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At least 91 records · Page 5

Lignocellulosic Biomass-Derived Nanocellulose Crystals as Fillers in Membranes for Water and Wastewater Treatment: A Review

The improvement of membrane applications for wastewater treatment has been a focal point of research in recent times, with a wide variety of efforts being made to enhance the performance, integrity and environmental friendliness of the existing membrane materials. Cellulose nanocrystals (CNCs) are sustainable nanomaterials derived from microorganisms and plants with promising potential in wastewater treatment. Cellulose nanomaterials offer a satisfactory alternative to other environmentally harmful nanomaterials. However, only a few review articles on this important field are available in the open literature, especially in membrane applications for wastewater treatment. This review briefly highlights the circular economy of waste lignocellulosic biomass and the isolation of CNCs from waste lignocellulosic biomass for membrane applications. The surface chemical functionalization technique for the preparation of CNC-based materials with the desired functional groups and properties is outlined. Recent uses of CNC-based materials in membrane applications for wastewater treatment are presented. In addition, the assessment of the environmental impacts of CNCs, cellulose extraction, the production techniques of cellulose products, cellulose product utilization, and their end-of-life disposal are briefly discussed. Furthermore, the challenges and prospects for the development of CNC from waste biomass for application in wastewater treatment are discussed extensively. Finally, this review unraveled some important perceptions on the prospects of CNC-based materials, especially in membrane applications for the treatment of wastewater.

59 BASIC BIOLOGICAL SCIENCES↗

Stall Margin Improvement in a Transonic Compressor with a Casing Treatment: Flow Mechanism

Effects of casing treatments for improved stall margin in transonic compressors are investigated. Two types of compressor casing treatments, circumferential grooves and axial slots casing treatments, are studied in detail. The primary objective of the current paper is to identify the underlying fluid mechanics that change the stall margin of transonic compressors with these two casing treatments. Large eddy simulation (LES) is applied to calculate the compressor flow fields with these two types of casing treatments. Calculated flow fields are first compared with measured experimental data to validate the LES simulation. Details of the calculated unsteady flow structures are examined to unearth the underlying flow mechanism for the improved stall margin. Further possible design optimization of the casing treatment for the stall margin extension without any performance penalty near the design condition is also explored.

compressor↗

The Influence of Heat Treatments on the Microstructure and Tensile Properties of Additively Manufactured Inconel 939

This study investigated the effect of heat treatment variations on the microstructure and tensile properties of laser powder bed fused Inconel 939 manufactured via laser powder bed fusion. Three different heat treatment schedules, all of which comprise stress relief, hot isostatic pressing, solution annealing, and aging, were followed, and resulting changes in microstructure were analyzed using scanning electron microscopy. Tensile tests were conducted on specimens subjected to different heat treatments to evaluate the mechanical properties at room temperature. Microstructural results showed that solution treatment at 1190 °C for 4 h led to better removal of dendritic microstructure, while second-step aging at 850 °C resulted in monomodal distribution of precipitates. However, the second-step aging temperatures from 750 to 800 °C resulted in bi-modal distribution. The optimal heat treatment schedule, which yielded a superior combination of strength and ductility, involved solution treatment at 1190 °C for 4 h and two-step aging at 1000 °C for 6 h and 800 °C for 4 h.

Laser powder bed fusion (L-PBF)↗

Interim Measures Work Plan: South Repeater Building: Solid Waste Management Unit 121: Hydraulic Containment and Groundwater Treatment System for Per- and Polyfluoroalkyl Substances: Kennedy Space Center, Florida

