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Sharp, high numerical aperture (NA), nanoimprinted bare pyramid probe for optical mapping

The ability to correlate optical hyperspectral mapping and high resolution topographic imaging is critically important to gain deep insight into the structure–function relationship of nanomaterial systems. Scanning near-field optical microscopy can achieve this goal, but at the cost of significant effort in probe fabrication and experimental expertise. To overcome these two limitations, we have developed a low-cost and high-throughput nanoimprinting technique to integrate a sharp pyramid structure on the end facet of a single-mode fiber that can be scanned with a simple tuning-fork technique. The nanoimprinted pyramid has two main features: (1) a large taper angle (~70°), which determines the far-field confinement at the tip, resulting in a spatial resolution of 275 nm, an effective numerical aperture of 1.06, and (2) a sharp apex with a radius of curvature of ~20 nm, which enables high resolution topographic imaging. Optical performance is demonstrated through evanescent field distribution mapping of a plasmonic nanogroove sample, followed by hyperspectral photoluminescence mapping of nanocrystals using a fiber-in-fiber-out light coupling mode. Through comparative photoluminescence mapping on 2D monolayers, we also show a threefold improvement in spatial resolution over chemically etched fibers. These results show that the bare nanoimprinted near-field probes provide simple access to spectromicroscopy correlated with high resolution topographic mapping and have the potential to advance reproducible fiber-tip-based scanning near-field microscopy.

47 OTHER INSTRUMENTATION↗

Geostationary Spectrograph (GeoSpec) for Earth and Atmospheric Science Applications

GeoSpec will support several possible future mission concepts in the Atmospheric Sciences and in Land and Ocean Sciences by measurement of both chemically linked atmospheric trace gas concentrations and profiles of important molecules such as OS, N02, CH20 and SO2 and at the same time coastal and ocean pollution events, tidal effects, and the origin and evolution of aerosol plumes. The instrument design concept we will describe is a dual spectrograph covering the WMS wavelength region of 310- 481 nm and the VIS/NIR wavelength region of 500-900 nm. A third channel in the short- wave infrared (SWIR) region between 2.2 p and 2.4 pn for total column measurements of CO, CH4, and N20 will also be described. The goal is to design a system capable of making moderate spatial resolution (750 meters at nadir) hyperspectral measurements (0.2 to 1.2 nm resolution) from a geostationary orbit. This would enable studies of time- varying pollution and coastal change processes with a temporal resolution of 5 minutes on a regional scale to 1 hour on a continental scale. Technological advances in the design and fabrication of convex holographic gratings and large format, high dynamic range PIN/CMOS detectors at the focal plane will be exploited. By simply changing the focal length of the front-end telescope GeoSpec can accommodate different orbital altitudes, including low Earth orbit, the Sun-side Lagrangian point L1, and/or different spatial resolutions.

Janz, Scott J.↗

A Cassini ISS Search for Regolith-Texture Variations on Tethys

On October 28, 2004 the Cassini spacecraft flew within 255,500km of Saturn's heavily-cratered icy moon, Tethys. The ISS Narrow Angle Camera (NAC) obtained its first closeup multi-color images of Tethys at a Voyager-comparable spatial resolution of 1.5 km/pixel. The imaging sequence provided 23 NAC images covering 10 NAC color-filter bandpasses (ranging from 338nm to 930nm wavelengths), as well as a Wide Angle Camera (WAC), 3-color (BGR) image set. The images show whole-disk views of Tethys' trailing hemisphere viewed at a phase angle of 50 degrees and with a sub-spacecraft point of (22 deg. N, 270 deg. W). At the spatial resolution of our NAC images, Tethys' 1060 km diameter presents a disk-size of about 350 pixels. Among the images returned are nine frames obtained through NAC polarization-filters at three different spectral bandpasses (UV3: 341nm, GRN: 569nm, and MT2: 727 nm, respectively). In the present study, we use these polarization images to search for possible variations in the microscopic texture of regolith on Tethys.

