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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 901 records · Page 50

Matrix spectroscopic studies of chlorine atom-ozone reaction products

A spectroscopic study is presented of the matrix-isolated products of the direct combination reaction of chlorine atoms with ozone and of the microwave discharge reaction of chlorine and oxygen. Infrared spectra in the wavenumber range 2000 to 200 per cm were recorded for reaction products trapped by the condensation of a matrix of solid argon. Evidence for the formation of the ClO radical as well as the ClOO and ClClO radicals during the direct chlorine-ozone reaction is obtained, however no evidence is found for the presence of asymmetric ClO3 under conditions thought favorable for its formation. The ClO molecule is also observed following the microwave discharge reaction of chlorine and oxygen in argon in the isotopic forms (Cl-35)(O-16), (Cl-37)(O-16), (Cl-35)(O-18), and (Cl-37)(O-18). It is noted that the vibrational frequency for the (Cl-35)(O-16) radical at 849.2 per cm is blue-shifted 5 per cm above its gas-phase fundamental.

Carter, R. O., III↗

Experimental investigation of a variable speed constant frequency electric generating system from a utility perspective

As efforts are accelerated to improve the overall capability and performance of wind electric systems, increased attention to variable speed configurations has developed. A number of potentially viable configurations have emerged. Various attributes of variable speed systems need to be carefully tested to evaluate their performance from the utility points of view. With this purpose, the NASA experimental variable speed constant frequency (VSCF) system has been tested. In order to determine the usefulness of these systems in utility applications, tests are required to resolve issues fundamental to electric utility systems. Legitimate questions exist regarding how variable speed generators will influence the performance of electric utility systems; therefore, tests from a utility perspective, have been performed on the VSCF system and an induction generator at an operating power level of 30 kW on a system rated at 200 kVA and 0.8 power factor.

Herrera, J. I.↗

Oscillations in sunspots

Recent observational and theoretical work on oscillations in sunspots is reviewed. The characteristic 3-minute umbral oscillations and flashes are resonant modes of the sunspot itself, whereas the 5-minute oscillations in the umbra are a passive response to forcing by p modes in the surrounding convection zone. The observational evidence suggests that the fundamental cause of the 3-minute oscillations is the photospheric fast-mode resonance, with chromospheric slow-mode resonances perhaps producing additional oscillation frequencies in the chromosphere. Observations and theoretical models of the interaction of 5-minute p-mode oscillations with a sunspot offer a means of probing the structure of a sunspot magnetic flux tube beneath the solar surface. The observed differences between running penumbral waves in the chromosphere and in the photosphere may be explained by the effect of the Evershed flow on trapped magneto-atmospheric waves in the penumbra.

Thomas, J. H.↗

A seal test facility for the measurement of isotropic and anisotropic linear rotordynamic characteristics

A new seal test facility for measuring high-pressure seal rotor-dynamic characteristics has recently been made operational at Case Western Reserve University (CWRU). This work is being sponsored by the Electric Power Research Institute (EPRI). The fundamental concept embodied in this test apparatus is a double-spool-shaft spindle which permits independent control over the spin speed and the frequency of an adjustable circular vibration orbit for both forward and backward whirl. Also, the static eccentricity between the rotating and non-rotating test seal parts is easily adjustable to desired values. By accurately measuring both dynamic radial displacement and dynamic radial force signals, over a wide range of circular orbit frequency, one is able to solve for the full linear-anisotropic model's 12 coefficients rather than the 6 coefficients of the more restrictive isotropic linear model. Of course, one may also impose the isotropic assumption in reducing test data, thereby providing a valid qualification of which seal configurations are well represented by the isotropic model and which are not. In fact, as argued in reference (1), the requirement for maintaining a symmetric total system mass matrix means that the resulting isotropic model needs 5 coefficients and the anisotropic model needs 11 coefficients.

Adams, M. L.↗

STS-87 Mission Highlights Resources Tape

The STS-87 mission the flight crew, Commander Kevin R. Kregel, Pilot Steven W. Lindsey, Mission Specialists Winston E. Scott, Kalpana Chawla, and Takao Doi, and Payload Specialist Leonid K. Kadenyuk present an overview of there mission. STS-87 will fly the United States Microgravity Payload (USMP-4), the Spartan-201, the Orbital Acceleration Research Experiment (OARE), the EVA Demonstration Flight Test 5 (EDFT-05). The objective of the observations are to investigate the mechanisms causing the heating of the solar corona and the acceleration of the solar wind which originates in the corona. While flying separately in the cargo bay, the Orbital Acceleration Research Experiment (OARE) is an integral part of USMP-04. It is a highly sensitive instrument designed to acquire and record data of low-level aerodynamic acceleration along the orbiter's principal axes in the free-molecular flow regime at orbital altitudes and in the transition regime during re-entry. OARE data will support advances in space materials processing by providing measurements of the low-level, low frequency disturbance environment affecting various microgravity experiments. OARE data will also support advances in orbital drag prediction technology by increasing the understanding of the fundamental flow phenomena in the upper atmosphere.

