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Probing large-scale UV background inhomogeneity associated with quasars using metal absorption

ABSTRACT We study large-scale UV background inhomogeneity in three-dimensions associated with the observed quasar populations at high redshift. We do this by measuring metal absorption through quasar absorption spectrum stacking as a function distance to closest quasar in SDSS-IV/eBOSS on 10 s of comoving megaparsec scales. We study both intergalactic medium absorbers and mixed circumgalactic medium absorbers and probe absorption in O vi, C iv, and Si iv, and Si iii. Overall, stronger high ionization species absorption is seen closer to quasars at 2.4 < z < 3.1. O vi absorption shows a particularly strong change, with effects in C iv evident in some cases, and more marginal effects in Si iii and Si iv. We further study 2.05 < z < 2.4 (with weak signs of increasing homogeneity with time) and explore the study of metal absorption as a function of integrated SDSS-r band flux quasar flux (yielding consistent but less significant results). While the metal absorption does show sensitivity to large-scale 3D quasar proximity, the current incomplete quasar samples limit detailed interpretation. This work does, however, demonstrate that UV background inhomogeneities exist on scales of several 10 s of comoving megaparsecs associated with quasars and that they can be measured with precision by examining metal absorption in the intergalactic medium.

79 ASTRONOMY AND ASTROPHYSICS↗

AMiBA: cluster Sunyaev-Zel'dovich effect observations with the expanded 13-element array

The Yuan-Tseh Lee Array for Microwave Background Anisotropy (AMiBA) is a co-planar interferometer array operating at a wavelength of 3 mm to measure the Sunyaev–Zel’dovich effect (SZE) of galaxy clusters at arcminute scales. The first phase of operation—with a compact 7-element array with 0.6 m antennas (AMiBA-7)—observed six clusters at angular scales from 5{sup ′} to 23{sup ′}. Here, we describe the expansion of AMiBA to a 13-element array with 1.2 m antennas (AMiBA-13), its subsequent commissioning, and cluster SZE observing program. The most noticeable changes compared to AMiBA-7 are (1) array re-configuration with baselines ranging from 1.4 m to 4.8 m, allowing us to sample structures between 2{sup ′} and 10{sup ′}, (2) 13 new lightweight carbon-fiber-reinforced plastic (CFRP) 1.2 m reflectors, and (3) additional correlators and six new receivers. Since the reflectors are co-mounted on and distributed over the entire six-meter CFRP platform, a refined hexapod pointing error model and phase error correction scheme have been developed for AMiBA-13. These effects—entirely negligible for the earlier central close-packed AMiBA-7 configuration—can lead to additional geometrical delays during observations. Our correction scheme recovers at least 80 ± 5% of the point-source fluxes. We, therefore, apply an upward correcting factor of 1.25 to our visibilities to correct for phase decoherence, and a ±5% systematic uncertainty is added in quadrature with our statistical errors. We demonstrate the absence of further systematics with a noise level consistent with zero in stacked uv-visibilities. From the AMiBA-13 SZE observing program, we present here maps of a subset of 12 clusters with signal-to-noise ratios above five. We demonstrate combining AMiBA-7 with AMiBA-13 observations on Abell 1689, by jointly fitting their data to a generalized Navarro–Frenk–White model. Our cylindrically integrated Compton-y values for five radii are consistent with results from the Berkeley-Illinois-Maryland Array, the Owens Valley Radio Observatory, the Sunyaev–Zel’dovich Array, and the Planck Observatory. We also report the first targeted SZE detection toward the optically selected cluster RCS J1447+0828, and we demonstrate the ability of AMiBA SZE data to serve as a proxy for the total cluster mass. Finally, we show that our AMiBA-SZE derived cluster masses are consistent with recent lensing mass measurements in the literature.

79 ASTRONOMY AND ASTROPHYSICS↗

THE SUB-mJy RADIO POPULATION OF THE E-CDFS: OPTICAL AND INFRARED COUNTERPART IDENTIFICATION

We study a sample of 883 sources detected in a deep Very Large Array survey at 1.4 GHz in the Extended Chandra Deep Field South. This paper focuses on the identification of their optical and infrared (IR) counterparts. We use a likelihood-ratio technique that is particularly useful when dealing with deep optical images to minimize the number of spurious associations. We find a reliable counterpart for 95% of our radio sources. Most of the counterparts (74%) are detected at optical wavelengths, but there is a significant fraction (21%) that are only detectable in the IR. Combining newly acquired optical spectra with data from the literature, we are able to assign a redshift to 81% of the identified radio sources (37% spectroscopic). We also investigate the X-ray properties of the radio sources using the Chandra 4 Ms and 250 ks observations. In particular, we use a stacking technique to derive the average properties of radio objects undetected in the Chandra images. The results of our analysis are collected in a new catalog containing the position of the optical/IR counterpart, the redshift information, and the X-ray fluxes. It is the deepest multi-wavelength catalog of radio sources, which will be used for future study of this galaxy population.

