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NASA NTRS1994

Correlation of ozone loss with the presence of volcanic aerosols

Statistically significant reductions of ozone compared to a climatological profile have been measured above the Observatoire de Haute Provence (OHP) in Southern France (43.9 deg N, 5.7 deg E) during the months of July and August, 1992. Lidar profiles of ozone, temperature and aerosols were recorded on 25 separate nights during that time. The change in the ozone profile is correlated with the presence of volcanic aerosols from the eruption of Mt. Pinatubo. The total ozone loss amounts to approximately a 10% reduction in the total ozone column over OHP.

Mcgee, Thomas J.↗
NASA NTRS1993

Observations of the loss of stratospheric NO2 following volcanic eruptions

Observations of stratospheric column amounts of nitrogen dioxide (NO2), nitric oxide (NO) and nitric acid (HNO3) have been made following major eruptions of the El Chichon and Mt. Pintatubo volcanoes. Midlatitude abundances of NO2 and NO were reduced by as much as 70% in the months following the appearance of the volcanic aerosols as compared to volcanically quite periods. There are heterogeneous reactions which could occur on the volcanic aerosols to convert NO2 into HNO3 but no commensurate increase in HNO3 column amounts was observed at the times of NO2 decrease.

Coffey, M. T.↗
NASA NTRS1995

TOMS total ozone trends in potential vorticity coordinates

Global total ozone measurements from the Nimbus 7 Total Ozone Mapping Spectrometer (TOMS) are analyzed using potential vorticity (PV) as an approximate vortex-following coordinate. We analyze the time period November 1978-May 1991, prior to the volcanic eruption of Mt. Pinatubo. The TOMS data are remapped into PV coordinates and trends are calculated, thereby characterizing ozone losses inside and outside the winter polar vortices. These analyses show large regions of ozone loss outside of the vortex in both hemispheres. Furthermore, these data suggest that midlatitude losses in the NH during winter-spring do not result solely from the transport of ozone depleted air from inside to outside the vortex.

Randel, William J.↗
NASA NTRS1995

First 2.2 micrometer results from the iota interferometer

We present the first infrared fringe visibility measurements made with the Infrared Optical Telescope Array on Mt. Hopkins. Effective temperatures are derived for RX Boo, RS Cnc, and Beta Peg. RX Boo is the coolest small-amplitude variable giant star to have an effective temperature determination. We compare the size of its photosphere at infrared wavelengths with the sizes of its SiO and H20 radio emission regions. We also discuss initial performance parameters for the interferometer.

Dyck, H. M.↗
NASA NTRS1994

Scaling craters in carbonates: Electron paramagnetic resonance analysis of shock damage

Carbonate samples from the 8.9-Mt nuclear (near-surface explosion) crater, OAK, and a terrestrial impact crater, Meteor Crater, were analyzed for shock damage using electron paramagnetic resonance (EPR). Samples from below the OAK apparent crater floor were obtained from six boreholes, as well as ejecta recovered from the crater floor. The degree of shock damage in the carbonate material was assessed by comparing the sample spectra to the spectra of Solenhofen and Kaibab limestone, which had been skocked to known pressures. Analysis of the OAK Crater borehole samples has identified a thin zone of allocthonous highly shocked (10-13 GPa) carbonate material underneath the apparent crater floor. This approx. 5- to 15-m-thick zone occurs at a maximum depth of approx. 125 m below current seafloor at the borehole, sited at the initial position of the OAK explosive, and decreases in depth towards the apparent crater edge. Because this zone of allocthonous shocked rock delineates deformed rock below, and a breccia of mobilized sand and collapse debris above, it appears to outline the transient crater. The transient crater volume inferred in this way is found to by 3.2 +/- 0.2 times 10(exp 6)cu m, which is in good agreement with a volume of 5.3 times 10(exp 6)cu m inferred from gravity scaling of laboratory experiments. A layer of highly shocked material is also found near the surface outside the crater. The latter material could represent a fallout ejecta layer. The ejecta boulders recovered from the present crater floor experienced a range of shock pressures from approx. 0 to 15 GPa with the more heavily shocked samples all occurring between radii of 360 and approx. 600 m. Moreover, the fossil content, lithology and Sr isotopic composition all demonstrate that the initial position of the bulk of the heavily shocked rock ejecta sampled was originally near surface rock at initial depths in the 32 to 45-m depth (below sea level) range. The EPR technique is also sensitive to prehistoric shock damage. This is demonstrated by our study of shocked Kaibab limestone from the 49,000-year-old Meteor (Barringer) Crater Arizona.

