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Cellulosic Biomass Pretreatment and Sugar Yields as a Function of Biomass Particle Size

Three lignocellulosic pretreatment techniques (ammonia fiber expansion, dilute acid and ionic liquid) are compared with respect to saccharification efficiency, particle size and biomass composition. In particular, the effects of switchgrass particle size (32–200) on each pretreatment regime are examined. Physical properties of untreated and pretreated samples are characterized using crystallinity, surface accessibility measurements and scanning electron microscopy (SEM) imaging. At every particle size tested, ionic liquid (IL) pretreatment results in greater cell wall disruption, reduced crystallinity, increased accessible surface area, and higher saccharification efficiencies compared with dilute acid and AFEX pretreatments. The advantages of using IL pretreatment are greatest at larger particle sizes (.75 mm).

59 BASIC BIOLOGICAL SCIENCES↗

Fast Pyrolysis Behavior of Banagrass as a Function of Temperature and Volatiles Residence Time in a Fluidized Bed Reactor

A reactor was designed and commissioned to study the fast pyrolysis behavior of banagrass as a function of temperature and volatiles residence time. Four temperatures between 400 and 600°C were examined as well as four residence times between ~1.0 and 10 seconds. Pyrolysis product distributions of bio-oil, char and permanent gases were determined at each reaction condition. The elemental composition of the bio-oils and chars was also assessed. The greatest bio-oil yield was recorded when working at 450°C with a volatiles residence time of 1.4 s, ~37 wt% relative to the dry ash free feedstock (excluding pyrolysis water). The amounts of char (organic fraction) and permanent gases under these conditions are ~4 wt% and 8 wt% respectively. The bio-oil yield stated above is for 'dry' bio-oil after rotary evaporation to remove solvent, which results in volatiles and pyrolysis water being removed from the bio-oil. The material removed during drying accounts for the remainder of the pyrolysis products. The 'dry' bio-oil produced under these conditions contains ~56 wt% carbon which is ~40 wt% of the carbon present in the feedstock. The oxygen content of the 450°C, 1.4 s 'dry' bio-oil is ~38 wt%, which accounts for ~33 wt% of the oxygen in the feedstock. At higher temperature or longer residence time less bio-oil and char is recovered and more gas and light volatiles are produced. Increasing the temperature has a more significant effect on product yields and composition than increasing the volatiles residence time. At 600°C and a volatiles residence time of 1.2 seconds the bio-oil yield is ~21 wt% of the daf feedstock, with a carbon content of 64 wt% of the bio-oil. The bio-oil yield from banagrass is significantly lower than from woody biomass or grasses such as switchgrass or miscanthus, but is similar to barley straw. In conclusion, the reason for the low bio-oil yield from banagrass is thought to be related to its high ash content (8.5 wt% dry basis) and high concentration of alkali and alkali earth metals (totaling ~2.8 wt% relative to the dry feedstock) which are catalytic and increase cracking reactions during pyrolysis.

60 APPLIED LIFE SCIENCES↗

Genome assembly of the fungus Cochliobolus miyabeanus , and transcriptome analysis during early stages of infection on American wildrice ( Zizania palustris L.)

Here, the fungus Cochliobolus miyabeanus causes severe leaf spot disease on rice ( Oryza sativa ) and two North American specialty crops, American wildrice ( Zizania palustris ) and switchgrass ( Panicum virgatu ). Despite the importance of C. miyabeanus as a disease-causing agent in wildrice, little is known about either the mechanisms of pathogenicity or host defense responses. To start bridging these gaps, the genome of C. miyabeanus strain TG12bL2 was shotgun sequenced using Illumina technology. The genome assembly consists of 31.79 Mbp in 2,378 scaffolds with an N 50 = 74,921. It contains 11,000 predicted genes of which 94.5% were annotated. Approximately 10% of total gene number is expected to be secreted. The C. miyabeanus genome is rich in carbohydrate active enzymes, and harbors 187 small secreted peptides (SSPs) and some fungal effector homologs. Detoxification systems were represented by a variety of enzymes that could offer protection against plant defense compounds. The non-ribosomal peptide synthetases and polyketide synthases (PKS) present were common to other Cochliobolus species. Additionally, the fungal transcriptome was analyzed at 48 hours after inoculation in planta . A total of 10,674 genes were found to be expressed, some of which are known to be involved in pathogenicity or response to host defenses including hydrophobins, cutinase, cell wall degrading enzymes, enzymes related to reactive oxygen species scavenging, PKS, detoxification systems, SSPs, and a known fungal effector. This work will facilitate future research on C. miyabeanus pathogen-associated molecular patterns and effectors, and in the identification of their corresponding wildrice defense mechanisms.

