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At least 901 records · Page 50

Stress Testing of the Philips 60W Replacement Lamp L Prize Entry

The Pacific Northwest National Laboratory, operated by Battelle for the U.S. Department of Energy, worked with Intertek to develop a procedure for stress testing medium screw-base light sources. This procedure, composed of alternating stress cycles and performance evaluation, was used to qualitatively compare and contrast the durability and reliability of the Philips 60W replacement lamp L Prize entry with market-proven compact fluorescent lamps (CFLs) with comparable light output and functionality. The stress cycles applied simultaneous combinations of electrical, thermal, vibration, and humidity stresses of increasing magnitude. Performance evaluations measured relative illuminance, x chromaticity and y chromaticity shifts after each stress cycle. The Philips L Prize entry lamps appear to be appreciably more durable than the incumbent energy-efficient technology, as represented by the evaluated CFLs, and with respect to the applied stresses. Through the course of testing, all 15 CFL samples permanently ceased to function as a result of the applied stresses, while only 1 Philips L Prize entry lamp exhibited a failure, the nature of which was minor, non-destructive, and a consequence of a known (and resolved) subcontractor issue. Given that current CFL technology appears to be moderately mature and no Philips L Prize entry failures could be produced within the stress envelope causing 100 percent failure of the benchmark CFLs, it seems that, in this particular implementation, light-emitting diode (LED) technology would be much more durable in the field than current CFL technology. However, the Philips L Prize entry lamps used for testing were carefully designed and built for the competition, while the benchmark CFLs were mass produced for retail sale—a distinction that should be taken into consideration. Further reliability testing on final production samples would be necessary to judge the extent to which the results of this analysis apply to production versions of the Philips L Prize entry.

L Prize↗

LOWERING THE LEVELIZED COST OF ELECTRICITY OF A CONCENTRATING SOLAR POWER TOWER WITH A SUPERCRITICAL CARBON DIOXIDE POWER CYCLE

In order to maintain viability as a future power-generating technology, concentrating solar power (CSP) must reduce its levelized cost of electricity (LCOE). The cost of CSP is assessed with the System Advisor Model (SAM) from the National Renewable Energy Laboratory (NREL). The performance of an integrally geared compressor-expander recuperated recompression cycle with supercritical carbon dioxide (sCO2) as the working fluid is modeled. A comparison of the cycle model to the integrated SAM cycle performance is made. The cycle model incorporates innovative cycle control methods to improve the range of efficiency, including inventory control. The SAM model is modified to accommodate the predicted cycle performance. The ultimate goal of minimizing the LCOE is targeted through multiple approaches, including the cost of the power block, the impact of system scale, the sizing of the thermal system relative to the power block system, the operating approach for changes in ambient temperature and availability of sunlight. Through reduced power block cost and a detailed cycle model, the LCOE is modeled to be 5.98 ¢/kWh, achieving targeted techno-economic performance. The LCOE of the CSP system is compared to the cost of hybrid solar and fossil-fired systems. An analysis is made on the efficacy of a fossil backup system with CSP and how that relates to potential future costs of carbon dioxide emissions

schmitt, josh↗

Robust dynamic operation of high temperature electrolysis solid oxide cells

Here, this study evaluates the durability of Ni/YSZ-supported SOECs under dynamic operating conditions relevant to real-world applications. Systematic tests were conducted to assess cell performance under steam cycling (3 to 75% humidified H 2 ), mode cycling between SOFC and SOEC operation, thermal cycling (150 to 750 °C at OCV, and 600 to 800 °C at 1.3V), and redox cycling (between 50% humidified H 2 and 50% humidified N 2 ). Steam cycling, mode cycling, and thermal cycling at OCV do not significantly accelerate performance degradation. Thermal cycling at 1.3V caused minimal damage within 600 to 800 °C. Full redox cycling (multi-hour oxidation holds) induced cell structural failure, while partial redox cycling (0.5 h holds) was tolerated. Extensive characterization revealed some material evolution, namely Sr and Co secondary phase formation, within the oxygen electrode due to La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-δ instability, especially for steam cycling and mode cycling. Minimal changes were identified within the Ni-YSZ fuel electrodes. These findings provide critical insights into SOEC reliability under dynamic conditions, supporting their application in dynamic or intermittent energy systems.

08 HYDROGEN↗

Advanced blade tip seal system, volume 2

The results of the endurance and performance engine tests conducted on monocrystal/abrasive-tipped CF6-50 Stage 1 HPT blades fabricated in Task VII of MATE Project 3 are presented. Two engine tests are conducted. The endurance engine test is conducted for 1000 C cycles. The performance engine test is conducted on a variable cycle core engine. Posttest evaluation and analyses of the blades and shrouds included visual, dimensional, and destructive evaluations.

