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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 901 records · Page 50
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Solar thermal aerogel receiver and materials therefor

A silica aerogel having a mean pore size less than 5 nm with a standard deviation of 3 nm. The silica aerogel may have greater than 95% solar-weighted transmittance at a thickness of 8 mm for wavelengths in the range of 250 nm to 2500 nm, and a 400° C. black-body weighted specific extinction coefficient of greater than 8 m2/kg for wavelengths of 1.5 μm to 15 μm. Silica aerogel synthesis methods are described. A solar thermal aerogel receiver (STAR) may include an opaque frame defining an opening, an aerogel layer disposed in the opaque frame, with at least a portion of the aerogel layer being proximate the opening, and a heat transfer fluid pipe in thermal contact with and proximate the aerogel layer. A concentrating solar energy system may include a STAR and at least one reflector to direct sunlight to an opening in the STAR.

Chen, Gang↗
DOE OSTI2025

Low-Cost Sulfur Thermal Storage for Solar Industrial Process Heat Applications

Industrial process heat (IPH) is one of the largest energy demands in U.S., representing about 10% of all domestic energy consumption. Fuel costs to generate this industrial process heat are generally a top three cost for industry, a major component in American manufacturing competitiveness. Roughly 60% of US IPH demand (about 6,500 TBtu annually) falls in the medium-temperature range of 100–250 °C. While concentrated solar thermal (CST) technologies can provide a cost-effective source of heat in this temperature range, solar intermittency limits their adoption in industries that operate 24/7. Element 16 Technologies, Inc. developed a low-cost sulfur thermal energy storage (TES) technology to bridge this gap by capturing excess solar heat during the day and dispatching it reliably during non-solar hours. The core innovation is the use of sulfur, an abundant, industrial waste byproduct that costs ten times less than molten salt used in commercial TES systems. The overall goal of the project was to advance the design and development of molten sulfur TES to a manufacturing-relevant prototype stage for solar industrial process heat applications, while establishing and validating a realistic pathway to commercial success. Key tasks included corrosion and mechanical durability testing to identify cost-effective materials, design investigations using physics-based simulation tools, techno-economic evaluations of system lifetime costs, and pilot-scale testing for performance verification. Corrosion testing of steel alloys under cyclic molten sulfur conditions showed that austenitic stainless steels in the 300 series performed particularly well, with no structural degradation of welds or joints. Thermal cyclic testing of pilot sulfur TES units up to 1.5 MWh quantified charge/discharge rates, heat losses, round-trip efficiency and validated the system's capability to operate effectively under intermittent charging conditions. A techno-economic model, informed by sulfur TES performance model validated using pilot test data, showed that hybrid solar+sulfur TES+NG boiler systems are economically competitive with incumbent natural gas boilers for multiple locations in the southwest US. In summary, this project established molten sulfur TES as a technically viable pathway to improve economic competitiveness of American manufacturing by lowering the cost of solar industrial process heat.

14 SOLAR ENERGY↗
DOE OSTI2025

Uncertainty-Based Design: Finite Element and Explainable Machine Learning Modeling of Carbon–Carbon Composites for Ultra-High Temperature Solar Receivers

Design under uncertainty has significantly grown in research developments during the past decade. Additionally, machine learning (ML) and explainable ML (XML) have offered various opportunities to provide reliable predictable models. The current article investigates the use of finite element modeling (FEM), ML and XML predictions, and uncertain-based design of carbon-carbon (C-C) composites for use in ultra-high temperatures. A C-C composite concentrating solar power (CSP) as a microvascular receiver is considered as a case study. These C-C composites are fiber composites with directly integrated carbonized microchannels to form a lightweight, high-absorptivity material that includes an embedded microvascular network of channels. The topology of these microchannels is engineered to optimize heat transfer to a supercritical carbon dioxide (sCO2) heat transfer fluid. The mechanical characterization of C-C composites is highly challenging. Thus, designing every component made of C-C composites for ultra-high temperature applications needs an uncertainty-based analysis. As a part of a comprehensive project on the development of a novel carbonized microvascular C-C composite, this paper explores C-C composite sensitivity analysis, FEM, ML prediction, and XML analysis. The resulting composite can then be carbonized and coated with an oxidation-resistant coating to form a thermally efficient and mechanically robust C-C composite. An ANSYS 3-D-FE model was used to analyze the CSP’s stress/strain. To consider the variability in the mechanical and thermal properties of C-C composites, various mechanical properties are considered as the ANSYS FEM’s input. A synthetic dataset from 730 ANSYS runs was produced to feed into the ML and XML algorithms for uncertainty analysis and prediction. The ML and XML algorithms could accurately predict the CSP stresses/strains.