59 BASIC BIOLOGICAL SCIENCES↗

Water impacts of U.S. biofuels: Insights from an assessment combining economic and biophysical models

Biofuels policies induce land use changes (LUC), including cropland expansion and crop switching, and this in turn alters water and soil management practices. Policies differ in the extent and type of land use changes they induce and therefore in their impact on water resources. We quantify and compare the spatially varying water impacts of biofuel crops stemming from LUC induced by two different biofuels policies by coupling a biophysical model with an economic model to simulate the economically viable mix of crops, land uses, and crop management choices under alternative policy scenarios. We assess the outputs of an economic model with a high-resolution crop-water model for major agricultural crops and potential cellulosic feedstocks in the US to analyze the impacts of three alternative policy scenarios on water balances: a counterfactual ‘no-biofuels policy’ (BAU) scenario, a volumetric mandate (Mandate) scenario, and a clean fuel-intensity standard (CFS) scenario incentivizing fuels based on their carbon intensities. While both biofuel policies incentivize more biofuels than in the counterfactual, they differ in the mix of corn ethanol and advanced biofuels from miscanthus and switchgrass (more corn ethanol in Mandate and more cellulosic biofuels in CFS). The two policies differ in their impact on irrigated acreage, irrigation demand, groundwater use and runoff. Net irrigation requirements increase 0.7% in Mandate and decrease 3.8% in CFS, but in both scenarios increases are concentrated in regions of Kansas and Nebraska that rely upon the Ogallala aquifer for irrigation water. Our study illustrates the importance of accounting for the overall LUC and shifts in agricultural production and management practices in response to policies when assessing the water impacts of biofuels.

09 BIOMASS FUELS↗

Effects of nitrogen fertilization and bioenergy crop type on topsoil organic carbon and total Nitrogen contents in middle Tennessee USA

Nitrogen (N) fertilization affects bioenergy crop growth and productivity and consequently carbon (C) and N contents in soil, it however remains unclear whether N fertilization and crop type individually or interactively influence soil organic carbon (SOC) and total N (TN). In a three-year long fertilization experiment in switchgrass (SG: Panicum virgatum L.) and gamagrass (GG: Tripsacum dactyloides L.) croplands in Middle Tennessee USA, soil samples (0–15cm) were collected in plots with no N input (NN), low N input (LN: 84 kg N ha -1 yr -1 in urea) and high N input (HN: 168 kg N ha -1 yr -1 in urea). Besides SOC and TN, the aboveground plant biomass was also quantified. In addition to a summary of published root morphology data based on a separated mesocosm experiment, the root leachable dissolved organic matter (DOM) of both crops was also measured using archived samples. Results showed no significant interaction of N fertilization and crop type on SOC, TN or plant aboveground biomass (ABG). Relative to NN, HN (not LN) significantly increased SOC and TN in both crops. Though SG showed a 15–68% significantly higher ABG than GG, GG showed a 9.3–12% significantly higher SOC and TN than SG. The positive linear relationships of SOC or TN with ABG were identified for SG. However, GG showed structurally more complex and less readily decomposed root DOM, a larger root volume, total root length and surface area than SG. Collectively, these suggested that intensive N fertilization could increase C and N stocks in bioenergy cropland soils but these effects may be more likely mediated by the aboveground biomass in SG and root chemistry and morphology in GG. Future studies are expected to examine the root characteristics in different bioenergy croplands under the field fertilization experiment.