This document presents the design details of a granular activated carbon (GAC) hydraulic containment and groundwater treatment system Interim Measures Work Plan for the South Repeater Building site (South Repeater, Solid Waste Management Unit 121), located at John F. Kennedy Space Center (KSC), Florida. The interim measures (IM) treatment area includes the source area and downgradient property boundary, which have been impacted by per- and polyfluoroalkyl substances (PFAS). The objectives of the IM are to treat the source area and mitigate PFAS migration to areas outside of KSC boundaries. This document was prepared by AECOM Technical Services, Inc., for the National Aeronautics and Space Administration under Contract 80KSC019D0010, Task Order 80KSC021F0096. The IM consists of the installation and operation of 19 extraction wells and an associated groundwater treatment system. A total of 13 wells will be installed to a depth of 34 feet below land surface (bls) to target the upper medium-grained sand with shell layer. A total of six wells will be installed to a depth of 56 feet bls to target the lower layer of poorly graded sand with shell fragments. The system will be designed to operate each extraction well simultaneously using submersible pumps at flow rates of 5 or 10 gallons per minute (gpm), excluding one extraction well with a flow rate of 30 gpm. The extracted groundwater will be conveyed to a groundwater treatment system, where it will be treated via GAC prior to disposal via infiltration. To evaluate treatment system performance, baseline groundwater sampling will be conducted prior to treatment system startup. Performance monitoring will be completed quarterly for the first year. A total of eight performance monitoring wells will be installed to a depth of 12 feet bls, and eight performance monitoring wells will be installed to a depth of 30 feet bls. In addition to the installation of 16 performance monitoring wells, 12 existing monitoring wells will be incorporated into the performance monitoring program.

groundwater treatment↗

Effect of Heat Treatment on Microstructure and Mechanical Property of 316L Stainless Steel Produced by Laser Powder Bed Fusion

The advanced non-light water reactor designs (Gen IV reactors), including molten salt/ very high temperature/ sodium-cooled and lead-cooled fast reactors, typically operate at higher temperatures and more extreme radiation conditions than light water reactors. An intrinsic part of the deployment and progress of Gen IV reactor designs is selecting the most suitable structural material for a specific application. Additive manufacturing (AM), a fairly new process of making physical, three-dimensional objects from a computer design file, is going to completely change the way of design, build and certify nuclear systems. It offers a range of opportunities to produce complex geometries from existing materials, offers new routes for processing of previously difficult to process materials, allows for design of new high-performance materials, and finally facilitates hybridization of dissimilar materials. This emerging technology has successfully produced cars, wind turbine blade molds and even live cells. It could also open up big opportunities for the nuclear industry to quickly deploy technologies at a fraction of the cost. So far, AM techniques have been preliminarily applied in the field of nuclear reactors, including the classical parts such as the pressure vessel of a small reactor with 508-III steel, the bottom nozzle of a fuel assembly with 304L steel, the fuel cladding with zirconium alloy and the integrated impeller of a pump and the multi-channel valve body with 316L steel [6,7]. The AM applications for operating nuclear reactors started in auxiliary plant components and have slowly migrated to metallic reactors and core components, but many of these are not safety critical components. Although many parts used for nuclear reactors have been fabricated by AM techniques, practical applications in engineering are still a long way off due to the uncertainty factors focused on the processing, material properties, analysis methods and application standards, which feeds the safety and life-cycle of the nuclear reactor. Due to rapid, repeated heating and cooling during production, a high dislocation density was present in the AM material. This microstructure feature is unstable at elevated temperature while high temperature is one of the typical operation environments for nuclear reactors. Thus, it is important to understand the thermal effect on the microstructure of AM material. The objectives of this study are to investigate the effect of heat treatment on the microstructure and mechanical properties of 316L stainless steel produced by laser powder bed fusion additive manufacturing, and to determine an appropriate heat treatment practice that will be applied to the lightweight AM lattice-structured material with the same chemistry. The heat treatment study consisted of annealing the samples at a temperature range of 800 to 1200 oC with a 50 oC increment for different times (1-24 hours), followed by vacuum or air cooling. Microstructural characterization was carried out by Scanning Electron Microscope (SEM). Grain size and crystallographic orientation were investigated by Electron Backscatter Diffraction (EBSD). Vickers hardness tests with a 0.5 kg load were employed to determine the hardness of samples after different heat treatments. After heat treatment, the random crystallographic orientation was preserved, and the volume fraction of high-angle grain boundaries (grain boundary misorientation =15 oC) remained the same. The dislocation density decreased with annealing temperature due to recovery. The fine subgrain structures in the as-printed specimen were quite stable up to 1200 oC. Minimal recrystallization was observed up to 1200 oC. Recrystallization initiated only after 8.5 hours at 1200 oC. The SEM images did not show obvious dependence of microstructure on cooling rate. The hardness of the specimens decreased with increasing annealing temperature as a result of the decrease in dislocation density. It is interesting to note that the AM material showed very similar hardness to the wrought material when annealing at similar temperature, although the microstructures are very different. Annealing at 1050 oC for 1 hour followed by air cooling was selected as the heat treatment procedure for the lattice designed lightweight AM 316L material.

