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Increasing melt efficiency and secondary alloy usage in aluminum die casting

In this project, the focus was to develop thermodynamic and kinetic models for the aluminum melting process involving secondary alloys, refractory materials and flux materials. The major research outcome of this study is 1) the refractory composition of CaO (8-12%), microsilica (1-3%), BaSO 4 and/or BaO (no more than 5%), B 2 O 3 (5%) and Al 2 O 3 (balance) effectively reduced the reactions with liquid Al and alloying/impurity elements and heat transfer during melting and holding process. 2) a flux composition of NaCl-KCl-(1-10%)KAlF 4 exhibited an effective covering effect and prevented the dross formation during melting of Al process. 3) A high Fe (0.44%) content recycled Al alloy with compatible mechanical properties was developed based on the impurities control methods, which provides great potential to replace the commercial structural alloys from primary Al and increase the usage of secondary alloys.

36 MATERIALS SCIENCE↗

Blade‐Cast Nonfullerene Organic Solar Cells in Air with Excellent Morphology, Efficiency, and Stability

Abstract Blade‐coating serving as a prototype tool for slot‐die coating can be very compatible with large‐area roll‐to‐roll coating. Using blade‐coating in an ambient environment, an average power conversion efficiency (PCE) of 10.03% is achieved in nonfullerene organic solar cells, which is higher than that of the optimal spin‐coated device with a PCE of 9.41%. It is demonstrated that blade‐coating can induce a higher degree of molecular packing for both conjugated polymer donors and small‐molecular acceptors as it helps to produce a seeding film containing numerous crystal grains, subsequently providing nucleation sites for the residual solution when the motion of the blade exposes a liquid front. Due to this effect, blade‐coating can partially replace the role of the additive 1,8‐diiodooctane (DIO) and thus achieves the optimized morphology with fewer additives. Moreover, it is found that the blade‐coated film with 0.25% DIO possesses not only a smaller domain size but also higher domain purity, suggesting more D/A (donor/acceptor) interfaces and a purer phase domain as compared to the spin‐coated film with 1% DIO. Encouragingly, the blade‐coated device with less DIO (0.25%) exhibits much better stability than the spin‐coated device with 1% DIO, showing excellent prospects.

Zhang, Lin↗