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All sourcesNASA NTRSDOE OSTI
NASA NTRS1980

Origins and size distribution of metallic iron particles in the lunar regolith

The metallic iron concentration has been measured in three ranges of metal particle diameters for 79 lunar soils by a combination of static magnetic and ferromagnetic resonance techniques. Based on these measurements, a model has been developed which apportions the total metallic iron content of lunar soils between three components: (1) metallic iron particles produced from the exposure-induced reduction of ferrous iron; they range from 40 to 330 A in diameter and are predominantly associated with agglutinate glass; (2) metallic iron particles derived from the metallic phases of the micrometeorites involved in the formation of agglutinate glass; these particles are mostly greater than 300 A in diameter; and (3) metallic iron particles in the source materials such as bedrock and breccias; these are usually greater than 330 A in diameter. The maximum concentration of metallic iron in lunar regolith is estimated at about 0.7 equiv. wt% in highland regions (approximately 5.0 wt% FeO) and about 1.0 equiv. wt% in mare regions (approximately 15.0 wt% FeO).

Morris, R. V.↗
NASA NTRS2003

Measurement of Mars Dust Particle Size and Electrostatic Charge Distributions Using the E-SPART Analyzer

There are strong indications that dust is of great importance on Mars. Dust appears to have both long-term effects on the surface geologic evolution as well as on the aeolian processes in the present climate conditions. Early spacecraft missions confirmed hypotheses from telescopic work that changes observed in the planet s surface markings are caused by wind-driven redistribution of dust. Suspended dust is known to alter the atmospheric thermal structure and circulation as well as to obscure our ability for remote observation of the planet s surface, especially during the occasional development of larger, planet-encircling dust storms which occur on average once every three Martian years.

Mazumder, M. K.↗
DOE OSTI2025

Quantifying dispersity in size and shape of nanoparticles from small-angle scattering data using machine learning based CREASE

Here, we use machine learning (ML) enhanced computational reverse engineering analysis of scattering experiments (CREASE) to interpret small-angle X-ray scattering (SAXS) data obtained from a system of nanoparticles without a priori knowledge of their exact shapes (e.g. spheres or ellipsoids), sizes (0.5–50 nm) and distributions. The SAXS measurements yielded three categories of scattering profiles exhibiting 'strong', 'weak' and 'no' features. Diminishing features (e.g. broadening or disappearing peaks) in scattering profiles have always been attributed to the presence of significant dispersity in the system. Such featureless SAXS data are not suitable for traditional analysis using analytical models. If one were to fit a relevant analytical model (e.g. the lmfit analytical model for polydisperse spheres) to these 'weak' and 'no' SAXS profiles from our nanoparticle systems, one would obtain non-unique interpretations of the data. Relying on electron microscopy to identify the distributions of nanoparticle shapes and sizes is also unfeasible, especially in high-throughput synthesis and characterization loops. In such situations, to identify the distributions of particle sizes and shapes that could be present in the sample, one must rely on methods like ML-CREASE to interpret the data quickly and output all relevant interpretations about the structure present in the system. The ML-CREASE optimization loop takes the experimental scattering profile as input and outputs multiple candidate solutions whose computed scattering profiles match the SAXS profile input. The ML-CREASE method outputs distributions of relevant structural features, such as the volume fraction of the nanoparticles in the system and the mean and standard deviation of the particle size and aspect ratio, assuming a type of distribution (e.g. normal, log-normal) for size and aspect ratio. We find that, for the SAXS profiles analyzed here, accounting for the shape dispersity along with size dispersity of the nanoparticles using ML-CREASE improved the match between the computed scattering profiles and input experimental profiles.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRSDate not supplied

Particle and Trace Gas Emissions Indices Measured During the 2021 Boeing ecoDemonstrator Emissions Ground Test

