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DOE OSTI2020

Search for Slow Magnetic Monopoles with the NOνA Far Detector

The magnetic monopole is a hypothetical particle with a magnetic charge. It is an important field configuration in many Grand Unified Theories. Dirac in 1931 derived a charge quantization condition, which suggests that the existence of one magnetic monopole in the universe will explain electric charge quantization. Since then, a search of the elusive particle has begun, and yet all came with negative results. The NO$\nu$A Far Detector is able to probe some of the parameter space for the search for monopoles. To achieve this, two dedicated triggers, one for fast monopoles and the other for slow monopoles, have been developed to record signals. Results for the first 8 months of high-gain slow monopole data were obtained, and a 90\% CL limit was established with no monopole observed. The analysis in this thesis is focused on new data with a higher gain, and we have explored potential improvement in efficiency and improvements in the reconstruction algorithm. We have done this an alysis on Monte-Carlo generated simulated data to establish efficiencies and examined a control set of the new data to understand its differences from the old.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

NASA NTRS1992

Habituation and adaptation of the vestibuloocular reflex: a model of differential control by the vestibulocerebellum

We habituated the dominant time constant of the horizontal vestibuloocular reflex (VOR) of rhesus and cynomolgus monkeys by repeated testing with steps of velocity about a vertical axis and adapted the gain of the VOR by altering visual input with magnifying and reducing lenses. After baseline values were established, the nodulus and ventral uvula of the vestibulocerebellum were ablated in two monkeys, and the effects of nodulouvulectomy and flocculectomy on VOR gain adaptation and habituation were compared. The VOR time constant decreased with repeated testing, rapidly at first and more slowly thereafter. The gain of the VOR was unaffected. Massed trials were more effective than distributed trials in producing habituation. Regardless of the schedule of testing, the VOR time constant never fell below the time constant of the semicircular canals (approximately 5 s). This finding indicates that only the slow component of the vestibular response, the component produced by velocity storage, was habituated. In agreement with this, the time constant of optokinetic after-nystagmus (OKAN) was habituated concurrently with the VOR. Average values for VOR habituation were obtained on a per session basis for six animals. The VOR gain was adapted by natural head movements in partially habituated monkeys while they wore x 2.2 magnifying or x 0.5 reducing lenses. Adaptation occurred rapidly and reached about +/- 30%, similar to values obtained using forced rotation. VOR gain adaptation did not cause additional habituation of the time constant. When the VOR gain was reduced in animals with a long VOR time constant, there were overshoots in eye velocity that peaked at about 6-8 s after the onset or end of constant-velocity rotation. These overshoots occurred at times when the velocity storage integrator would have been maximally activated by semicircular canal input. Since the activity generated in the canals is not altered by visual adaptation, this finding indicates that the gain element that controls rapid changes in eye velocity in the VOR is separate from that which couples afferent input to velocity storage. Nodulouvulectomy caused a prompt and permanent loss of habituation, returning VOR time constants to initial values. VOR gain adaptation, which is lost after flocculectomy, was unaffected by nodulouvulectomy. Flocculectomy did not alter habituation of the VOR or of OKAN. Using a simplified model of the VOR, the decrease in the duration of vestibular nystagmus due to habituation was related to a decrement in the dominant time constant of the velocity storage integrator (1/h0).(ABSTRACT TRUNCATED AT 400 WORDS).

NASA Discipline Neuroscience↗

DOE OSTI2021

Sixty days of head-down tilt bed rest with or without artificial gravity do not affect the neuromuscular secretome