79 ASTRONOMY AND ASTROPHYSICS↗

Structural and magnetic properties of hard magnetic system Ce(Co 1 -Fe ) 4.4 Cu 0.6 (0 ≤ x ≤ 0.19)

The Ce(Co 1 -Fe ) 4.4 Cu 0.6 (0 ≤ x ≤ 0.19) is a composite, hard magnetic system that is based on the CaCu 5 -type structure (1:5). It shows both, unique magnetic and microstructural features that are essential for permanent magnets, e.g., exceptional squareness of the 2nd. quadrant of the magnetization loops and microstructural features typically needed for pinning. Samples solidified in alumina crucibles are coarse-grained and often clearly faceted and readily align in a magnetic field. X-ray, SEM, and TEM analyses show a 1:5-type single-phase material when quenched from high temperature, which, after heat treatment, transforms into a laminar coherent nanostructure through the formation of a dense array of extended intercalated regions. Furthermore, these extended intercalated regions are comprised of segments of the Ce 2 Ni 7 –type structure (2:7) which segregate into various closely related precipitates forming a nanostructure similar to the SmCo 5 - Sm 2 Co 17 composites seen in Sm-Co permanent magnets. Based on TEM and Lorentz microscopy of well-aligned single grain particles, the magnetic domains’ reversal mechanism is regulated by anisotropy fluctuations occurring along the easy direction of magnetization and strong exchange interactions between the matrix and defects (e.g.: stacking faults). Lorentz microscopy suggests the domain wall is not physically pinned by the defect, but rather is offset/deflected when it interacts with the defect. The Lorentz and magnetization data suggest that defects cause a bending of the moment away from the c axis inside the grains.

36 MATERIALS SCIENCE↗

The star formation, dust, and abundance of galaxies with unWISE -CIB cross-correlations

Here, the cosmic infrared background (CIB) is the accumulated infrared (IR) radiation mainly from interstellar dust heated up by early stars. In this work, we measure the cross-correlation between galaxies from the unWISE catalog and the CIB maps from the Planck satellite to simultaneously constrain the cosmic star formation rate (SFR), dust spectral energy distribution (SED), and the halo occupation distribution (HOD). The unWISE galaxy catalog is divided into three tomographic bins centered at z ~ 0.6, 1.1, 1.5, and the CIB maps are at 353, 545, and 857 GHz. We measure the cross-correlations between these galaxy samples and CIB maps and get a 194σ signal within an angular scale 100 < ℓ < 2000, from which we constrain two CIB halo models from previous literature and one new model. The SFR, SED, and HOD model parameters are constrained consistently among the three models. Specifically, the dust temperature at z = 0 is constrained T 0 = $21.14^{+1.02}_{-1.34}$ K, which is slightly lower than T 0 = 24.4±1.9 K measured by the Planck collaboration. The halo mass that gives the most efficient star formation is around 10 11.79 $^{+0.73}_{-0.86}$ M ⊙ . From the model parameters, combined with the SFR density at z = 0 synthesized from multi-wavelength observations, we break the degeneracy between SED and SFR and recover the cosmic star formation history that is consistent with multi-wavelength surveys. We also constrain the graybody SED model in agreement with previous measurements from infrared flux stacking. From the HOD constraints, we derive an increasing trend of galaxy linear bias along redshifts that agrees with the results from cross- and auto-correlation with unWISE galaxies. This study indicates the power of using CIB-galaxy cross-correlation to study star formation, dust, and abundance of galaxies across cosmic time.