Helfenstein, P.↗

Analysis of CO Transport from Australia Fires and Its Impact to Ozone, Water Vapor and Clouds Using CrIS Single-Field-of-View Sounder Products and Other Remote Sensing and MERRA-2 Reanalysis Data

Australia’s unprecedented fire disasters at the end of 2019 to early 2020 emitted huge amounts of carbon monoxide (CO) and fire aerosol particles, and the long-range transport of the smoke plumes poses great impact to climate change, such as altering the Antarctic ozone (O3) hole. Spaceborne observations from satellites have been proven successful in monitoring CO from wildfires in the past decade and can be used to examine the associated CO transport. The primary remote sensing data used in this study is the Single Field of View (SFOV) Sounder Atmospheric Product (SiFSAP) derived from the Cross-track Infrared Sounder (CrIS) on SNPP, a new product that will be generated at NASA and released to the public in a few months. SiFSAP has a high spatial resolution of ~14 km and includes atmospheric profiles of temperature, water vapor, CO, O3, as well as cloud products, and as the SiFSAP algorithm performs both day- and night-time retrievals, it provides an additional observation for night-time in comparison to the day-time-only solar polar satellite instruments such as MOPPIT, OMPS, and TROPOMI. Most recent significant improvements in the quality of this product plus its good spatial resolution (better than most global weather and climate models) enable us to conduct process-oriented analysis of CO transport, and the variation of water vapor, O3 and clouds (optical depth, effective radius and cloud height) within and around the fire plumes. The wind fields from MERRA-2 reanalysis will be used to help characterize the transport. Other remote sensing data, such as CO from AIRS, MOPPIT and TROPOMI, O3 from OMPS and TROPOMI, as well as the UV aerosol index from OMI and OMPS, will be used and compared with SiFSAP sounder products. Cross-validation of CO and O3 from these different sensors with the corresponding MERRA-2 products will also be carried out. Along the plume transport path, some enhancement of O3 and correlation between fire aerosol, cloud optical depth and water vapor have been found but need further investigation. Using the transport of fire plumes over the Southern Pacific Ocean as a unique testbed, this study will demonstrate the trace species monitoring capability of current satellite observations, in particular, for CO and O3, and hopefully, it will provide some insight on the impacts on fire emissions on air quality and climate.

Xiaozhen (Shawn) Xiong↗

“Gray Zone” Simulations Using a Three-Dimensional Planetary Boundary Layer Parameterization in the Weather Research and Forecasting Model

Abstract Generating accurate weather forecasts of planetary boundary layer (PBL) properties is challenging in many geographical regions, oftentimes due to complex topography or horizontal variability in, for example, land characteristics. While recent advances in high-performance computing platforms have led to an increase in the spatial resolution of numerical weather prediction (NWP) models, the horizontal gridcell spacing (Δ x ) of many regional-scale NWP models currently fall within or are beginning to approach the gray zone (i.e., Δ x ≈ 100–1000 m). At these gridcell spacings, three-dimensional (3D) effects are important, as the most energetic turbulent eddies are neither fully parameterized (as in traditional mesoscale simulations) nor fully resolved [as in traditional large-eddy simulations (LES)]. In light of this modeling challenge, we have implemented a 3D PBL parameterization for high-resolution mesoscale simulations using the Weather Research and Forecasting Model. The PBL scheme, which is based on the algebraic model developed by Mellor and Yamada, accounts for the 3D effects of turbulence by calculating explicitly the momentum, heat, and moisture flux divergences in addition to the turbulent kinetic energy. In this study, we present results from idealized simulations in the gray zone that illustrate the benefit of using a fully consistent turbulence closure framework under convective conditions. While the 3D PBL scheme reproduces the evolution of convective features more appropriately than the traditional 1D PBL scheme, we highlight the need to improve the turbulent length scale formulation. Significance Statement The spatial resolution of weather models continues to increase at a rapid rate in accordance with the enhancement of computing power. As a result, smaller-scale atmospheric features become more explicitly resolved. However, most numerical models still ignore the impact of horizontal weather variations on boundary layer flows, which becomes more important at these smaller spatial scales. To address this issue, we have implemented a new modeling approach, using fundamental principles, which accounts for horizontal variability. Our results show that including three-dimensional effects of turbulence is necessary to achieve realistic boundary layer characteristics. This novel technique may be useful for many applications including complex terrain flows, pollutant dispersion, and surface–atmosphere interaction studies.