Polanskey, Carol A.↗
NASA NTRS1995

Evolution of the Pinatubo volcanic aerosol column above Pasadena, California observed with a mid-infrared backscatter lidar

The evolution of the volcanic debris plume originating from the June 1991 eruption of Mt. Pinatubo has been monitored since its genesis using a ground-based backscatter lidar facility sited at the Jet Propulsion Laboratory (JPL). Both absolute and relative pre- and post-Pinatubo backscatter observations are in accord with Mie scattering projections based on measured aerosol particle size distributions reported in the literature. The post-Pinatubo column-integrated backscatter coefficient peaked approximately 400 days after the eruption, and the observed upper boundary of the aerosol column subsided at a rate of approximately 200 m/mon.

Tratt, David M.↗
NASA NTRS1995

Evolution of the Pinatubo volcanic cloud over Hampton, Virginia

The eruption of Mt. Pinatubo in June 1991 produced the largest enhancement of stratospheric aerosol loading ever observed by lidar over Hampton, Virginia. Low altitude layers (less than 20 km) were the first to arrive over Hampton in early August, the result of transport associated with a tropospheric anticyclonic cell over North America. The maximum peak scattering ratio, 34 at 22.4 km, and the maximum stratospheric integrated backscatter of 0.0053 sr(exp -1), both at 694 nm, observed since the eruption were measured on February 20, 1992. After decreasing during the spring and summer of 1992, the aerosol burden increased significantly during the winter of 1992-93, evidence of a poleward winter transport from the equatorial reservoir. Over the period from February 1992 to February 1994, the stratospheric aerosol loading decreased with an average 1/e decay time of 10.1 months. The vertical distribution, intensity, and transport of Pinatubo aerosols over this site are described and compared with similar measurements after El Chichon.

Osborn, Mary T.↗
NASA NTRS1993

Sines and Cosines. Part 2 of 3

The Law of Sines and the Law of Cosines are introduced and demonstrated in this 'Project Mathematics' series video using both film footage and computer animation. This video deals primarily with the mathematical field of Trigonometry and explains how these laws were developed and their applications. One significant use is geographical and geological surveying. This includes both the triangulation method and the spirit leveling method. With these methods, it is shown how the height of the tallest mountain in the world, Mt. Everest, was determined.

Apostol, Tom M.↗
NASA NTRS1995

An infrared imaging study of galaxies in the local universe

This poster was a preliminary report on a survey of galaxies in the local universe at J and K using a NICMOS3 256 x 256 infrared photometric camera attached to the 61 inch telescope on Mt. Bigelow. Deep images are being obtained for a representative sample of galaxies in the Uppsala General Catalogue. Structural and color parameters are determined for a wide variety of galactic types. These data should prove to be valuable in characterizing stellar populations within disks and bulges, determining if IR-active galaxies have unusual global as well as- nuclear properties, and understanding the effects of evolution and redshift dimming in distant galaxies.

Grauer, Albert D.↗
NASA NTRS1993

Machine translation project alternatives analysis

The Machine Translation Project consists of several components, two of which, the Project Plan and the Requirements Analysis, have already been delivered. The Project Plan details the overall rationale, objectives and time-table for the project as a whole. The Requirements Analysis compares a number of available machine translation systems, their capabilities, possible configurations, and costs. The Alternatives Analysis has resulted in a number of conclusions and recommendations to the NASA STI program concerning the acquisition of specific MT systems and related hardware and software.