79 ASTRONOMY AND ASTROPHYSICS↗

PROPERTIES OF THE INTERSTELLAR MEDIUM IN STAR-FORMING GALAXIES AT z ∼ 1.4 REVEALED WITH ALMA

We conducted observations of {sup 12}CO(J = 5–4) and dust thermal continuum emission toward 20 star-forming galaxies on the main sequence at z ∼ 1.4 using ALMA to investigate the properties of the interstellar medium. The sample galaxies are chosen to trace the distributions of star-forming galaxies in diagrams of stellar mass versus star formation rate and stellar mass versus metallicity. We detected CO emission lines from 11 galaxies. The molecular gas mass is derived by adopting a metallicity-dependent CO-to-H{sub 2} conversion factor and assuming a CO(5–4)/CO(1–0) luminosity ratio of 0.23. Masses of molecular gas and its fractions (molecular gas mass/(molecular gas mass + stellar mass)) for the detected galaxies are in the ranges of (3.9–12) × 10{sup 10} M{sub ⊙} and 0.25–0.94, respectively; these values are significantly larger than those in local spiral galaxies. The molecular gas mass fraction decreases with increasing stellar mass; the relation holds for four times lower stellar mass than that covered in previous studies, and the molecular gas mass fraction decreases with increasing metallicity. Stacking analyses also show the same trends. Dust thermal emissions were clearly detected from two galaxies and marginally detected from five galaxies. Dust masses of the detected galaxies are (3.9–38) × 10{sup 7} M{sub ⊙}. We derived gas-to-dust ratios and found they are 3–4 times larger than those in local galaxies. The depletion times of molecular gas for the detected galaxies are (1.4–36) × 10{sup 8} yr while the results of the stacking analysis show ∼3 × 10{sup 8} yr. The depletion time tends to decrease with increasing stellar mass and metallicity though the trend is not so significant, which contrasts with the trends in local galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗

High Quantum Efficiency Uni-Traveling-Carrier Photodiode for Optical to Microwave Transduction

Modern Quantum Information Systems (QIS) employ optical photons for long distance communication, operating at ambient temperature, between microwave cavities, which house microwave photons used in quantum computing and microwave detection. These optical photons, carried by fiber-optic or free-space links, offer a low-cost, uncooled alternative to bulky, expensive microwave coaxial cables, which are lossy, susceptible to EMI, and a significant thermal conductor to the outside ambient environment. To convert between these two types of photons and implement these optical interconnects, it is necessary to develop a high-performance photodetector for optical to microwave transduction. Freedom Photonics and the University of Virginia have a well-established partnership in developing high-performance photodiodes. In this Phase I effort, we collaborated in designing, fabricating, and testing an advanced, high-speed, high quantum efficiency prototype photodiode for transduction from optical to microwave frequencies. These devices have applications not only in quantum computing and axion detection, but also in other optical-cryogenic interconnect applications, in fields such as radio astronomy and quantum cryptography, as well as in quantum metrology and plasmonics. During this Phase I DOE program, we designed, fabricated, and tested prototype PIN GaAs photodiodes which targeted the performance parameters defined by the program. This process involved identifying a new target wavelength, different from that proposed initially, based on conversations with the Oak Ridge National Lab customer. We designed an epitaxial stack, optimized in theory for ≥95% quantum efficiency at 795 nm, ≥5 GHz, per the target objectives of the program. Additionally, we designed a fabrication process and associated mask plates for top-illuminated, AR-coated devices with device diameters ranging from 50 µm to 800 µm. Using these, we fabricated two 3” wafer quarters of devices, and characterized the devices’ dark current, quantum efficiency, and bandwidth for various device diameters. The prototype devices achieved a quantum efficiency of 89% at the target 795 nm detection wavelength. The bandwidth of the devices proved tricky to characterize, but a 50 µm diameter device shows a 3-dB bandwidth of at least 1.6 GHz, possibly a full 5 GHz, depending on the measurement setup. In the future, we plan to characterize the bandwidth of these devices using an impulse response measurement. All tasks for the Phase I were successfully completed, and sample prototype devices were provided to Oak Ridge National Lab Quantum Information Science researchers. The work performed in Phase I has established a strong foundation for future design and fabrication cycles in Phase II, if granted. The early tests at Oak Ridge National Labs will provide guidance for the required photodiode performance in devices to be supplied in Phase II.