54 ENVIRONMENTAL SCIENCES↗

Genetic Control and Comparative Genomic Analysis of Flowering Time in Setaria (Poaceae)

We report the first study on the genetic control of flowering in Setaria, a panicoid grass closely related to switchgrass, and in the same subfamily as maize and sorghum. A recombinant inbred line mapping population derived from a cross between domesticated Setaria italica (foxtail millet) and its wild relative Setaria viridis (green millet), was grown in eight trials with varying environmental conditions to identify a small number of quantitative trait loci (QTL) that control differences in flowering time. Many of the QTL across trials colocalize, suggesting that the genetic control of flowering in Setaria is robust across a range of photoperiod and other environmental factors. A detailed comparison of QTL for flowering in Setaria, sorghum, and maize indicates that several of the major QTL regions identified in maize and sorghum are syntenic orthologs with Setaria QTL, although the maize large effect QTL on chromosome 10 is not. Several Setaria QTL intervals had multiple LOD peaks and were composed of multiple syntenic blocks, suggesting that observed QTL represent multiple tightly linked loci. Candidate genes from flowering time pathways identified in rice and Arabidopsis were identified in Setaria QTL intervals, including those involved in the CONSTANS photoperiod pathway. However, only three of the approximately seven genes cloned for flowering time in maize colocalized with Setaria QTL. This suggests that variation in flowering time in separate grass lineages is controlled by a combination of conserved and lineage specific genes.

54 ENVIRONMENTAL SCIENCES↗

Does Plant Biomass Manipulation in Static Chambers Affect Nitrous Oxide Emissions from Soils?

One of the most widespread approaches for measurement of greenhouse gas emissions from soils involves the use of static chambers. This method is relatively inexpensive, is easily replicated, and is ideally suited to plot-based experimental systems. Among its limitations is the loss of detection sensitivity with increasing chamber height, which creates challenges for deployment in systems including tall vegetation. It is not always possible to avoid inclusion of plants within chambers or to extend chamber height to fully accommodate plant growth. Thus, in many systems, such as perennial forages and biomass crops, plants growing within static chambers must either be trimmed or folded during lid closure. Currently, data on how different types of biomass manipulation affect measured results is limited. For this study, we compare the effects of cutting vs. folding of biomass on nitrous oxide measurements in switchgrass (Panicum virgatum L.) and alfalfa (Medicago sativa L.) systems. We report only limited evidence of treatment effects during discrete sampling events and little basis for concern that effects may intensify over time as biomass manipulation is repeatedly imposed. However, nonsignificant treatment effects that were consistently present amounted to significant overall trends in three out of the four systems studied. Such minor disparities in flux could amount to considerable quantities over time, suggesting that caution should be exercised when comparing cumulative emission values from studies using different biomass manipulation strategies.

54 ENVIRONMENTAL SCIENCES↗

Perennialization and Cover Cropping Mitigate Soil Carbon Loss from Residue Harvesting

