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At least 901 records · Page 50

Plagioclase feldspars - Visible and near infrared diffuse reflectance spectra as applied to remote sensing

Visible and near IR diffuse reflectance spectra of plagioclase feldspars are characterized by absorption features caused by minor amounts of Fe(2+) that occur bound in the crystal structure. It is found that identification of terrestrial feldspars by remote sensing appears to be feasible for the compositional range An50 to An80, providing that other minerals do not mask the feldspar signatures. Determination of plagioclase composition using the wavelength of the Fe(2+) band may be possible for lunar samples, where the plagioclase can be assumed to be more calcic than An65.

Adams, J. B.↗

Interplanetary dust: The interstellar connection

Although not proven, there is the widespread belief that comets consist, at least in part, of interstellar material that was originally present in the solar nebula. Furthermore, there are strong arguments in favor of the view that much of the interplanetary dust complex is derived from comets. The main arguments supporting this view are based on mass balance, analysis of the orbital parameters of meteors, and the long known association between meteor showers and specific comets. Laboratory measurements on interplanetary dust particles (IDPs) collected in the stratosphere have confirmed the view that many of the dust particles are primitive in the sense that they show striking enrichments of D/H relative to average solar system materials. It has also been demonstrated that the mid-infrared absorption spectra of one infrared red class of particles show strong similarities to IR sources such as the protostar W-33A. However, the laboratory studies of IDPs have shown that they represent a diverse set of objects and the measurement of the orbital parameters of specific dust particles is essential to answering the question of sources. The observation of the IRAS dust bands reopens the question of the role of asteroids in supplying a significant fraction of the dust and part of the diversity observed may be due to the fact that some of the dust is asteroidal and some cometary. In addition, some fraction of interplanetary dust must consist of an interstellar component intercepted by the solar system in its motion through the local interstellar medium. It has been shown that dust derived from nearby stars will have 75% of their orbits with eccentricities or equal to 1.1 and might be difficult to distinguish from interplanetary dust based on orbital measurements alone.

Carey, W. C.↗

Upper limits for stratospheric H2O2 and HOCl from high resolution balloon-borne infrared solar absorption spectra

Solar absorption spectra from two stratospheric balloon flights have been analyzed for the presence of H2O2 and HOCl absorption in the 1230.0 to 1255.0 per cm region. The data were recorded at 0.02 per cm resolution during sunset with the University of Denver interferometer system on October 27, 1978 and March 23, 1981. Selected spectral regions were analyzed with the technique of nonlinear least squares spectral curve fitting. Upper limits of 0.33 ppbv for H2O2 and 0.36 ppbv for HOCl near 28 km are derived from the 1978 flight data while upper limits of 0.44 ppbv for H2O2 and 0.43 ppbv for HOCl at 29.5 km are obtained from the 1981 flight data.

Larsen, J. C.↗

Concentrations of carbonyl sulfide and hydrogen cyanide in the free upper troposphere and lower stratosphere deduced from ATMOS/Spacelab 3 infrared solar occultation spectra

This paper presents the results on the volume mixing ratio profiles of carbonyl sulfide and hydrogen cyanide, deduced from the spectroscopic analysis of IR solar absorption spectra obtained in the occultation mode with the Atmospheric Trace Molecule Spectroscopy (ATMOS) instrument during its mission aboard Spacelab 3. A comparison of the ATMOS measurements for both northern and southern latitudes with previous field investigations at low midlatitudes shows a relatively good agreement. Southern Hemisphere volume mixing ratio profiles for both molecules were obtained for the first time, as were the profiles for the Northern Hemisphere covering the upper troposphere and the lower stratosphere simultaneously.

Zander, R.↗

Measurements of size and composition of particles in polar stratospheric clouds from infrared solar absorption spectra

Results are presented on polar stratospheric cloud (PSC) observations, based on IR measurements of solar extinction, made by the airborne JPL Mark IV interferometer during the Airborne Antarctic Ozone Expedition in 1987, together with the instrumentation and the theoretical aspects of data analysis. Thirty-three PSC cases were analyzed and categorized into two types, I and II, which were found to occur at different altitudes during September. Type I clouds, seen at altitudes above 15 km, contained particles with radii of about 0.5 micarons and nitric acid concentrations greater than 40 percent, while type II clouds, found usually below 15 km, contained particles with radii of 6 microns and larger, composed of water ice. In addition, particles of larger than the 15-micron-size detection limit were encounterd.

Kinne, S.↗

Long-term trends in the concentrations of SF6, CHClF2, and COF2 in the lower stratosphere from analysis of high-resolution infrared solar occultation spectra

Long-term trends in the concentrations of SF6, CHClF2 in the lower stratosphere are derived using results from analyses of the 1980 and of several more recently obtained IR solar occultation spectra. Results show that the increase rates of SF6 and CHClF2 were about 7.4/yr and 9.4/yr, respectively, which correspond to cumulative increases by factors of about 1.7 and 2.0 in the concentrations of these gases over the 7.2 yr measurement period. The average increase rate for COF2 was 10.3/yr over the same time period. The present results are compared with previously reported observations and trends and with one-dimensional model calculations.

Rinsland, C. P.↗

The dark side of Venus - Near-infrared images and spectra from the Anglo-Australian Observatory

Near-IR images and spectra of the night side of Venus taken at the Anglo-Australian Telescope during February 1990 reveal four new thermal emission windows at 1.10, 1.18, 1.27, and 1.31 microns, in addition to the previously discovered windows at 1.74 and 2.3 microns. Images of the Venus night side show similar bright and dark markings in all windows, but their contrast is much lower at short wavelengths. The 1.27-micron window includes a bright, high-altitude O2 airglow feature in addition to a thermal contribution from the deep atmosphere. Simulations of the 1.27- and 2.3-micron spectra indicate water vapor mixing ratios near 40 + or - 20 ppm by volume between the surface and the cloud base.

Crisp, D.↗

Spectral Irradiance Calibration in the Infrared: Calibrated Stellar Spectra Using Dirbe Radiometry - 9

The absolute calibration of the COBE/DIRBE data in the range 1-25 microns is examined through the in-band fluxes of DIRBE's own set of point-source calibration objects. Using the values of DIRBE fluxes expected for Sirius and for 10 of our published set of absolutely calibrated K and M giants that are in common with DIRBE's own calibration network, I find consistency with the project's formal basis, namely, our published calibrated spectrum of Sirius. This consistency means that one can use the DIRBE radiometry to construct absolutely calibrated "stellar templates" (i.e., continuous calibrated spectra from 1 to 35 microns) on the assumption that the intrinsic stellar spectrum of a star of given spectral class matches the intrinsic spectrum for the star of the same spectral class among the set of K and M giants, the spectrum of which has been absolutely defined. This technique is validated using a set of early M giants with well-characterized ground-based photometry and confirmed with IRAS low-resolution spectra.

Cohen, Martin↗