42 ENGINEERING↗

Sustainable Shape Memory Elastomers with Reduced Melt Viscosity and Enhanced Stiffness

Melt reactive processing of lignin with nitrile rubber is a promising approach to synthesizing shape memory materials. The strong intramolecular interactions in lignin macromolecular structures, caused by π–π stacking in aromatic rings and hydrogen bonding, often result in large phase separation or low miscibility with rubbers. In this study, we investigated the chemical and molecular characteristics, as well as the stiffness and complex viscosity, of modified kraft lignin melt-reacted with an acrylonitrile/butadiene copolymer containing 41% acrylonitrile (NBR41). To enhance the macromolecular compatibility of kraft lignin with NBR41, kraft lignin was cross-linked with poly(propylene glycol) diglycidyl ether (PPDE) and trimethylolpropane triglycidyl ether (TTE), both rich in epoxy reactive groups capable of forming chemical bonds with hydroxyl and carboxyl groups. Here, our findings demonstrate that the modification of kraft lignin with PPDE and TTE resulted in significantly increased stiffness of the composites. The elastic modulus of NBR41-Kraft lignin-PPDE and NBR41-Kraft lignin-TTE increased by 82 and 162%, respectively. Both the yield strength and Young’s modulus of these two samples showed dramatic improvements. Specifically, the yield strength and Young’s modulus of NBR41-Kraft lignin-TTE increased nearly 4 and 3-fold, respectively, compared to the control sample. Interestingly, despite significant improvements in mechanical properties, the viscosity of NBR41-Kraft lignin-PPDE was substantially lower than that of the control sample. At 210 °C and an angular frequency of 1 rad/s, the complex viscosity of NBR41-Kraft lignin was approximately 100.25 ± 4.77 kPa·s, while that of NBR41-Kraft lignin-PPDE was significantly lower at 56 ± 0.93 kPa·s. These findings were validated through Fourier transform infrared spectroscopy, scanning electron microscopy, dynamic mechanical analysis, thermal characterization, rheological tests, and quasi-elastic neutron scattering techniques.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Geochemical Reaction Mechanism Discovery from Molecular Simulation

Methods to explore reactions using computer simulation are becoming increasingly quantitative, versatile, and robust. In this review, a rationale for how molecular simulation can help build better geochemical kinetics models is first given. We summarize some common methods that geochemists use to simulate reaction mechanisms, specifically classical molecular dynamics and quantum chemical methods and discuss their strengths and weaknesses. Useful tools such as umbrella sampling and metadynamics that enable one to explore reactions are discussed. Several case studies wherein geochemists have used these tools to understand reaction mechanisms are presented, including water exchange and sorption on aqueous species and mineral surfaces, surface charging, crystal growth and dissolution, and electron transfer. The impact that molecular simulation has had on our understanding of geochemical reactivity are highlighted in each case. In the future, it is anticipated that molecular simulation of geochemical reaction mechanisms will become more commonplace as a tool to validate and interpret experimental data, and provide a check on the plausibility of geochemical kinetic models.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Effect of Aging on the Delamination Fracture Energy of Glass Solar Reflectors

Thin metal and metal oxide films deposited on glass or polymer substrates have been widely applied to manufacture front surfaced solar reflectors such as those used in the concentrated solar power (CSP) systems due to the facts that they are highly transparent, resistant to ultraviolet (UV) light and abrasion, and chemically inert. However, the reliable operation over long periods of outdoor exposure of such solar reflectors depends on the adequate adhesion between each layer to prevent delamination and subsequent failure. We report results from measurements of the delamination fracture energy (DFE) of the weakest interface in both as-deposited and aged reflectors, where the reflector construction consists of a glass/copper/silver/oxide stack. In this study, DFE was measured using a width-tapered beam method and the test results showed that the weakest interface of this solar reflector is the copper-glass interface, with a delamination fracture energy of approximately 4.4 J/m 2 . In order to verify the test results, finite element (FE) simulations were run using the commercial software package ABAQUS 6.14 based on the cohesive zone model (CZM). In the simulations, the DFE derived from the delamination measurement was treated as an input and the delamination forces from the FE simulations were compared to the experimental results. The good agreement between the tested and simulated delamination force indicated that this width-tapered beam method is accurate even for very small DFE, making it appropriate to test the DFE of front surfaced glass solar reflectors. Additionally, in order to study the aging effect on the DFE, accelerated aging tests were conducted using samples with different protective coatings, one group of samples with alumina ( Al 2 O 3 ) protective coating and the other group with titania ( TiO 2 ) protective coating. The DFE after 50 and 100 hours of accelerated aging were measured. The test results showed that the copper-glass interface would still be the weakest interface for all samples after aging, and the DFE for samples with Al 2 O 3 protective coating was unchanged whereas the copper-glass interface was found to undergo statistically significant change after both 50 and 100 hours of aging for samples with TiO 2 protective coating. We found that DFE at the copper/glass interface decreased after 50 hours of aging then increased after 100 hours of aging. The origin of this non-monotonic response of TiO 2 coated reflectors under accelerated aging conditions is unknown.