Juliano, Timothy W.↗

Characterizing Spatial and Temporal Variability of California’s Coastal Upwelling Using a Satellite-Derived CUTI Index

Ocean upwelling off California is a wind-driven coastal process with complex interactions between spatial wind patterns and sea surface temperatures. Large-scale spatial and temporal upwelling characterizations are traditionally based on numerical models, while quantifying upwelling with direct observations is not straightforward. To complement model-based upwelling characterizations, here we use satellite estimates of winds, sea surface temperatures, and ocean currents along the California coast to calculate the coastal upwelling transport index (CUTI), originally calculated from a numerical ocean model. The CUTI framework accounts for both Ekman and geostrophic offshore-directed ocean transport, the latter of which is often neglected in satellite-based upwelling assessments. The approach yields the CUTI over a 30-yr period at a daily temporal and 0.25° spatial resolution to analyze upwelling patterns, with focus on potential Morro Bay and Humboldt wind energy areas. Morro Bay (CUTI median of 0.63 m 2 s −1 ) exhibits stronger, more consistent upwelling throughout the year, whereas Humboldt (CUTI median of 0.45 m 2 s −1 ) exhibits a pronounced seasonal cycle with strongest upwelling in the summer and occasional downwelling in winter. The cluster analysis of 1993–2022 satellite maps of CUTI identifies four characteristic spatial upwelling patterns along the coast, corresponding to distinct spatial distributions of sea surface temperature anomalies, Ekman transport, and geostrophic ocean water transport. This dataset provides an observation-based foundation for characterizing natural coastal upwelling off the California coast, showing good agreement with the original model CUTI while being based on satellite data and offering increased spatial resolution.

16 TIDAL AND WAVE POWER↗

Remote Sensing of Atlanta's Urban Sprawl and the Distribution of Land Cover and Surface Temperatures

Between 1973 and 1992, an average of 20 ha of forest was lost each day to urban expansion of Atlanta, Georgia. Urban surfaces have very different thermal properties than natural surfaces-storing solar energy throughout the day and continuing to release it as sensible heat well after sunset. The resulting heat island effect serves as catalysts for chemical reactions from vehicular exhaust and industrialization leading to a deterioration in air quality. In this study, high spatial resolution multispectral remote sensing data has been used to characterize the type, thermal properties, and distribution of land surface materials throughout the Atlanta metropolitan area. Ten-meter data were acquired with the Advanced Thermal and Land Applications Sensor (ATLAS) on May 11 and 12, 1997. ATLAS is a 15-channel multispectral scanner that incorporates the Landsat TM bands with additional bands in the middle reflective infrared and thermal infrared range. The high spatial resolution permitted discrimination of discrete surface types (e.g., concrete, asphalt), individual structures (e.g., buildings, houses) and their associated thermal characteristics. There is a strong temperature contrast between vegetation and anthropomorphic features. Vegetation has a modal temperature at about 20 C, whereas asphalt shingles, pavement, and buildings have a modal temperature of about 39 C. Broad-leaf vegetation classes are indistinguishable on a thermal basis alone. There is slightly more variability (plus or minus 5 C) among the urban surfaces. Grasses, mixed vegetation and mixed urban surfaces are intermediate in temperature and are characterized by broader temperature distributions with modes of about 29 C. Thermal maps serve as a basis for understanding the distribution of "hotspots", i.e., how landscape features and urban fabric contribute the most heat to the lower atmosphere.

