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At least 901 records · Page 50

Modernization of the Radiation Measurements Laboratory at the Advanced Test Reactor Complex

The Advanced Test Reactor (ATR) at the Idaho National Laboratory (INL) is a unique, water-cooled, high-flux test reactor capable of performing tests prototypical of PWR operating conditions. The Radiation Measurements Laboratory (RML) was founded in the 1960s to support reactor operations and to conduct independent scientific research. For nearly six decades RML has performed four primary functions: monitoring of radioactivity by gamma-ray spectroscopy of routine reactor samples, fluence rate determinations for irradiation cycles, fission-rate measurements for the ATR-Critical (ATR-C) Facility, and independent research and development of radiation detection systems and applications. Through the decades, RML has seen technological advancements that have been integrated into each of the critical functions of the laboratory. However, many of the measurement and analysis systems employed to this day can be improved by modernization. Recent progress at RML is improving reliability and accuracy of the radiation measurements performed in support of nuclear energy research for the U.S.A. Department of Energy. The control and data collection systems supporting ATR-C have been upgraded. New High-Purity Germanium (HPGe) spectrometers have been procured with liquid nitrogen recycling capabilities to improve up-time and reduce measurement uncertainties. Fluence-rate measurement techniques are also being improved to ensure accuracy, avoid systemic errors, and identify biases. In a parallel effort, new scientific research avenues are being explored which will provide an opportunity to further enhance the utilization of ATR and ensure the sustainability of the RML as nuclear research continues to evolve. The RML is improving the effectiveness of irradiation services provided by ATR while ensuring a sustainable future for nuclear energy research.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Comparison of fluence-rate determination techniques for the Advanced Test Reactor-Critical Facility

The Advanced Test Reactor (ATR) at the Idaho National Laboratory (INL) is a unique, water-cooled, high-flux test reactor capable of performing tests prototypical of PWR operating conditions. The design and safe operation of experiments in ATR is aided by the operation of the ATR-Critical Facility (ATR-C), a lower-power reactor with the same size and geometry of the ATR. Short, low-power irradiations at the ATR-C are used to study the effects of control devices and test assemblies on the overall power distribution of various core loadings and to compare calculated data for reactor models. A technique was developed at INL to measure fission rates in fuel plate assembly reactors utilizing small, enriched uranium-aluminum (U-Al) alloy monitors, and to support ATR-C irradiations for forty years. Several hundred monitor wires placed throughout the reactor provide fine spatial resolution of the fission rates. A direct correlation exists between the fission rates of the U-Al monitors and the immediately adjacent reactor region. Extensive calibration was previously performed to determine the conversion factor for beta-particle activity of the irradiated U-Al monitors. The fission rate in the U-Al monitors can thus be determined by measuring the beta-particle decay of fission-products following irradiation of the monitors. The American Society for Testing and Materials (ASTM International) has established a standard practice for determining neutron fluence rate by radioactivation of depleted uranium. The ASTM standard practice also measures the concentration of fission-products in the uranium monitors. Rather than measuring the beta-particle decay from fission-products, the decay rate of fission-products is determined by gamma-ray spectroscopy. The feasibility of the ASTM standard practice was investigated for ATR-C irradiations and compared to the present method. The need to analyze hundreds of samples for each irradiation posed several challenges. Therefore, practical considerations such as expected fluence-rates, sample activity, and counting-time were compared between the two methods and the expected sources of error for each method were investigated.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Reducing communication in algebraic multigrid with multi-step node aware communication

Algebraic multigrid (AMG) is often viewed as a scalable [Formula: see text] solver for sparse linear systems. Yet, AMG lacks parallel scalability due to increasingly large costs associated with communication, both in the initial construction of a multigrid hierarchy and in the iterative solve phase. This work introduces a parallel implementation of AMG that reduces the cost of communication, yielding improved parallel scalability. It is common in Message Passing Interface (MPI), particularly in the MPI-everywhere approach, to arrange inter-process communication, so that communication is transported regardless of the location of the send and receive processes. Performance tests show notable differences in the cost of intra- and internode communication, motivating a restructuring of communication. In this case, the communication schedule takes advantage of the less costly intra-node communication, reducing both the number and the size of internode messages. Node-centric communication extends to the range of components in both the setup and solve phase of AMG, yielding an increase in the weak and strong scaling of the entire method.