While the US Midwest is expected to serve as a primary feedstock source for cellulosic biofuel production, the impacts of residue harvesting on soil organic carbon (SOC) may greatly limit sustainable production capacity. However, viable feedstock production could be realized through adoption of management practices and cropping systems that offset residue‐harvest‐induced SOC losses. Sequestration of SOC can be enhanced by increasing the duration of crop soil cover through cover or double cropping or cultivation of dedicated perennials. However, assessing the efficacy of such options across sites and over long periods is experimentally challenging. Hence, we use the Environmental Productivity Integrated Climate (EPIC) model to provide such an assessment. Model‐data integration was used to calibrate and evaluate model suitability, which exhibited reasonable effectiveness through R 2 of 0.97 and 0.63 for SOC stock and yield, respectively. Long‐term simulations indicate considerable capacity for offsetting SOC loss. Incorporating rye ( Secale cereal L.) into continuous corn ( Zea mays L.) and corn–soybean [ Glycine max (L.) Merr.] systems offset the SOC losses induced by harvesting 21.2 and 38.3% of available stover, respectively. Similarly, converting 20.4% of corn–soybean land to miscanthus ( Miscanthus × giganteus J.M. Greef & Deuter ex Hodkinson & Renvoize) or 27.5% of land to switchgrass ( Panicum virgatum L.) offset the SOC impacts of harvesting 60% of stover from the remaining corn–soybean lands. These responses indicate that adoption of such measures would sizably affect the life cycle consequences of residue‐derived biofuels and expand estimates of sustainable cellulosic feedstock production capacity from the US Midwest. Core Ideas EPIC suitably assessed SOC under annual, cover, double, and perennial crops. Perennial cultivation offset the SOC losses of considerable residue harvesting. Rye double crops offset sizable residue‐induced SOC losses. Adoption could greatly expand Midwestern sustainable biofuel production capacity.

Jones, Curtis D.↗

Nitrate Leaching from Continuous Corn, Perennial Grasses, and Poplar in the US Midwest

Leaching from annual corn ( Zea mays L.) crops is a primary source of nitrate (NO 3 - ) pollution of ground and surface waters. Here, we compare NO 3 - losses from no-till corn with losses from various alternative perennial cropping systems (switchgrass [ Panicum virgatum L.], miscanthus [ Miscanthus ×giganteus J.M. Greef & Deuter ex Hodkinson & Renvoiz], a native grass mixture, and restored prairie), as well as hybrid poplar ( Populus nigra L. × P. maximowiczii A. Henry ‘NM6’), all grown on a well-drained soil in Michigan. Soil water was sampled from below the root zone using suction cup samplers during nonfrozen periods (March–November) between 2009 and 2016. Leaching was estimated from NO 3 - concentrations in soil water and modeled drainage (percolation) rates. Drainage rates were not significantly different among crops, constituting ~30% of total annual precipitation. Aboveground net primary production (Mg ha -1 yr -1 ) averaged across the 7 yr was highest in poplar (30.8 ± 1.9 [SE]) followed by miscanthus (23.9 ± 2.4) and corn (20.4 ± 0.9). Volume-weighted mean NO 3 - concentrations (mg N L -1 ) and NO 3 - leaching (kg ha -1 yr -1 ) averaged across the 7 yr were 9.2 and 34.1, 2.3 and 5.9, and 3.0 and 7.2, respectively, for corn, perennial grasses and poplar. Approximately 10 to 32% of applied N was lost as NO 3 - from these crops, with the highest percent losses from poplar (32%) followed by corn (20%). Perennial cropping systems leached considerably more NO 3 - in first few years after planting, but over 7 yr they lost much less NO 3 - than corn. Perennial crops may therefore help ameliorate NO 3 - pollution in agricultural landscapes even if they receive modest N fertilization.

54 ENVIRONMENTAL SCIENCES↗

Legume Addition to Perennial Warm‐Season Grass Swards Increases Harvested Biomass

The adoption of perennial warm‐season grass crops for bioenergy production faces significant social, economic, and agronomic challenges. The inclusion of legumes in warm‐season grass swards may increase productivity, reduce weed pressure and the need for fertilizer inputs, and allow farmers greater management flexibility. The objectives of this study were (i) to evaluate whether the overseeding of red clover ( Trifolium pratense L.) in warm‐season grass swards can improve biomass yields and reduce weed cover, (ii) to determine if biomass yield gains arise from increased N availability or the biomass production of the legume crop, and (iii) to determine whether switchgrass ( Panicum virgatum L.) or big bluestem ( Andropogon gerardii Vitman.) accessions respond differently to red clover overseeding. Once established, red clover addition increased biomass yields in unfertilized swards to levels equivalent to fertilization with 112 kg N ha −1 and reduced weed cover by 7%. The yield gains with clover addition were consistent irrespective of the warm‐season grass accession tested and were attributable to the production of biomass by the clover. The incorporation of legumes in mixtures with perennial warm‐season grasses can and should play a part in improving the viability of these cropping systems. Future studies should consider alternative planting, harvesting, and weed control in a long‐term experimental framework to refine management of legume and warm‐season grass mixtures.