Laymon, Charles A.↗

Remote Sensing of Atlanta's Urban Sprawl and the Distribution of Land Cover and Surface Temperature

Between 1973 and 1992, an average of 20 ha of forest was lost each day to urban expansion of Atlanta, Georgia. Urban surfaces have very different thermal properties than natural surfaces-storing solar energy throughout the day and continuing to release it as sensible heat well after sunset. The resulting heat island effect serves as catalysts for chemical reactions from vehicular exhaust and industrialization leading to a deterioration in air quality. In this study, high spatial resolution multispectral remote sensing data has been used to characterize the type, thermal properties, and distribution of land surface materials throughout the Atlanta metropolitan area. Ten-meter data were acquired with the Advanced Thermal and Land Applications Sensor (ATLAS) on May 11 and 12, 1997. ATLAS is a 15-channel multispectral scanner that incorporates the Landsat TM bands with additional bands in the middle reflective infrared and thermal infrared range. The high spatial resolution permitted discrimination of discrete surface types (e.g., concrete, asphalt), individual structures (e.g., buildings, houses) and their associated thermal characteristics. There is a strong temperature contrast between vegetation and anthropomorphic features. Vegetation has a modal temperature at about 20 C, whereas asphalt shingles, pavement, and buildings have a modal temperature of about 39 C. Broad-leaf vegetation classes are indistinguishable on a thermal basis alone. There is slightly more variability (+/-5 C) among the urban surfaces. Grasses, mixed vegetation and mixed urban surfaces are intermediate in temperature and are characterized by broader temperature distributions with modes of about 29 C. Thermal maps serve as a basis for understanding the distribution of "hotspots", i.e., how landscape features and urban fabric contribute the most heat to the lower atmosphere.

Laymon, Charles A.↗

Surface albedo spatial variability in North America: Gridded data vs. local measurements

Considering the current booming interest for the large-scale deployment of bifacial photovoltaic modules, the solar industry now requires accurate estimates of broadband surface albedo at high spatial resolution. In this context, the present study evaluates the adequacy and performance over North America of two Moderate Resolution Imaging Spectroradiometer (MODIS) white-sky albedo products (at 500-m and 1-km resolution) and the National Solar Radiation Database (NSRDB) product at 4-km resolution. Two variations of the 500-m MODIS product are also considered: black-sky albedo and all-sky albedo. Albedo observations from 36 radiometric stations during 2011–2015 are analyzed while considering the apparent homogeneity of the surface characteristics over the 4x4 km NSRDB pixel in which they are located. Even at sites where the albedo around the station has been found “homogeneous” in the literature, marked differences are found between the daily observations and the gridded estimates at any spatial resolution. Furthermore, differences in seasonal behavior and between the three different albedo types also impact the accuracy of the albedo estimates, with overtones caused by local specificities and inhomogeneities. All this precludes the desirable evaluation of the local albedo at a specific site of relatively small size compared to its corresponding 4x4-km pixel if only the mean albedo over that pixel is known. Significant discrepancies are also found at snow-impacted sites, most importantly in the case of the NSRDB albedo estimates, which are typically much too high.

14 SOLAR ENERGY↗

In-Situ Spatial Mapping of Hydrogen in Yttrium Hydrides at LANSCE (FY23 Version, Rev. 1)

