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NASA NTRS1991

A redshift survey of IRAS galaxies. III - Reconstruction of the velocity and density fields in N-body model universes

N-body simulations of a 'cold dark matter' universe are presently used to calibrate the accuracy, and assess the limitations, of the procedure previously employed to predict the velocity field within 8000 km/sec of the Local Group through the application of linear gravitational theory to a full-sky, flux-limited sample of IRAS galaxies. The rms difference between the one-dimensional acceleration and velocity of field particles is an increasing function of local density; linear theory can in this way account for all but one-sixth of kinetic energy. A series of artificial IRAS catalogs closely matching the real sample in space density and clustering amplitude is constructed. Velocity correlation functions are used to demonstrate that the predicted velocity fields are in good agreement with the true velocity fields on large scales.

Davis, Marc↗

NASA NTRS1991

Nitric oxide in star-forming regions - Further evidence for interstellar N-O bonds

Nitric oxide has been newly detected toward several star-forming clouds, including Orion-KL, Sgr B2(N), W33A, W51M, and DR21(OH) via its J = 3/2-1/2 transitions near 150 GHz, using the FCRAO 14 m telescope. Both lambda-doubling components of NO were observed toward all sources. Column densities derived for nitric oxide in these clouds are 10 to the 15th-10 to the 16th/sq cm, corresponding to fractional abundances of 0.5-1.0 x 10 to the -8th, relative to H2. Toward Orion-KL, the NO line profile suggests that the species arises primarily from hot, dense gas. Nitric oxide may arise from warm material toward the other clouds as well. Nitric oxide in star-forming regions could be synthesized by high-temperature reactions, although the observed abundances do not disagree with values predicted from low-temperature, ion-molecule chemistry by more than one order of magnitude.

Ziurys, L. M.↗

NASA NTRS1990

Photovoltaic characteristics of n(+)pp(+) InP solar cells grown by OMVPE

The photovoltaic characteristics of n(+)/p/p(+) homojunction InP solar cells fabricated by organometallic vapor-phase epitaxy (OMVPE) are described. The cells are characterized by I-V, C-V and quantum efficiency measurements, and simulations are used to obtain various device and material parameters. The I-V characteristics show a high recombination rate in the depletion region; this is shown to be independent of the impurity used. It is shown that cadmium is easier to use as an acceptor for the p base and p(+) buffer and is therefore beneficial. The high quantum efficiency of 98 percent at long wavelengths measured in these cells indicates a very good collection efficiency in the base. The short-wavelength quantum efficiency is poor, indicating a high surface recombination.

Tyagi, S.↗

NASA NTRS1991

Sputtered Ta-Si-N diffusion barriers in Cu metallizations for Si

Electrical measurements on shallow Si n+-p junction diodes with a 30-nm TiSi2 contacting layer demonstrate that an 80-nm-thick amorphous Ta36Si14N50 film prepared by reactive RF sputtering of a Ta5Si3 target in an Ar/N2 plasma very effectively prevents the interaction between the Si substrate with the TiSi2 contacting layer and a 500-nm Cu overlayer. The Ta36Si14N50 diffusion barrier maintains the integrity of the I-V characteristics up to 900 C for 30-min annealing in vacuum. It is concluded that the amorphous Ta36Si14N50 alloy is not only a material with a very low reactivity for copper, titanium, and silicon, but must have a small diffusivity for copper as well.

Kolawa, E.↗

NASA NTRS1991

Experimental and analytical comparison of flowfields in a 110 N (25 Lbf) H2/O2 rocket

A gaseous hydrogen/gaseous oxygen 110 N (25 lbf) rocket has been examined through the RPLUS code using the full Navier-Stokes equations with finite-rate chemistry. Performance tests were conducted on the rocket in an altitude test facility. Preliminary parametric analyses have been performed for a range of mixture ratios and fuel film cooling percentages. It is shown that the computed values of specific impulse and characteristic exhaust velocity follow the trend of the experimental data. Specific impulse computed by the code is lower than the comparable test values by about two to three percent. The computed characteristic exhaust velocity values are lower than the comparable test values by three to four percent. Thrust coefficients computed by the code are found to be within two percent of the measured values. It is concluded that the discrepancy between computed and experimental performance values could not be attributed to experimental uncertainty.