36 MATERIALS SCIENCE↗

Opportunities for Treatment and Reuse of Agricultural Drainage in the United States

Irrigation accounts for 42% of the total freshwater withdrawals in the United States. Climate change, the pressure of a growing population, degrading water quality, and increased competition from other sectors could constrain continuous supply to meet future agricultural water demand. This study presents an evaluation framework to assess the potential reuse of agricultural drainage water for crop irrigation. Using a regional approach, we review the current state of agricultural drainage treatment and reuse and the institutional, economic, and other barriers that can influence the reuse decision. In the 31 eastern states, agricultural drainage contains valuable nutrients that can be reused for irrigation with minimal treatment, while the 17 western states struggle with large volumes of saline drainage that can contain constituents of concern (e.g., selenium), preventing reuse without treatment. Using a new decision-support tool called WaterTAP3, a potential treatment train for saline agricultural drainage was analyzed to identify treatment challenges, research needs, and the potential implementation at a larger scale. As demonstrated by our case study, desalination of agricultural drainage is costly and energy intensive and will require sizable investments to fully develop and optimize technologies as well as manage the generated waste and brine.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Advancing Insights into Electrochemical Pre‐Treatments of Supported Nanoparticle Electrocatalysts by Combining a Design of Experiments Strategy with In Situ Characterization

Activation, break-in, and/or pre-treatment protocols are generally applied to energy conversion devices before regular operation to reach stable performance. There remains much to understand about the relationships among physical properties, performance, and electrochemical pre-treatments. Here, a design-of-experiments (DoE) strategy is employed to address this gap by demonstrating the influence of five pre-treatment parameters for carbon-supported Pt-nanoparticle catalysts on the electrocatalytic oxygen reduction reaction (ORR). A subset of pre-treatments, developed using a central composite design, are tested in a flow cell combined with an inductively-coupled plasma mass spectrometer (on-line ICP-MS). The DoE-based approach facilitates comprehensive insights from two orders of magnitude fewer experiments than a conventional grid search. The coupled on-line ICP-MS setup enables effective catalysis and real-time catalyst dissolution data. Leveraging insights from DoE for on-line ICP-MS and additional characterization, a model is built between the degradation of a multi-dimensional supported Pt surface, its performance, and applied electrochemical parameters. These investigations identify surface modifications, such as oxidation, and subsequent restructuring of Pt during pre-treatment as a primary cause of performance deterioration during ORR. By combining DoE with advanced characterization techniques, a powerful approach is demonstrated to gain a mechanistic understanding of pre-treatment protocols that can be broadly adapted to various reaction chemistries.

Platinum↗

Trace metal transfer to passerines inhabiting wastewater treatment wetlands

Wastewater treatment wetlands are cost-effective strategies for remediating trace metals in industrial effluent. However, biogeochemical exchange between wastewater treatment wetlands and adjacent environments provides opportunities for trace metals to cycle in surrounding ecosystems. The transfer of trace metals to wildlife inhabiting treatment wetlands must be considered when evaluating wetland success. Using passerine birds as bioindicators, we conducted a multi-tissue analysis to investigate the mobilization of zinc, copper, and lead derived from wastewater to terrestrial wildlife in treatment wetlands and surrounding habitat. In addition, we evaluate the strength of relationships between metal concentrations in non-lethal (blood and feathers) and lethal (muscle and liver) sample types for estimation of toxicity risk. From July 2020 to August 2021, 177 passerines of seven species were captured at two wetlands constructed to treat industrial wastewater and two reference wetlands in the coastal plain of South Carolina. Feather, blood, liver, and muscle samples from each bird were analyzed for fourteen metals using inductively coupled plasma mass spectrometry and direct mercury analysis. Passerines inhabiting wastewater treatment wetlands accumulated higher concentrations of zinc in liver, copper in blood, and lead in feathers than passerines in reference wetlands, but neither blood nor feather concentrations were correlated with internal tissue concentrations. Of all the detected metals, only mercury in the blood showed a strong predictive relationship with mercury in internal tissues. This study indicates that trace metals derived from wastewater are bioavailable and exported to terrestrial wildlife and that passerine biomonitoring is a valuable tool for assessing metal transfer from treatment wetlands. Furthermore, regular blood sampling can reveal proximate trace metal exposure but cannot predict internal body burdens for most metals.