Highlights: • Long-term bed rest with/without artificial gravity does not affect the neuromuscular secretome. • Serum concentrations of markers of muscle wasting are not affected by bed rest/artificial gravity. • C-terminal Agrin Fragment serum concentrations are not affected by bed rest/artificial gravity. • Human centrifugation during bed rest does not have a negative impact on the neuromuscular secretome. Artificial gravity is a potential countermeasure to attenuate effects of weightlessness during long-term spaceflight, including losses of muscle mass and function, possibly to some extent attributable to disturbed neuromuscular interaction. The 60-day AGBRESA bed-rest study was conducted with 24 participants (16 men, 8 women; 33 ± 9 years; 175 ± 9 cm; 74 ± 10 kg; 8 control group, 8 continuous (cAG) and 8 intermittent (iAG) centrifugation) to assess the impact of bed rest with or without daily 30-min continuous/intermittent centrifugation with 1G at the centre of mass. Fasting blood samples were collected before and on day 6, 20, 40 and 57 during 6° head-down tilt bed rest. Concentrations of circulating markers of muscle wasting (GDF-8/myostatin; slow skeletal muscle troponin T; prostaglandin E2), neurotrophic factors (BDNF; GDNF) and C-terminal Agrin Fragment (CAF) were determined by ELISAs. Creatine kinase activity was assessed by colorimetric enzyme assay. Repeated-measures ANOVAs were conducted with TIME as within-subject, and INTERVENTION and SEX as between-subject factors. The analyses revealed no significant effect of bed rest or sex on any of the parameters. Continuous or intermittent artificial gravity is a safe intervention that does not have a negative impact of the neuromuscular secretome.

60 APPLIED LIFE SCIENCES↗

DOE OSTI2026

Mechanistic implications of excited high-spin states, spin–spin coupling, and differential [2Fe–2S] + cluster temperature relaxations in the electron-bifurcating NfnABC from Thermococcus sibiricus

Electron bifurcation (EB) is a mechanism of biological energy transduction in which multiple oxidation–reduction (redox) reactions are thermodynamically coupled within a single enzyme, enabling the enzyme to harness the excess free energy from an exergonic process to drive an endergonic process. Because of this unprecedented chemistry, there is interest to translate EB principles to artificial and bioengineered systems, but a hurdle is that knowledge pertaining to the fundamental design principles of EB enzymes remains scarce. Here, we investigated the fundamental physical and electronic properties of electron transfer sites in a spectroscopically uncharacterized member of the BfuABC family of EB enzymes, the NADH-dependent reduced-ferredoxin:NADP + oxidoreductase from Thermococcus sibiricus (Tsi NfnABC). Cryo-EM structures of Tsi NfnABC previously demonstrated that it contains twelve redox cofactors: two flavins (one FAD and one FMN), eight [4Fe–4S] clusters, and two [2Fe–2S] clusters. The FMN, one [4Fe–4S] cluster, and one [2Fe–2S] cluster comprise the bifurcating active site termed the electron-bifurcating flavobicluster (BF-FBC), which is found in all BfuABC family members. By using electron paramagnetic resonance spectroscopy, we identified spectral signatures originating from interactions between the FMN radical and [4Fe–4S] + cluster in the BF-FBC and observed temperature dependent behavior of the BF-FBC's [2Fe–2S] + cluster indicative of moderately slow spin–lattice relaxation. Additionally, we uncovered numerous spectral features corresponding to half-integer, S > ½ spin states of [4Fe–4S] + clusters, including one attributable to the consequences of lysine-ligation of a [4Fe–4S] cluster unique to NfnABC. We contextualize these findings to electron transfer theory and NfnABC's structure. Our insights further the understanding of how enzymes are designed to exert control over electron transfer to conduct thermodynamically challenging reactions.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

NASA NTRS1985

Changes in skeletal muscle properties following hindlimb suspension

Changes in AChE regulation, the functions of the sarcoplasmic reticulum (SR), and muscle fiber-type population in the extensor digitorium longus (EDL) and soleus of male rats suspended in a nonweight-bearing position are studied. Muscle weight, AChE activity, protein content, SR calcium loading rates, and muscle types in the suspended and control rats are evaluated and compared. It is observed that following 1-4 weeks of suspension the EDL is unaffected; however, the soleus muscle weight, and protein content decrease and the AChE activity increases. The SR calcium loading rates of EDL decrease 10 percent and the soleus increase 50 percent in the suspended rats. The data reveal that the population of muscle type 1 (slow fibers) decreases and type 2 (fast fibers) increases for the soleus, and the distribution is unchanged for the EDL of the suspended rats. It is detected that a nonweight-bearing position affects the soleus (a fast-twitch muscle), but not the EDL (a slow-twitch muscle).