We present particle and trace gas emissions indices sampled on the ground at 30 meters behind the CFM LEAP-1B engines of the 2021 Boeing ecoDemonstrator, an Alaska Airlines 737-9 aircraft. Testing was carried out at Boeing Field in Seattle, WA, USA in Fall of 2021. Four different fuels were investigated including a 100% sustainable aviation fuel (SAF), a petroleum-based Jet A fuel, and two SAF blends. Total and non-volatile particle number concentrations were measured with a pair of condensation particle counters with one operating behind a custom-built thermal denuder heated to 350 degrees Celsius. Similarly, total and non-volatile particle number size distributions were measured with a pair of Scanning Mobility Particle Sizers (SMPSs). Non-volatile particle mass was estimated from particle light absorption techniques using an assumed mass absorption coefficient, while particle chemical speciation was measured by an Soot Particle Aerosol Mass Spectrometer (SP-AMS). A detailed list of instruments is given on the project website [1]. Overall, the results are consistent with expectations based on ICAO Emissions Databank certification data for the LEAP-1B with a stark reduction in non-volatile particle number and mass observed for the higher thrust conditions when the combustor was staged. The production of volatile particles under these conditions as well as experimental considerations related to background subtraction methods will be discussed. References: [1] Boeing ecoDemonstrator Science and Engineering Team (2022). 2021 Boeing ecoDemonstrator Emissions Ground Test Dataset

Richard H Moore↗
NASA NTRSDate not supplied

Particle and Trace Gas Emissions Indices Measured During the 2021 Boeing ecoDemonstrator Emissions Ground Test

We present particle and trace gas emissions indices sampled on the ground at 30 meters behind the CFM LEAP-1B engines of the Boeing ecoDemonstrator 737-9 aircraft. Testing was carried out at Boeing Field in Seattle, WA, USA in Fall of 2021. Four different fuels were investigated including a 100% sustainable aviation fuel (SAF), a petroleum-based Jet A fuel, and two SAF blends. Total and non-volatile particle number concentrations were measured with a pair of condensation particle counters with one operating behind a custom-built thermal denuder heated to 350 degrees Celsius. Similarly, total and non-volatile particle number size distributions were measured with a pair of Scanning Mobility Particle Sizers (SMPSs). Non-volatile particle mass was estimated from particle light absorption techniques using an assumed mass absorption coefficient, while particle chemical speciation was measured by an Soot Particle Aerosol Mass Spectrometer (SP-AMS). A detailed list of instruments is given on the project website [1]. Overall, the results are consistent with expectations based on ICAO Emissions Databank certification data for the LEAP-1B with a stark reduction in non-volatile particle number and mass observed for the higher thrust conditions when the combustor was staged. The production of volatile particles under these conditions as well as experimental considerations related to background subtraction methods will be discussed.

Benjamin A. Nault↗
NASA NTRS2015

Incorporation of New Convective Ice Microphysics into the NASA GISS GCM and Impacts on Cloud Ice Water Path (IWP) Simulation

The CMIP5 configurations of the GISS Model-E2 GCM simulated a mid- and high latitude ice IWP that decreased by 50 relative to that simulated for CMIP3 (Jiang et al. 2012; JGR). Tropical IWP increased by 15 in CMIP5. While the tropical IWP was still within the published upper-bounds of IWP uncertainty derived using NASA A-Train satellite observations, it was found that the upper troposphere (200 mb) ice water content (IWC) exceeded the published upper-bound by a factor of 2. This was largely driven by IWC in deep-convecting regions of the tropics.Recent advances in the model-E2 convective parameterization have been found to have a substantial impact on tropical IWC. These advances include the development of both a cold pool parameterization (Del Genio et al. 2015) and new convective ice parameterization. In this presentation, we focus on the new parameterization of convective cloud ice that was developed using data from the NASA TC4 Mission. Ice particle terminal velocity formulations now include information from a number of NASA field campaigns. The new parameterization predicts both an ice water mass weighted-average particle diameter and a particle cross sectional area weighted-average size diameter as a function of temperature and ice water content. By assuming a gamma-distribution functional form for the particle size distribution, these two diameter estimates are all that are needed to explicitly predict the distribution of ice particles as a function of particle diameter.GCM simulations with the improved convective parameterization yield a 50 decrease in upper tropospheric IWC, bringing the tropical and global mean IWP climatologies into even closer agreement with the A-Train satellite observation best estimates.