Bajis, Catherine J.↗
NASA NTRS1995

Validation of stratospheric ozone observed by the Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment during 1992

Measurements of stratospheric ozone were made by the Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment from onboard the Space Shuttle during the period 8-16 April 1992. The precision and accuracy of the measurements are discussed in the context of establishing the accuracy and compatibility of the measurements relative to other space-based measurements of ozone. Coincident measurements were obtained from the Stratospheric Aerosol and Gas Experiment (SAGE) 2 instrument onboard the Earth Radiation Budget Satellite (ERBS) and three instruments, the Microwave Limb Sounder (MLS), the Cryogenic Limb Array Etalon Spectrometer (CLAES), the Halogen Occultation Experiment (HALOE) onboard the Upper Atmospheric Research Satellite (UARS). Three of the instruments, ATMOS, SAGE-2 and MLS are demonstrated to be consistent to within +10% over the altitude range between 100 hPa and 0.5 hPa (approximately 20 to 60 km), with ATMOS and MLS displaying a zero mean bias and a root mean square deviation (rms) of 3% and SAGE-2 displaying an essentially systematic bias of -5% over the majority of the altitude range, except for below 30 hPa where SAGE-2 displays a large positive systematic bias due to the effect of the aerosol attenuation resulting from the Mt. Pinatubo volcanic eruption in 1991. The comparison with HALOE indicates that ozone levels observed by ATMOS are systematically higher than HALOE by 5 to 25% with a clear gradient in the differences; in contrast the comparison with CLAES displays differences of as much as + 30% with no obvious systematic scaling possible. Comparisons are evaluated in two separate schemes, by geographical coincidence and through zonal averages which illustrate the limitations of both schemes. Latitudinal and longitudinal variation are used to assess the sensitivity of the ATMOS measurements and to confirm the precision and accuracy, which should be less than 4% and 10% respectively.

Abrams, M. C.↗
NASA NTRS1995

The use of LinkWinds for the validation and analysis of 14 years of Microwave Sounder Unit daily global temperature anomaly data

Temperature data derived from the Microwave Sounder Unit (MSU) provides an opportunity for investigating atmospheric temperatures on a global scale since 1979. Fourteen years of global data sets of daily temperature anomalies within the lower stratosphere and lower troposphere are being generated at NASA Marshall Space Flight Center. LinkWinds, a visualization/analysis package under development at NASA Jet Propulsion Laboratory, has been extremely useful for validating and analyzing these data sets. LinkWinds provides the ability to interactively scroll and animate through the 10,220 images of temporal data, to selectively slice and view the data along latitude, longitude, or temporal axes, to interactively analyze spatial and temporal variability within the data, and to perform correlative analysis between various elements of the data. These capabilities have been invaluable in allowing the recognition of processing artifacts, as well as the effects that physical phenomena, such as the El Ninos effects and the Mt. Pinatubo eruption, have had on atmospheric temperatures.

Botts, Michael E.↗
NASA NTRS1996

STS-72 Post Flight Presentation

In this post flight presentation video for the STS-72 mission, the flight crew, Cmdr. Brian Duffy, Pilot Brent Jett, and Mission Specialists Daniel T. Barry, Winston E. Scott, Leroy Chiao, and Koichi Wakata (NASDA), discuss their mission using flight footage and slides. The pre-launch and launching activities are shown. Using the robot arm inside the space shuttle's cargo bay, the Japanese Space Flyer Unit (SFU) is retrieved and berthed and the Office of Aeronautics and Space Technology (OAST) Flyer satellite is deployed, retrieved, and reberthed. Chiao and Barry performed the first of the two 6 1/2 hour EVAs and Chiao and Scott performed the second. In both EVAs, the thermal properties of the new space suits were tested, along with new tools and equipment that will eventually be used to build the International Space Station. Space shuttle landing activities are also shown. Earth views include cloud shadows, Africa, Brazil, Australia, and Mt. Kilimanjaro.