Patterson, G. T.↗

NASA NTRS1997

Data Base for CFD Validation

The flow behind the shock wave formed around objects which fly at hypervelocity behaves differently from that of a perfect gas. Molecules become vibrationally excited, dissociated, and ionized. The hot gas may emit or absorb radiation. When the atoms produced by dissociation reach the wall surface, chemical reactions, including recombination, may occur. The thermochemical phenomena of vibration, dissociation, ionization, surface chemical reaction, and radiation are referred to commonly as high-temperature real-gas phenomena. The phenomena cause changes in the dynamic behavior of the flow and the surface pressure and heat transfer distribution around the object. The character of a real gas is described by the internal degrees of freedom and state of constituent molecules; nitrogen and oxygen for air. The internal energy states, rotation, vibration and electronic, of the molecules are excited and, in the limit, the molecular bonds are exceeded and the gas dissociated into atomic and, possibly, ionic constituents. The process of energy transfer causing excitation, dissociation and recombination is a rate process controlled by particle collisions. Binary, two-body, collisions are sufficient to cause internal excitation, dissociation and ionization while three-body collisions are required to recombine the particles into molecular constituents. If the rates of energy transfer are fast with respect to the local fluid dynamic time scale the gas is in, or nearly in, equilibrium. If the energy transfer rates are very slow the gas can be described as frozen. In all other instances, wherein any of the energy exchange rates are comparable to the local fluid time scale, the gas will be thermally or chemically reacting and out of equilibrium. Real gas thermochemical nonequilibrium processes are important in the determination of aerodynamic heating; both convective (including wall catalytic effects) and radiative heating. To illustrate this we consider the hypervelocity flow over a bluff body typical of an atmospheric entry vehicle or an aerospace transfer vehicle (ASTV). The qualitative aspects of a hypersonic flow field over a bluff body are discussed in two parts, forebody and afterbody, with attention to which particular physical effects must be included in an analysis. This will indicate what type of numerical modeling will be adequate in each region of the flow. A bluff forebody flow field is dominated by the presence of the strong bow shock wave and the consequent heating, and chemical reaction of the gas. At high altitude hypersonic flight conditions the thermal excitation and chemical reaction of the gas occur slowly enough that a significant portion of the flow field is in a state of thermochemical nonequilibrium. A second important effect is the presence of the thick boundary layer along the forebody surface. In this region there are large thermal and chemical species gradients due to the interaction of the gas with the wall. Also at high altitudes the shock wave and the boundary layer may become so thick that they merge; in this case the entire shock layer is dominated by viscous effects.

Deiwert, George S.↗

NASA NTRS2008

Magnetotail Current Sheet Thinning and Magnetic Reconnection Dynamics in Global Modeling of Substorms

Magnetotail current sheet thinning and magnetic reconnection are key elements of magnetospheric substorms. We utilized the global MHD model BATS-R-US with Adaptive Mesh Refinement developed at the University of Michigan to investigate the formation and dynamic evolution of the magnetotail thin current sheet. The BATSRUS adaptive grid structure allows resolving magnetotail regions with increased current density up to ion kinetic scales. We investigated dynamics of magnetotail current sheet thinning in response to southwards IMF turning. Gradual slow current sheet thinning during the early growth phase become exponentially fast during the last few minutes prior to nightside reconnection onset. The later stage of current sheet thinning is accompanied by earthward flows and rapid suppression of normal magnetic field component $B-z$. Current sheet thinning set the stage for near-earth magnetic reconnection. In collisionless magnetospheric plasma, the primary mechanism controlling the dissipation in the vicinity of the reconnection site is non-gyrotropic effects with spatial scales comparable with the particle Larmor radius. One of the major challenges in global MHD modeling of the magnetotail magnetic reconnection is to reproduce fast reconnection rates typically observed in smallscale kinetic simulations. Bursts of fast reconnection cause fast magnetic field reconfiguration typical for magnetospheric substorms. To incorporate nongyritropic effects in diffusion regions we developed an algorithm to search for magnetotail reconnection sites, specifically where the magnetic field components perpendicular to the local current direction approaches zero and form an X-type configuration. Spatial scales of the diffusion region and magnitude of the reconnection electric field are calculated self-consistently using MHD plasma and field parameters in the vicinity of the reconnection site. The location of the reconnection sites and spatial scales of the diffusion region are updated during the simulations. Such an approach allows quantifying the interaction between large-scale global magnetospheric dynamics and microphysical processes in diffusion regions localized near reconnection sites. To clarify the role of smallscale non-MHD effects in diffusion region on the global magnetospheric dynamic and to test different models of dissipation we perform simulations with steady southward IMF driving of the magnetosphere.