36 MATERIALS SCIENCE↗

The kinematics of C iv in star-forming galaxies at z ∼ 1.2

We present the first statistical sample of rest-frame far-UV spectra of star-forming galaxies at z ∼ 1. These spectra are unique in that they cover the high-ionization C iv λλ1548, 1550 doublet. We also detect low-ionization features such as Si ii λ1526, Fe ii λ1608, Al ii λ1670, Ni ii λλ1741, 1751, and Si ii λ1808, and intermediate-ionization features from Al iii λλ1854, 1862. Comparing the properties of absorption lines of lower- and higher-ionization states provides a window into the multiphase nature of circumgalactic gas. Our sample is drawn from the DEEP2 survey and spans the redshift range 1.01 ≤ z ≤ 1.35 (〈z〉=1.25). By isolating the interstellar C iv absorption from the stellar P Cygni wind profile, we find that 69% of the C iv profiles are blueshifted with respect to the systemic velocity. Furthermore, C iv shows a small but significant blueshift relative to Fe ii (offset of the best-fit linear regression −76 ± 26 km s{sup −1}). At the same time, the C iv blueshift is on average comparable to that of Mg ii λλ2796, 2803. At this point, in explaining the larger blueshift of C iv absorption at the ∼3σ level, we cannot distinguish between the faster motion of highly ionized gas relative to gas traced by Fe ii and filling in on the red side from resonant C iv emission. We investigate how far-UV interstellar absorption kinematics correlate with other galaxy properties using stacked spectra. These stacking results show a direct link between C iv absorption and the current star formation rate, though we only observe small velocity differences among different ionization states tracing the outflowing interstellar medium.

79 ASTRONOMY AND ASTROPHYSICS↗

STAR FORMATION IN THE EARLY UNIVERSE: BEYOND THE TIP OF THE ICEBERG

We present late-time Hubble Space Telescope (HST) imaging of the fields of six Swift gamma-ray bursts (GRBs) lying at 5.0 {approx}< z {approx}< 9.5. Our data include very deep observations of the field of the most distant spectroscopically confirmed burst, GRB 090423, at z = 8.2. Using the precise positions afforded by their afterglows, we can place stringent limits on the luminosities of their host galaxies. In one case, that of GRB 060522 at z 5.11, there is a marginal excess of flux close to the GRB position which may be a detection of a host at a magnitude J{sub AB} Almost-Equal-To 28.5. None of the others are significantly detected, meaning that all the hosts lie below L* at their respective redshifts, with star formation rates (SFRs) {approx}< 4 M{sub Sun} yr{sup -1} in all cases. Indeed, stacking the five fields with WFC3-IR data, we conclude a mean SFR <0.17 M{sub Sun} yr{sup -1} per galaxy. These results support the proposition that the bulk of star formation, and hence integrated UV luminosity, at high redshifts arises in galaxies below the detection limits of deep-field observations. Making the reasonable assumption that GRB rate is proportional to UV luminosity at early times allows us to compare our limits with expectations based on galaxy luminosity functions (LFs) derived from the Hubble Ultra-Deep Field and other deep fields. We infer that an LF, which is evolving rapidly toward steeper faint-end slope ({alpha}) and decreasing characteristic luminosity (L*), as suggested by some other studies, is consistent with our observations, whereas a non-evolving LF shape is ruled out at {approx}> 90% confidence. Although it is not yet possible to make stronger statements, in the future, with larger samples and a fuller understanding of the conditions required for GRB production, studies like this hold great potential for probing the nature of star formation, the shape of the galaxy LF, and the supply of ionizing photons in the early universe.