Source record↗

Low-Power Radio-Frequency SiGe Analog-to-Digital Converter

A low-power, radio-frequency analog-to-digital converter (RF-ADC) for soil moisture remote sensing was designed and fabricated. The RF-ADC is the fundamental component used in a direct-sampling digital radiometer, which is proposed to minimize the power dissipation and system complexity for synthetic thinned array radiometer. The circuit was implemented using 0.8 micron 35-GHz silicon germanium BiCMOS technology. The total power dissipation was 222 mW.

Thompson, Willie L, II↗

Performance Enhancement of Tunable Bandpass Filters Using Selective Etched Ferroelectric Thin Films

The inclusion of voltage-tunable barium strontium titanate (BSTO) thin films into planar band pass filters offers tremendous potential to increase their versatility. The ability to tune the passband so as to correct for minor deviations in manufacturing tolerances, or to completely reconfigure the operating frequencies of a microwave communication system, are highly sought-after goals. However, use of ferroelectric films in these devices results in higher dielectric losses, which in turn increase the insertion loss and decrease the quality factors of the filters. This study explores the use of patterned ferroelectric layers to minimize dielectric losses without degrading tunability. Patterning the ferroelectric layers enables us to constrict the width of the ferroelectric layers between the coupled microstrip lines, and minimize losses due to ferroelectric layers. Coupled one-pole microstrip bandpass filters with fundamental resonances at approx. 7.2 GHz and well defined harmonic resonances at approx. 14.4 and approx. 21.6 GHz, were designed, simulated and tested. For one of the filters, experimental results verified that its center frequency was tunable by 528 MHz at a center frequency of 21.957 GHz, with insertion losses varying from 4.3 to 2.5 dB, at 0 and 3.5 V/micron, respectively. These data demonstrate that the tuning-to-loss figure of merit of tunable microstrip filters can be greatly improved using patterned ferroelectric thin films as the tuning element, and tuning can be controlled by engineering the ferroelectric constriction in the coupled sections.

Miranda, Felix A.↗

Unidirectional amplification in the frozen mode regime enabled by a nonlinear defect

A stationary inflection point (SIP) is a spectral singularity of the Bloch dispersion relation ω(k) of a periodic structure where the first and the second derivatives of ω with respect to k vanish. An SIP is associated with a third-order exceptional point degeneracy in the spectrum of the unit-cell transfer matrix, where there is a collapse of one propagating and two evanescent Bloch modes. At the SIP frequency, the incident wave can be efficiently converted into the frozen mode with greatly enhanced amplitude and vanishing group velocity. This can be very attractive for applications, including light amplification. Due to its non-resonant nature, the frozen mode regime (FMR) has fundamental advantages over common cavity resonances. Furthermore, we propose, a novel, to the best of our knowledge, scheme for FMR-based unidirectional amplifiers by leveraging a tailored amplification/attenuation mechanism and a single nonlinear defect. The defect breaks the directional symmetry of the periodic structure and enables nonlinearity-related unidirectional amplification/attenuation in the vicinity of the SIP frequency. We demonstrate the robustness of the amplification mechanism to local impurities and parasitic nonlinearity.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Generalizing Similarity Laws for Radio-Frequency Discharge Plasmas across Nonlinear Transition Regimes

We generalize similarity theory based on the scaling and solution invariance of the Boltzmann equation, coupled with the Poisson equation, and demonstrate similarity laws for radio-frequency (rf) discharge plasmas across three nonlinear transitional regimes, namely, the alpha-gamma mode transition, the stochastic-Ohmic-heating mode transition, and the bounce-resonance-heating mode transition. Fundamental plasma parameters, e.g., the electron power absorption, under similar discharge conditions are examined via fully kinetic particle-in-cell simulations, and electron-kinetic invariance is exemplified in similar rf discharge plasmas. The results unambiguously confirm the applicability of similarity laws for rf plasmas in extended operating regimes, and strengthen the foundations and framework of similarity physics with universality.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Ambient Ion Trapping and Separations for High Throughput Structurally Selective Material Deposition

