProbData as wellas its detailed design and implementation. The advising procedure and performance benefits of ProbData are illustrated and evaluated by proof-of-concept experiments in real-life networks.

Rao, Nageswara S.↗

DOE OSTI2020

Conjugate Heat Transfer Analysis of the Supercritical CO2 Based Counter Flow Compact 3D Heat Exchangers

Compact heat exchangers using supercritical fluids such as CO2 are preferred due to their high heat transfer capacity and smaller footprint. Three-dimensional conjugate forced convection heat transfer analysis was performed on several shell-and-tube counter-flow microchannel heat exchangers. Numerical simulations were conducted to test effect of change in mass flow rate, hydraulic diameter and various cross sections on the heat transfer. Increasing mass flow rate improved heat transfer up to a maximum value and then decreased downstream with increasing turbulence. Maximum heat transfer was obtained for the micro channel with the smallest hydraulic diameter. Amongst the cross sections analyzed (circular, square, circular with radial ribs, and square with radial ribs), the most uniform distribution of temperature and maximum heat transfer were obtained for circular cross section with radial ribs. An optimally efficient operation of such a heat exchanger can be attained by considering these factors during multi-objective constrained optimization of geometric parameters and requirements for additive manufacturing of such compact heat exchangers.

Chitale, Janhavi↗

DOE OSTI2021

Ball transfer mechanism with polycrystalline diamond bearing support

A ball transfer mechanism for a harmonic drive and linear piston motor is disclosed. The ball transfer mechanism includes a spherical ball and a cylindrical seat portion. The seat portion defines a hemispherical shaped recess with a contour for receiving the ball. The ball transfer mechanism is in an exterior wall of a housing for converting rotary motion to linear motion, driving a linear piston motor. The harmonic drive drives a rotor of the linear piston motor. The harmonic drive includes a hollow cylindrical coupler portion engaging a rotor portion for transferring torque to the rotor portion. Transfer mechanisms disposed along a housing wall of the linear piston motor engage the coupler portion. The coupler portion includes harmonic cam grooves for receiving spherical balls in the ball transfer mechanism that drives rotational motion in the rotor in response to axially linear movement of the piston assembly.

Raymond, David W.↗

DOE OSTI2022

Heat transfer systems for nuclear reactor cores, and related systems

A system for transferring heat from a nuclear reactor comprises a nuclear reactor comprising a nuclear fuel and a reactor vessel surrounding the nuclear reactor and a heat transfer system surrounding the nuclear reactor. The heat transfer system comprises an inner wall surrounding the nuclear reactor vessel, first fins coupled to an outer surface of inner wall, an outer wall between the inner wall and a surrounding environment, and second fins coupled to an inner surface of the outer wall and extending in a volume between the outer surface of the inner wall and the inner surface of the outer wall, the outer surface of the inner wall and the first fins configured to transfer heat from the nuclear reactor core to the second fins and the inner surface of the outer wall by thermal radiation. The heat transfer system may be directly coupled to the nuclear reactor vessel, or may be coupled to an external reflector surrounding the nuclear reactor vessel. Related heat transfer systems and systems for selectively removing heat from a nuclear reactor are disclosed.

Ougouag, Abderrafi Mohammed El-Amine↗

DOE OSTI2023

Ball transfer mechanism with polycrystalline diamond bearing support

Raymond, David W.↗

DOE OSTI2013

Development and Qualification of Advancements in Submersible Transfer Pump Performance and Life, and Implications for Advancing and Supporting Processing Options - 13343

