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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

Bias Correction and Statistical Downscaling of Solar Radiation Using NA-CORDEX and the NSRDB

The current state-of-art for estimating long-term PV production uses long-term estimates of solar radiation variables, such as global horizontal irradiance (GHI), from previous years. This data is used in models such as the System Advisor Model (SAM) or PYSyst to predict annual production for a PV plant. This information is then used to estimate the production over the next 20 years (a typical plant lifetime) under the assumption that the variability over the current period is representative of the future. As the PV industry moves to extend plant lifetimes to 50 years the current assumptions of representativeness of weather may not be appropriate. This is especially true as our climate changes rapidly. To assess long-term PV production, future projections for solar radiation based on projected carbon emissions are readily available in regional and global climate models. However, climate model projections contain inherent biases that may need to be corrected for accurate analysis of future projections of climate variables. Several studies have analyzed projections of solar radiation for future years, however the accuracy of the model output compared to current and historic data has not been widely studied. Chen (2021) showed that available climate models do not accurately represent solar radiation in some cases, over-projecting GHI at the surface while under-projecting its obstructions, such as clouds and aerosols. This works aims to (1) increase understanding of the accuracy of solar radiation currently available in global and regional climate models and (2) implement bias correction through linear models based on reanalysis data compared to observed solar radiation. The latter aim will be conducted using available observed solar radiation data and modeled data from several regional climate models (RCMs). The bias correction method will be applied to projections of solar radiation resulting in a more accurate representation of the future of solar production.

climate data↗

Spectra-to-exposure conversion using polynomial response models for gamma-ray field characterization

Accurate measurement of exposure rate from gamma-ray spectral data remains a critical challenge during radiological emergency response operations. Conventional methods rely on pre-defined static conversion factors derived from fixed geometries and isotopic compositions, which often fail to capture real-world environmental variability. This study presents a generalized approach as a "next-step" for converting gamma-ray spectral data into exposure rate using polynomial response models. The method introduces a flexible weighting scheme based on the in-situ detector response to distributed sources, enabling a pathway towards improved correspondence between measured spectra and "ground-truth" exposure rates. Experimental data from sodium iodide NaI(Tl) detectors were used to validate the approach as, at least equivalent to the current count-to-exposure method employed in emergency response CONOPS. Results show that the polynomial weighting model is sufficiently equal to the count-to-exposure method and may help improve accuracy given its adaptability to real-world conditions.

61 RADIATION PROTECTION AND DOSIMETRY↗

Why Are 5-Thioglycopyranosyl Donors More Axially Selective than their Glycopyranosyl Counterparts? A Low and Variable Temperature NMR Spectroscopy and Computational Study

5-Thioglycopyranosyl donors differ in reactivity and selectivity from simple glycopyranosyl donors. An extensive study has been conducted on the nature and stability of the reactive intermediates generated on the activation of per-O-acetyl and per-O-methyl 5-thioglucopyranosyl donors and the corresponding glucopyranosyl donors. Variable temperature nuclear magnetic resonance (NMR) studies with per-O-methylated or per-O-acetyl glycosyl sulfoxides and trichloroacetimidates on activation with trifluoromethanesulfonic anhydride or trimethylsilyl triflate are reported. These show that following initial adduct formation with the promoter conversion of the 5-thioglucopyranosyl donors to the 5-thioglucopyranosyl triflates requires higher temperatures than that of the glucopyranosyl donors to the glucopyranosyl triflates. It is demonstrated that neighboring group participation is a less important phenomenon for the peracetylated thioglucosyl donors than for the peracetylated glucosyl donors. A simple thiocarbenium ion was generated by protonation of 2,3-dihydro-4H-thiopyran at low temperature and characterized by NMR spectroscopy. However, the corresponding 5-thioglucopyranosyl thenium ions were not observed in any of the NMR studies of the 5-thiopyranosyl donors: the electron-withdrawing C–O bonds around the thiopyranoside core discourage thiocarbenium ion formation, just as they discourage oxocarbenium ion formation. Density functional theory (DFT) calculations reveal the tetrahydrothiopyranyl thiocarbenium ion to be approximately 2.5 kcal/mol lower in energy than the corresponding tetrahydropyranyl oxocarbenium ion relative to the corresponding covalent triflates. However, the computations reveal a 5.8 kcal/mol activation barrier for conversion of the tetrahydrothiopyranyl triflate to the thiocarbenium ion, while formation of the oxocarbenium ion–triflate ion pair from tetrahydropyranyl triflate requires only 2.6 kcal·mol –1 . Overall, the greater axial selectivity of 5-thioglycopyranosyl donors compared to analogous glycopyranosyl donors derives from (i) the lower kinetic reactivity necessitating higher reaction temperatures, (ii) the greater stability of the thiocarbenium ion over the oxocarbenium ion facilitating equilibration under thermodynamic conditions, (iii) the greater magnitude of the anomeric effect in the 5-thiosugars, and (iv) decreased neighboring group participation in the per-esterified 5-thiosugars.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Torque Teno Sus Virus 1: A Potential Surrogate Pathogen to Study Pig-Transmitted Transboundary Animal Diseases