tropical regions↗
NASA NTRS1980

Physical characteristics of cometary dust from dynamical studies - A review

Progress made in the determination of the physical characteristics of cometary dust particles from studies of dust tail dynamics is reviewed. Applications of the combined dynamical photometric approach of Finson and Probstein (1968) to studies of cometary tails exhibiting continuous light intensity variations are discussed, with attention given to determinations of the particle-size-related distribution function of the solar radiation pressure exerted on the particles, the contribution of comets to the interplanetary dust, calculations of dust ejection rates and a Monte Carlo approach to the analysis of dust tails. Investigations of dust streamers and striae, which are believed to be related to comet outbursts entailing brief but sharp enhancements of dust production, are then reviewed, with particular attention given to observations of Comet West 1976 VI. Finally, the question of cometary particle type is addressed, and it is pointed out that the presence of submicron absorbing particles in the striae of Comet West is not incompatible with the presence of micron-size dielectric particles in the inner coma.

Sekanina, Z.↗
NASA NTRS2002

Studies of Transient Meteor Activity

Meteoroids bombard Earth's atmosphere daily, but occasionally meteor rates increase to unusual high levels when Earth crosses the relatively fresh ejecta of comets. These transient events in meteor activity provide clues about the whereabouts of Earth-threatening long-period comets, the mechanisms of large-grain dust ejection from comets, and the particle composition and size distribution of the cometary ejecta. Observations of these transient events provide important insight in natural processes that determine the large grain dust environment of comets, in natural phenomena that were prevalent during the time of the origin of life, and in processes that determine the hazard of civilizations to large impacts and of man-made satellites to the periodic blizzard of small meteoroids. In this proposal, three tasks form a coherent program aimed at elucidating various aspects of meteor outbursts, with special reference to planetary astronomy and astrobiology. Task 1 was a ground-based effort to observe periods of transient meteor activity. This includes: (1) stereoscopic imaging of meteors during transient meteor events for measurements of particle size distribution, meteoroid orbital dispersions and fluxes; and (2) technical support for Global-MS-Net, a network of amateur-operated automatic counting stations for meteor reflections from commercial VHF radio and TV broadcasting stations, keeping a 24h vigil on the level of meteor activity for the detection of new meteor streams. Task 2 consisted of ground-based and satellite born spectroscopic observations of meteors and meteor trains during transient meteor events for measurements of elemental composition, the presence of organic matter in the meteoroids, and products generated by the interaction of the meteoroid with the atmosphere. Task 3 was an airborne effort to explore the 2000 Leonid meteor outbursts, which are anticipated to be the most significant of transient meteor activity events in the remainder of the agreement period. This includes technical support for a multi-instrument aircraft campaign, Leonid MAC.

Jenniskens, Peter M. M.↗
DOE OSTI2026

Urban wash-off of tire wear particles

Tire wear particles (TWPs) are an important class of microplastics due to their toxicity and abundance. Because most TWPs are generated on impervious road surfaces, urban wash-off is the critical first phase of waterborne transport from their zone of production to stormwater drainage. However, little is known about the driving factors behind their mobilization. In this study, we use a rainfall simulator to investigate how surface roughness, rainfall intensity, and surface slope affect wash-off behaviors of TWPs. We also analyze how the size and shape of mobilized TWPs change over the course of simulated storm events. We found that low surface roughness, high rainfall intensity (most significant factor), and low slope result in the most rapid conveyance of TWP load. On average, large particles (>1000 µm) travelled faster than small particles (<125 µm). Particle shape explained a very small amount of variance in TWP wash-off velocity but was found to be more important under higher surface roughness conditions. In addition to wash-off velocity, we found similar conditions controlled the percent mobilization of TWPs. Low surface roughness and high rainfall intensity resulting in higher TWP wash-off rates is consistent with mineral sediment wash-off behavior. Conversely, low surface slope and large particle size leading to faster conveyance is directly opposed to mineral sediment wash-off. Our findings suggest drag-dominated flow and that sufficient runoff depth is the most important parameter governing TWP wash-off. These findings are important first steps to understanding wash-off behaviors of TWPs and informing future modeling efforts and mitigation strategies.