Daghigh, Vahid (ORCID:0000000298941620)↗
NASA NTRS1980

SEPS comet rendezvous performance assessment

This paper presents an assessment of delivered payload capability for a number of selected rendezvous missions to periodic comets with launch opportunities through the years 1986-1996. These missions are chosen using a selection criteria that considers both expected scientific interest and earth-based sighting considerations. Some 22 mission opportunities are found that satisfies the selection criteria. Spacecraft performance is presented for each mission opportunity based on use of a space shuttle, a twin stage inertial-upper-stage, and a conceptual solar-electric-propulsion-system with a nominal rendezvous 50 days before comet perihelion. Additional trajectory and propulsion enhancements are investigated for several comet rendezvous missions in order to improve spacecraft performance. An indirect transfer trajectory for an Encke mission is shown to offer substantial delivered payload. In addition the use of concentrator solar arrays is considered for several of the more interesting comet missions.

Sauer, C. G., Jr.↗
DOE OSTI2023

Dynamic Modeling of a Solar-To-Hydrogen Flexible High Temperature Steam Electrolysis Plant

Sustainble hydrogen production for use as a renewable combustible fuel and clean chemical feedstock is an important objective as the world moves towards a renewable energy future. High temperature steam electrolysis is a promising hydrogen production technology due to its reduced electric input that is offset by heat input into steam generation and steam superheating. An option to provide this heat is to use concentrating solar thermal technology that can sustainably provide heat input while renewable electricity is used for the electrolysis reaction. In this work, a solar-to-hydrogen high temperature steam electrolysis plant is designed and dynamically modeled, showing continuous hydrogen production by utilizing supplemental heating and efficient recuperative heating from the electrolysis product streams. Through this design, over 90% of the required heat input for the process can by met by a combination of solar and recuperative heat. Additionally, the plant can flexibility operate by ramping down hydrogen production and through flexible heat integration, which intelligently integrates solar heat based on solar conditions. Smooth operation with flexible hydrogen production is demonstrated which decreases electrical input during on-peak grid times and also decreases the total supplemental heat load over the course of a day from 26.1% to 24.5%. In addition, by using flexible heat integration, the plant can increase its solar heat usage by 4.1% relative to a base case. Both options for flexibility show efficient use of solar thermal energy to sustainably and continuously produce hydrogen.

Immonen, Jake (ORCID:0000000341231625)↗
DOE OSTI2022

System and technoeconomic analysis of solar thermochemical hydrogen production

Hydrogen is a promising energy carrier that can be obtained from various feedstocks using renewable energy sources. Direct solar thermochemical hydrogen (STCH) production by water splitting can utilize the full spectrum of solar radiation and has the potential to achieve high solar energy conversion efficiencies. Currently STCH research areas focus on material discovery. This paper evaluates the performance of various STCH materials in the context of a system platform to assess techno-economic benefits and gaps in the path to STCH scale-up. Additionally, to analyze the hydrogen production cost, a concentrating solar thermal (CST) system is introduced as a platform for integrating STCH materials and accommodating generalized thermochemical processes. The thermochemical process is based on a two-step STCH cycle using metal oxide that consists of a high temperature step for metal oxide reduction, followed by an oxidation step for water splitting at a lower temperature. A preferred configuration is to have the high temperature step occurring in a directly irradiated solar receiver reactor. To this end, we conceptualized a receiver design and associated solar field layout and investigated STCH operational boundaries, component costs and sensitivity parameters on the $2/kgH 2 goal of hydrogen production. The study explored system-related variables and factors associated with scaling up. The CST platform allows more comprehensive studies that encompass aspects of STCH materials and systems such as cost, hydrogen productivity and replacement frequency, alongside other system components like heliostat field, tower, and potential receiver costs.