Computer Science↗

Multi-Scale Thermal Analysis for Design of SiC-Based Medium Voltage Motor Drive: Preprint

This paper describes a multi-scale thermal analysis approach for the design of an air-cooled 1.7-kV SiC MOSFET-based medium-voltage variable-speed motor drive. The National Renewable Energy Laboratory supported the project objectives by providing thermal management design support to the project partner The Ohio State University (OSU). The scope of the models and limited resources required efficient and flexible thermal models to be developed. Two modeling techniques are described that significantly reduced model run time and enabled more complex models to be run faster while retaining needed accuracy. The first technique uses the effectiveness-NTU method to extract convection boundary conditions from a computational fluid dynamics (CFD) model that can be applied to a fast-running finite element analysis model. The second is a porous media technique that enables system-level CFD simulations that incorporate effects from heat exchangers (e.g., pin fin heat sinks) that run in a fraction of the time required for fully resolved CFD simulations. The multi-scale approach to the thermal analysis enabled fast and accurate simulation for the converter design ranging from the die level up to the full system with 36 submodules. The modeling results were validated against experimental data from system tests performed by OSU.

DIRECT ENERGY CONVERSION↗

Control of Radioactive Methyl Iodide Gases by Mesoporous Hybrid Adsorbents at High Humid Condition - 19329

During the operation of nuclear facility as well as decommissioning stage, various radioactive gaseous wastes are generated. It is generally recognized that radioiodine is potentially one of the most hazardous gas on the human body and environment. Iodine-131 release in the gaseous effluents at the nuclear facilities had been a critical environmental concern. Reducing iodine release is a critical issue in radioactive waste system evaluation, especially in their adherence to the 'as low as reasonably achievable' (ALARA) criteria because radioiodine among these gaseous wastes has radiological harm. Therefore, numerous studies for the removal of radioiodine from the off-gas stream of nuclear facilities have been performed with formation processes and chemical structure. There has been some concern regarding the use of TEDA-impregnated activated carbon as an adsorbent for radioiodine removal, because of the low ignition point of TEDA and the possible release of TEDA from the charcoal in continuously flowing air streams. Therefore, the TEDA-impregnated activated carbon cannot use to trap radioiodine generated from high humid condition, due to the rapid drop of the removal efficiency. It is obvious that high humid can be expected during design basis event such as loss-of-coolant accident (LOCA). Therefore, investigation on the retention of organic radioiodine (CH3I131) by various activated carbons at high humid condition has extensively been performed so far. But there are no good results on the adsorption of methyl iodide at high humid condition up to now. As a result, the promising approach to the problem of iodine removal under high humid conditions is to use organic-inorganic hybrid adsorbents in which are enough retention characteristics from hydrophobic property. In order to develop the best removal efficiency for the control of radioiodine gas generated from a high humid process, a hydrophobic adsorbents was developed and the performance test of adsorbent using radioactive methyl iodide tracer was also performed. Demonstration test of adsorbent using radioactive methyl iodide tracer was performed at high humid conditions up to 97% relative humidity. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A novel defoamer for processing nuclear waste: Testing and performance

Abstract Legacy radioactive waste from nuclear weapons material processing is the biggest environmental challenge in the state of South Carolina, and one of the biggest in the United States. Although substantial progress has been made in processing and vitrifying high‐level radioactive waste at the Savannah River site, approximately 35 million gallons remains to be treated and dispositioned. In this article, we show the development of a new defoamer for use in the processing of high‐level radioactive waste. The application of the new defoamer is not only more effective at controlling foam but will shorten the batch processing time leading to safer and more efficient processing. This has the potential to help shorten the overall site mission lifetime, saving the federal government hundreds of millions of dollars. The novel aspect of the new defoamer is its effectiveness and stability in the harsh conditions needed for processing high‐level radioactive waste: high temperatures, pH 4–13, strong oxidizing and reducing agents, and numerous metal catalysts. The defoamer will replace an existing antifoam agent that decomposes to form multiple flammable gases. Because the existing antifoam agent decomposes quickly, processing changes increased processing time. Statement of novelty We demonstrate that a new defoamer has been developed for use in processing high‐level radioactive waste. This novel defoamer is effective and stable in the harsh processing conditions with no detectable flammable by‐products. Because the existing antifoam agent decomposes quickly, processing changes, including lowering acid addition rates and evaporation rates, increased processing time. The new defoamer is not only more effective at controlling foam but will shorten the batch processing time and lead to safer and more efficient processing by eliminating the production of flammable gases. Statement of industrial relevance Foaming is of great concern in many industrial processes involving three‐phase gas/liquid/fine‐solids systems, like in water evaporation, mineral floatation, air sparging in situ remediation techniques, and in those found in the paper industry.