63 RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTAN↗

Several Small or Single Large? Quantifying the Catchment-Wide Performance of On-Site Wastewater Treatment Plants with Inaccurate Sensors

On-site wastewater treatment plants (OSTs) often lack monitoring, resulting in unreliable treatment performance. They thus appear to be a stopgap solution despite their potential contribution to circular water management. Low-maintenance but inaccurate soft sensors are emerging that address this concern. However, how their inaccuracy impacts the catchment-wide treatment performance of a system of many OSTs has not been quantified. Here, we develop a stochastic model to estimate catchment-wide OST performances with a Monte Carlo simulation. In our study, soft sensors with a 70% accuracy improved the treatment performance from 66% of the time functional to 98%. Soft sensors optimized for specificity, indicating the true negative rate, improve the system performance, while sensors optimized for sensitivity, indicating the true positive rate, quantify the treatment performance more accurately. This new insight leads us to suggest programming two soft sensors in practical settings with the same hardware sensor data as input: one soft sensor geared to high specificity for maintenance scheduling and one geared to high sensitivity for performance quantification. Our findings suggest that a maintenance strategy combining inaccurate sensors with appropriate alarm management can vastly improve the mean catchment-wide treatment performance of a system of OSTs.

54 ENVIRONMENTAL SCIENCES↗

Comparison of multi-stage air treatment process divided by the same temperature and enthalpy difference

The multi-stage air treatment system has been proposed recently, and lower grade chilled/hot water could be used and energy efficiency could be improved. However, it has not been studied which division method of air treatment processes has higher energy efficiency. In this study, the model to calculate the energy consumption of multi-stage air treatment process is introduced, and the effects of two division methods, i.e. multi-stage air treatment process divided by the same temperature difference (ST method) or same enthalpy difference (SE method) between inlet and outlet at each stage, under 9 different air inlet parameters in the 2-stage and 3-stage air treatment processes are analysed and compared. The results show that (1) the system energy consumption of the SE method is generally lower than that of the ST method; (2) there is generally a larger energy consumption reduction rate of SE method when the air relative humidity is 70% compared to relative humidity of 50% and 90%; (3) the difference between ST method and SE method is not great, so both methods can be used for the design of multi-stage treatment system although SE method is normally recommended.

Wang, Wentao↗

An $\bar{F}$ Meshfree Treatment for Nearly Incompressible Materials

The computational modeling of nearly incompressible materials is a difficult task for many numerical methods, and even after several decades of investigation, it is still an active research area. This report seeks to address the treatment of incompressible materials in meshfree methods using a synergistic combination of two treatments. The first treatment is an $\bar{F}$ method, where the decomposed dilatational and deviatoric parts are calculated over different smoothing domains. The second treatment “activates” additional nodes throughout the domain to increase the flexibility of the model. We implement this synergistic combination in the context of the reproducing kernel particle method (RKPM) and present results for the Cook’s membrane benchmark problem. The results are compared with those using the composite tet10 finite element with a volume-averaged J formulation. We show that the combined treatment is an effective way to deal with nearly incompressible materials in a meshfree framework and compares well with other highly-effective treatments.