Zelahy, J. W.↗

Results of deep DoD life cycle tests at high rates on 12Ah NiCd cells

A 12 Ah Nickel-Cadmium (NiCd) Low Earth Orbit (LEO) life cycle test that induced 47 percent more deep Depth Of Discharge cycles by mixing them with shallow DOD cycles is discussed. The test showed how aggressive recharging to a C/D ratio of 1.15 nearly doubled performance over cycling below a C/D of 1.11.

Panneton, Paul E.↗

A Review on the State of the Art of Machine Learning and Satellite Imaging: Detecting Scene Changes in Selected Nuclear Fuel Cycle Datasets

The timely detection of clandestine nuclear facilities is one of the greatest challenges faced by the International Atomic Energy Agency’s (IAEA). Idaho National Laboratory is currently applying machine learning (ML) to existing satellite imagery (SI) datasets to find facilities within the nuclear fuel life cycle, with primary focus placed on identifying critical predecessor (i.e., fuel fabrication and fuel enrichment) and successor (i.e., nuclear power plants) facilities. This could provide a satellite image methodology that the IAEA could leverage to discover clandestine facilities. The work presented in this paper describes the evolution of a workflow developed by this team for object detection related to critical infrastructure by expanding that workflow for the purpose of identifying nuclear fuel cycle components and automating dependency assessments. This will be done using two methods housed within a single pipeline. The first method involves implementing a DenseNet161 convolutional neural network to classify the images and explain the results using Local Interpretable Model-Agnostic Explanations (LIME). The second method implements You Only Look Once version 5 (YoloV5), to detect objects within images, provide a probability for the detection, and provide a bounding box that corresponds to the object of interest. The results of this work are anticipated to provide a clear picture of this portion of the nuclear fuel cycle and perform as a stand-alone tool for image assessment that can be expanded to additional fuel cycle components and implemented in international safeguards and national security domains. This capability addresses the IAEA’s need to detect undeclared nuclear materials and activities within a state while encompassing the entire nuclear fuel cycle.

97 MATHEMATICS AND COMPUTING↗

Advanced oxygen-hydrocarbon rocket engine study

This study identifies and evaluates promising LO2/HC rocket engine cycles, produces a consistent and reliable data base for vehicle optimization and design studies, demonstrates the significance of propulsion system improvements, and selects the critical technology areas necessary to realize an improved surface to orbit transportation system. Parametric LO2/HC engine data were generated over a range of thrust levels from 890 to 6672 kN (200K to 1.5M 1bF) and chamber pressures from 6890 to 34500 kN (1000 to 5000 psia). Engine coolants included RP-1, refined RP-1, LCH4, LC3H8, LO2, and LH2. LO2/RP-1 G.G. cycles were found to be not acceptable for advanced engines. The highest performing LO2/RP-1 staged combustion engine cycle utilizes LO2 as the coolant and incorporates an oxidizer rich preburner. The highest performing cycle for LO2/LCH4 and LO2/LC3H8 utilizes fuel cooling and incorporates both fuel and oxidizer rich preburners. LO2/HC engine cycles permitting the use of a third fluid LH2 coolant and an LH2 rich gas generator provide higher performance at significantly lower pump discharge pressures. The LO2/HC dual throat engine, because of its high altitude performance, delivers the highest payload for the vehicle configuration that was investigated.

Obrien, C. J.↗

Rate mechanism of vanadium oxide coated tin dioxide nanowire electrode for lithium ion battery

Correlating composition and structures with battery performance is key aspect of electrode material design and improvement. Here utilizing in situ open cell transmission electron microscopy, we studied the in situ cycling rate performance of vanadium oxide coated tin dioxide nanowire electrode by tuning the lithiation/delithiation current. In situ results show that the good rate performance of such high capacity compositional material lies in the layered vanadium oxide coating strategy. For cycling at high rate, the layered vanadium oxide also serves as fast ions and electrons transportation route while tin nanoparticles aggregate to the surface with sizes controlled by the coating layer, cycle induced volume change is released to the surface and excellent mechanical tolerance of tin nanoparticle and inner nanowire ensure improved cyclability of the electrode.