Understanding the epidemiology and transmission dynamics of transboundary animal diseases (TADs) among wild pigs (Sus scrofa) will aid in preventing the introduction or containment of TADs among wild populations. Given the challenges associated with studying TADs in free-ranging populations, a surrogate pathogen system may predict how pathogens may circulate and be maintained within wild free-ranging swine populations, how they may spill over into domestic populations, and how management actions may impact transmission. We assessed the suitability of Torque teno sus virus 1 (TTSuV1) to serve as a surrogate pathogen for molecular epidemiological studies in wild pigs by investigating the prevalence, persistence, correlation with host health status and genetic variability at two study areas: Archbold’s Buck Island Ranch in Florida and Savannah River Site in South Carolina. We then conducted a molecular epidemiological case study within Archbold’s Buck Island Ranch site to determine how analysis of this pathogen could inform transmission dynamics of a directly transmitted virus. Prevalence was high in both study areas (40%, n = 190), and phylogenetic analyses revealed high levels of genetic variability within and between study areas. Our case study showed that pairwise host relatedness and geographic distance were highly correlated to pairwise viral genetic similarity. Molecular epidemiological analyses revealed a distinct pattern of direct transmission from pig to pig occurring within and between family groups. Our results suggest that TTSuV1 is highly suitable for molecular epidemiological analyses and will be useful for future studies of transmission dynamics in wild free-ranging pigs.