Jakubowski, Andrew R.↗

Computational Resources for Biofuel Feedstock Species

While current production of ethanol as a biofuel relies on starch and sugar inputs, it is anticipated that sustainable production of ethanol for biofuel use will utilize lignocellulosic feedstocks. Candidate plant species to be used for lignocellulosic ethanol production include a large number of species within the Grass, Pine and Birch plant families. For these biofuel feedstock species, there are variable amounts of genome sequence resources available, ranging from complete genome sequences (e.g. sorghum, poplar) to transcriptome data sets (e.g. switchgrass, pine). These data sets are not only dispersed in location but also disparate in content. It will be essential to leverage and improve these genomic data sets for the improvement of biofuel feedstock production. The objectives of this project were to provide computational tools and resources for data-mining genome sequence/annotation and large-scale functional genomic datasets available for biofuel feedstock species. We have created a Bioenergy Feedstock Genomics Resource that provides a web-based portal or clearing house for genomic data for plant species relevant to biofuel feedstock production. Sequence data from a total of 54 plant species are included in the Bioenergy Feedstock Genomics Resource including model plant species that permit leveraging of knowledge across taxa to biofuel feedstock species. We have generated additional computational analyses of these data, including uniform annotation, to facilitate genomic approaches to improved biofuel feedstock production. These data have been centralized in the publicly available Bioenergy Feedstock Genomics Resource (http://bfgr.plantbiology.msu.edu/).

09 BIOMASS FUELS↗

Engineering phenolics metabolism in the grasses using transcription factors

The economical competitiveness of agriculture-derived biofuels can be significantly enhanced by increasing biomass/acre yields and by furnishing the desired carbon balance for facilitating liquid fuel production (e.g., ethanol) or for high-energy solid waste availability to be used as biopower (e.g., for electricity production). Biomass production and carbon balance are tightly linked to the biosynthesis of phenolic compounds, which are found in crops and in agricultural residues either as lignins, as part of the cell wall, or as soluble phenolics which play a variety of functions in the biology of plants. The grasses, in particular maize, provide the single major source of agricultural biomass, offering significant opportunities for increasing renewable fuel production. Our laboratory has pioneered the use of transcription factors for manipulating plant metabolic pathways, an approach that will be applied here towards altering the composition of phenolic compounds in maize. Previously, we identified a small group of ten maize R2R3-MYB transcription factors with all the characteristics of regulators of different aspects of phenolic biosynthesis. Here, we propose to investigate the participation of these R2R3-MYB factors in the regulation of soluble and insoluble maize phenolics, using a combination of over-expression and down-regulation of these transcription factors in transgenic maize cultured cells and in maize plants. Maize cells and plants altered in the activity of these regulatory proteins will be analyzed for phenolic composition by targeted metabolic profiling. Specifically, we will I) Investigate the effect of gain- and loss-of-function of a select group of R2R3-MYB transcription factors on the phenolic composition of maize plants and II) Identify the biosynthetic genes regulated by each of the selected R2R3-MYB factors. While a likely outcome of these studies are transgenic maize plants with altered phenolic composition, this research will significantly contribute to understanding how different branches of the phenolic biosynthetic grid are regulated. Given the conservation of the selected regulators in other grasses, results derived from this project are likely to provide important tools for the manipulation of phenolic compounds in other emerging biomass producers (e.g., switchgrass or miscanthus), either through conventional breeding techniques (e.g., marker-assisted breeding) or by using transgenic approaches.

