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At least 91 records · Page 5

Tabulated Values of Bond Dissociation Energies, Ionization Potentials, and Electron Affinities for Some Molecules Found in High-Temperature Chemical Reactions

Values of the bond dissociation energies, ionization potentials, and electron affinities that were taken from the literature are presented in tables for some monatomic, diatomic, and polyatomic molecules which are found in many high-temperature chemical reactions including combustion reactions. Much of the information came from literature published after 1950 which either reported experimental and theoretical energy values or gave a review of previous literature on the subject. In some cases values for the bond dissociation energies were calculated from recently published heats of formation.

IONIZATION POTENTIAL↗

Indicators of the effect of jet noise on the value of real estate

Airport neighbors typically contend that their property should enjoy airport-accelerated appreciation in value but not suffer counterbalancing effects from jet noise. The paper discusses the effect of jet noise on property value as indicated by (1) market value changes, (2) insulation costs, (3) easement costs, and (4) litigation.

Jet aircraft noise↗

A curve of growth determination of the f-values for the fourth positive system of CO and the Lyman-Birge-Hopfield system of N2.

The curve of growth method has been employed to determine f-values for the fourth positive system of CO and the magnetic dipole and electric quadrupole components of the Lyman-Birge-Hopfield system of N2. No significant dependence on r-centroid was found. The mean value of the ratio of the electric quadrupole to magnetic dipole f-values was 0.076.

Pilling, M. J.↗

Estimation of longitudinal aerodynamic coefficients and comparison with wind-tunnel values

Some recent experience at Ames Research Center in the estimation of aerodynamic coefficients for the Lear-Jet and the Augmentor Wing Jet STOL Research Aircraft is reviewed. The coefficients estimated from flight data are compared with values based on large-scale wind-tunnel tests. The results obtained by the regression and quasilinearization identification techniques are also compared. The regression method generally provides the lower standard deviation in the coefficient estimates and provides the better fit to the wind-tunnel values. The addition of nonlinear terms in the aerodynamic equations decreases the difference between the estimated and measured time histories but also increases the standard deviation in the estimated coefficient values.

Wingrove, R. C.↗

Oxygen fugacity values of Apollo 12, 14, and 15 lunar samples and reduced state of lunar magmas

The oxygen fugacity values of lunar samples were measured directly with an improved solid-electrolyte oxygen cell between 1000 and 1200 C with an accuracy mostly better than 0.2 log f(02) unit. The bulk rock f(02) values of basaltic igneous rocks 12009, 12053, 15058, and 15595 ranged from 10 to -15.4 power to 10 to the -15.7 power at 1000 C and from 10 to the -12.3 power to 10 to the -12.8 power at 1200 C. Those of microbreccia 14321 also fell in this range, but the change of oxygen fugacity with temperature was irregular in the first heating cycle in comparison to the smooth changes observed with the basaltic igneous rocks. Two different samples of rock 14310 also showed similar f(02) values below 1170 C, but exhibited irreversible sudden rise in f(02) at this temperature for reasons yet to be determined. The data on the phenocryst olivine and the groundmass of basalt 12009 do not conclusively indicate progressive reduction of the lunar magma during cooling.

Sato, M.↗

A table of semiempirical gf values. Part 1: Wavelengths: 5.2682 nm to 272.3380 nm

The gf values for 265,587 atomic lines selected from the line data used to calculate line-blanketed model atmospheres are tabulated. These data are especially useful for line identification and spectral synthesis in solar and stellar spectra. The gf values are calculated semiempirically by using scaled Thomas-Fermi-Dirac radial wavefunctions and eigenvectors found through least-squares fits to observed energy levels. Included in the calculation are the first five or six stages of ionization for sequences up through nickel. Published gf values are included for elements heavier than nickel. The tabulation is restricted to lines with wavelengths less than 10 micrometers.

Kurucz, R. L.↗

A well posed boundary value problem in transonic gas dynamics

A boundary value problem for the Tricomi equation was studied in connection with transonic gas dynamics. The transformed equation delta u plus 1/3Y u sub Y equals 0 in canonical coordinates was considered in the complex domain of two independent complex variables. A boundary value problem was then set by prescribing the real part of the solution on the boundary of the real unit circle. The Dirichlet problem in the upper unit semicircle with vanishing values of the solution at Y = 0 was solved explicitly in terms of the hypergeometric function for the more general Euler-Poisson-Darboux equation. An explicit representation of the solution was also given for a mixed Dirichlet and Neumann problem for the same equation and domain.

Sanz, J. M.↗

A well posed boundary value problem in transonic gas dynamics

A new approach considered by Garabedian and Korn (1976) to solve a problem of airfoil design has led to a transonic boundary value problem. It remains to be shown that this problem is well posed. A description is presented of an investigation in which it is shown that a corresponding problem for the Tricomi equation is well posed. The solution to the boundary value problem is characterized, in a unique way, as a sum of two particular solutions. The Poisson formulas for the unit semicircle for the Euler-Poisson-Darboux equation are considered and reflection laws for solutions of the general Euler-Poisson-Darboux equation are established. It is proved that the considered boundary value problem for the case in which the involved function is periodic and continuous is well posed within the specified class of solutions.

Sanz, J. M.↗

Comments on numerical solution of boundary value problems of the Laplace equation and calculation of eigenvalues by the grid method

The mathematics involved in numerically solving for the plane boundary value of the Laplace equation by the grid method is developed. The approximate solution of a boundary value problem for the domain of the Laplace equation by the grid method consists of finding u at the grid corner which satisfies the equation at the internal corners (u=Du) and certain boundary value conditions at the boundary corners.