This report summarizes the development of neutron imaging capabilities and experimental activities performed at the Los Alamos Neutron Science Center (LANSCE) with the main goal of measuring temperature-driven hydrogen diffusion within bulk-yttrium hydride (YH x ) materials. Yttrium hydride is the leading candidate to serve as a solid neutron moderator in microreactor cores, owing to its high density of hydrogen atoms as well as its superior thermal stability compared to all other metal hydrides. The experimental results and technique developments reported herein support the U.S. Department of Energy Office of Nuclear Energy’s (DOE-NE) Microreactor Program under Technology Maturation. In particular, it addresses the critical need to experimentally validate and verify hydrogen-diffusion models of metal hydrides used in high-temperature microreactor designs by means of high-spatial-resolution neutron imaging. These capabilities were designed to apply large temperature gradients across centimeter-sized YH x pellets to simulate conditions faced in the microreactor environment. In principle, neutron imaging, combined with in-situ sample heating, enables near real-time tracking of hydrogen diffusion in YH x on the sub-millimeter scale. In this report, an overview of neutron imaging methodology and technologies are given in the context of recent spatial measures of hydrogen concentrations in similar metal hydrides. Additionally, the commissioning and operation of a custom-built compact dual-zone furnace is given along with details on three in-situ heating measurements of YH x performed over the 2020 to 2022 LANSCE operation cycles. The aims of these experiments ranged from furnace commissioning, determining sample quality, i.e., hydrogen uniformity via neutron computed tomography, and studying the effects of applied temperature-gradients on YH x pellets. Analyses and results from these neutron imaging measurements are given along with outlooks and guidelines for optimal future hydrogen diffusion measurements. Our conclusions are as follows. Image analyses indicate that centimeter-sized yttrium hydride cylindrical pellets exhibit uniform, whole-body hydrogen desorption and absorption without clear temperature dependence as reflected in the image attenuation at the opposing ends of each sample. This suggests that despite the large magnitude in temperature gradients applied by the furnace heating elements, the sample equilibrates to an unknown intermediate temperature. The origin of this result is likely the combination of short sample length (∼1cm) and use of a TZM can for containment where the latter created a thermal short across the sample. Nevertheless, the results from the most recent measurements indicate that neither significant concentration gradients of hydrogen were formed in centimeter-sized samples through the entire temperature range (25 °C to 950 °C) nor any formed due to temperature gradients on the order of 50 °C/cm up to 700 °C/cm. Furthermore, images from the FY2021 and FY2022 measurements indicate that samples of YH x , fabricated from either the direct hydride or powder metallurgy methods, are highly uniform in their hydrogen concentration to within the measurements’ spatial resolutions. The following questions arise from these latest results: 1) What is the intermediate temperature of the pellets in the TZM cans? 2) How quickly does the temperature equilibrate within the sample? and, 3) Do the observed changes in image attenuation follow known pressure-composition-temperature relations of yttrium hydride?

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Fabrication of Silicon Sensors Based on Low-Gain Avalanche Diodes

Low-Gain Avalanche Diodes are a recently-developed class of silicon sensors. Characterized by an internal moderate gain that enhances the signal amplitude and if built on thin silicon substrates of a few tens of microns, they feature fast signals and exhibit excellent timing performance. Thanks to their fast timing they are planned to be exploited in timing detectors in High-Energy Physics experiments, for example for the upgrades of the ATLAS and CMS detectors at the High Luminosity Large Hadron Collider (HL-LHC) at CERN. However, to achieve a spatially uniform multiplication a large pixel pitch is needed, preventing a fine spatial resolution. To overcome this limitation, the AC-coupled LGAD approach was introduced. In this type of device, metal electrodes are placed over an insulator at a fine pitch, and signals are capacitively induced on these electrodes. The fabrication technology is similar for the two LGAD families, although a fine tuning of a few process parameters needs to be carefully studied. Other R&D efforts towards detectors that can simultaneously provide good time and spatial resolution, based on the LGAD concept, are under way. These efforts aim also to mitigate the loss of performance at high irradiation fluences due to the acceptor removal within the gain layer. In this paper we describe the main points in the fabrication of LGADs and AC-LGADs in a clean-room. We also discuss novel efforts carried on related topics.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Assessing Hurricane Katrina Damage to the Mississippi Gulf Coast Using IKONOS Imagery

