Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “H2O”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 901 records · Page 50
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Global lower mesospheric water vapor revealed by LIMS observations

The Limb Infrared Monitor of the Stratospheric water vapor channel data analysis has been extended from the 1. mb level (about 48 km) to the .3 mb level (about 60 km) through a radiance averaging procedure and better understanding of systematic errors. The data show H2O mixing ratio peaks near the .5 mb level varying from 4 to 7 ppmv with latitude and season. Above this level the mixing ratio drops off quickly with altitude, but, due to experimental uncertainties, at an uncertain rate. The stratospheric results are virtually the same as determined from the archived LIMS results with a tropical hygropause and enhanced H2O concentration in the lower levels at high winter latitudes.

Gordley, L. L.↗
NASA NTRS1986

Brown dwarfs and Jovian planets: A comparison

The recent detection of a subluminous companion to the M dwarf star VB8 has renewed interest in the characteristics of objects spanning the mass range from Jupiter to hydrogen burning stars. Atmospheric and interior models were constructed for objects in this mass regime, up to 30 Jupiter masses, with emphasis on understanding the relationship of brown dwarfs such as the VB8 companion to the better-studied Jovian planets. The atmospheric model solves the equation of radiative transfer assuming frequency dependent molecular opacity sources H2, He, H2O, CO, and CH4 which are important by virtue of the high cosmic abundance of their constituent atoms. Condensation of cosmochemically important materials, iron and silicates, in the atmosphere is possible, and the effect of such grains as opacity sources is assessed. The luminosity of the object is presumed due to degenerate cooling following a collapse phase and possibly deuterium burning and an interior model is constructed using as an outer boundary condition the temperature and pressure level at which the atmosphere becomes convective. The interior model is analogous to Jupiter, with a large liquid metallic-hydrogen core and a thinner molecular-hydrogen envelope. The oxidation state of carbon in the outer envelope of a brown dwarf of similar age to Jupiter is a function of the object's mass. This makes the wavelength dependence of the atmospheric opacity sensitive to the carbon to oxygen ratio, since the abundance of the primary source of molecular opacity, H2O, decreases as more oxygen is tied up as CO.

Lunine, J. I.↗
NASA NTRS1986

Airborne infrared investigation of water in the coma of Halley's Comet

An infrared Fourier transform spectrometer on the Kuiper Airborne Observatory (KAO) was used to obtain high resolution spectra of the intense, solar-pumped infrared fluorescent emission in the (001 to 000) band of H2O near 2.6 microns. Differences between the observed H2O excitation and original expectations are discussed, and KAO water production rates are compared to those derived from International Ultraviolet Explorer observations. Possible future directions for high resolution IR spectroscopy of comets are discussed.

Weaver, Harold A.↗
NASA NTRS1986

Ion morphology in the inner tail of Comet P/Halley

Comet Halley CCD images taken in the light of CO(+) and H2O(+) were analyzed. Most of the ionic emission originates in a diffuse component on which the ion ray structure appears to be superimposed. On average, the peak enhancement in the CO(+) rays is 20% over the adjacent minima, where the emission is due to the underlying component. The H2O(+):CO(+) ratio varies by as much as 30% from ray to ray.

Hoban, Susan↗
NASA NTRS1987

Interaction of transient radiation in nongray gaseous systems

A general formulation is presented to investigate the transient radiative interaction in nongray absorbing-emitting species between two parallel plates. Depending on the desired sophistication and accuracy, any nongray absorption model from line-by-line models to the wide band model correlations can be employed in the formulation to investigate the radiative interaction. Special attention is directed to investigate the radiative interaction in a system initially at a uniform reference temperature and suddenly the temperature of the bottom plate is reduced to a lower but constant temperature. The interaction is considered for the case of radiative equilibrium as well as for combined radiation and conduction. General as well as limiting forms of the governing equations are presented and solutions are obtained numerically by employing the method of variation of parameters. Specific results are obtained for CO, CO2, H2O, and OH. The information on species H2O and OH is of special interest for the proposed scramjet engine application. The results demonstrate the relative ability of different species for radiative interactions.

Tiwari, S. N.↗
NASA NTRS1985

Rocket observation of the ultraviolet spectrum of Comet Halley

An ultraviolet sounding rocket telescope/spectrograph experiment observed Comet Halley on Feb. 26, 1986, 17 days after perihelion. From the long-slit spectra, the production rates of O, C, and CO are calculated. The derived water production rate is a lower limit of 5.0 x 10 to the 29th/s and the volume mixing ratio of CO to H2O is 21 percent. The predicted brightness distribution from a radial outflow model with H2O and CO as parent molecules are in accordance with the measured spatial profiles of O I and CO emissions. The ratio of the production rates of CO to C is 2.7 which is consistent with the carbon source being the photodissociation of CO. However, the radial outflow model which best fits the CO data predicts significantly weaker C I emissions than was observed. A better fit to the carbon data is found when an inner coma source of C at a rate of 3 percent of the water production rate is included in the model.