Kuznetsova, M. M.↗

DOE OSTI2024

An Integrated Deposition and Passivation Strategy for Controlled Crystallization of 2D/3D Halide Perovskite Films

Abstract This work introduces a simplified deposition procedure for multidimensional (2D/3D) perovskite thin films, integrating a phenethylammonium chloride (PEACl)‐treatment into the antisolvent step when forming the 3D perovskite. This simultaneous deposition and passivation strategy reduces the number of synthesis steps while simultaneously stabilizing the halide perovskite film and improving the photovoltaic performance of resulting solar cell devices to 20.8%. Using a combination of multimodal in situ and additional ex situ characterizations, it is demonstrated that the introduction of PEACl during the perovskite film formation slows down the crystal growth process, which leads to a larger average grain size and narrower grain size distribution, thus reducing carrier recombination at grain boundaries and improving the device's performance and stability. The data suggests that during annealing of the wet film, the PEACl diffuses to the surface of the film, forming hydrophobic (quasi‐)2D structures that protect the bulk of the perovskite film from humidity‐induced degradation.

2D/3D perovskites↗

DOE OSTI2023

Growth of ZrO 2 films on mesoporous silica sieve via atomic layer deposition

The atomic layer deposition of ZrO 2 thin films over the mesopores of a mesoporous silica sieve, SBA-15 (Santa Barbara Amorphous-15), using the tetrakis(dimethylamino)zirconium(IV) (TDMAZ) as ZrO 2 precursor was tested and characterized using N 2 adsorption-desorption isotherms, taking advantage of the well-defined shape and size distribution of the pores in the SBA-15. Three samples were prepared, using 2, 4, and 6 deposition cycles to control the thickness of the films. It was determined that, as the average size of the pores decreased (with the increasing number of cycles), their size distribution remained narrow, indicating a homogeneous distribution of the ZrO 2 throughout the surfaces of the SBA-15 pores. This conclusion was confirmed by transmission electron microscopy and X-ray photoelectron spectroscopy. Further, the deposition rate appears to slow down after 4 cycles, an observation that we explain by different chemisorption properties of TDMAZ molecules over SBA-15 and ZrO 2 surface and by relating the kinetic diameter of TDMAZ with the pore diameter of SBA-15 after 4 deposition cycles: mass transport limitations have become significant at this point. They may be affected by complex factors like electronic effects caused by exposed ZrO 2 surface and the multi-directional adsorption of precursor molecules in the pore walls.

36 MATERIALS SCIENCE↗

DOE OSTI2026

Slow-Light Mid-IR Silicon Photonic Chips for NO 2 and CH 4 Gas Detection

A compact, chip-scale mid-infrared gas sensor is demonstrated, leveraging a two-dimensional photonic crystal waveguide (PCW) fabricated on a silicon-on-insulator (SOI) platform. The PCW comprises a hexagonal lattice with lattice constant a = 860 nm and hole radius r = 0.22a, incorporating a central line defect of reduced-radius holes (r s = 0.7r) to induce slow-light propagation near the photonic band edge with a group index of approximately 73, thereby enhancing light-matter interaction. The sensor operates at fundamental absorption wavelengths of 3.42 μm for nitrogen dioxide (NO 2 ) and 3.40 μm for methane (CH 4 ), utilizing the strongest molecular vibrational transitions for maximum sensitivity. Experimental validation was conducted using dynamically diluted gas mixtures generated by mass flow controllers, with signal acquisition performed by a liquid nitrogen-cooled InSb detector. For NO 2 , the sensor exhibited excellent linear response over 5–25 ppm (part per million) with coefficient of determination R 2 = 0.9934, achieving a detection limit of 210 ppb (part per billion)─representing the first reported silicon photonic-based NO 2 detection. For CH 4 , exposure to 25 ppm resulted in a 6.4% decrease in transmitted intensity, demonstrating multigas sensing capability. The CMOS-compatible fabrication process and compact 3 mm device footprint establish this SOI-PCW platform as a scalable, low-power solution for integrated mid-infrared gas sensing, with significant potential for environmental monitoring and industrial safety applications.