25 ENERGY STORAGE↗

Optimization of a Residential Air Source Heat Pump using Refrigerants with GWP <150 for Improved Performance and Reduced Emission

Using low-GWP refrigerants can reduce the Green House Gas (GHG) emission of heat pump systems. Heat exchangers and compressors are the key components and have a prominent impact on system performance, significant research is devoted to reducing the cost of the heat exchangers while achieving the same or better system performance with refrigerant charge reduction.To better understand the environmental impacts of optimized systems with low-GWP refrigerants, Life Cycle Climate Performance (LCCP) evaluation method was used to evaluate the direct and indirect emissions of the system over the course of its lifetime from manufacturing to disposal. The DOE/ORNL Heat Pump Design Model (HPDM) is used to evaluate the performance of heat pumps. Multi-objective optimizations using Particle Swarm Optimization (PSO) algorithm are performed on a 3-ton R410A residential air source heat pump on market. Seven R410A alternatives, i.e., R32, R454B, R454C, R455A, R457A, R1234yf and R1234ze(E) are investigated. The last five fluids have GWP lower than 150.As a result, 5.5%-12.8% seasonal energy efficiency ratio 2 (SEER2) improvement is achieved, and the optimized systems reduce life cycle CO2 emission by 8.5%-28.6% with GWP lower than 150 refrigerants. The optimal heat exchangers can fit into the original R410A fan-coil units; therefore, the proposed design method establishes a production and installation path to produce cost-effective low-GWP heat pumps easily accepted by end users.

Li, Zhenning↗

High Energy, Long Cycle Life Lithium-ion Batteries for PHEV Application

High-loading and high quality PSU Si anode has been optimized and fabricated. The electrochemical performance has been utilized. The PSU Si-graphite anode exhibits the mass loading of 5.8 mg/cm2, charge capacity of 850 mAh/ g and good cycling performance. This optimized electrode has been used for full-cell fabrication. The performance enhancement of Ni-rich materials can be achieved by a diversity of strategies. Higher Mn content and a small amount of Al doping can improve the electrochemical performance by suppressing interfacial side reactions with electrolytes, thus greatly benefiting the cyclability of the samples. Also, surface coatings of Li-rich materials and AlF 3 are able to improve the performance stability of Ni-rich cathodes. One kilogram of optimized concentration-gradient LiNi 0.76 Co 0.10 Mn 0.14 O 2 (CG) with careful control of composition, morphology and electrochemical performance was delivered to our collaborators. The sample achieved an initial specific capacity close to 190 mA h g -1 at C/10 rate and 180 mA h g -1 at C/3 rate as well as good cyclability in pouch full cells with a 4.4 V upper cut-off voltage at room temperature. Electrolyte additive with Si-N skeleton forms a less resistant SEI on the surface of silicon anode (from PSU) as evidenced by the evolution of the impedance at various lithiation/de-lithiation stages and the cycling data The prelithiation result demonstrates a solution processing method to achieve large area, uniform SLMP coating on well-made anode surface for the prelithiation of lithium-ion batteries. The prelithiation effect with this method is applied both in graphite half cells, graphite/NMC full cells, SiO half cells, SiO/NMC full cells, Si-Graphite half cells and Si-Graphite/NMC full cells with improvements in cycle performance and higher first cycle coulombic efficiency than their corresponding cells without SLMP prelithiation. As to the full cell fabrication and test, full pouch cells with high capacity of 2.2 Ah and 1.2 Ah have been fabricated and delivered. The cells show great uniformity and good cycling performance. The prelithiation method effectively compensate the loss in the first cycle. The cell with high energy density and long-cycle life has been achieved.

25 ENERGY STORAGE↗

High-performance SO 2 -depolarized electrolysis cell using advanced polymer electrolyte membranes

Three different proton conducting polymeric membrane materials (Nafion® 115, Nafion® 212, and sulfonated Diels-Alder polyphenylene [SDAPP]) were evaluated for use in SO 2 -depolarized electrolyzers for the production of hydrogen via the hybrid sulfur cycle. Their performance was measured using different water feed strategies to minimize overpotential losses while maintaining high product acid concentration. Both thin membranes (Nafion® 212 and SDAPP) showed performance superior to that of the thicker Nafion® 115. Here, the SDAPP membrane electrode assembly (MEA) performed well at higher acid concentrations, maintaining low ohmic and kinetic overpotentials. Finally, short-term (100-h) stability tests under constant current conditions showed minimal degradation for the SDAPP and Nafion® 212 MEAs. SDAPP MEA performance approached the targets needed to make the hybrid sulfur cycle a competitive process for hydrogen production (product acid concentration ≥65 wt% H 2 SO 4 at ≤ 0.6-V cell potential and ≥0.5 A-cm –2 current density).

08 HYDROGEN↗

Lithium Batteries and Supercapacitors Capable of Operating at Low Temperatures for Planetary Exploration

Demonstrated improved performance with wide operating temperature electrolytes containing ester co - solvents (i.e., methyl propionate and ethyl butyrate) in a number of prototype cells: center dot Successfully scaled up low temperature technology to 12 Ah size prismatic Li - ion cells (Quallion, LCC), and demonstrated good performance down to - 60 o C. center dot Demonstrated wide operating temperature range performance ( - 60 o to +60 o C) in A123 Systems LiFePO 4 - based lithium - ion cells containing methyl butyrate - based low temperature electrolytes. These systems were also demonstrated to have excellent cycle life performance at ambient temperatures, as well as the ability to be cycled up to high temperatures.