Woods, T. N.↗
NASA NTRS1987

Transient radiative energy transfer in nongray gases

A general formulation is presented to investigate the transient radiative interaction in nongray absorbing-emitting species between two parallel plates. Special attention is directed to investigate the radiative interaction in a system initially at a uniform reference temperature where suddenly the temperature of the bottom plate is reduced to a lower but constant temperature. The interaction is considered for the case of radiative equilibrium as well as for combined radiation and conduction. General as well as limiting forms of the govering equations are presented and solutions are obtained numerically by employing the method of variation of parameters. Specific results are obtained for CO, CO2, H2O, and OH. The information on species H2O and OH is of special interest for the proposed scramjet engine application. The results demonstrate the relative ability of different species for radiative interactions.

Tiwari, S. N.↗
NASA NTRS1986

Vibrational and rotational cooling of electrons by water vapor

The cooling of electrons by vibrational and rotational excitation of water molecules plays an important role in the thermal balance of electrons in cometary ionospheres. The energy-loss function for rotational excitation and deexcitation of H2O by electron impact is calculated theoretically. The rotational cooling rate is calculated using this loss function for a wide range of electron and neutral temperatures. The vibrational cooling rate is calculated using measured values of electron-impact vibrational excitation cross sections. Analytical formulas are provided for some of the cooling rates. The interaction of ions with H2O molecules is also discussed, and a formula is suggested for the momentum-transfer collision frequency.

Cravens, T. E.↗
NASA NTRS1986

Rocket ultraviolet spectroscopy of comet Halley and abundance of carbon monoxide and carbon

Two far ultraviolet observations of comet Halley made on 26 February, 1986 and 13 March, 1986 with a sounding rocket experiment are reported. The observed CO spatial profiles can be modelled by a radial outflow model for a parent molecule and suggest that the CO is produced directly from the nucleus of the comet. Using the observed O I emission profile to deduce the H2O production rate, the abundance of CO relative to H2O is found to be 20 percent + or - 5 percent for the first flight and 17 percent + or - 4 percent for the second flight, making CO the second most abundant parent molecule in the coma. The derived production rate of atomic carbon is consistent with that expected from the photodissociation of carbon monoxide.

Woods, T. N.↗
NASA NTRS1987

Ultraviolet spectrophotometry of Comet Giacobini-Zinner during the ICE encounter

The IUE's UV spectrophotometer was used to monitor Comet Giacobini-Zinner's H2O production rate from June to October, 1985, in support of the International Cometary Explorer (ICE) mission. Observation results for the spatial and temporal variation and the abundance or upper limits of C, CO, CO(+), CO2(+), CS, H, Mg(+), O, OH, and S, between September 9 and 12, included the time of the ICE encounter: at this time, the H2O production rate obtained was consistent with a number of gas production rates derived indirectly from the ICE experiments. A comparison of the CO2(+) ion abundance with the total electron density measured by the plasma electron and radio science experiments on ICE implies an ion deficiency relative to electrons, so that the satisfaction of charge balance criteria requires the presence of a major ion population not detected by remote sensing.

Mcfadden, Lucy A.↗
NASA NTRS1987

Thermal ion perturbations observed in the vicinity of the Space Shuttle

Thermal ion characteristics in the vicinity of the Space Shuttle, derived from RF spectrometer measurements of the Plasma Diagnostic Package (PDP) flown aboard Spacelab 2, are discussed. During the Reaction Control System firings, short pulses of enhanced ion fluxes of NO(+), O2(+), and H2O(+) were detected in the near wake within and in near proximity to the open payload. During the release of the PDP as a free flying satellite, the spin modulation of the ion fluxes in the ion spectrometer indicated the presence of plasma streams of O(+) and H2O(+) which were separated in direction by as much as 77 deg. It is concluded that the presence of contaminant NO and O2(+) ions makes the near environment of the Shuttle an unsuitable place for obtaining accurate ambient ion concentration measurements.

Grebowsky, J. M.↗
NASA NTRS1987

Vertical constituent transport in the mesosphere

Ground-based microwave spectroscopy measurements of mesospheric CO and H2O vertical mixing ratio profiles are used to infer vertical mixing rates in the upper mesosphere. The CO and H2O data consistently imply vertical eddy diffusion coefficients in the 70- to 85-km region of 100,000-200,000 sq cm/s during spring through summer at midlatidues. Although chemical acceleration of vertical transport is substantial for O and O3, below the mesopause, the divergences of their associated fluxes are modest, with at most a factor of 2 effect on the concentrations of O and O3 for measured variability in gravity wave activity. Comparison of Solar Mesosphere Explorer (SME) O3 data with model results reinforces the conclusions of slow vertical mixing in the upper mesosphere as a consequence of the reduced HO(x) catalytic loss of odd oxygen. The changes in chemical rate constants recommended by Rusch and Eckman (1985), in conjunction with slow vertical mixing, yield good agreement with SME O3 data. The slow vertical mixing deduced in this study is consistent with upper limits obtained from studies of the mesospheric heat budget and could be construed as evidence for an advectively controlled mesosphere. A comparison of the vertical eddy diffusion coefficients for momentum stresses, constituent transport, and heat transport suggests that the eddy Prandtl number must be of order 10.