60 APPLIED LIFE SCIENCES↗

Photoinitiated Reactions of Molecules and Radicals in Molecular Beams

The UV photochemistry of organic molecules is a fundamental process that governs reactions in the atmosphere, synthetic chemistry, processing of organic aerosols, and biological damage in living tissues. In many organic molecules, the ensuing evolution involves pathways that are in competition, giving rise to different products, isomerization, coupling to other electronic states, and secondary reactive collisions. Because photodissociation is usually fast (picoseconds to microseconds), these processes are far from equilibrium and are controlled by kinetic competition and dynamical forces. The work accomplished was focused primarily on the photochemistry of alpha-keto carboxylic acids, a group of acids produced from natural sources, which are implicated in aerosol formation and biological processes. In the atmosphere, they are destroyed mainly by solar radiation. Studying their photochemistry has been surprisingly difficult because of the complexity of their excited electronic states, and the effect of collisions and secondary reactions. The second project investigated the lifetime of excited electronic states of pyrazine and picoline and had both experimental and theoretical aspects. The work focused on a model molecule, pyruvic acid (PA), because it was hypothesized that it should be a good source of the unstable carbene, methylhydroxycarbene (MHC). PA has an internal hydrogen bond that controls the evolution of its decomposition. The decomposition was studied following excitation to two of its lowest excited states reached by laser irradiation at 351 and 193 nm. The photodissociation dynamics in the absence and presence of collisions was monitored and compared. Understanding the UV photochemistry requires the use of complementary experimental approaches. Two methods were enlisted, which together generated a comprehensive and detailed set of results: (i) The time-sliced velocity map imaging (SVMI) instrument at USC was exploited to determine kinetic energy release of fragments, fast dissociation timescales, and internal state distributions of fragments for which Resonance Enhanced Multiphoton Ionization (REMPI) schemes exist; and (ii) The multiplexed photoionization mass spectrometer (MPIMS) setup developed at the Sandia Combustion Research Facility was used for product discovery, achieved by exploiting tunable narrowband VUV radiation at the Advanced Light Source (ALS), and to follow in real time their subsequent unimolecular and bimolecular reactions. The experimental conditions ranged from collisionless molecular beams to study nascent products to flow reactors of variable pressures to study subsequent bimolecular reactions of the products. The goals stated above were successfully accomplished. By exciting PA to its lowest excited state, MHC was identified as the only primary product and its isomerization to vinylalcohol and acetaldehyde was directly observed in real time. Moreover, we reported the first bimolecular reaction of MHC, which was with acetaldehyde, and identified its reaction product. This paves the way for the study of other reactions of this important carbene intermediate. When excitation was carried out at 193 nm, which imparted much higher energy to PA, many more products were directly observed in real time, some deriving from three-body dissociation. Quantitative branching ratios and secondary reactions of radical products were also determined and analyzed. The studies of pyrazine and picoline focused on the second excited state of these molecules and showed (via ionization studies) that their excited states were very short lived (<100 fs) because of efficient couplings to lower electronic states via vibronic coupling. Theoretical work on modeling the absorption spectrum and decay mechanisms of the excited states are in progress in collaboration with theoreticians.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A numerical study of the meso-structure variability in the compaction process of prepreg platelet molded composites

Compaction deformations in a thermoplastic composite system molded from chopped prepreg platelets were analyzed to obtain statistical distributions of local distortions that define the final consolidated meso-structure. This study provides an insight into and allows quantification of the intrinsic geometric variability of the composite meso-structure that controls the variability of the effective composite mechanical properties. A two-phase viscoelastic finite element model was utilized to treat the behavior of molten prepreg platelets, which were assumed to be incompressible and inextensible in the fiber direction during processing. A two-step simulation procedure with discretely modeled platelets and platelet-to-platelet contacts is proposed. The analysis begins with a drop simulation of the uncontrolled material deposition followed by a 3D finite element analysis of the preform compaction and bulk material flow. The proposed model provides a method for generating a composite meso-structure ab initio starting from a statistical sampling of the initial conditions for platelet deposition. The predicted platelet thickness distribution, intra-platelet fiber waviness and out-of-plane platelet undulations were found to be in good agreement with experimental measurements. An estimate of the volume of resin pockets was inferred from the compaction simulation.

36 MATERIALS SCIENCE↗

Limited Role of Absolute Humidity in Intraurban Heat Variability

Abstract Monitoring and understanding the variability of heat within cities is important for urban planning and public health, and the number of studies measuring intraurban temperature variability is growing. Recognizing that the physiological effects of heat depend on humidity as well as temperature, measurement campaigns have included measurements of relative humidity alongside temperature. However, the role the spatial structure in humidity, independent from temperature, plays in intraurban heat variability is unknown. Here we use summer temperature and humidity from networks of stationary sensors in multiple cities in the United States to show spatial variations in the absolute humidity within these cities are weak. This variability in absolute humidity plays an insignificant role in the spatial variability of the heat index and humidity index (humidex), and the spatial variability of the heat metrics is dominated by temperature variability. Thus, results from previous studies that considered only intraurban variability in temperature will carry over to intraurban heat variability. Also, this suggests increases in humidity from green infrastructure interventions designed to reduce temperature will be minimal. In addition, a network of sensors that only measures temperature is sufficient to quantify the spatial variability of heat across these cities when combined with humidity measured at a single location, allowing for lower-cost heat monitoring networks. Significance Statement Monitoring the variability of heat within cities is important for urban planning and public health. While the physiological effects of heat depend on temperature and humidity, it is shown that there are only weak spatial variations in the absolute humidity within nine U.S. cities, and the spatial variability of heat metrics is dominated by temperature variability. This suggests increases in humidity will be minimal resulting from green infrastructure interventions designed to reduce temperature. It also means a network of sensors that only measure temperature is sufficient to quantify the spatial variability of heat across these cities when combined with humidity measured at a single location.