97 MATHEMATICS AND COMPUTING↗

A Review of Tank 48H Treatment of Tetraphenylborate with Permanganate

Tank 48H contains roughly 270,000 gallons of radioactive waste material. The waste stored in this tank was to be processed in multiple stages utilizing facilities at the Savannah River Site (SRS) almost 30 years ago. The In-Tank Precipitation Process (ITP) was initiated in Tank 48H, which precipitated highly radioactive cesium-137 using sodium tetraphenylborate (NaTPB). While the process succeeded in precipitating the Cs, Sr, and other actinides, it also generated an unexpectedly large amount of benzene. The evolved benzene created a safety concern and made the waste incompatible with further downstream processing. This halted the ITP, and a new method of treatment was required to continue processing the legacy waste contained in Tank 48H. A myriad of treatment options have been proposed with multiple teams of researchers assembled to work on this highly complex issue over the last few decades. This review investigated one potentially viable treatment option, in-tank oxidation with sodium permanganate. Permanganate has been well known in literature as a strong oxidizing agent for organic compounds, as well as being utilized at the Savannah River Site (SRS) in other processes. A small number of studies have been conducted utilizing waste simulants to evaluate the use of permanganate as an oxidant for tetraphenylborate (TPB). A search of the literature and data from these studies indicates that permanganate could be a viable treatment for destruction of TPB in Tank 48H. While the scoping studies had a small number of individual experiments and nonideal conditions, the permanganate decomposed up to 90% of the TPB. A free hydroxide concentration above 1.0 M is required for tank corrosion control. Simulant studies indicate no decrease in TPB decomposition by permanganate until pH 14. The simulant studies show an increase in TPB decomposition as the temperature of the solution is increased to 40 °C. The post-reaction analysis of previous simulant tests did not look at all of the organic degradation products. Investigations into what these organic products are and in what quantity will help guide determinations as to whether the downstream processing facilities are able to handle the material that will be generated. Study on the time frame for the reaction between permanganate and TPB should be investigated as the literature reports only extend out to two weeks reaction time. The permanganate treatment conditions indicate no corrosion control concerns and a longer timescale reaction may be needed for in-tank treatment. In addition, further study would be useful to identify a lower boundary condition for the ratio of TPB and oxidant. The simulant tests applied large excesses of permanganate, and this may be unnecessary. The size constraint of the tank means that there will be practical limitations on the amount of sodium permanganate that can be added to the tank. The amount of permanganate should be minimized as much as possible while still ensuring decomposition of the TPB to minimize the amount of manganese dioxide solids generated.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Acoustic testing of a supersonic tip speed fan with acoustic treatment and rotor casting slots. Quiet engine program scale model fan C

Acoustic tests were conducted on a high tip speed (1550 ft/sec, 472.44 m/sec) single stage fan with varying amounts of wall acoustic treatment and with circumferential slots over the rotor blade tips. The slots were also tested with acoustic treatment placed behind the slots. The wall treatment results show that the inlet treatment is more effective at high fan speeds and aft duct treatment is more effective at low fan speeds. Maximum PNL's on a 200-foot (60.96 m) sideline show the untreated slots to have increased the rear radiated noise at approach. However, when the treatment was added to the slots inlet radiated noise was decreased, resulting in little change relative to the solid casing on an EPNL basis.

Kazin, S. B.↗

Effect of mechanical surface and heat treatments on erosion resistance

The effects of mechanical surface treatments as well as heat treatments on the erosion resistance of 6061 aluminum alloy and 1045 steel were studied. Mechanical surface treatments were found to have little or no effect on the erosion resistance. This is due to the formation by particle impact of a work hardened surface layer regardless of the initial surface condition. The erosion resistance of Al single crystals is found to be independent of orientation. This is due to destruction of the surface microstructure and formation of a polycrystalline surface layer by the impact of erodant particles as observed by X-ray diffraction. While upon solution treatment of annealed 6061 aluminum the increase in hardness is accompanied by an increase in erosion resistance, precipitation treatment which causes a further increase in hardness results in slightly lower erosion resistance. Using two types of erodant particles, glass beads and crushed glass, the erosion rate is found to be strongly dependent on erodant particle shape, being an order of magnitude higher for erosion with crushed glass as compared to glass beads. While for erosion with glass beads heat treatment of 1045 steel had a profound effect on its erosion resistance, little or no such effect was observed for erosion with crushed glass.