Lambert, Dan P.↗

A compact design for an electric driven hydraulic gear machine capable of multiple quadrant operation

This paper presents an innovative design of an integrated electro-hydraulic (EH) flow generation unit able to operate in multiple quadrants. The proposed unit is composed of a hydraulic machine which can operate in either pumping or motoring mode, and an electric machine, which can operate as electric motor or generator. The adopted morphological integration of the two unit fulfills the goals of maximizing compactness, power to weight ratio, energy efficiency and quietness. Furthermore, the design results from a numerical optimization procedure that includes detailed simulation of both the electric machine and the hydraulic machine, using simulation tools previously developed by the authors, but combined for the first time in this work. After describing the optimization procedure, the paper focuses on the design integration aspects of the novel unit. A 9 kW prototype of the integrated unit was also fabricated and tested to verify its performance. Tests results show a measured overall energy efficiency up to 69%, demonstrating the potentials of the proposed concept, despite some limitations present in the first prototypes which could be addressed in future design refinements.

42 ENGINEERING↗

Molecular Level Understanding of How Oxygen and Carbon Monoxide Improve NOx Storage in Palladium/SSZ-13 Passive NOx Adsorbers: The Role of NO+ and Pd(II)(CO)(NO) Species

Addition of molecular oxygen to NO-containing stream improves NOx storage of the Pd/H-SSZ-13. Model Pd/SSZ-13 with high dispersion of Pd ions (0.1 and 1 wt% Pd) was synthesized. The material was characterized with FTIR and cryo-STEM. Adsorption of NO leads to the formation of Pd(II)-NO and Pd(I)-NO complexes as well as NO+ species that replace residual H+ (extra framework) sites. These nitrosyl species are characterized by notable thermal stability, with resistance to decomposition under high vacuum at 200 ºC. Addition of O2 to NO slightly increases the amount of Pd(II)-NO complex with ?NO at ~1865 cm-1 whereas the low frequency ?NO band at 1805 cm-1, assigned to Pd(I)-NO, decreases in intensity. Simultaneously, polydentate nitrate species appear in small amounts, contributing to the high temperature NOx release stage during a PNA cycle. The concentration of NO+ (characterized by the broad IR band centered at 2170 cm-1), in the presence of O2, increases in intensity profoundly and contributes to the increased capacity of Pd/SSZ-13 to store NOx and release it at temperatures >140 ºC. In the presence of H2O/O2, Pd/SSZ-13 does not perform satisfactorily as PNA, but the addition of CO to the stream improves the PNA storage capacity and shifts the NOx release peak temperature to >320 ºC where SCR catalysts are the most effective. With the aid of FTIR spectroscopy, we reveal the selective formation of a mixed carbonyl-nitrosyl complex Pd(II)(NO)(CO) in the presence of CO. Due to shielding of the Pd(II) ion from excess water and selective formation of stable coordinately saturated Pd(NO)(CO) complexes, the PNA performance is improved by CO. Therefore, we demonstrate that beside NO species adsorbed on Pd, nitrosyl ions (NO+) in extra framework positions of chabazite are important for PNA storage. Furthermore, the important role of CO in promoting PNA performance is elucidated, thus highlighting the utility of the combined spectroscopic approach (in addition to materials performance testing) to derive structure/PNA performance relationships and identify new avenues to improve the PNA performance.

Khivantsev, Konstantin↗

Development and Optimization of Modular Hybrid Plasma Reactor

INL developed a bench–scale, modular hybrid plasma system for gas-phase nanomaterials synthesis. The system was optimized for WO 3 nanoparticle production and scale-model projection to a 300 kW pilot system. During the course of technology development, many modifications were made to the system to resolve technical issues that surfaced and also to improve performance. All project tasks were completed except two optimization subtasks. Researchers were unable to complete these two subtasks, a four-hour and an eight-hour continuous powder production run at 1 lb/hr powder-feeding rate, due to major technical issues developed with the reactor system. The 4-hour run was attempted twice, and on both occasions, the run was terminated prematurely. The termination was due to (1) heavy material condensation on the modular electrodes, which led to system operational instability, and (2) pressure buildup in the reactor due to powder clogging of the exhaust gas and product transfer line. The modular electrode for the plasma system was significantly redesigned to address the material condensation problem on the electrodes. However, the cause for product powder clogging of the exhaust gas and product transfer line led to a pressure build up in the reactor that was undetected. Fabrication of the redesigned modular electrodes and additional components was completed near the end of the project life. However, insufficient resource was available to perform tests to evaluate the performance of the new modifications. More development work would be needed to resolve these problems prior to scaling.