08 HYDROGEN↗
NASA NTRS1989

Analysis of Nd3+:glass, solar-pumped, high-powr laser systems

The operating characteristics of Nd(3+):glass lasers energized by a solar concentrator were analyzed for the hosts YAG, silicate glass, and phosphate glass. The modeling is based on the slab zigzag laser geometry and assumes that chemical hardening methods for glass are successful in increasing glass hardness by a factor of 4. On this basis, it was found that a realistic 1-MW solar-pumped laser might be constructed from phosphate glass 4 sq m in area and 2 mm thick. If YAG were the host medium, a 1-MW solar-pumped laser need only be 0.5 sq m in area and 0.5 cm thick, which is already possible. In addition, Nd(3+) doped glass fibers were found to be excellent solar-pumped laser candidates. The small diameter of fibers eliminates thermal stress problems, and if their diameter is kept small (10 microns), they propagate a Gaussian single mode which can be expanded and transmitted long distances in space. Fiber lasers could then be used for communications in space or could be bundled and the individual beams summed or phase-matched for high-power operation.

Zapata, L. E.↗
NASA NTRS1983

JPL tests of a LaJet concentrator facet

A LaJet Energy Company (LEC) concentrator facet, 60 in. in diameter, was tested for imaging quality. The following two methods were used: (1) autofocus tests with a point source of light at the facet's radius of curvature; and (2) tests with the Sun close to the horizon as a distant source. The tests of the LaJet facet indicate that all of the solar image reflected by an LEC 460 solar concentrator made of like facets should fall within a 9-in. aperture if the outer facets are carefully adjusted. Such a concentrator would have acceptable performance, but complete evaluation must be made with an assembled concentrator.

Dennison, E. W.↗
DOE OSTI2023

A reduced-order modeling of a tubular solar reactor for long duration thermochemical energy storage

The storage of solar energy in a solid form, referred to as a “solar fuel”, can be achieved through a process known as endothermic solar thermochemistry. This process transforms the absorbed solar energy into a stable and retrievable form that can be stored for extended periods of time. This paper presents a low–order heat transfer model of a counter–current tubular falling bed reactor designed to produce thermally reduced magnesium manganese oxide pellets for long duration thermochemical energy storage. The energy required for the endothermic reduction was supplied by concentrated solar energy or renewable electricity via indirect heating of the gas and solid reactants flowing in a ceramic tube. The counter-current gas flow enhances the mixing of the solid particles with the heat recuperation zone, allowing the gas and particles to enter and exit the tubular reactor close to room temperature. Further, the reactor was vertically oriented and was heated circumferentially by an adjustable level heat flux along a finite segment of its length. The temperature distribution of the reactor in response to transient changes along the tube was modeled by considering conduction, convection, and radiation heat transfer. Governing equations for the heat transfer model were solved by discretizing the reactor tube into a finite number of control volumes and using an energy balance for the heat exchange between the reactor wall, gas, and particles within the control volume. The energy absorbed during this endothermic reaction was modeled numerically by fitting the data of the chemical conversion rate with the corresponding temperature of particles in the heating zone. The numerical model has been experimentally validated using a reactor prototype made of a 121.92 cm alumina tube heated by a 7kW electric tube–furnace. The alumina tube receives magnesium manganese oxide pellets of 3.66±0.516 mm in diameter from the top, and a counter–current gas flow from the bottom. The reactor wall temperature was monitored by six thermocouples installed along the reactor tube length. The experimental procedure was numerically simulated, and the temperature variation along the reactor tube was compared with a matrix of experimental runs for a range of particles mass flowrates (0.75–1.25g/s) and corresponding gas flowrates (36–65 SLPM). The reactor system was heated gradually from room temperature to a steady state temperature of 1673K, and then cooled down to room temperature. The heating and cooling processes were simulated, and the numerical and experimental results were compared throughout processes. The numerical model showed similar trends to the experimental results, with an error of 0.69 to 7.9% for the particle inlet and 0.7 to 7.9% for the gas inlet during steady-state operation. The proposed numerical model can be implemented as a simplified physical model to design a feedback control system to regulate reactor temperature.