79 ASTRONOMY AND ASTROPHYSICS↗

Geometric magnetic frustration in RE{sub 2}O{sub 2}S oxysulfides (RE = Sm, Eu and Gd)

Graphical abstract: Stacked planes in the <001> direction of an oxysulfide structure, showing the triangular nets formed by rare earth cations, which moments present geometric magnetic frustration. - Highlights: • We prepared monophasic RE{sub 2}O{sub 2}S Oxysulfides (RE = Sm, Eu and Gd). • RE{sub 2}O{sub 2}S compounds were characterized regarding structural and magnetic properties. • Mössbauer spectra were obtained for Eu{sub 2}O{sub 2}S and Gd{sub 2}O{sub 2}S at different temperatures. • Oxysulfides present geometric magnetic frustration of the rare-earth sublattice. - Abstract: RE{sub 2}O{sub 2}S oxysulfides (with RE = Sm, Eu and Gd) were prepared and characterized regarding their structural and magnetic properties. The compounds crystallized in the trigonal symmetry (space group P-3m/D{sub 3}{sup 3}d), with the lattice parameter varying linearly with the ionic radius of the RE cation. All these oxysulfides are magnetically frustrated and only the gadolinium sample showed magnetic order down to 3 K. The magnetic frustration is attributed to the spatial distribution of cations over the lattice, where the RE’s magnetic moments occupy the sites forming a triangular plane lattice, perpendicular to the direction. This geometric magnetic frustration was firstly recognized for these oxysulfides.

36 MATERIALS SCIENCE↗

Lyman Alpha Emitting Galaxies at 2 < z < 3: Towards a Calibrated Probe of Dark Energy

The goal of this project was to establish the physical properties of Ly{alpha} emitting galaxies from redshifts of 2 to 3 in order to better calibrate the use of LAEs as probes of the large scale structure of the universe for upcoming dark energy experiments, such as the Hobby Eberly Telescope Dark Energy Experiment (HETDEX). We have obtained narrow-band imaging of the Extended Chandra Deep Field South (ECDF-S) in two different narrow-band filters centered at Lyα at z=2.1 and 3.1. The resulting of samples of LAEs were used to determine the LAE luminosity function, equivalent width distribution and clustering properties (bias) of LAEs at these redshifts. While the results from the ECDF-S appear robust, they are based on a single field. To explore the effects of cosmic variance and galaxy environment on the physical properties of LAEs, we have also obtained narrow-band data at both redshifts (z = 2:1 and 3:1) in three additional fields (SDSS 1030+-05, the Extended Hubble Deep Field South, and CW 1255+01). The narrow-band imaging data has been reduced and LAE catalogs are being generated. We have calculated preliminary luminosity functions, equivalent width distributions, and clustering properties. We have also obtained follow-up spectroscopy in the optical (using VLT/FORS) and in the near-infrared (using Magellan/MMIRS). Since individual LAEs have too little S/N to enable meaningful fits for stellar population parameters, our previous work has analyzed stacked Spectral Energy Distributions (SEDs). SED fitting was performed on several subsets of LAEs selected by their rest-UV luminosity, UV spectral slope, Ly alpha luminosity, Equivalent Width, or rest-optical (IRAC) luminosity.

79 ASTRONOMY AND ASTROPHYSICS↗

Star Formation Activity of Barred Spiral Galaxies

We study the star formation activity of nearby galaxies with bars using a sample of late-type galaxies at 0.02⩽z⩽0.05489 and M{sub r}<−19.5 from the Sloan Digital Sky Survey. We compare the physical properties of strongly and weakly barred galaxies with those of non-barred galaxies that have stellar mass and redshift distributions similar to barred galaxies. We find that the star formation activity of strongly barred galaxies probed by starburstiness, g−r, NUV−r, and mid-infrared [3.4]–[12] colors is, on average, lower than that of non-barred galaxies. However, weakly barred galaxies do not show such a difference between barred and non-barred galaxies. The amounts of atomic and molecular gas in strongly barred galaxies are smaller than those in non-barred galaxies, and the gas metallicity is higher in strongly barred galaxies than in non-barred galaxies. The gas properties of weakly barred galaxies again show no difference from those of non-barred galaxies. We stack the optical spectra of barred and non-barred galaxies in several mass bins and fit to the stacked spectra with a spectral fitting code, STARLIGHT. We find no significant difference in stellar populations between barred and non-barred galaxies for both strongly and weakly barred galaxies. Our results are consistent with the idea that the star formation activity of barred galaxies was enhanced in the past along with significant gas consumption, and is currently lower than or similar to that of non-barred galaxies. The past star formation enhancement depends on the strength of bars.