36 MATERIALS SCIENCE↗

Clothes Dryer Automatic Termination Evaluation

Volume 2: Improved Sensor and Control Designs Many residential clothes dryers on the market today provide automatic cycles that are intended to stop when the clothes are dry, as determined by the final remaining moisture content (RMC). However, testing of automatic termination cycles has shown that many dryers are susceptible to over-drying of loads, leading to excess energy consumption. In particular, tests performed using the DOE Test Procedure in Appendix D2 of 10 CFR 430 subpart B have shown that as much as 62% of the energy used in a cycle may be from over-drying. Volume 1 of this report shows an average of 20% excess energy from over-drying when running automatic cycles with various load compositions and dryer settings. Consequently, improving automatic termination sensors and algorithms has the potential for substantial energy savings in the U.S.

algorithm↗

Measured Performance of Residential Dehumidifiers Under Cyclic Operation

Residential construction practices are progressing toward higher levels of energy efficiency. A proven strategy to save energy is to simultaneously increase building insulation levels and reduce outdoor air infiltration. Overall, this strategy results in a shift in the mix of latent and sensible space conditioning loads, requiring proportionally more moisture to be removed compared to standard homes. In this project, researchers at the National Renewable Energy Laboratory (NREL) developed steady state performance maps to predict dehumidifier performance at a variety of indoor conditions. However, installed heating, ventilating, and air-conditioning (HVAC) equipment rarely operates at steady state. Part load performance testing of residential dehumidifiers is not mandated by current test standards. Therefore, the team tested the part load performance of four residential dehumidifiers in NREL’s Advanced HVAC Systems Laboratory . The part load efficiency of each dehumidifier was measured under 13 cycling scenarios, and combined with NREL field data to develop part load fraction (PLF) performance curves under realistic cycling scenarios.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Advanced Demonstration of Motion Correction for Ship-to-Ship Passive Inspections

Passive radiation detection is a key tool for detecting illicit nuclear materials. In maritime applications it is most effective against small vessels where attenuation is of less concern. Passive imaging provides: discrimination between localized (threat) and distributed (non-threat) sources, removal of background fluctuations due to nearby shorelines and structures, source localization to an individual craft in crowded waters, and background subtracted spectra. Unfortunately, imaging methods cannot be easily applied in ship-to-ship inspections because relative motion of the vessels blurs the results over many pixels, significantly reducing sensitivity. This is particularly true for the smaller water craft where passive inspections are most valuable. In this project we performed tests and improved the performance of an instrument (developed earlier under, “Motion Correction for Ship-to-Ship Passive Inspections”) that uses automated tracking of a target vessel in visible-light images to generate a 3D radiation map of the target vessel from data obtained using a gamma-ray imager.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

TRP Cutter Head Improvement

The current Target Rod Preparation (TRP) Cutter Head suffers from overheating problems during TPBAR breaching operations. The overheating leads to work stoppage due to the periodic need to allow the TRP Cutter Head motor to cool. This work stoppage and allowance for cooldown of the motor leads to a very inefficient TPBAR breaching process. Due to the increased need for Tritium gas, the system must be improved to increase the efficiency of the TPBAR breaching process. The project would include the following major steps: Determine likely causes of overheating of the TRP cutter head motor. Identify and research methods for cooling currently installed motor. Identify and research alternate motors for TRP cutter head. Procure a new motor for testing. Perform TPBAR breaching mockup testing with new motor. Write report on results and recommendations on potential path forward.

42 ENGINEERING↗

Hydrogen Component Performance Diagnostic Testing (CRADA CRD-18-743 Final Report)

H2@Scale is focused on the wide scale adoption of hydrogen as a flexible energy storage medium. Due to the low volumetric energy density of gaseous hydrogen, compressors are an essential component of hydrogen storage. Hydrogen compressors that support a flexible grid and on-demand vehicle fueling undergo challenging operating conditions, such as a high number of start and stop cycles and wide input and discharge pressure ranges. Equally robust components are required for these conditions while still meeting the financial requirements of sustainable hydrogen compression.

08 HYDROGEN↗