Meteorology & Atmospheric Sciences↗

Dome-like pressure-temperature phase diagram of the cooperative Jahn–Teller distortion in NaNiO 2

NaNiO 2 is a Ni 3+ -containing layered material consisting of alternating triangular networks of Ni and Na cations, separated by octahedrally-coordinated O anions. At ambient pressure, it features a collinear Jahn–Teller distortion below $T^{JT}_{onset} ≈ 480$ K, which disappears in a first-order transition on heating to $T^{JT}_{onset} ≈ 500$ K, corresponding to the increase in symmetry from monoclinic to rhombohedral. It was previously studied by variable-pressure neutron diffraction (Nagle-Cocco et al 2022 ACS Inorg. Chem. 61 4312) and found to exhibit an increasing $T^{JT}_{onset}$ with pressure up to ∼5 GPa. In this work, powdered NaNiO 2 was studied via variable-pressure synchrotron x-ray diffraction up to pressures of ∼67 GPa at 294 K and 403 K. Suppression of the collinear Jahn–Teller ordering is observed via the emergence of a high-symmetry rhombohedral phase, with the onset pressure occurring at ∼18 GPa at both studied temperatures. Further, a discontinuous decrease in unit cell volume is observed on transitioning from the monoclinic to the rhombohedral phase. These results taken together suggest that in the vicinity of the transition, application of pressure causes the Jahn–Teller transition temperature, $T^{JT}_{onset}$, to decrease rapidly. We conclude that the pressure-temperature phase diagram of the cooperative Jahn–Teller distortion in NaNiO 2 is dome-like.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Stochastic Ensemble Generation for Improved Characterization of Representing Geologic Variability in a Reservoir: IBDP Case Study for SMART Initiative

This document is a poster covering the findings from activities on training data generation, specifically geologic ensemble generation. The generated geologic realizations captured the range of possible permeability distributions of the subsurface at the Illinois Basin - Decatur Project (IBDP) site, based on available well log variabilities. The percentages of reservoirs and baffles in the injection zone and a truncation of baffle permeability led to more variance in the simulations. This will be used to build forward modeling, history matching, and optimization workflows. The geologic realizations were also ranked according to dynamic measures of hydraulic diffusivity, and simulations confirm a greater contrast between the reservoir and the baffles during injection.

stochastic ensemble generation↗

Search and identification of transient and variable radio sources using MeerKAT observations: a case study on the MAXI J1820+070 field

ABSTRACT Many transient and variable sources detected at multiple wavelengths are also observed to vary at radio frequencies. However, these samples are typically biased towards sources that are initially detected in wide-field optical, X-ray, or gamma-ray surveys. Many sources that are insufficiently bright at higher frequencies are therefore missed, leading to potential gaps in our knowledge of these sources and missing populations that are not detectable in optical, X-rays, or gamma-rays. Taking advantage of new state-of-the-art radio facilities that provide high-quality wide-field images with fast survey speeds, we can now conduct unbiased surveys for transient and variable sources at radio frequencies. In this paper, we present an unbiased survey using observations obtained by MeerKAT, a mid-frequency (∼GHz) radio array in South Africa’s Karoo Desert. The observations used were obtained as part of a weekly monitoring campaign for X-ray binaries (XRBs) and we focus on the field of MAXI J1820+070. We develop methods to efficiently filter transient and variable candidates that can be directly applied to other data sets. In addition to MAXI J1820+070, we identify four likely active galactic nuclei, one source that could be a Galactic source (pulsar or quiescent XRB) or an AGN, and one variable pulsar. No transient sources, defined as being undetected in deep images, were identified leading to a transient surface density of <3.7 × 10−2 deg−2 at a sensitivity of 1 mJy on time-scales of 1 week at 1.4 GHz.