From the 1950's through the 1990's, relatively inexpensive, 'off-the-shelf' type, vertical turbine pumps (VTP) were used to transfer Hanford waste. The technology of those pumps was rooted primarily in the mining and agricultural (irrigation) industries. HNF-3218, Double Shell Tank (DST) Transfer Pump History and Reliability Report, 1998, provides a summary of Hanford DST pump history to that date. Such pumps operated in the Hanford radioactive waste environment for an average of only 400 hours before failure. However, at that time, operating life was not a driving criteria within the Department of Energy (DOE) complex, as the failure of transfer pumps represented a relatively low replacement and disposal cost. The Environmental Protection Agency (EPA) issuance of the 'Debris Rule' in 1992, which mandated that mixed radioactive waste contaminated equipment be decontaminated to a 'low level waste' category prior to burial, elevated the significance of transfer pump reliability and decontamination capability as life-cycle cost criteria. Minimizing the frequency of transfer pump failures and design for decontamination became significantly important and served to drive the need toward specific, designed for application pumps to meet this challenge. To this end, Washington River Protection Solutions (WRPS) and the supplier, Curtiss-Wright EMD (EMD), have recently collaborated on an intense program to further transfer pump technology and performance. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2015

System impacts of accelerated transfer of used nuclear fuel to dry storage - 15220

In the wake of the September 11, 2001 terror attacks, and again after the March 11, 2011, accident at the Fukushima Dai-Ichi station from the Great East Japan Earthquake/tsunami, concern was expressed regarding security of current spent fuel storage practices in the United States. An approach recurrently proposed to reduce the potential for fire and the release of radionuclides in an accident or sabotage scenario is to reduce the loading of the reactor fuel pools, which are frequently maintained near their full capacity at many reactor sites in the U.S. We assess the impact on the waste management system of different scenarios for accelerating the schedule of used nuclear fuel (UNF) transfer from reactor pools to dry storage casks. We consider scenarios where the spent fuel pools are drawn down to 50% or 25% of full capacity over 5- or 10-year schedules. The scenarios include status quo, where UNF continues to remain in dry storage at the reactor sites, as well as scenarios with UNF transfer to interim storage and eventually to a mined geologic repository. The primary purpose is to evaluate how the different scenarios for accelerating the transfer of UNF to at-reactor dry storage would affect the performance of the entire UNF management system. Areas that were considered include an estimate of the additional system costs that could be incurred and where the existing infrastructure at the reactor sites would come under stress from the transfer demands. This study considered only the fuel-handling logistics and rough-order-of-magnitude cost at reactor sites, interim storage facility, and operations to package UNF into disposal canisters. The effects of minimum fuel age that could be transferred and the accelerated transfer starting date are also examined, but found to have relatively little effect. Impacts on safety and worker dose are not evaluated quantitatively, although effects can be inferred from increases in handling operations, etc. from the scenarios considered. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2018

Real-time Erosion-Corrosion Detection in Waste Transfer Pipelines using Guided Wave Ultrasonic Sensors - 18368

A Fitness-for-Service (FFS) program for the Waste Transfer System has been implemented by the United States Department of Energy Hanford Site Tank Farm to examine structural parameters of the waste transfer systems in order to develop erosion/corrosion rates for relevant system components. The FFS information is acquired from opportunistic evaluations of pipelines that have been removed from service. The objective is to deliver more realistic estimates to the remaining useful life of the components and incorporate those estimates into future design/testing plans across the DOE complex. To aid to this objective, previous efforts at Hanford included the installation of sensors on some of the POR 104 components, to provide real time pipe wall thickness measurements. Due to certain limitations, alternative approaches for remote permanently mounted pipe wall ultrasonic thickness measurement systems have been investigated by FIU. Present research work is a supportive effort by FIU-ARC for DOE and WRPS, which investigates the option for remote-permanently mount guided wave ultrasonic transducer (UT) systems for HLW pipe wall thickness measurements. Specific applications include straight sections, elbows and other fittings used in jumper pits, evaporators, and valve boxes. The proposed method will provide information that will assist engineers with understanding the failure potential of HLW transfer components due to corrosion and erosion. This information can assist in determining if and when lines need to be removed, saving time and resources on the unneeded excavation of transfer lines. This information will also assist engineers with designing new transfer systems by establishing more detailed/accurate guidelines governing the life expectancy of the transfer system and its components. In the previous work, FIU has investigated the use of various ultrasonic systems that are either commercially available or used previously at Hanford and selected the most promising systems for further evaluation. The down-selected system is the guided wave UT sensor system from Permasense which is a UK based manufacturer. It is an integrated wireless sensor network system which used a patented technology for the acoustic wave propagation and has proven applications in the oil and gas industries. Scope of the present research includes the initial verification and validation of the Permasense Guided Wave sensor system as a potential erosion/corrosion detection system for carbon steel pipelines under static conditions. In future, the real-time erosion/corrosion detection will be investigated by measuring the thinning of the pipe sections by circulating simulants and continuous monitoring. This is achieved by passing abrasive and caustic solutions through an in-house designed pipe loop system. Results obtained provide realistic wear rates on 2 inch and 3 inch carbon steel pipes with straight sections and elbows using the Permasense UT sensor system. Thus, the present research delivers solutions for sensor evaluations, conducts bench scale testing followed by data acquisition and analysis for corrosion and erosion assessment. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2024