Peterson, Glen↗
NASA NTRS1995

STS-74 Post Flight Presentation

The flight crew of the STS-74 Space Shuttle Orbiter Atlantis (Cmdr. Ken Cameron, Pilot Jim Halsell, and Mission Specialists Chris Hadfield, Jerry Ross, and William McArthur) present an overview of their flight mission, whose primary objective was the rendezvous and space docking with the Russian Mir Space Station. Video film footage includes: prelaunch and launch activities; shuttle launch; installation of the Russian-made docking module to the orbiter; in-orbit rendezvous; in-orbit docking between Mir and the orbiter; general crew activities; transfer of supplies, equipment, and a crystal growth experiment to Mir; data collection of Mir thruster firings; undocking maneuvers and Mir fly around; pre-return checkout of flight systems; and reentry and landing of the orbiter. Earth views include horizon sunsets, atmospheric boundary layers, and a variety of geographical location footage (New Orleans; Atlanta; James Bay, Canada; Poland; Turkey; Mt. Pinatubo, Philippines; Salt Lake City, Utah; and Colorado).

Source record↗
NASA NTRS1996

STS-74 Mission Highlights Resource Tape

The flight crew of the STS-74 Space Shuttle Orbiter Atlantis Cmdr. Ken Cameron, Pilot Jim Halsell, and Mission Specialists Chris Hadfield, Jerry Ross, and William McArthur present an overview of their flight mission, whose primary objective is the rendezvous and space docking with the Russian Mir Space Station. Video film footage includes the following: prelaunch and launch activities; shuttle launch; in-orbit rendezvous; installation of the Russian-made docking module; in-orbit docking between Mir and the orbiter; general crew activities; transfer of supplies, equipment, and a crystal growth experiment to Mir; data collection from Mir thruster firings; undocking maneuvers and a Mir fly around; pre-return checkout of flight systems; and the reentry and landing of the orbiter. Earth views include horizon sunsets, atmospheric boundary layers, and a variety of geographical location footage (New Orleans; Atlanta; James Bay, Canada; Poland; Turkey; Mt. Pinatubo, Philippines; Salt Lake City, Utah; and Colorado).

Source record↗
NASA NTRS1994

Heterogeneous Reactions of ClONO2, HCl, and HOCl on Liquid Sulfuric Acid Surfaces

The heterogeneous reactions of ClONO2 + H2O yields HNO3 + HOCl (1), ClONO2 + HCl yields C12 + HNO3 (2), and HOCl + HCl yields Cl2 + H2O (3) on liquid sulfuric acid surfaces have been studied using a fast flow reactor coupled to a quadrupole mass spectrometer. The main objectives of the study are to investigate: (a) the temperature dependence of these reactions at a fixed H2O partial pressure typical of the lower stratosphere (that is, by changing temperature at a constant water partial pressure, the H2SO4 content of the surfaces is also changed), (b) the relative importance or competition between reactions 1 and 2, and (c) the effect of HNO3 on the reaction probabilities due to the formation of a H2SO4/HNO3/H2O ternary system. The measurements show that all the reactions depend markedly on temperature at a fixed H2O partial pressure: they proceed efficiently at temperatures near 200 K and much slower at temperatures near 220 K. The reaction probability (gamma(sub 1)) for ClONO2 hydrolysis approaches 0.01 at temperatures below 200 K, whereas the values for gamma(sub 2) and gamma(sub 3) are on the order of a few tenths at 200 K. Although detailed mechanisms for these reactions are still unknown, the present data indicate that the competition between ClONO2 hydrolysis and ClONO2 reaction with HCl may depend on temperature (or H2SO4 Wt %): in the presence of gaseous HCl at stratospheric concentrations, reaction 2 is dominant at lower temperatures (less than 200 K), but reaction 1 becomes important at temperatures above 210 K. Furthermore, reaction probability measurements performed on the H2SO4/HNO3/ H2O ternary solutions do not exhibit noticeable deviation from those performed on the H2SO4/H2O binary system, suggesting little effect of HNO3 in sulfate aerosols on the ClONO2 and HOCl reactions with HCl. The results reveal that significant reductions in the chlorine-containing reservoir species (such as ClONO2 and HCl) can take place on stratospheric sulfate aerosols at high latitudes in winter and early spring, even at temperatures too warm for Polar Stratospheric Clouds (PSCs) to form or in regions where nucleation of PSCs is sparse. This is particularly true under elevated sulfuric acid loading, such as that after the eruption of Mt. Pinatubo. Comparisons between our results and those presently available have also been made.