Rowlinson, A. (ORCID:0000000211957022)↗

Time variability of ultra fast BAL outflows using SALT: C IV equivalent width analysis

We study the time variability (over ≤7.3 yr) of ultra fast outflows (UFOs) detected in a sample of 64 C IV broad absorption line (BAL) quasars (with 80 distinct BAL components) monitored using the Southern African Large Telescope. By comparing the properties of the quasar in our sample with those of a control sample of non-BAL quasars, we show that the distributions of black hole mass are different and the bolometric luminosities and optical photometric variations of UFO BAL quasars are slightly smaller compared to that of non-BAL quasars. The detection fraction of C IV equivalent width (W) variability (∼95 per cent), the fractional variability amplitude $\left(\frac{\Delta W}{W}\right)$ and the fraction of ‘highly variable’ BAL (i.e. $\big|$$\frac{\Delta W}{W}$$\big|$ > 0.67) components (∼33 per cent) are higher in our sample compared to the general BAL population. The scatter in $\frac{\Delta W}{W}$ and the fraction of ‘highly variable’ BALs increase with the time-scale probed. The $\frac{\Delta W}{W}$ distribution is asymmetric at large time scales. We attribute this to the BAL strengthening time-scales being shorter than the weakening time-scales. The BAL variability amplitude correlates strongly with the BAL properties compared to the quasar properties. BALs with low W, high-velocity, shallow profiles, and low-velocity width tend to show more variability. When multiple BAL components are present, a correlated variability is seen between low- and high-velocity components with the latter showing a larger amplitude variations. We find an anticorrelation between the fractional variations in the continuum flux and W. While this suggests photoionization induced variability, the scatter in continuum flux is much smaller than that of W.

79 ASTRONOMY AND ASTROPHYSICS↗

Quantifying Solar PV Variability at Multiple Timescales for Power Systems Studies: Preprint

Increasing penetration of solar photovoltaics (PV) has concerned power system operators about their ability to balance load and generation over multiple timescales and maintain acceptable frequency profile because of the variability and uncertainty associated with solar PV. This paper focuses on developing metrics to quantify solar PV variability at multiple temporal scales ranging from seconds to an hour to help power system operators and planners better understand and account for solar PV variability under high solar PV penetration. Fourier coefficients of solar irradiation spectrum and average size of solar irradiation ramps over a day are the two metrics that are used to quantity the variability. It is shown that by using the two metrics the days with highest and lowest solar irradiation variability can be identified, which is useful information for operations planning or long-term power system planning studies. The key findings of the paper are (i) single sensor-based variability quantification can significantly exaggerate the variability of a solar PV plant, particularly at seconds to 1-min temporal resolution, (ii) at 1-minute or lower temporal resolutions, single sensor-based variability quantification of an entire plant can be fairly accurate, with the accuracy increasing as the temporal resolution reduces from 1-minute to 1-hour, (iii) at each 1-minute and lower temporal resolutions, maximum solar irradiation ramps appear to be independent of the geographical location of the sensor, and (iv) significant reduction in solar PV plant variability over a region with multiple plants is possible at all temporal scales, but more high quality, high temporal resolution data is needed to quantify the reduction with high confidence.

photovoltaics↗

Expanded Understanding of the Western Antarctic Peninsula Sea‐Ice Environment Through Local and Regional Observations at Palmer Station