14 SOLAR ENERGY↗
NASA NTRS1981

Urban air pollution and solar energy

The design and performance of solar energy systems for many potential applications (industrial/residential heat, electricity generation by solar concentration and photovoltaics) will be critically affected by local insolation conditions. The effects of urban air pollution are considered and reviewed. A study of insolation data for Alhambra, California (9 km south of Pasadena) shows that, during a recent second-stage photochemical smog alert (greater than or equal to 0.35 ppm ozone), the direct-beam insolation at solar noon was reduced by 40%, and the total global by 15%, from clean air values. Similar effects have been observed in Pasadena, and are attributable primarily to air pollution. Effects due to advecting smog have been detected 200 km away, in the Mojave Desert. Preliminary performance and economic simulations of solar thermal and photovoltaic power systems indicate increasing nonlinear sensitivity of life cycle plant cost to reductions in insolation levels due to pollution.

Gammon, R. B.↗
DOE OSTI2024

Air separation and N 2 purification with Ba 0.15 Sr 0.85 FeO 3-$δ$ via a two-step thermochemical process

Thermochemical air separation to produce high-purity N 2 was demonstrated in a vertical tube reactor via a two-step reduction–oxidation cycle with an A-site substituted perovskite Ba 0.15 Sr 0.85 FeO 3–δ (BSF1585). BSF1585 particles were synthesized and characterized in terms of their chemical, morphological, and thermophysical properties. A thermodynamic cycle model and sensitivity analysis using computational heat and mass transfer models of the reactor were used to select the system operating parameters for a concentrating solar thermal-driven process. Thermal reduction up to 800 °C in air and temperature-swing air separation from 800 °C to minimum temperatures between 400 and 600 °C were performed in the reactor containing a 35 g packed bed of BSF1585. The reactor was characterized for dispersion, and air separation was characterized via mass spectrometry. Gas measurements indicated that the reactor produced N 2 with O 2 impurity concentrations as low as 0.02 % for > 30 min of operation. Additionally, a parametric study of air flow rates suggested that differences in observed and thermodynamically predicted O 2 impurities were due to imperfect gas transport in the bed. Temperature swing reduction/oxidation cycling experiments between 800 and 400 °C in air were conducted with no statistically significant degradation in N 2 purity over 50 cycles.

14 SOLAR ENERGY↗
DOE OSTI2024

DOE’s National Solar Thermal Test Facility Operations and Maintenance

This report details operations and maintenance (O&M) activities performed across Fiscal Years 2022 through 2024 in support of the continued capabilities of the National Solar Thermal Testing Facility (NSTTF) at Sandia National Laboratories. The NSTTF O&M project is funded by the U.S. Department of Energy Solar Energy Technologies Office (SETO) to support research activities and testing on behalf of external customers at the facility under award number CPS 38491. During the project period, the NSTTF made progress in the areas of site metrics, site maintenance and utilization tracking, and customer engagement. The O&M project also supported special initiatives including procurement of a heat exchanger for particle concentrating solar thermal processes and a scoping and cost study for refurbishment and repair of component in the NSTTF heliostat field.

14 SOLAR ENERGY↗
DOE OSTI2022

Development of an Open-source Alloy Selection and Lifetime Assessment Tool for Structural Components in CSP