79 ASTRONOMY AND ASTROPHYSICS↗

Mechanistic insights into rubidium ion adsorption at the quartz (101) surface from quantum chemical metadynamics

Ion sorption extent and mechanism depend in part on the mineral surface termination, which can be highly complex. Variations in surface functional groups, particularly with defect density and surface roughness, influence mineral reactivity towards solutes. In this work, we investigate the adsorption of a rubidium cation (Rb + ) at pristine and defect quartz (101) surface sites using well-tempered metadynamics, based on simulations with the quantum chemical density-functional tight-binding (DFTB) method. We compare the relative energetics of Rb + adsorption across selected sites for each surface, with nanosecond-level sampling, highlighting similarities between vicinal and geminal silanol sites. We find that the positive Rb + partial atomic charge can increase by as much as 0.5e as it approaches the surface, with implications for modulation of ion adsorption strength and extent at the quartz (101) surface with surface vacancies, silanol coverage, and charge.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Outside the Lyman-break box: detecting Lyman continuum emitters at 3.5 < z < 5.1 with CLAUDS

ABSTRACT Identifying non-contaminated sample of high-redshift galaxies with escaping Lyman continuum (LyC) flux is important for understanding the sources and evolution of cosmic reionization. We present CLAUDS (CFHT Large Area u-band deep survey) u-band photometry of the COSMOS field to probe LyC radiation from spectroscopically confirmed galaxies at $z$ ≥ 3.5 and outside the standard Lyman-break galaxy colour-selection expectations. Complementary to the CLAUDS data, we use Subaru multifilter photometry, Hubble Space Telescope (HST) multifilter imaging, and the spectroscopic surveys D10K, VUDS, and 3D-HST. We present a sample of Lyman continuum galaxy (LCG) candidates in the redshift range 3.5 ≲ $z$ ≲ 5.1. Here, we introduce 5 LCG candidates, where two are flagged quality 1 and three quality 2. The estimated $f_{\rm esc}^{\rm abs}$ for quality 1 candidates are in the range $\sim 5 - 73{{\ \rm per\ cent}}$ and $\sim 30 - 93{{\ \rm per\ cent}}$. These estimates are based on our derived parameters from individual galaxies as inputs to a range of BPASS models as well as mean intergalactic medium (IGM) and maximal intergalactic and circumgalactic media (IGM+CGM) transmission. We conclude that our search for LCGs is most likely biased to lines of sight with low H i densities or free from Lyman limit systems. Our two best LCG candidates have EW (Lyα) ≤ 50 Å and we find no correlation or anticorrelation between EW (Lyα), $f_{\rm esc}^{\rm abs}$, and Robs, the ratio of ionizing to non-ionizing observed flux in the measured passbands. Stacking candidates without solid LyC detections (S/N < 3) results in an estimated $f_{\rm esc}^{\rm abs}$ from galaxies not greater than $1{{\ \rm per\ cent}}$.

Meštrić, U.↗

Cosmological shocks around galaxy clusters: A coherent investigation with DES, SPT & ACT

We search for signatures of cosmological shocks in gas pressure profiles of galaxy clusters using the cluster catalogs from three surveys: the Dark Energy Survey (DES) Year 3, the South Pole Telescope (SPT) SZ survey, and the Atacama Cosmology Telescope (ACT) data releases 4, 5, and 6, and using thermal Sunyaev-Zeldovich (SZ) maps from SPT and ACT. The combined cluster sample contains around $10^5$ clusters with mass and redshift ranges $10^{13.7} < M_{\rm 200m}/M_\odot < 10^{15.5}$ and $0.1 < z < 2$, and the total sky coverage of the maps is $\approx 15,000 \,\,{\rm deg}^2$. We find a clear pressure deficit at $R/R_{\rm 200m}\approx 1.1$ in SZ profiles around both ACT and SPT clusters, estimated at $6\sigma$ significance, which is qualitatively consistent with a shock-induced thermal non-equilibrium between electrons and ions. The feature is not as clearly determined in profiles around DES clusters. We verify that measurements using SPT or ACT maps are consistent across all scales, including in the deficit feature. The SZ profiles of optically selected and SZ-selected clusters are also consistent for higher mass clusters. Those of less massive, optically selected clusters are suppressed on small scales by factors of 2-5 compared to predictions, and we discuss possible interpretations of this behavior. An oriented stacking of clusters -- where the orientation is inferred from the SZ image, the brightest cluster galaxy, or the surrounding large-scale structure measured using galaxy catalogs -- shows the normalization of the one-halo and two-halo terms vary with orientation. Finally, the location of the pressure deficit feature is statistically consistent with existing estimates of the splashback radius.

79 ASTRONOMY AND ASTROPHYSICS↗