Hurricane Katrina hit southeastern Louisiana and the Mississippi Gulf Coast as a Category 3 hurricane with storm surges as high as 9 m. Katrina devastated several coastal towns by destroying or severely damaging hundreds of homes. Several Federal agencies are assessing storm impacts and assisting recovery using high-spatial-resolution remotely sensed data from satellite and airborne platforms. High-quality IKONOS satellite imagery was collected on September 2, 2005, over southwestern Mississippi. Pan-sharpened IKONOS multispectral data and ERDAS IMAGINE software were used to classify post-storm land cover for coastal Hancock and Harrison Counties. This classification included a storm debris category of interest to FEMA for disaster mitigation. The classification resulted from combining traditional unsupervised and supervised classification techniques. Higher spatial resolution aerial and handheld photography were used as reference data. Results suggest that traditional classification techniques and IKONOS data can map wood-dominated storm debris in open areas if relevant training areas are used to develop the unsupervised classification signatures. IKONOS data also enabled other hurricane damage assessment, such as flood-deposited mud on lawns and vegetation foliage loss from the storm. IKONOS data has also aided regional Katrina vegetation damage surveys from multidate Land Remote Sensing Satellite and Moderate Resolution Imaging Spectroradiometer data.

Spruce, Joseph↗

Evaluation of the soil moisture prediction accuracy of a space radar using simulation techniques

Image simulation techniques were employed to generate synthetic aperture radar images of a 17.7 km x 19.3 km test site located east of Lawrence, Kansas. The simulations were performed for a space SAR at an orbital altitude of 600 km, with the following sensor parameters: frequency = 4.75 GHz, polarization = HH, and angle of incidence range = 7 deg to 22 deg from nadir. Three sets of images were produced corresponding to three different spatial resolutions; 20 m x 20 m with 12 looks, 100 m x 100 m with 23 looks, and 1 km x 1 km with 1000 looks. Each set consisted of images for four different soil moisture distributions across the test site. Results indicate that, for the agricultural portion of the test site, the soil moisture in about 90% of the pixels can be predicted with an accuracy of = + or - 20% of field capacity. Among the three spatial resolutions, the 1 km x 1 km resolution gave the best results for most cases, however, for very dry soil conditions, the 100 m x 100 m resolution was slightly superior.

Ulaby, F. T.↗

MOS Circuitry Would Detect Low-Energy Charged Particles

Metal oxide semiconductor (MOS) circuits for measuring spatially varying intensities of beams of low-energy charged particles have been developed. These circuits are intended especially for use in measuring fluxes of ions with spatial resolution along the focal planes of mass spectrometers. Unlike prior mass spectrometer focal-plane detectors, these MOS circuits would not be based on ion-induced generation of electrons, and photons; instead, they would be based on direct detection of the electric charges of the ions. Hence, there would be no need for microchannel plates (for ion-to-electron conversion), phosphors (for electron-to-photon conversion), and photodetectors (for final detection) -- components that degrade spatial resolution and contribute to complexity and size. The developmental circuits are based on linear arrays of charge-coupled devices (CCDs) with associated readout circuitry (see figure). They resemble linear CCD photodetector arrays, except that instead of a photodetector, each pixel contains a capacitive charge sensor. The capacitor in each sensor comprises two electrodes (typically made of aluminum) separated by a layer of insulating material. The exposed electrode captures ions and accumulates their electric charges during signal-integration periods.

Sinha, Mahadeva↗

Quadrant anode image sensor

A position-sensitive event-counting electronic readout system for microchannel plates (MCPs) is described that offers the advantages of high spatial resolution and fast time resolution. The technique relies upon a four-quadrant electron-collecting anode located behind the output face of the microchannel plate, so that the electron cloud from each detected event is partly intercepted by each of the four quadrants. The relative amounts of charge collected by each quadrant depend on event position, permitting each event to be localized with two ratio circuits. A prototype quadrant anode system for ion, electron, and extreme ultraviolet imaging is described. The spatial resolution achieved, about 10 microns, allows individual MCP channels to be distinguished.