Lack of sufficient data on high temperature mechanical and corrosion behavior of structural materials is a huge barrier in the technological maturity of current and future Concentrating Solar Power (CSP) technologies. Rapid development and selection of materials cannot be achieved by expensive and time-consuming acquisition of experimental data. The goal of the proposed work is development of an open-source alloy selection and lifetime prediction tool that will integrate validated physics-based models to describe influence of temperature, alloy composition, environment and component geometry (thickness) on mechanical and corrosion behavior of Ni and Fe-based alloys employed in molten salts/sCO 2 heat exchangers. This one-year project leveraged the extensive dataset on the creep\corrosion behavior of candidate materials generated at ORNL through past projects and input from current collaborations with industrial partners. Based on previous experience and the feedback provided by industry (Brayton Energy and Echogen), three candidate materials of interest, Ni-based alloys 740H, 282 and 625 and application-specific operating conditions (max. temperature of 730 °C and stress of 150 MPa) were identified for the heat exchanger. An extensive corrosion and creep dataset was assimilated for the relevant operating conditions and was supported by detailed characterization of about 100 metallographic cross-sections. The corrosion dataset consisted of scanning electron microscopy images (secondary electron and backscatter electron), measured concentration profiles of alloying elements using energy dispersive X-ray spectroscopy (EDS), widths of denuded zones (dissolution of strengthening phases) and depths of attack in molten KCl-MgCl 2 mixtures using image analyses. The creep dataset comprised of creep rupture data and creep strain curves (for 740H and 282). Coupled thermodynamic-kinetic microstructure-based models were employed to predict the stress-corrosion induced compositional and phase evolutions in the alloy during operation under the identified operating conditions. Reduced order models were developed from advanced physics-based models and were integrated in a user-friendly alloy selection tool. The corrosion model was able to predict the time to a critical Cr concentration at the oxide/alloy interface (chemical lifetime) within ±10% (1 standard deviation) of typical statistical variation in corrosion tests and EDS measurement errors (±0.5 wt%). The initial scope of the project was limited to predict creep rupture times (Larson-Miller parameter). Based on the input provided by industry, the mechanical lifetime of the heat exchanger is governed by accumulated creep strains (2%) rather than creep rupture. To be able to predict the times to specific creep strains, a more extensive creep model development was undertaken largely beyond the initial scope of the project. The continuum damage mechanics creep model was able to predict times to 2% creep strain, t 2% with an accuracy of ±500h. Ultimately, a screening protocol for SiC was generated to demonstrate the pathway for integration of one of the currently immature materials from a commercial adoption standpoint in the current material evaluation tool. The modeling tool developed here is accessible to the science community and stakeholders and lays the foundation for methods that will enable a rapid evaluation of optimum materials for CSP applications and reliable prediction of material degradation thereby considerably reducing operational costs, improving reliability and increasing overhaul intervals. However, the complete potential of such a tool to include a wider range of materials and test conditions can only be realized with a more concentrated combined experimental-characterization-computation effort.

14 SOLAR ENERGY↗
NASA NTRS1986

Direct solar-pumped iodine laser amplifier

In order to evaluate the feasibility of the solar pumped dye laser, the parametric study of a dye laser amplifier pumped by a solar simulator and flashlamp was carried out, and the amplifier gains were measured at various pump beam irradiances on the dye cell. Rhodamine 6G was considered as a candidate for the solar pumped laser because of its good utilization of the solar spectrum and high quantum efficiency. The measurement shows that a solar concentration of 20,000 is required to reach the threshold of the dye. The work to construct a kinetic model algorithm which predicts the output parameter of laser was progressed. The kinetic model was improved such that there is good agreement between the theoretical model and experimental data for the systems defined previously as flashlamp pumped laser oscillator, and the long path length solar pumped laser.

Han, Kwang S.↗
NASA NTRS1989

Advanced solar-propelled cargo spacecraft for Mars missions

At the University of Washington, three concepts for an unmanned, solar powered, cargo spacecraft for Mars-support missions have been investigated. These spacecraft are designed to carry a 50,000 kg payload from a low Earth orbit to a low Mars orbit. Each design uses a distinctly different propulsion system: a solar radiation absorption (SRA) system, a solar-pumped laser (SPL) system, and a solar powered mangetoplasmadynamic (MPD) arc system. The SRA directly converts solar energy to thermal energy in the propellant through a novel process developed at the University of Washington. A solar concentrator focuses sunlight into an absorption chamber. A mixture of hydrogen and potassium vapor absorbs the incident radiation and is heated to approximately 3700 K. The hot propellant gas exhausts through a nozzle to produce thrust. The SRA has an I(sub sp) of approximately 1000 sec and produces a thrust of 2940 N using two thrust chambers. In the SPL system, a pair of solar-pumped, multi-megawatt, CO2 lasers in sun-synchronous Earth orbit converts solar energy to laser energy. The laser beams are transmitted to the spacecraft via laser relay satellites. The laser energy heats the hydrogen propellant through a plasma breakdown process in the center of an absorption chamber. Propellant flowing through the chamber, heated by the plasma core, expands through a nozzle to produce thrust. The SPL has an I(sub sp) of 1285 sec and produces a thrust of 1200 N using two thrust chambers. The MPD system uses indium phosphide solar cells to convert sunlight to electricity, which powers the propulsion system. In this system, the argon propellant is ionized and electromagnetically accelerated by a magnetoplasmadynamic arc to produce thrust. The MPD spacecraft has an I(sub sp) of 2490 sec and produces a thrust of 100 N. Various orbital transfer options are examined for these concepts. In the SRA system, the mother ship transfers the payload into a very high Earth orbit and a small auxiliary propulsion system boosts the payload into a Hohmann transfer to Mars. The SPL spacecraft releases the payload as the spacecraft passes by Mars. Both the SRA-powered spacecraft and the SPL-powered spacecraft return to Earth for subsequent missions. The MPD-propelled spacecraft, however, remains at Mars as an orbiting space station. A patched conic approximation was used to determine a heliocentric interplanetary transfer orbit for the MPD propelled spacecraft. All three solar-powered spacecraft use an aerobrake procedure to place the payload into a low Mars parking orbit. The payload delivery times range from 160 days to 873 days (2.39 years).