09 BIOMASS FUELS↗

Fuel Flexible Turbine System (FFTS) Program

In this fuel flexible turbine system (FFTS) program, the Parker gasification system was further optimized, fuel composition of biomass gasification process was characterized and the feasibility of running Capstone MicroTurbine(TM) systems with gasification syngas fuels was evaluated. With high hydrogen content, the gaseous fuel from a gasification process of various feed stocks such as switchgrass and corn stover has high reactivity and high flashback propensity when running in the current lean premixed injectors. The research concluded that the existing C65 microturbine combustion system, which is designed for natural gas, is not able to burn the high hydrogen content syngas due to insufficient resistance to flashback (undesired flame propagation to upstream within the fuel injector). A comprehensive literature review was conducted on high-hydrogen fuel combustion and its main issues. For Capstone's lean premixed injector, the main mechanisms of flashback were identified to be boundary layer flashback and bulk flow flashback. Since the existing microturbine combustion system is not able to operate on high-hydrogen syngas fuels, new hardware needed to be developed. The new hardware developed and tested included (1) a series of injectors with a reduced propensity for boundary layer flashback and (2) two new combustion liner designs (Combustion Liner Design A and B) that lead to desired primary zone air flow split to meet the overall bulk velocity requirement to mitigate the risk of core flashback inside the injectors. The new injector designs were evaluated in both test apparatus and C65/C200 engines. While some of the new injector designs did not provide satisfactory performance in burning target syngas fuels, particularly in improving resistance to flashback. The combustion system configuration of FFTS-4 injector and Combustion Liner Design A was found promising to enable the C65 microturbine system to run on high hydrogen biomass syngas. The FFTS-4 injector was tested in a C65 engine operating on 100% hydrogen and with the redesigned combustion liner - Combustion Liner Design A - installed. The results were promising for the FFTS program as the system was able to burn 100% hydrogen fuel without flashback while maintaining good combustion performance. While initial results have been demonstrated the feasibility of this program, further research is needed to determine whether these results will be repeated with FFTS-4 injectors installed in all injector ports and over a wide range of operating conditions and fuel variations.

42 ENGINEERING↗

Logistics, Costs, and GHG Impacts of Utility Scale Cofiring with 20% Biomass

This report presents the results of an evaluation of utility-scale biomass cofiring in large pulverized coal power plants. The purpose of this evaluation is to assess the cost and greenhouse gas reduction benefits of substituting relatively high volumes of biomass in coal. Two scenarios for cofiring up to 20% biomass with coal (on a lower heating value basis) are presented; (1) woody biomass in central Alabama where Southern Pine is currently produced for the wood products and paper industries, and (2) purpose-grown switchgrass in the Ohio River Valley. These examples are representative of regions where renewable biomass growth rates are high in correspondence with major U.S. heartland power production. While these scenarios may provide a realistic reference for comparing the relative benefits of using a high volume of biomass for power production, this evaluation is not intended to be an analysis of policies concerning renewable portfolio standards or the optimal use of biomass for energy production in the U.S.

biomass↗

GREET Pretreatment Module

A wide range of biofuels and biochemicals can be produced from cellulosic biomass via different pretreatment technologies that yield sugars. Process simulations of dilute acid and ammonia fiber expansion pretreatment processes and subsequent hydrolysis were developed in Aspen Plus for four lignocellulosic feedstocks (corn stover, miscanthus, switchgrass, and poplar). This processing yields sugars that can be subsequently converted to biofuels or biochemical. Material and energy consumption data from Aspen Plus were then compiled in a new Greenhouses Gases, Regulated Emissions, and Energy Use in Transportation (GREET TM ) pretreatment module. The module estimates the cradle-to-gate fossil energy consumption (FEC) and greenhouse gas (GHG) emissions associated with producing fermentable sugars. This report documents the data and methodology used to develop this module and the cradle-to-gate FEC and GHG emissions that result from producing fermentable sugars.