Lampton, M.↗

How can biosphere models simulate enough vegetation biomass in the mountains of the western United States? Implications of meteorological forcing

Most carbon stocks and fluxes in the western United States are found in mountainous terrain, where observations and modeling are difficult. Terrestrial biosphere models generally underestimate above-ground biomass (AGB) over this region. In this report, we identify methods to reduce this underestimation by focusing upon 1) biases in meteorological datasets, 2) model representation of water stress, and 3) spatial resolution. We adopted the widely-used Community Land Model version 4.5 (CLM 4.5) with six different meteorological datasets and found a 6-fold variation in simulated AGB across Utah/Colorado. Simulations underestimated AGB because of warm and dry biases within the meteorological datasets that reduced water availability and restricted plant growth. To eliminate the AGB underestimation we adopted a meteorological dataset designed for complex terrain (gridMET), combined with a representation of plant hydraulic stress (CLM 5.0). Conversely, changes in spatial resolution (meteorological variables and land surface description) had negligible impact on simulated AGB.

54 ENVIRONMENTAL SCIENCES↗

Tropospheric Emissions: Monitoring of Pollution (TEMPO)

TEMPO (Tropospheric Emissions: Monitoring of Pollution) was selected in 2012 by NASA as the first Earth Venture Instrument, for launch between 2018 and 2021. It will measure atmospheric pollution for greater North America from space using ultraviolet and visible spectroscopy. TEMPO observes from Mexico City, Cuba, and the Bahamas to the Canadian oil sands, and from the Atlantic to the Pacific, hourly and at high spatial resolution (approximately 2.1 kilometers N/S by 4.4 kilometers E/W at 36.5 degrees N, 100 degrees W). TEMPO provides a tropospheric measurement suite that includes the key elements of tropospheric air pollution chemistry, as well as contributing to carbon cycle knowledge. Measurements are made hourly from geostationary (GEO) orbit, to capture the high variability present in the diurnal cycle of emissions and chemistry that are unobservable from current low-Earth orbit (LEO) satellites that measure once per day. The small product spatial footprint resolves pollution sources at sub-urban scale. Together, this temporal and spatial resolution improves emission inventories, monitors population exposure, and enables effective emission-control strategies. TEMPO takes advantage of a commercial GEO host spacecraft to provide a modest cost mission that measures the spectra required to retrieve ozone (O3), nitrogen dioxide (NO2), sulfur dioxide (SO2), formaldehyde (H2CO), glyoxal (C2H2O2), bromine monoxide (BrO), IO (iodine monoxide),water vapor, aerosols, cloud parameters, ultraviolet radiation, and foliage properties. TEMPO thus measures the major elements, directly or by proxy, in the tropospheric O3 chemistry cycle. Multi-spectral observations provide sensitivity to O3 in the lowermost troposphere, substantially reducing uncertainty in air quality predictions. TEMPO quantifies and tracks the evolution of aerosol loading. It provides these near-real-time air quality products that will be made publicly available. TEMPO will launch at a prime time to be the North American component of the global geostationary constellation of pollution monitoring together with the European Sentinel-4 (S4) and Korean Geostationary Environment Monitoring Spectrometer (GEMS) instruments.

tropospheric measurement suite↗

Broadband coherent anti-Stokes Raman scattering (BCARS) microscopy for rapid, label-free biological imaging

Broadband coherent anti-Stokes Raman scattering (BCARS) microscopy is a label-free imaging approach that provides detailed chemical information at high spatial resolution in a sample through nonlinear, coherent excitation of molecular vibrations and detection of Raman spectra. While its utility for biological imaging has been demonstrated, many aspects of this technique must mature before it can be widely adopted. One of the areas of required improvement is imaging speed—most BCARS implementations involve sample rastering, which limits imaging speed. Beam scanning can provide faster BCARS imaging but presents some unique challenges. Here, we describe a beam-scanning BCARS microscopy system that improves spatial resolution twofold and imaging speed by fivefold over a previous beam-scanning implementation. These enhancements were enabled by an improvement in supercontinuum power and the use of a sCMOS camera for its high data transfer rate and low read noise. Implementation of the sCMOS camera required correction for the significant pixel-to-pixel background and photon response nonuniformity. Here, we report on the method that we implemented for calibrating and correcting the pixel-to-pixel differences in sCMOS camera noise.

Dixon, Jessica Z. [Georgia Institute of Technology↗