Evaluating Liquid Waste Transfers and their Impacts to the SRS Tank Farm to Support Operations and Closure

The Liquid Waste (LW) contractor at the Savannah River Site, Savannah River Mission Completion (SRMC), supports the storage, processing, and safe disposition of legacy, radioactive liquid waste. The LW Tank Farms contain approximately 127 million liters (33.5 million gallons) of liquid waste within 43 active, underground waste tanks. To meet mission critical milestones for the closure of waste tanks and processing of 34 million liters (9 million gallons) of salt waste per year by the LW Salt Waste Processing Facility (SWPF), an increase in Tank Farm operations, including waste tank transfers, is required. Waste is compiled in salt and sludge batches in the Tank Farms and transferred to SWPF and the Defense Waste Processing Facility (DWPF) for treatment. All waste tank transfers, such as waste removal and batch compilation transfers, must be pre-evaluated to ensure Documented Safety Analysis (DSA) requirements are met via Evaluated Transfer Approval Forms (ETAFs). Facility conditions and configurations may change as a result of a waste transfer. These changes must be reflected in the Tank Farms Emergency Response Datasheet (ERD), which contains data utilized for operation and emergency situations.

Peterson, Shelby R.↗

DOE OSTI2016

pH-dependent electron transfer reaction and direct bioelectrocatalysis of the quinohemoprotein pyranose dehydrogenase

A pyranose dehydrogenase from Coprinopsis cinerea (CcPDH) is an extracellular quinohemoeprotein, which consists a b-type cytochrome domain, a pyrroloquinoline-quinone (PQQ) domain, and a family 1-type carbohydrate-binding module. The electron transfer reaction of CcPDH was studied using some electron acceptors and a carbon electrode at various pH levels. Phenazine methosulfate (PMS) reacted directly at the PQQ domain, whereas cytochrome c (cyt c) reacted via the cytochrome domain of intact CcPDH. Thus, electrons are transferred from reduced PQQ in the catalytic domain of CcPDH to heme b in the N-terminal cytochrome domain, which acts as a built-in mediator and transfers electron to a heterogenous electron transfer protein. The optimal pH values of the PMS reduction (pH 6.5) and the cyt c reduction (pH 8.5) differ. The catalytic currents for the oxidation of L-fucose were observed within a range of pH 4.5 to 11. Bioelectrocatalysis of CcPDH based on direct electron transfer demonstrated that the pH profile of the biocatalytic current was similar to the reduction activity of cyt c characters. - Highlights: • pH dependencies of activity were different for the reduction of cyt c and DCPIP. • DET-based bioelectrocatalysis of CcPDH was observed. • The similar pH-dependent profile was found with cyt c and electrode. • The present results suggested that IET reaction of CcPDH shows pH dependence.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2016