While ion mobility coupled to mass spectrometry (IMS/MS) has been increasingly adapted to biological analysis, the structural and molecular specificity offered by IMS/MS has untapped potential for creating novel materials (for energy, catalysis, biomolecular switches etc.) with rationally tailored properties by precisely controlling the chemical structure and composition of these materials. While electrochemical and catalytic properties of the bulk material are understood by mass-selective ion-soft-landing, different structures of one molecule can exhibit distinct properties from the bulk. Many biological phenomenon occur at interfaces and are highly structurally specific. IMS/MS offers means to separate molecules in a sample (which is first ionized and released to gas phase from the condensed phase) based on mass and structure. Species thus separated can potentially be deposited onto surfaces with molecular and structural specificity, to perform fundamental investigations for understanding critical interfacial phenomenon. Key performance metrics for IMS/MS analysis are resolution of separations and sensitivity. Recently developed Structures for Lossless Ion Manipulations (SLIM)4 enabled unprecedented resolution in IMS separations. In addition, high sensitivity was enabled in SLIM due to lossless confinement of ions using radio frequency fields. Thus, SLIM enabled extremely long path length separations (up to 0.1 km thus far) providing efficient separation of molecular ions never before achieved (e.g. isotopologues, D&L amino acids). While SLIM has unprecedented analytical separations power/utility, the use of SLIM platform for depositing mobility and mass selected molecular ions has two specific technological challenges: (a) Pulsed nature of IMS separations and their low duty cycle and (b) the need for a low vacuum of ~4 torr for lossless ion confinement. These limitations lead to long deposition times due to loss of ions generated from the sample. Enabling ion confinement at atmospheric pressure will be path-breaking contribution to the fundamental understanding of ion manipulations and separations and will also enable novel science currently precluded due to the inability of the present technologies to confine ions under ambient conditions. Traditionally used radio frequency fields are ineffective in confining ions at high pressures due to ion/neutral collisions. To address these, we propose to (a) develop methods for confining and manipulating ions for lossless IMS separations at atmospheric pressure enabling high sensitivity and throughput and (b) use the high specificity of IMS/MS and high throughput from ambient ion confinement to perform mobility and mass selective ion deposition at atmospheric pressure. Our goal is to enable the study of the fundamental properties of energy/catalysis materials and biomolecules. This project paves the way for high-throughput, mass and structure selective material deposition for highly specific surface creation/functionalization (discussed in Section 2 of the report). Further, the developments reported continue to push the boundaries of this process to ambient conditions (discussed in Section 3 of the report). We conclude with a list of specific intellectual property and publications which have been the outcome of this funded project.

36 MATERIALS SCIENCE↗

Evaluating Scalograms for Seismic Event Denoising

Denoising contaminated seismic signals for later processing is a fundamental problem in seismic signals analysis. The most straightforward denoising approach, using spectral filtering, is not effective when noise and seismic signal occupy the same frequency range. Neural network approaches have shown success denoising local signal when trained on short-time Fourier transform spectrograms (Zhu et al 2018; Tibi et al 2021). Scalograms, a wavelet-based transform, achieved ~15% better reconstruction as measured by dynamic time warping on a seismic waveform test set than spectrograms, suggesting their use as an alternative for denoising. We train a deep neural network on a scalogram dataset derived from waveforms recorded by the University of Utah Seismograph Stations network. We find that initial results are no better than a spectrogram approach, with additional overhead imposed by the significantly larger size of scalograms. A robust exploration of neural network hyperparameters and network architecture was not performed, which could be done in follow on work.

58 GEOSCIENCES↗

Chemical and Optical Control of Spin Crossover: Ultrafast XUV Spectroscopy of Molecular Magnets in Native Solvation Environments

With support from the US Department of Energy Office of Science, we have developed and utilized extreme ultraviolet (XUV) spectroscopy and sum frequency generation vibrational spectroscopy as probes of charge, spin, and solvation structure and dynamics in molecules and at interfaces. This work is crucial to advancing fundamental understanding of the processes that control the efficiency and speed of energy conversion and information processing in molecules and at interfaces. Accordingly, it has important applications for developing next generation technologies for information storage and processing with increasing data storage density and processing rates as well as developing new methods for efficient energy conversion and storage.

74 ATOMIC AND MOLECULAR PHYSICS↗

Public values failure associated with Hurricane Ian power outages

Power outages from extreme weather events can diminish community resilience, making it difficult for the areas impacted to bounce back after such events. For socially vulnerable populations, the frequency and duration of power outages can be even more severe. Governments have an obligation to protect public values, or those values that are most fundamental to society, which includes equitable resilience. Using Jørgensen and Bozeman's inventory of public values, this manuscript explores how power outages from extreme weather events create public values failures. More specifically, the manuscript evaluates intraorganizational aspects of public administration during power outages in Florida during Hurricane Ian in 2022. Framing power outages as a public values failure may motivate greater time and effort toward improving equitable access to more resilient power systems.