Zhang, Renyi↗
NASA NTRS1996

A New Method of Deriving Time-Averaged Tropospheric Column Ozone over the Tropics Using Total Ozone Mapping Spectrometer (TOMS) Radiances: Intercomparison and Analysis Using TRACE A Data

Error analysis of archived total 03 from total ozone mapping spectrometer (TOMS) (version 6) presented. Daily total 03 maps for the tropics, from the period October 6-21, 1992, are derived from TOMS radiances following correction for these errors. These daily maps, averaged together, show a wavelike feature, which is observed in all latitude bands, underlying sharp peaks which occur at different longitudes depending on the latitude. The wave pattern is used to derive both time-averaged stratospheric and tropospheric 03 fields. The nature of the wave pattern (stratospheric or tropospheric) cannot be determined with certainty due to missing data (no Pacific sondes, no lower stratospheric Stratospheric Aerosol and Gas Experiment (SAGE) ozone for 18 months after the Mt. Pinatubo eruption) and significant uncertainties in the corroborative satellite record in the lower stratosphere (solar backscattered ultraviolet (SBUV), microwave limb sounder (MLS)). However, the time- averaged tropospheric ozone field, based on the assumption that the wave feature is stratospheric, agrees within 10% with ultraviolet differential absorption laser Transport and Atmospheric Chemistry near the Equator-Atlantic) (TRACE A) 03 measurements from the DC-8 and with ozonesonde measurements over Brazzaville, Congo, Ascension Island, and Natal, Brazil, for the period October 6-21, 1992. The derived background (nonpolluted) Indian Ocean tropospheric ozone amount, 26 Dobson units (DU), agrees with the cleanest African ozonesonde profiles for September-October 1992. The assumption of a totally tropospheric wave (flat stratosphere) gives 38 DU above the western Indian Ocean and 15-40% disagreements with the sondes. Tropospheric column 03 is high from South America to Africa, owing to interaction of dynamics with biomass burning emissions. Comparison with fire distributions from advanced very high resolution radiometer (AVHHR) during October 1992 suggests that tropospheric 03 produced from biomass burning in South America and Africa dominates the 03 budget in the tropical southern hemisphere during the study period.

Kim, J. H.↗
NASA NTRS1997

Mid-Infrared Observational and Theoretical Studies of Star Formation and Early Solar Systems

The first 2 years of this program were used to make mid-IR observations of regions of star formation in the Orion nebula with the UCSD mid-IR camera at the UCSD/University of Minnesota telescope at Mt. Lemmon. These observations attempted to make the first systematic study of an extended region, known to have newly forming stars, and expected to have complex mid-IR emission. We discovered, to our surprise, that most of the thermal emission originated from extended sources rather than from point sources. This interesting observation made the analysis of the data much more complex, since the chop/nod procedures used at these wavelengths produce a differential measurement of the emission in one region compared to that in the adjacent region. Disentangling complex extended emission in such a situation is very difficult. In parallel with this work we were also observing comets in the thermal infrared, the other component of the original proposal. Some spectacular data on the comet Swift-Tuttle was acquired and published. A changing jet structure observed over a 2 week period is described. The rotation period of the comet can be measured at 66 hours. The size of the nucleus can also be estimated (at 30 km) from the observed excess flux from the nucleus. These data have lead to the development of models describing the action of dust particles of differing sizes and composition leaving the nucleus. The spatial distribution of the predicted IR emission has been compared to the observed jet structures, leading to estimates of both particles sizes, relative amounts of silicate vs organic grains, and the amounts of dust emitted in the jets vs isotopic emission.

Jones, Barbara↗