Crystals↗

NASA NTRS2020

Aerocapture as an Option for Ice Giants Mission

Aerocapture is an atmospheric maneuver where the aerodynamic forces of the vehicle (lift and drag) are used to provide the 𝞓V needed to slow down from the approach hyperbolic trajectory to achieve the desired captured orbit around the target planet. The aeroassist capture provides a large savings in propulsion needed to change the velocity of the vehicle, since aerodynamic forces rather than propulsive systems provide the change in velocity. Aerocapture requires an integrated system level design, including thermal protection systems, actuator systems for aerodynamic modulation, and guidance and control systems that can autonomously command the change in the aeroassist forces. Although aerocapture has been proposed for many situations in the past, including Mars, Venus, Titan, Saturn, Uranus, and Neptune orbiters as well as for Earth demonstration missions, it has not been attempted on any missions. However, many studies in the past three decades that have considered aerocapture as a design option have concluded that there are large mass savings that come from using aeroassist forces rather than propulsive forces to put a spacecraft into a captured orbit. The benefits are destination dependent, but some of the largest mass savings occur for the Ice Giants planets. Due to the large hyperbolic velocities of interplanetary trajectories approaching Uranus and Neptune, large amount of propulsion must be used to put a spacecraft in science orbits around these planets. Aerocapture can reduce the propulsion needs by dissipating energy in the sizable atmospheres of Uranus and Neptune. NASA commissioned a detailed study analysis to quantify the benefits, if any, for use at Neptune. The study found that even having to provide a heat shield aerocapture could deliver 40% more payload than an all-propulsive vehicle, and also provides for a 3–4-year reduction in trip time. Mass savings are expected also at Uranus with an aerocapture mission. Additionally, more recent advances in thermal protection systems and guidance and control systems show a path to increase capabilities beyond those results. This paper will discuss the merits of including aerocapture as an option for an Ice Giants mission. The discussion will focus on the cost and mass savings of using aerocapture instead of propulsive burns for Ice Giants orbiter mission scenarios while also detailing a potential concept of operations and entry vehicle design. Finally, the talk will discuss more recent work that shows aerocapture design is possible without the development of any novel entry vehicle. Thus, aerocapture can significantly improve science capabilities for an Ice Giants mission.

Soumyo Dutta↗

NASA NTRS1994

Fracture Behavior of Ceramics Under Displacement Controlled Loading

A Mode I fracture specimen and loading method has been developed which permits the observation of stable crack extension in monolithic and in situ toughened ceramics. The developed technique was used to conduct room temperature tests on commercial grade alumina (Coors' AD-995) and silicon nitride (Norton NC-132). The results of these tests are reported. Crack growth for the alumina remained subcritical throughout testing revealing possible effects of environmental stress corrosion. The crack growth resistance curve for the alumina is presented. The silicon nitride tests displayed a series of stable (slow) crack growth segments interrupted by dynamic (rapid) crack extension. Crack initiation and arrest stress intensity factors, K(sub Ic) and K(sub Ia), for silicon nitride are reported. The evolution of the specimen design through testing is briefly discussed.

Calomino, Anthony↗

DOE OSTI2023

Development of Novel Ferritic-Martensitic Steels with Superior Creep Properties for Power Plant Applications

A creep resistant martensitic steel, CPJ-7, was developed with an operating temperature approaching 650°C. Subsequently, another creep resistant martensitic steel, JMP, was designed with the potential to operate at, or slightly above, 650°C. This report describes the development of these alloys from early iterations of CPJ steels to the final CPJ-7 formulation as well as the more heat resistant JMP steel formulation. The design originated from computational modeling for phase stability and precipitate strengthening using fifteen constituent elements. Approximately forty heats of CPJ and ten of JMP, each weighing ~7 kg, were vacuum induction melted. A computationally optimized heat treatment schedule was developed to homogenize the ingots prior to hot forging and rolling prior to final normalization and tempering. Overall, wrought and cast versions of CPJ-7 present superior creep properties when compared to wrought and cast versions of COST alloys for steam turbine and wrought and cast versions of P91/92 for boiler applications. For instance, the Larson Miller Parameter curve for CPJ-7 at 650°C almost coincides with that of COST E at 620°C. The prolonged creep life was attributed to slowing down the process of the destabilization of the MX and M 23 C 6 precipitates at 650°C. On the other hand, the cast version of CPJ-7 also revealed superior mechanical performance, well above commercially available cast 9% Cr martensitic steel or derivatives, especially for creep life at 650°C. The casting process employed slow cooling to simulate the conditions of a thick wall full-size steam turbine casing but utilized a separate homogenization step prior to final normalization and tempering. To advance the development of CPJ-7 for commercial applications, a process was used to scale up the production of the alloy using vacuum induction melting (VIM) and electroslag remelting (ESR), which underlined the importance of melt processing control of intentionally designed minor and trace elements in these advanced alloys. Following the work on CPJ-7, the JMP steels were designed with higher Co for increased solid solution strengthening, Si for oxidation resistance and increased W (with low Mo content) for matrix strength and stability as well as solid solution strengthening. The JMP steels showed increases in creep life compared to CPJ-7 between 118 to 150% at 650°C for testing at various stresses between 138 MPa and 207 MPa. On a Larson-Miller plot, the performance of the JMP steels surpasses that of state-of-the-art MARBN and other MARBN-type steels. The influence of various elements within the composition of the alloys on the microstructure and mechanical properties are discussed. This report presents approximately 420,000 h of in-house creep testing, the equivalent of almost 50 years of cumulative creep tests.