Li-ion Batteries↗

Evolution of thermo-mechanical properties of concrete with calcium aluminate cement and special aggregates for energy storage

Highlights: • CAC Concrete with stable aggregates is suitable for high temperatures with cycles. • Concrete suffered performance changes after the first thermal cycle (dehydration). • Subsequent thermal cycles showed stabilization and slight performance decreases. With the ever-expanding presence of solar energy, the design of cost-efficient heat energy storage systems is becoming increasingly relevant. Concrete is a potential solid material for these systems but raises questions of its response at high temperatures in operating conditions. This work studies concrete designed with calcium aluminate cement and three types of aggregates that are stable at high temperatures. The designed concrete mixes were exposed to thermal cycles (290–550 °C), and their thermal fatigue response was evaluated with mechanical, cracking, thermal, and microstructural analyses at room temperature after heat cycles. The obtained results show that the main changes are mostly produced after the first thermal cycle and are stabilized during successive thermal cycles, with only a slight decrease in the thermo-mechanical properties. The results showed stabilization of cracking, crack widths between 10 and 80 μm, reduction of compressive strength, around 50–65%, and reduction of the thermal conductivity by 30%.

36 MATERIALS SCIENCE↗

Electric and Conventional Vehicle Performance over Eco-Driving Cycles: Energy Benefits and Component Loss

Battery electric vehicles (BEVs) are expected to be a pathway towards meeting greenhouse and criteria pollutant gas reductions in the current and future transportation sector. However, BEV technologies are still evolving, including efficiency optimization and enhancement. Emerging connected and automated vehicle (CAV) technologies provide an in-depth insight for developing innovative applications and systems to leverage BEV energy efficiency and substantially transform transportation systems. Therefore, we present simulation studies of various BEV types and compare the performance between measured, real-world drive cycles and highly optimized eco-driving cycles that are representative of trajectory modifications using advanced CAV technologies. The investigated vehicles include a compact car and a Class 7 delivery truck. The results demonstrate that eco-driving has a high potential to reduce energy consumption for the BEVs considered. As part of the study, a comprehensive EV powertrain model was developed to account for key EV components and powertrain configurations. The impact of eco-driving was further evaluated for conventional vehicles with characteristics that are comparable to the modeled BEVs.

Gao, Zhiming↗

Electric and Conventional Vehicle Performance over Eco-Driving Cycles: Energy Benefits and Component Loss

Battery electric vehicles (BEVs) are expected to be a pathway towards meeting greenhouse and criteria pollutant gas reductions in the current and future transportation sector. However, BEV technologies are still evolving, including efficiency optimization and enhancement. Emerging connected and automated vehicle (CAV) technologies provide an in-depth insight for developing innovative applications and systems to leverage BEV energy efficiency and substantially transform transportation systems. Therefore, we present simulation studies of various BEV types and compare the performance between measured, real-world drive cycles and highly optimized eco-driving cycles that are representative of trajectory modifications using advanced CAV technologies. The investigated vehicles include a compact car and a Class 7 delivery truck. The results demonstrate that eco-driving has a high potential to reduce energy consumption for the BEVs considered. As part of the study, a comprehensive EV powertrain model was developed to account for key EV components and powertrain configurations. The impact of eco-driving was further evaluated for conventional vehicles with characteristics that are comparable to the modeled BEVs.

Gao, Zhiming↗

Evaluation of electric vehicle component performance over eco-driving cycles

We report that battery electric vehicles (BEVs) are a critical pathway towards achieving energy independence and meeting greenhouse and criteria pollutant gas reduction goals in the current and future transportation sector. Emerging connected and automated vehicle (CAV) technologies further open the door for developing innovative applications and systems to leverage vehicle efficiency and substantially transform transportation systems. Therefore, we present a simulation study of various BEV types and compare the performance when driving on real-road drive cycles to highly optimized eco-driving cycles using advanced CAV technologies. Additionally, the results demonstrate that eco-driving has a high potential to reduce energy consumption for all types of BEVs considered. The investigated BEVs include a compact vehicle, a transit city bus, and a Class 7 delivery truck. The impact of eco-driving on conventional vehicles was also compared to comparable BEVs. Compared to the BEVs, eco-driving provides a larger reduction in the conventional vehicle's braking energy loss, and also provides conventional vehicles with greater reductions in the engine mechanical energy output but the fuel savings did not show a consistent trend among all the conventional vehicle types. As part of the study, a comprehensive EV powertrain model was developed to account for key EV components and powertrain configurations.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