Strobel, Darrell F.↗
NASA NTRS1987

Optical observations related to the molecular chemistry in diffuse interstellar clouds

Observations, which have been published since 1979, of molecular species in diffuse clouds are discussed. Particular attention is given to the ultraviolet measurements of CO with the Copernicus and IUE satellites and to ground-based optical measurements of CH, CH(+), CN, and 02. These data encompass large enough samples to test the chemical schemes expected to occur in diffuse clouds. Upper limits for other species (e.g., H2O, H2O(+), and C3) place restrictions on the pathways for molecular production. Moreover, analysis of the rotational distribution of the C2 molecule results in the determination of the physical conditions of the cloud. These parameters, including density, temperature, and the intensity of the radiation field, are necessary for modeling the chemistry.

Federman, S. R.↗
NASA NTRS1987

Measurement of stratospheric trace constituent distributions from balloon-borne far infrared observations

FIR limb thermal emission spectra obtained from balloon-borne measurements made as a part of the Balloon Intercomparison Campaign (BIC) have been analyzed for retrieval of stratospheric trace-constituent distributions. The measurements were made with a high-resolution Michelson interferometer and covered the 15-180/cm spectral range with an unapodized spectral resolution of 0.0033/cm. The retrieved vertical profiles of O3, H2O, HDO, HCN, CO, and isotopes of O3 are presented. The results are compared with the BIC measurements for O3 and H2O made from the same balloon gondola and with other published data. A comparison of the simultaneously retrieved profiles for several gases with the published data shows good agreement and indicates the validity of the FIR data and retrieval techniques and the accuracy of the inferred profiles.

Abbas, M. M.↗
NASA NTRS1988

Laboratory studies of sticking coefficients and heterogeneous reactions important in the Antarctic stratosphere

Laboratory studies of sticking coefficients of H2O, HCl, Cl2, and HNO3 on ice and heterogeneous reactions of ClONO2 with ice or HCl/ice have been performed in a fast flow reactor. A quadrupole mass spectrometer with electron impact ionization was used as a detector. Measured sticking coefficients are: 0.3 (+0.7, -0.1) for H2O, 0.4 (+0.6, -0.2) for HCL, less than 0.0001 for Cl2, and 0.3 (+0.7, -0.1) for HNO3 at 200 K. The reaction probability of ClONO2 on ice was found to be 0.06 (+ or - 0.03) while HOCl was observed as a sole product in the gas phase. With HCl present in ice, the reaction probability of ClONO2 is greatly enhanced, approaching 0.27 (+0.73, -0.13) while molecular chlorine was found to be the major product in the gas phase. Another reaction product was nitric acid which remained in the solid phase. Since the polar stratospheric clouds contain ice particles or possibly HCl/ice particles on the surface, the present results should be a major factor in producing the observed springtime ozone depletion in the Antarctic stratosphere.

Leu, Ming-Taun↗
NASA NTRS1988

The ice band in IRAS 09371 + 1212

Spectra from 2 to 4 microns of the unusual IRAS source 09371 + 1212, a bipolar nebula, reveal a deep H2O ice absorption band near 3.1 microns. No long-wavelength wing is present, implying that the absorbing grain mantles are of high purity. The structure of the absorption feature is reasonably well modeled by a mixture of amorphous and crystalline H2O ice mantles on silicate grains, but discrepancies remain that could indicate other absorbers also.

Geballe, T. R.↗
NASA NTRS1988

SiH and the unidentified 4.6 micron feature

Results from experimental studies of the irradiation of SiH4-H2O and Fe(CO)5-SiH4-H2O ice mixtures at 15 K using 1 MeV protons have revealed the synthesis of a very stable infrared spectral feature at 4.6 microns which is characteristic of the SiH functional group. This feature persists through warmup of the ice, exposure to air at 300 K, and vacuum annealing to at least 400 K. Because of the high cosmic abundance of both silicon and hydrogen and the unexpected stability of the SiH feature in our experiments, it is suggested that SiH might be responsible for the 4.6 micron absorption feature observed in W33A.

Nuth, Joseph A.↗
NASA NTRS1988

Cloud microphysics of the giant planets

The characteristic time constants for the atmospheres of the giant planets were compared for the purpose of finding analogs for clouds in the atmospheres of these planets among the several types of cloud systems found on earth. The NH3 clouds on Jupiter and Saturn were found to be weakly precipitating systems, similar to the thicker cirrus clouds on earth, while the H2O clouds were found to be much more massive than the water clouds on earth. The CH4 and H2O clouds on Uranus and Neptune are completely unlike any cloud on earth, being 10 to 100 times more massive than the densest water clouds on earth. It is concluded that, while the microphysical characteristics of the clouds on Jupiter and Saturn are comparable to those of terrestrial stratus and cumulus clouds, the massive clouds on Uranus and Neptune reach conditions unlike anything on earth.

Carlson, Barbara E.↗