Entress, Rebecca M.↗

The local dispersion relation for magneto-atmospheric waves

The local dispersion relation for magneto-atmospheric waves is discussed in terms of the linearized theory of waves in a plane-stratified, inviscid, perfectly conducting atmosphere under uniform gravity. The normally used local dispersion relation is demonstrated to not be unique, depending instead on the order of derivation from the fundamental first-order perturbation equations of continuity, momentum, energy, and induction. Furthermore, it is shown that the local dispersion relation predicts that the cutoff frequency decreases with increasing magnetic field strength, while the WKB approximation method projects an increase in the cutoff frequency with increasing magnetic field strength. A new form of the local dispersion relation is developed, and consideration is given to the special case of a global dispersion relation in conditions of an isothermal atmosphere with a horizontal magnetic field.

Thomas, J. H.↗

Evanescent pressure gradient response in the upper ocean to subinertial wind stress forcing of finite wavelength

A schematic model is used to interpret field observations related to the mixed layer response to wind stress at subinertial frequencies. It is shown that subinertial density and pressure fluctuations can arise locally from the finite wavelength character of the wind stress forcing as a fundamental part of the upper ocean transient, wind-driven response on time scales of 2-10 pendulum days. Evanescent vertical motions arise which alter the density field of the pycnocline, and hence the pressure field over the entire upper ocean. It is thus found that in the real ocean driven by wind stress, a transient geostrophic response exists which can be as large or larger than the transient Eckman response.

White, Warren B.↗

Asteroseismology of the DOV star PG 1159 - 035 with the Whole Earth Telescope

Results are reported from 264.1 hr of nearly continuous time-series photometry on the pulsating prewhite dwarf star (DPV) PG 1159 - 035. The power spectrum of the data set is completely resolved into 125 individual frequencies; 101 of them are identified with specific quantized pulsation modes, and the rest are completely consistent with such modal assignment. It is argued that the luminosity variations are certainly the result of g-mode pulsations. Although the amplitudes of some of the peaks exhibit significant variations on the time scales of a year or so, the underlying frequency structure of the pulsations is stable over much longer intervals. The existing linear theory is invoked to determine, or strongly constrain, many of the fundamental physical parameters describing this star. Its mass is found to be 0.586 solar mass, is rotation period 1.38 days, its magnetic field less than 6000 G, its pulsation and rotation axes to be aligned, and its outer layers to be compositionally stratified.

Winget, D. E.↗

Modeling Pilot Pulse Control

In this study, behavioral models are developed that closely reproduced pulsive control response of two pilots from the experimental pool using markedly different control techniques (styles) while conducting a tracking task. An intriguing find was that the pilots appeared to: 1) produce a continuous, internally-generated stick signal that they integrated in time; 2) integrate the actual stick position; and 3) compare the two integrations to issue and cease pulse commands. This suggests that the pilots utilized kinesthetic feedback in order to perceive and integrate stick position, supporting the hypothesis that pilots can access and employ the proprioceptive inner feedback loop proposed by Hess' pilot Structural Model. The Pulse Models used in conjunction with the pilot Structural Model closely recreated the pilot data both in the frequency and time domains during closed-loop simulation. This indicates that for the range of tasks and control styles encountered, the models captured the fundamental mechanisms governing pulsive and control processes. The pilot Pulse Models give important insight for the amount of remnant (stick output uncorrelated with the forcing function) that arises from nonlinear pilot technique, and for the remaining remnant arising from different sources unrelated to tracking control (i.e. neuromuscular tremor, reallocation of cognitive resources, etc.).

workload↗

Time and Laser Ranging: A Window of Opportunity for Geodesy, Navigation, and Meteorology

Recent progress in the domain of time and frequency (T/F) standards requires important improvements in existing timedistribution links, in term of accuracy in particular. Satellite Laser Ranging (SLR) has proven to be a fundamental tool,offering a straightforward, conceptually simple, highly accurate, and unambiguous observable. Several time transfers by laserlink projects have been carried out over the past 10 years with numerous scientific and metrological objectives. Depending on the mission, SLR is used to transmit time over two-way or one-way distances from 500 to several millions of kilometers.The following missions and their objectives employed this technique: European Laser Timing (ELT, expected in 2020) at 450 km, Time Transfer by Laser Link (T2L2) at 1336 km, Laser Time Transfer at 36,000 km, Lunar Reconnaissance Orbiter at 350,000 km, and MErcury Surface, Space ENvironment, GEochemistry, and Ranging at tens of million km. This article describes the synergy between SLR and T/F technologies developed on the ground and in space and as well as the state of the art of their exploitation. The performance and sources of limitation of such space missions are analyzed. It shows that currentand future challenges lie in the improvement in the time accuracy and stability of the time for ground geodetic observatories.The role of the next generation of SLR systems is emphasized both in space and at ground level, from the point of view of Global Geodetic Observing System and valuable exploitation of the synergy between time synchronization, ranging, and data transfer.

Laser ranging↗