Reed, Brian D.↗

NASA NTRS1991

The biasing scheme in N-body simulations

A popular prescription for the galaxy formation, i.e., identifying peaks in the linear density field as sites of galaxy formation, is numerically justified under the Cold Dark Matter cosmogony. In particular, the peak-background scheme, originally developed to simplify analytic calculations of peak properties in a Gaussian random density field, is proven to be an excellent prescription for assigning peak tracers in low-resolution N-body simulations through many statistical comparisons. It is found that statistical properties of peak tracers allocated by the peak-background scheme closely resemble those of true peaks when the background smoothing length is about three times the galaxy scale and the correspondence improves as they evolve gravitationally. It is also shown that these peak particles are indeed strongly associated with nonlinear objects that are presently collapsed.

Park, Changbom↗

NASA NTRS1991

The fundamental quadrupole band of (N-14)2 - Line positions from high-resolution stratospheric solar absorption spectra

Accurate measurements of the positions of O- and S-branch lines of the (1-0) vibration-rotation quadrupole band of molecular nitrogen (N-14)2 are reported. Improved Dunham coefficients were derived from a simultaneous least squares analysis of these measurements and selected infrared and far infrared data. The new measurements were performed using stratospheric solar occultation spectra recorded with Fourier transform spectrometer instruments, operated at unapodized spectral resolutions of 0.002 and 0.01/cm.

Rinsland, C. P.↗

NASA NTRS1992

The swelling mechanism of cathodes in Li/(CFx)(sub n) cells

Active material particles spatial arrangement in combination with the nature of the electrochemical reduction mechanism were found to be the major cause of excessive swelling in cathodes in Li/(CF(x))n cells. A better understanding of the chemical reaction mechanism, a possible new role for the carbon, and a model for cathode growth are discussed.

Margalit, Nehemiah↗

NASA NTRS1991

Observations on a Slow Burning Regime for Hydrocarbon Droplets - N-Heptane/Air Results

Experiments on n-heptane/airdroplet combustion under reduced gravity have served as a benchmark for much of the existing theoretical efforts on the modeling of sphero-synmmetric droplet burning. New experiments conducted in the NASA-Lewis Research Center 2.2 second droptower (at less than 10 exp -5 g) which emphasize the production of sphero-symmetry and low relative droplet/gas convection produce burning rates in air (for about 1 mm droplets) as much as 40-percent lower than the classical result (0.78 sq mm/s). The burning rate is proportional to the measured droplet/gas relative velocity, and the observed functional dependence is much larger than predicted by published convective correlations. New results clearly indicate that the droplet/laboratory velocity does not correspond to the relative droplet/gas velocity. Thus, the convective effects on droplet combustion is not properly characterized by droplet motion alone. Differences in the burning rates are speculated to result from the effects of the accumulated soot as well as the asymmetry (caused by convection) in the temperature and species distributions surrounding the droplet.

Choi, Mun Y.↗

NASA NTRS1992

High photorefractive sensitivity in an n-type 45-deg-cut BaTiO3 crystal

The beam-coupling properties of a cobalt-doped oxygen-reduced n-type barium titanate crystal are reported in the 0 deg and 45 deg crystallographic orientations. Oxygen reduction improved the response time of the 0-deg-cut crystal by a factor of about 4.5 without diminishing the beam-coupling gain. The 45-deg-cut crystal has a peak gain of about 38.7/cm, a response time of about 21 ms, and a photorefractive sensitivity of 3.44 cu cm/kJ. From response time measurements an equivalent percentage change in the dc dielectric constant and the mobility with respect to crystallographic orientation is inferred.

Garrett, M. H.↗

NASA NTRS1991

Identification of dislocation etch pits in n-type GaAs by NIR transmission microscopy

An optical method is described for identifying dislocation etch pits in n-type GaAS, using near-IR brightfield transmission microscopy. Dislocations are revealed in a nondestructive manner through contrasts that are likely due to impurity decoration of the dislocation lines. By subjecting the same wafers to a photoetching technique, it was established that each etch pit on the surface is associated with a dislocation and that the termination of each (decorated) dislocation is an etch pit.

Cao, X. Z.↗

NASA NTRS1990

Performance of (CoPC)n catalyst in active lithium-thionyl chloride cells

An experimental study was conducted with anode limited D size cells to characterize the performance of an active lithium-thionyl chloride (Li/SOCl2) system using the polymeric cobalt phthalocyanine, (CoPC)n, catalyst in carbon cathodes. The author describes the results of this experiment with respect to initial voltage delays, operating voltages, and capacities. The effectiveness of the preconditioning methods evolved to alleviate passivation effects on storage are also discussed. The results clearly demonstrated the superior high rate capability of cells with the catalyst. The catalyst did not adversely impact the performance of cells after active storage for up to 6 months, while retaining its beneficial influences.