Abstract The Western Antarctic Peninsula (WAP) has been experiencing rapid regional warming since at least the 1950s, however, the impacts of this warming at the local scale are variable and nuanced. Previous studies that have linked sea‐ice variability to biogeochemical cycles and food web dynamics often combine local‐scale biogeochemical data with coarse‐resolution regional satellite sea‐ice data, which may not adequately capture local sea‐ice conditions. In this study, we analyzed local‐scale in situ sea‐ice observations collected as part of a 28‐year record (1992–2020) from the Palmer Long‐Term Ecological Research site at Anvers Island, mid‐WAP, in conjunction with isotopically‐derived sea‐ice meltwater (SIM) fractions and satellite‐derived sea‐ice motion and concentration, to quantify the variability and long‐term trends in local sea‐ice behavior. In situ sea ice observations at Palmer Station displayed higher variability than satellite observations and showed no significant declines over this time, despite region‐wide declines identified in prior studies. Higher spring SIM fractions were attributed to strong northward sea‐ice motion throughout the winter. Applying these local‐scale sea‐ice insights to similarly scaled stratification and chlorophyll‐ a measurements, we found that a longer‐lasting, more consistent sea‐ice pack led to greater water column stratification following the spring sea‐ice retreat. Greater sea‐ice persistence and stronger stratification led to larger peaks in chlorophyll‐ a , though sea‐ice metrics did not explain the positive temporal trends in either stratification strength or chlorophyll‐ a . Through this study, we identify how local sea‐ice observations and meltwater data can enhance satellite data to build an understanding of the intricate connections between ice, water column dynamics, and phytoplankton.

Goodell, E.↗

Wind-induced torsion of parabolic trough collectors in operation

Parabolic trough collector (PTC) systems, a type of concentrating solar power (CSP), use parabolic mirrors to reflect the sun's rays toward an absorber tube to heat the fluid inside. PTCs track the sun throughout the day and are sensitive to angular misalignment, which reduces optical performance. Torsion of the PTC, exacerbated by wind loading, contributes to angular misalignment, which has been quantified by previous studies using numerical simulations and experimental tests. However, angular misalignment due to torsion and wind loading has not yet been studied in an operational plant, which can experience more extreme and variable conditions. This study characterizes the angular misalignment due to torsion at three rows of the Nevada Solar One CSP plant and investigates the influence of wind loading. These findings reveal substantial torsion along the PTC support structure that depends on wind conditions and orientation. Strong winds perpendicular to the PTCs increase the median angular displacement of the outermost row by up to 18 mrad and increase the standard deviation by up to 8 mrad when compared to weak wind conditions. These findings can inform enhanced PTC design, controls and modeling that will improve the performance, reliability and bankability of future CSP plants.

14 SOLAR ENERGY↗

Causal interaction in high frequency turbulence at the biosphere–atmosphere interface: Structural behavior

High-frequency (e.g., 10 Hz) eddy covariance measurements are typically used to estimate fluxes at the land–atmosphere interface at timescales of 15–60 min. These multivariate data contain information about the interdependency at high frequency between the interacting variables such as wind, humidity, temperature, and CO 2⁠ . We use data at 10 Hz from an eddy covariance instrument located at 25 m above agricultural land in the Midwestern US, which offers an opportunity to move beyond the traditional spectral analyses to explore causal dependency among variables. In this study, we quantify the structure of inter-dependencies of interacting variables at high frequency represented by a directed acyclic graph (DAG). We compare DAGs to investigate changes in structural differences in causal interactions. We then apply a distance-based classification and -means clustering approach to identify the evolution of the causal structure represented by a DAG. Our method selects an unbiased number of clusters of similar structures and characterizes the similarities and differences between them. We explore a range of dynamic behavior using data from a clear sky day and during a solar eclipse in 2017. Our results show well-defined clusters of similar causal dependencies as the system evolves. Furthermore, our approach provides a methodological framework to understand how causal dependence in turbulence manifests in high-frequency data when represented through a DAG.