Electronic Coupling Calculations for Bridge-Mediated Charge Transfer Using Constrained Density Functional Theory (CDFT) and Effective Hamiltonian Approaches at the Density Functional Theory (DFT) and Fragment-Orbital Density Functional Tight Binding (FODFTB) Level

In this paper, four methods to calculate charge transfer integrals in the context of bridge-mediated electron transfer are tested. These methods are based on density functional theory (DFT). We consider two perturbative Green's function effective Hamiltonian methods (first, at the DFT level of theory, using localized molecular orbitals; second, applying a tight-binding DFT approach, using fragment orbitals) and two constrained DFT implementations with either plane-wave or local basis sets. To assess the performance of the methods for through-bond (TB)-dominated or through-space (TS)-dominated transfer, different sets of molecules are considered. For through-bond electron transfer (ET), several molecules that were originally synthesized by Paddon-Row and co-workers for the deduction of electronic coupling values from photoemission and electron transmission spectroscopies, are analyzed. The tested methodologies prove to be successful in reproducing experimental data, the exponential distance decay constant and the superbridge effects arising from interference among ET pathways. For through-space ET, dedicated p-stacked systems with heterocyclopentadiene molecules were created and analyzed on the basis of electronic coupling dependence on donor-acceptor distance, structure of the bridge, and ET barrier height. The inexpensive fragment-orbital density functional tight binding (FODFTB) method gives similar results to constrained density functional theory (CDFT) and both reproduce the expected exponential decay of the coupling with donor-acceptor distances and the number of bridging units. Finally, these four approaches appear to give reliable results for both TB and TS ET and present a good alternative to expensive ab initio methodologies for large systems involving long-range charge transfers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2022

Charge Transfer Dynamics in MoSe 2 /hBN/WSe 2 Heterostructures

Ultrafast charge transfer processes provide a facile way to create interlayer excitons in directly contacted transition metal dichalcogenide (TMD) layers. More sophisticated heterostructures composed of TMD/hBN/TMD enable new ways to control interlayer exciton properties and achieve novel exciton phenomena, such as exciton insulators and condensates, where longer lifetimes are desired. In this work, we experimentally study the charge transfer dynamics in a heterostructure composed of a 1 nm thick hBN spacer between MoSe 2 and WSe 2 monolayers. We observe the hole transfer from MoSe 2 to WSe 2 through the hBN barrier with a time constant of 500 ps, which is over 3 orders of magnitude slower than that between TMD layers without a spacer. Furthermore, we observe strong competition between the interlayer charge transfer and intralayer exciton–exciton annihilation processes at high excitation densities. Here, our work opens possibilities to understand charge transfer pathways in TMD/hBN/TMD heterostructures for the efficient generation and control of interlayer excitons.

36 MATERIALS SCIENCE↗

DOE OSTI2024

Structural Gating Enhances Long-Distance Light-Driven Interfacial Electron Transfer

Structural gating provides a molecular means to transfer electrons preferentially in one desired vectorial direction, a behavior needed for applications in artificial photosynthesis. At the interfaces utilized herein, visible-light absorption by a transition metal complex opens a “structural gate” by planarization of otherwise rotating phenyl rings in p-phenylene ethynylene (PE) bridge units. Planarization provides a conjugated pathway for electron flow toward a conductive oxide surface. Interfacial electron transfer to the oxide restores rotation and closes the gate to the unwanted recombination reaction. This structural gating results in nearly quantitative long-distance (>20 Å) interfacial electron transfer that occurs ~1000 times faster than transfer in the opposite direction. A comparative kinetic study of these complexes with those that contain ionic bridge units, without gating function, as a function of the applied potential and hence –ΔG° provided a physical basis for the structural gating. A small distance-dependent reorganization energy with weak electronic coupling underlies the success of this gate that enables efficient long-distance electron transfer and slow recombination.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