Lyusternik, L. A.↗

An overview of the value of parabolic dish solar thermal systems in industrial cogeneration applications

The essential elements of the cogeneration system configuration to be captured were the displacement of thermal energy by collection and use of the Brayton exhaust stream, and the sale back to the utility of any electricity production in excess of on-site requirements. In contrast to simply dumping these energy flows, their use or sale obviously serves, by itself, to increase gross value of the solar thermal energy system. Net allowable cost of the parabolic dish modules may or may not be increased, however. A consideration is that the waste heat capture and delivery subsystems are not free. This study does not address the incremental cost of adding waste heat capture, transport, and conversion (to steam, if necessary). It does compute a value for the thermal energy thereby displaced. This value can serve as a first-round input to any detailed economic evaluation of waste heat recovery.

Source record↗

Comparative values of advanced space solar cells

A methodology for deriving a first order dollar value estimate for advanced solar cells which consists of defining scenarios for solar array production and launch to orbit and the associated costs for typical spacecraft, determining that portion affected by cell design and performance and determining the attributable cost differences is presented. Break even values are calculated for a variety of cells; confirming that efficiency and related effects of radiation resistance and temperature coefficient are major factors; array tare mass, packaging and packing factor are important; but cell mass is of lesser significance. Associated dollar values provide a means of comparison.

Slifer, L. W., Jr.↗

The use of singular value gradients and optimization techniques to design robust controllers for multiloop systems

A method for designing robust feedback controllers for multiloop systems is presented. Robustness is characterized in terms of the minimum singular value of the system return difference matrix at the plant input. Analytical gradients of the singular values with respect to design variables in the controller are derived. A cumulative measure of the singular values and their gradients with respect to the design variables is used with a numerical optimization technique to increase the system's robustness. Both unconstrained and constrained optimization techniques are evaluated. Numerical results are presented for a two-input/two-output drone flight control system.

Newsom, J. R.↗

The use of singular value gradients and optimization techniques to design robust controllers for multiloop systems

A method for designing robust feedback controllers for multiloop systems is presented. Robustness is characterized in terms of the minimum singular value of the system return difference matrix at the plant input. Analytical gradients of the singular values with respect to design variables in the controller are derived. A cumulative measure of the singular values and their gradients with respect to the design variables is used with a numerical optimization technique to increase the system's robustness. Both unconstrained and constrained optimization techniques are evaluated. Numerical results are presented for a two output drone flight control system.

Newsom, J. R.↗

Singular value decomposition with systolic arrays

Systolic arrays for determining the singular value decomposition of a mxn, m n, matrix A of bandwidth w are presented. After A has been reduced to bidiagonal form B by means of Givens plane rotations, the singular values of B are computed by the Golub-Reinsch iteration. The products of plane rotations form the matrices of left and right singular vectors. Assuming each processor can compute or supply a plane rotation, O(wn) processors accomplish the reduction to bidiagonal form in O(np) steps, where p is the number of superdiagonals. A constant number of processors then determines each singular value in about 6n steps. The singular vectors are computed by rerouting the rotations through the arrays used for the reduction to bidiagonal form, or else along the way by employing another rectangular array of O(wm) processors.

Ipsen, I. C. F.↗

Recovering pointwise values of discontinuous data within spectral accuracy

The pointwise values of a function, f(x), can be accurately recovered either from its spectral or pseudospectral approximations, so that the accuracy solely depends on the local smoothness of f in the neighborhood of the point x. Most notably, given the equidistant function grid values, its intermediate point values are recovered within spectral accuracy, despite the possible presence of discontinuities scattered in the domain. (Recall that the usual spectral convergence rate decelerates otherwise to first order, throughout). To this end, a highly oscillatory smoothing kernel is employed in contrast to the more standard positive unit-mass mollifiers. In particular, post-processing of a stable Fourier method applied to hyperbolic equations with discontinuous data, recovers the exact solution modulo a spectrally small error. Numerical examples are presented.

Gottlieb, D.↗

A comparison of measured spacecraft modal damping values

The prediction and the measurement of modal damping values of spacecrafts for use in the determination of design loads were summarized. Realistic transient forcing functions were used. The solution of complex eigenvalue response solutions resulting from modal synthesis of subsystems in which each subsystem is assigned modal damping values is discussed. Damping data on both the Voyager and the Galileo spacecrafts using up to eight different types of techniques to analyze modal data are presented. It is concluded that it is difficult to estimate the true damping of a structure and the measured damping values which are dependent on the analysis method of the data.

Wada, B. K.↗

Singular value decomposition with systolic arrays

Systolic arrays for determining the singular value decomposition of a mxn, m greater than or equal to n, matrix A of bandwidth w are presented. After A has been reduced to bidiagonal form B by means of Givens plane rotations, the singular values of B are computed by the Golub-Reinsch iteration. The products of plane rotations form the matrices of left and right singular vectors. Assuming each processor can compute or supply a plane rotation, O(wn) processors accomplish the reduction to bidiagonal form in O(np) steps, where p is the number of superdiagonals. A constant number of processors then determines each singular value in about 6n steps. The singular vectors are computed by rerouting the rotations through the arrays used for the reduction to bidiagonal form, or else along the way by employing another rectangular array of O(wm) processors.

Ipsen, I.↗