Shah, Pinakin M.↗

NASA NTRS1992

Rate coefficients for the excitation of infrared and ultraviolet lines in C II, N III, and O IV

New and improved collision strengths and Maxwellian-averaged rate coefficients for temperatures between 1000 and 40,000 K are presented for all the prominent transitions in the spectra of C II, N III, and O IV. The collision strengths show extensive autoionization structures that are delineated in detail and which enhance the rate coefficients for several transitions by a considerable amount. Maxwellian-averaged collision strengths are calculated for all possible fine-structure transitions along the states included in the eigenfunction expansion of the target ion. All calculations are carried out in the close-coupling approximation using the R-matrix method as adapted for the Opacity Project.

Blum, Robert D.↗

NASA NTRS1992

The isotopic composition of cosmic-ray B, C, N, and O - Evidence for an overabundance of O-18

New observations of galactic cosmic rays at higher energies (about 400-780 MeV/nucleon) than obtained in previous direct mass measurements have resulted in determinations of the isotopic composition of B, C, N, and O. The derived cosmic-ray source abundances provide evidence for an enhancement of O-18/O-16 by a factor of 5.6 +/- 1.9 over the solar system value and give a C-13/C-12 ratio consistent with the solar system abundance ratio, but lower than some recent measurements of the local interstellar medium.

Gibner, P. S.↗

NASA NTRS1991

Effect of microstructure and composition on the improvement of n-type SiGe/GaP material

Experimental and theoretical work has been conducted at the Jet Propulsion Laboratory to improve the thermoelectric properties of n-type SiGe materials. Particular emphasis has been placed upon the understanding of the differences in dopant solid solubilities when multidoping with both Ga and P instead of P alone, as in standard SiGe alloys. A set of various experimental techniques for obtaining heavily doped hot-pressed samples coupled with thermodynamic theoretical considerations was used to relate microstructure and composition to electrical and thermal transport properties. Application of these results to high-temperature heat treatments of several SiGe/GaP samples achieved substantial improvements of the thermoelectric figure of merit Z, with average values close to 1 x 10-3K-1 over the 600-1000 C temperature range. A set of systematic anneals on heavily doped SiGe/GaP materials is reported in an attempt to consistently reproduce the optimized thermoelectric properties.

Fleurial, Jean-Pierre↗

NASA NTRS1991

Theoretical modeling, near-optimum design and predicted performance of n(+)pp(+) and p(+)nn(+) indium phosphide homojunction solar cells

Using a detailed simulation model of p(+)nn(+) and n(+)pp(+) indium phosphide (InP) homojunction solar cells, extensive parametric variation computer simulation runs are conducted to help arrive at near-optimum designs of these two solar cell configurations. Values of all the geometrical and material parameters corresponding to the near-optimal designs of both these configurations are presented. For each configuration, results are given for parametric variation runs showing how the performance parameters JSC, VOC, and eta vary with each of the cell parameters for the near-optimally designed cell.

Goradia, Chandra↗

NASA NTRS1991

High performance etchant for thinning p(+)-InP and its application to p(+)n InP solar cell fabrication

An etchant, namely (o-H3PO4)u: (HNO3)v: (H2O2)t: (H2O)1-(u+v+t) is developed for thinning, after contacting, the p(+) emitter layer of p(+)n InP structures made by thermal diffusion. Varying u, v, and t, reproducible etch rates of 5 to 110 nm/min are obtained. After thinning the 0.6- to 2.5-micron thick p(+) InP layer down to 60-250 nm, specular surfaces are obtained at up to 80 nm/min etch rate. Due to its intrinsic qualities the resisual P-rich oxide after thinning the emitter layer provides surface passivation of p(+) InP surfaces and can also serve as a first-layer AR coating.

Faur, Maria↗

NASA NTRS1992

Performance comparison of axisymmetric and three-dimensional hydrogen film coolant injection in a 110 N hydrogen/oxygen rocket

An experimental performance comparison of two geometrically different fuel film coolant injection sleeves was conducted on a 110 N gaseous hydrogen/oxygen rocket. One sleeve had slots milled axially down the walls and the other had a smooth surface to give axisymmetric flow. The comparison was made to investigate a conclusion in an earlier study that attributed a performance underprediciton to a simplifying modeling assumption of axisymmetric fuel film flow. The smooth sleeve had higher overall performance at one film coolant percentage and approximately the same or slightly better at another. The study showed that the lack of modeling of three-dimensional effects was not the cause of the performance underprediciton as speculated in earlier analytical studies.

Arrington, Lynn A.↗