09 BIOMASS FUELS↗

Expected international demand for woody and herbaceous feedstock

The development of a U.S. bioenergy market and ultimately ‘bioeconomy’ has primarily been investigated with a national focus. Limited attention has been given to the potential impacts of international market developments. The goal of this project is to advance the current State of Technology of a single biorefinery to the global level providing quantitative estimates on how international markets may influence the domestic feedstock supply costs. The scope of the project is limited to feedstock that is currently available and new crops being developed to be used in a future U.S. bioeconomy including herbaceous residues (e.g., corn stover), woody biomass (e.g., pulpwood), and energy crops (e.g., switchgrass). The timeframe is set to the periods of 2022, 2030, and 2040 to align with current policy targets (e.g., the RFS2) and future updates of the Billion Ton data. This particular milestone delivers demand volumes for generic woody and herbaceous feedstocks for the main (net) importing regions along the above timeframes. The regional focus of the study is the European Union (EU), currently the largest demand region for U.S. pellets made from pulpwood and forest residues. The pellets are predominantly used in large-scale power plants (>5MWel) in the United Kingdom (UK), the Netherlands (NL), Belgium (BE), and Denmark (DK).

09 BIOMASS FUELS↗

Supply Chain Sustainability Analysis of Indirect Liquefaction of Blended Biomass to Produce High Octane Gasoline

The Department of Energy’s (DOE) Bioenergy Technologies Office (BETO) aims at developing and deploying technologies to transform renewable biomass resources into commercially viable, high-performance biofuels, bioproducts and biopower through public and private partnerships (DOE, 2015). BETO also performs a supply chain sustainability analysis (SCSA). This report describes the SCSA of the production of renewable high octane gasoline (HOG) via indirect liquefaction (IDL) of lignocellulosic biomass. This SCSA was developed for the 2017 design case for feedstock logistics (INL, 2014) and for the 2022 target case for HOG production via IDL (Tan et al., 2015). The design includes advancements that are likely and targeted to be achieved by 2017 for the feedstock logistics and 2022 for the IDL conversion process. The 2017 design case for feedstock logistics demonstrated a delivered feedstock cost of $80 per dry U.S. short ton by the year 2017 (INL, 2014). The 2022 design case for the conversion process, as modeled in Tan et al. (2015), uses the feedstock 2017 design case blend of biomass feedstocks consisting of pulpwood, wood residue, switchgrass, and construction and demolition waste (C&D) with performance properties consistent with a sole woody feedstock type (e.g., pine or poplar). The HOG SCSA case considers the 2017 feedstock design case (the blend) as well as individual feedstock cases separately as alternative scenarios when the feedstock blend ratio varies as a result of a change in feedstock availability. These scenarios could be viewed as bounding SCSA results because of distinctive requirements for energy and chemical inputs for the production and logistics of different components of the blend feedstocks.

Cai, Hao↗

Supply Chain Sustainability Analysis of Indirect Liquefaction of Blended Biomass to Produce High Octane Gasoline

This report describes the SCSA of the production of renewable high octane gasoline (HOG) via indirect liquefaction (IDL) of lignocellulosic biomass. This SCSA was developed for both the 2015 SOT (Hartley et al., 2015; ANL, 2016; DOE, 2016) and the 2017 design case for feedstock logistics (INL, 2014) and for both the 2015 SOT (Tan et al., 2015a) and the 2022 target case for HOG production via IDL (Tan et al., 2015b). The design includes advancements that are likely and targeted to be achieved by 2017 for the feedstock logistics and 2022 for the IDL conversion process. In the SCSA, the 2015 SOT case for the conversion process, as modeled in Tan et al. (2015b), uses the 2015 SOT feedstock blend of pulpwood, wood residue, and construction and demolition waste (C&D). Moreover, the 2022 design case for the conversion process, as described in Tan et al. (2015a), uses the 2017 design case blend of pulpwood, wood residue, switchgrass, and C&D. The performance characteristics of this blend are consistent with those of a single woody feedstock (e.g., pine or poplar). We also examined the influence of using a single feedstock type on SCSA results for the design case. These single feedstock scenarios could be viewed as bounding SCSA results given that the different components of the feedstock blend have varying energy and material demands for production and logistics.

09 BIOMASS FUELS↗