Auziasdeturenne, J.↗
NASA NTRS1976

Technical feasibility of a modular dish solar electric system

The paper presents the technical feasibility of generating electricity by using a gas turbine in conjunction with a paraboloid of revolution (dish) solar concentrator. A conceptual design of a dish concentrator is obtained by parametrically examining the significant optical parameters. The optical performance analysis was conducted using a Monte Carlo ray-trace simulation program. The performance of four candidate thermodynamic cycles utilizing two working fluids was analyzed; the cycles were the regenerative and nonregenerative Brayton cycles of both open and closed type. Air and helium were the working fluids for the open and closed type respectively. Heat transfer from the solar radiation to the gas flowing in metal tubes at the receiver was also analyzed. A paraboloid of revolution dish with a cavity receiver using an open air regenerative Brayton cycle turbine emerged as a technically feasible concept in the power range from 30 to 100 KWth per module.

Gupta, B. P.↗
NASA NTRS1993

A general circulation model study of the effects of faster rotation rate, enhanced CO2 concentration, and reduced solar forcing: Implications for the faint young sun paradox

Solar energy at the top of the atmosphere (solar constant), rotation rate, and carbon dioxide (CO2) may have varied significantly over Earth's history, especially during the earliest times. The sensitivity of a general circulation model to faster rotation, enhanced CO2 concentration, and reduced solar constant is presented. The control simulation of this study has a solar constant reduced by 10% the present amount, zero land fraction using a swamp ocean surface, CO2 concentrations of 330 ppmv, present-day rotation rate, and is integrated under mean diurnal and seasonal solar forcing. Four sensitivity test are performed under zero land fraction and reduced solar constant conditions by varying the earth's rotation rate atmospheric CO2 concentration and solar constant. The global mean sea surface temperatures (SSTs) compared to the control simulation: were 6.6 K to 12 K higher than the control's global mean temperature of 264.7 K. Sea ice is confined to higher latitudes in each experiment compared to the control, with ice-free areas equatorward of the subtropics. The warm SSTs are associated with a 20% reduction in clouds for the rotation rate experiments and higher CO2 concentrations in the other experiments. These results are in contrast to previous studies that have used energy balance and radiative convective models. Previous studies required a much larger atmospheric CO2 increase to prevent an ice-covered Earth. The results of the study, suggest that because of its possible feedback with clouds, the general circulation of the atmosphere should be taken into account in understanding the climate of early Earth. While higher CO2 concentrations are likely in view of the results, very large atmospheric CO2 concentrations may not be necessary to counterbalance the lower solar constant that existed early in Earth's history.

Jenkins, Gregory S.↗
NASA NTRS2010

The 2010 Field Demonstration of the Solar Carbothermal Reduction of Regolith to Produce Oxygen

The Moon and other space exploration destinations are comprised of a variety of oxygen-bearing minerals, providing a virtually unlimited quantity of raw material which can be processed to produce oxygen. One attractive method to extract oxygen from the regolith is the carbothermal reduction process, which is not sensitive to variations in the mineral composition of the regolith. It also creates other valuable resources within the processed regolith, such as iron and silicon metals. Using funding from NASA, ORBITEC recently built and tested the Carbothermal Regolith Reduction Module to process lunar regolith simulants using concentrated solar energy. This paper summarizes the experimental test results obtained during a demonstration of the system at a lunar analog test site on the Mauna Kea volcano on Hawaii in February 2010.

Gustafson, R. J.↗