54 ENVIRONMENTAL SCIENCES↗

Simulink Modeling and Dynamic Study of Fixed-Speed, Variable-Speed, and Ternary Pumped Storage Hydropower

Pumped Storage Hydropower (PSH) is one of the most popular energy storage technologies in the world. It uses an upper reservoir to store water which can be later used during high-demand. In the United States, most of the energy storage capability actually corresponds to PSH. Moreover, PSH also brings multiple benefits to grid operation. This report presents the Simulink models of three common PSH technologies: Fixed-Speed (FS), Variable-Speed (VS), and Ternary (T)-PSH. These models are available to the general public on this GitHub repository, which contains the MATLAB model initialization files, the Simulink model files, and supplementary MATLAB code used to obtain the figures in this work. For each PSH model, an introductory description of the model components and other relevant functionalities are provided. For further information regarding the models and the initialization parameters, the reader is referred to the shared files in the repository. This report also presents the dynamic behavior of each model. The response of such models to a load event is analyzed and matched with each model's features. A custom IEEE 39 bus case is employed for the FS and T-PSH simulations, while the VS-PSH is simulated on a simplified three-bus test system due to the computational complexity of the model. For the T-PSH, the steady-state and the switching between several operating modes are also studied in this work.

13 HYDRO ENERGY↗

What are the Impacts on the HVAC System when it Provides Frequency Regulation? – A Comprehensive Case Study with a Multi-Zone Variable Air Volume (VAV) System

Heating, ventilation, and air-conditioning (HVAC) systems in commercial buildings have proven to be a great asset for providing secondary frequency regulation (FR) service to the power grid. However, how the provision of FR service affects the HVAC system Quality of Service (QOS) is still largely unknown. In particular, there exists a controversy regarding the energy efficiency impact. This paper investigates how a HVAC system performance and its associated controls are impacted during and after the FR service. For the assessment, we developed a dynamic Modelica-based medium office building model as a virtual testbed with the Air Handling Unit (AHU) fans providing the FR service. Different regulation capacities (demand levels) and standard test signals under various load profiles in the U.S. are considered. The results show that FR has little or no impact on the HVAC operation and occupant thermal comfort while the building is providing the service if an appropriate regulation capacity is pre-determined. However, if the regulation capacity is overestimated, the quality of the FR service provided by the HVAC system and the HVAC energy efficiency will be affected due to the equipment operating constraints. In addition, the AHU supply air temperature fluctuates, and the controller cannot maintain the desired setpoint as the FR magnitude is increased. After the FR service time, the system takes a certain period to return to normal operation. The recovery period extends with the increase in the FR magnitude. For this case study, there exists a control conflict between the FR control and the existing HVAC control (from ASHRAE Guideline 36-2018) during high load conditions, causing the fan speed to saturate. The fan power consumption could increase significantly; up to 77% increase compared to the baseline was observed. This case study demonstrates that the HVAC system controls need to be enhanced and adapted to minimize the interaction between the FR controller and the indoor environmental controls in order to preserve the HVAC system QOS while (during and after) providing satisfactory FR service.

Lu, Xing↗

Freshwater Flux Variability Lengthens the Period of the Low-Frequency AMOC Variability

Atlantic Meridional Overturning Circulation (AMOC) exhibits interdecadal to multidecadal variability, yet the extent to which the surface freshwater flux (FWF) variability affects the AMOC variability remains unclear. This study isolates the contribution of FWF variability in modulating AMOC through a partially coupled experiment, in which the FWF effect from the atmosphere and sea ice are disabled. It is demonstrated that the FWF effect can remarkably enhance the persistence of positive salinity anomalies in the Labrador Sea, and sustain the dense water formation that was initiated by the cold temperature anomalies. Therefore, the FWF variability serves as a positive feedback on AMOC and lengthens the period of the AMOC oscillation. Further lead-lag regressions of atmospheric and oceanic variables onto the AMOC time series illuminate that the persistent salinity anomalies are generated through two pathways: i) the phase lag between temperature and salinity anomalies in the Labrador Sea; and ii) a downstream propagation of extra high-salinity anomaly along the East Greenland Current, due to the reduced sea ice melting flux associated with an atmosphere forcing over the southern Greenland tip.

58 GEOSCIENCES↗