36 MATERIALS SCIENCE↗

DOE OSTI2026

From atomistic models to machine learning: Predictive design of nanocarbons under extreme conditions

The formation of technologically valuable nanocarbon structures under extreme conditions, such as those produced during high-explosive detonations, remains poorly understood but holds significant potential for the development of controlled synthesis pathways. While detonation shockwaves provide the high-pressure, high-temperature environment required for nanodiamond formation, subsequent cooling and decompression dictate whether the diamond phase is preserved or transformed into other nanocarbon structures. Here, in this study, we employ GPU-accelerated reactive molecular dynamics (ReaxFF) simulations to investigate the graphitization and structural remodeling of detonation nanodiamond under nonlinear quench and pressure-release trajectories. We further investigate how the initial nanodiamond morphology; cuboctahedral, octahedral, or hexagonal prism influences the resulting transformation products. Evolution of nanostructure, allotrope (via simulated x-ray diffraction), carbon hybridization, and ring statistics are tracked during a two-stage quench from 5000 K to 60 GPa. Rapid cooling combined with slow decompression optimizes cubic diamond retention, whereas slow cooling with rapid pressure release promotes surface-to-core graphitization, producing concentric sp 2 -hybridized layers and hollowed inner shells. Octahedral nanodiamonds evolve into carbon nano-onions, initially forming bucky diamonds that progressively transform into fully sp 2 -hybridized structures, while hexagonal prisms preferentially form parallel-stacked graphite layers resembling carbon dots. Transient hexagonal diamond (lonsdaleite) emerges as an interfacial phase, suggesting potential reversibility in the shock-induced graphite-to-diamond transformation pathway transformation route. To extend predictive capabilities, we trained machine learning (ML) regressors on over 10 5 node-hours of molecular dynamics (MD) trajectories. A multilayer perceptron (MLP) model reliably predicts the number of graphitized layers from temperature–pressure trajectories with a coefficient of determination (R 2 ) exceeding 0.90. This high predictive fidelity enables efficient, high-throughput mapping of the synthesis parameter space for optimized graphitization outcomes. Collectively, morphological control combined with optimized quench–decompression conditions promote the selective synthesis of nanocarbon allotropes. This work establishes a data-driven framework for the rational, a priori design of carbon nanomaterials for applications in energy storage, sensing, and biomedicine.

Detonation nanodiamond remodeling↗

DOE OSTI2022

Schmid factor crack propagation and tracking crystallographic texture markers of microstructural condition in direct energy deposition additive manufacturing of Ti-6Al-4V