Salik, J.↗

Effluent treatment for nuclear thermal propulsion ground testing

The objectives are to define treatment functions, review concept options, discuss PIPET effluent treatment system (ETS), and outline future activities. The topics covered include the following: reactor exhaust; effluent treatment functions; effluent treatment categories; effluent treatment options; concept evaluation; PIPETS ETS envelope; PIPET effluent treatment concept; and future activities.

Shipers, Larry R.↗

Measurement of Insertion Loss of an Acoustic Treatment in the Presence of Additional Uncorrelated Sound Sources

A method to intended for measurement of the insertion loss of an acoustic treatment applied to an aircraft fuselage in-situ is documented in this paper. Using this method, the performance of a treatment applied to a limited portion of an aircraft fuselage can be assessed even though the untreated fuselage also radiates into the cabin, corrupting the intensity measurement. This corrupting noise in the intensity measurement incoherent with the panel vibration of interest is removed by correlating the intensity to reference transducers such as accelerometers. Insertion loss of the acoustic treatments is estimated from the ratio of correlated intensity measurements with and without a treatment applied. In the case of turbulent boundary layer excitation of the fuselage, this technique can be used to assess the performance of noise control methods without requiring treatment of the entire fuselage. Several experimental studies and numerical simulations have been conducted, and results from three case studies are documented in this paper. Conclusions are drawn about the use of this method to study aircraft sidewall treatments.

Klos, Jacob↗

Passive Endwall Treatments for Enhancing Stability

These lecture notes were presented at the von Karman Institutes lecture series on Advances in Axial Compressor Aerodynamics, May 2006. They provide a fairly extensive overview of what's been learned from numerous investigations of various passive casing endwall technologies that have been proposed for alleviating the stall limiting physics associated with the compressor endwall flow field. The lecture notes are organized to give an appreciation for the inventiveness and understanding of the earliest compressor technologists and to provide a coherent thread of understanding that has arisen out of the early investigations. As such the lecture notes begin with a historical overview of casing treatments from their infancy through the earliest proposed concepts involving blowing, suction and flow recirculation. A summary of lessons learned from these early investigations is provided at the end of this section. The lecture notes then provide a somewhat more in-depth overview of recent advancements in the development of passive casing treatments from the late 1990's through 2006, including advancements in understanding the flow mechanism of circumferential groove casing treatments, and the development of discrete tip injection and self-recirculating casing treatments. At the conclusion of the lecture notes a final summary of lessons learned throughout the history of the development of passive casing treatments is provided. Finally, a list of future needs is given. It is hoped that these lecture notes will be a useful reference for future research endeavors to improve our understanding of the fluid physics of passive casing treatments and how they act to enhance compressor stability, and that they will perhaps provide a springboard for future research activities in this area of interest

Hathaway, Michael D.↗

Assessment of Evidence Base from Medical Debriefs Data on Space Motion Sickness Incidence and Treatment

An objective of this data compilation and analysis project is to examine incidence and treatment efficacy of common patho-physiological disturbances during spaceflight. Analysis of medical debriefs data indicated that astronauts used medications to alleviate symptoms of four major ailments for which astronauts received treatment for sleep disturbances, space motion sickness (SMS), pain (headache, back pain) and sinus congestion. In the present data compilation and analysis project on SMS treatment during space missions, subject demographics (gender, age, first-time or repeat flyer), incidence and severity of SMS symptoms and subjective treatment efficacy from 317 crewmember debrief records were examined from STS-1 through STS-89. Preliminary analysis of data revealed that 50% of crew members reported SMS symptoms on at least one flight and 22% never experienced it. In addition, there were 387 medication dosing episodes reported, and promethazine was the most commonly used medication. Results of analysis of symptom check lists, medication use/efficacy and gender and flight record differences in incidence and treatment efficacy will be presented. Evidence gaps for treatment efficacy along with medication use trend analysis will be identified.

Younker, D.R.↗