13 HYDRO ENERGY↗
DOE OSTI2021

Rapid measurement of RH-dependent aerosol hygroscopic growth using a humidity-controlled fast integrated mobility spectrometer (HFIMS)

Abstract. The ability of aerosol particles to uptake water (hygroscopic growth) is an important determinant of aerosol optical properties and radiative effects. Aerosol hygroscopic growth is traditionally measured by humidified tandem differential mobility analyzers (HTDMA), in which size-selected dry particles are exposed to elevated relative humidity (RH), and the size distribution of humidified particles is subsequently measured using a scanning mobility particle sizer. As a scanning mobility particle sizer can measure only one particle size at a time, HTDMA measurements are time consuming, and ambient measurements are often limited to a single RH level. Pinterich et al. (2017b) showed that fast measurements of aerosol hygroscopic growth are possible using a humidity-controlled fast integrated mobility spectrometer (HFIMS). In HFIMS, the size distribution of humidified particles is rapidly captured by a water-based fast integrated mobility spectrometer (WFIMS), leading to a factor of ∼10 increase in measurement time resolution. In this study we present a prototype HFIMS that extends fast hygroscopic growth measurements to a wide range of atmospherically relevant RH values, allowing for more comprehensive characterizations of aerosol hygroscopic growth. A dual-channel humidifier consisting of two humidity conditioners in parallel is employed such that aerosol RH can be quickly stepped among different RH levels by sampling from alternating conditioners. The measurement sequence is also optimized to minimize the transition time between different particle sizes. The HFIMS is capable of measuring aerosol hygroscopic growth of six particle diameters under five RH levels ranging from 20 % to 85 % (30 separate measurements) every 25 min. The performance of this HFIMS is characterized and validated using laboratory-generated ammonium sulfate aerosol standards. Measurements of ambient aerosols are shown to demonstrate the capability of HFIMS to capture the rapid evolution of aerosol hygroscopic growth and its dependence on both size and RH.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Modeling the Size Distribution and Chemical Composition of Secondary Organic Aerosols during the Reactive Uptake of Isoprene-Derived Epoxydiols under Low-Humidity Condition

Reactive uptake of isoprene epoxydiols (IEPOX), which are isoprene oxidation products, onto acidic sulfate aerosols is recognized to be an important mechanism for the formation of isoprene-derived secondary organic aerosol (SOA). While a mechanistic understanding of IEPOX-SOA formation exists, several processes affecting their formation remain uncertain. Evaluating mechanistic IEPOX-SOA models with controlled laboratory experiments under longer atmospherically relevant timescales is critical. Here, we implement our latest understanding of IEPOX-SOA formation within a box model to simulate the measured reactive uptake of IEPOX on polydisperse ammonium bisulfate seed aerosols within an environmental Teflon chamber. The model is evaluated with single-particle measurements of size distribution, volume, density, and composition of aerosols due to IEPOX-SOA formation at timescales of hours. Additionally, we find that the model can simulate the growth of particles due to IEPOX multiphase chemistry, as reflected in increases of the mean particle size and volume concentrations, and a shift of number size distribution to larger sizes. The model also predicts the observed evolution of particle number mean diameter and total volume concentrations at the end of the experiment. We show that in addition to self-limiting effects of IEPOX-SOA coatings, accounting for the molar balance between inorganic and organic sulfate and mass accommodation coefficient of IEPOX are important parameters governing modeling of IEPOX-SOA formation. Thus, models which do not account for the molar sulfate balance and/or diffusion limitations within IEPOX-SOA coatings are likely to predict too high IEPOX-SOA formation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

High–Performance NiCo 2 O 4 /Graphene Quantum Dots for Asymmetric and Symmetric Supercapacitors with Enhanced Energy Efficiency