Metallic additive manufacturing (AM) provides a customizable and tailorable manufacturing process for new engineering designs and technologies. The greatest challenge currently facing metallic AM is maintaining control of microstructural evolution during solidification and any solid state phase transformations during the build process. Ti-6Al-4V has been extensively surveyed in this regard, with the potential solid state and solidification microstructures explored at length. In this study, we evaluate the applicability of previously determined crystallo- graphic markers of microstructural condition observed in electron beam melting powder bed fusion (PBF-EB) builds of Ti-6Al-4V in a directed energy deposition (DED) build process. The aim of this effort is to elucidate whether or not these specific crystallographic textures are useful tools for indicating microstructural conditions in AM variants beyond PBF-EB. Parent β-Ti grain size was determined to be directly related to α-Ti textures in the DED build process, and the solid state microstructural condition could be inferred from the intensity of specific α-Ti orientations. Qualitative trends on the as-solidified β-Ti grain size were also determined to be related to the presence of a fiber texture, and proposed as a marker for as-solidified grain size in any cubic metal melted by AM. Analysis of the DED Ti-6Al-4V build also demonstrated a near complete fracture of the build volume, suspected to originate from accumulated thermal stresses in the solid state. Crack propagation was found to only appreciably occur in regions of slow cooling with large α +β colonies. Schmid factors for the basal and prismatic α-Ti systems explained the observed crack pathway, including slower bifurcation in colonies with lower Schmid factors of both slip systems. Colony morphologies and localized equiaxed β-Ti solidification were also found to originate from build pauses during production and uneven heating of the build edges during deposition. Tailoring of DED Ti-6Al-4V microstructures with the insight gained here is proposed, along with cautionary insight on preventing unplanned build pauses to maintain an informed and controlled thermal environment for microstructural control.

36 MATERIALS SCIENCE↗

DOE OSTI2023

Evolving radon diffusion through earthen barriers at uranium waste disposal sites

Field measurements of Rn-222 fluxes from the tops and bottoms of compacted clay radon barriers were used to calculate effective Rn diffusion coefficients (D Rn ) at four uranium waste disposal sites in the western United States to assess cover performance after more than 20 years of service. Values of D Rn ranged from 7.4 × 10 -7 to 6.0 × 10 -9 m 2 /s, averaging 1.42 × 10 -7 . Water saturation (S W ) from soil cores indicated that there was relatively little control of D Rn by S W , especially at higher moisture levels, in contrast to estimates from most steady-state diffusion models. Further, this is attributed to preferential pathways intrinsic to construction of the barriers or to natural process that have developed over time including desiccation cracks, root channels, and insect burrows in the engineered earthen barriers. A modification to some models in which fast and slow pathway D Rn values are partitioned appears to give a good representation of the data; 4% of the fast pathway was needed to fit the data regression. For locations with high S w and highest D Rn (and fluxes) at each site, the proportion of fast pathway ranged from 1.7% to 34%, but for many locations with lower fluxes, little if any fast pathway was needed.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

NASA NTRS1978

Applications and limitations of very large-scale integration in SAR azimuth processing

The major limitation of a convolution processor designed with CCD memory chips is the inability to operate in real time except for slow aircraft speeds or coarse resolutions. Two methods of summing the products were evaluated with respect to speed, power, and space requirements. A convolution processor was designed, and the number of chips as well as the power and volume requirements were determined using 4, 6, and 8 bit data words. The processor is flexible because range samples may be traded for additional azimuth samples by altering the control signals. The processor is also modular, and additional range or azimuth may be processed by adding more cards.

Kuhler, D. G.↗

NASA NTRS1989

Experimental observations and finite element analysis of the initiation of fiber microbuckling in notched composite laminates

An understanding was developed of the factors that determine the semi-circular edge-notched compressive strength and the associated failure mode(s) were identified of thermoplastic composite laminates with multidirectional stacking sequences. The experimental observations and the detailed literature review suggest at least four factors that affected the determination of the strain levels at which fiber microbuckling initiates and thus, partially control the composite's compression strength. The dependent variables studied are the compressive strength of a reduced gage section compression specimen and the compression strength of a compression specimen with two semi-circular edge notches (no opposite free edges) centered along the gage section. In this research, specimens containing two semi-circular edge notches (no opposite free edges) were loaded in compression at a relatively slow rate to provide more stable development of fiber microbuckling damage. The results indicate that the local constraints (free surfaces, supporting ply orientation, and resin-rich regions) significantly affect the strain level for the initiation of in-plane fiber microbuckling. Preliminary results at an elevated temperature, 77 C, showed the shear stress yield strength of the resin was reduced and consequently, the resistance to fiber microbuckling was also reduced. The finite element analysis of the perfectly straight fiber problem indicates that the free surface effect causes a 10 percent reduction in the critical buckling strain. However, the experimentally measured reduction for fibers with an initial fiber curvature, was 35 percent.

Guynn, E. Gail↗