For the sustainable growth of future generations, energy storage technologies like supercapacitors and batteries are becoming more and more common. However, reliable and high-performance materials’ design and development is the key for the widespread adoption of batteries and supercapacitors. Quantum dots with fascinating and unusual properties are expected to revolutionize future technologies. However, while the recent discovery of quantum dots honored with a Nobel prize in Chemistry, their benefits for the tenacious problem of energy are not realized yet. In this context, herein, chemical-composition tuning enabled exceptional performance of NiCo 2 O 4 (NCO)/graphene quantum dots (GQDs) is reported, which outperform the existing similar materials, in supercapacitors. A comprehensive study is performed on the synthesis, characterization, and electrochemical performance evaluation of highly functional NCO/GQDs in supercapacitors delivering enhanced energy efficiency. The high-performance, functional NCO/GQDs electrode materials are synthesized by the incorporation of GQDs into NCO. The effect of variable amount of GQDs on the energy performance characteristics of NCO/GQDs in supercapacitors is studied systematically. In-depth structural and chemical bonding analyses using X-ray diffraction (XRD) and Raman spectroscopic studies indicate that all the NCO/GQDs composites crystallize in the spinel cubic phase of NiCo 2 O 4 while graphene integration evident in all the NCO/GQDs. The scanning electron microscopy imaging analysis reveals homogeneously distributed spherical particles with a size distribution of 5–9 nm validating the formation of QDs. The high-resolution transmission electron microscopy analyses reveal that the NCOQDs are anchored on graphene sheets, which provide a high surface area of 42.27 m 2 g –1 and high mesoporosity for the composition of NCO/GQDs-10%. In addition to establishing reliable electrical connection to graphene sheets, the NCOQDs provide reliable 3D-conductive channels for rapid transport throughout the electrode as well as synergistic effects. Chemical-composition tuning, and optimization yields NCO/GQDs-10% to deliver the best specific capacitance of 3940 Fg –1 at 0.5 Ag –1 , where the electrodes retain ≈98% capacitance after 5000 cycles. The NCO/GQD-10%//AC asymmetric supercapacitor device demonstrates outstanding energy density and power density values of 118.04 Wh kg –1 and 798.76 W kg –1 , respectively. The NCO/GQDs-10%//NCO/GQDs-10% symmetric supercapacitor device delivers excellent energy and power density of 24.30 Wh kg –1 and 500 W kg –1 , respectively. These results demonstrate and conclude that NCO/GQDs are exceptional and prospective candidates for developing next-generation high-performance and sustainable energy storage devices.

25 ENERGY STORAGE↗
DOE OSTI2020

A comparative study on the physicochemical characteristics of nanoparticles released in vivo from CoCrMo tapers and cement–stem interfaces of total hip replacements

The good biocompatibility and corrosion resistance of the bulk CoCrMo alloy has resulted in it being used in the manufacture of implants and load bearing medical devices. These devices, however, can release wear and corrosion products which differ from the composition of the bulk CoCrMo alloy. The physicochemical characteristics of the particles and the associated in vivo reactivity are dictated by the wear mechanisms and electrochemical conditions at the sites of material loss. Debris released from CoCrMo hip bearings, taper junctions, or cement–stem interfaces can, therefore, have different chemical and morphological characteristics, which provide them with different in vivo toxicities. Here, we propose to assess and compare the characteristics of the particles released in vivo from CoCrMo tapers and cement–stem interfaces which have received less attention compared to debris originating from the hip bearings. The study uses state–of–art characterization techniques to provide a detailed understanding of the size, morphology, composition, and chemistry of the particles liberated from the wear and corrosion flakes from revised hip replacements, with an enzymatic treatment. The phase analyses identified Cr 2 O 3 nanoparticles released from tapers and cement–stem interfaces, whose composition did not vary with origin or particle morphology. The size distributions showed significantly smaller particles were released from the stems, compared to the particles originating from the corresponding tapers. Furthermore, the investigation demonstrates that the tribocorrosive processes occurring at the taper and stem interfaces both result in Cr 2 O 3 nanoparticle formation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Lies, damned lies, and turnover rates

A Rayleigh distribution of particles exposing (1 1 1) surface populations is consistent with the particle size dependence of the turnover rates of the electrochemical reduction of dioxygen catalyzed by a platinum cathode.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1990

Feeder System For Particle-Size Analyzer

Feeder system meters precise stream of powder into precise flow of gas. Used to feed light-scattering particle-size analyzer that determines distribution of sizes of particles in powder. Dry analysis of powder takes about one-third time of conventional wet analysis and consumes less powder. Feed rate more precisely controllable, leading to more precision in analysis. In dry analysis, no need to dispose of hazardous liquid waste.

Ramsey, Keith E.↗