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NASA NTRS2014

Thermodynamics in the Suppressed Phase of the Madden-Julian Oscillation Using a Multiplatform Strategy

The Madden-Julian Oscillation (MJO) represents a prominent mode of intraseasonal tropical variability. It is manifest by coherent large-scale changes in atmospheric circulation, convection, and thermodynamic processes. Preconditioning of the environment prior to the active phase of the MJO has been noted, but the balance of theorized mechanisms to accomplish this process remains unresolved. Further, there is a lack of consensus on the means by which primary initiation of an MJO event occurs. Observational and modeling efforts have recently been undertaken to advance our understanding of the physical underpinnings governing MJO development. However these intensive studies are often limited in space and/or time and are potentially subject to model deficiencies. Satellite observations, especially those providing vertical resolution of temperature and moisture, provide an opportunity to expand our knowledge of processes critical to MJO initiation and preconditioning. This work will provide an analysis of suppressed phase thermodynamics with an emphasis on the use of a complementary suite of satellite observations including AIRS/AMSU-A profiles, CERES radiative fluxes, and cloud properties observed by MODIS. Emphasis of this work will regard the distribution of cloud regimes, their radiative-convective effects, and their relationship to moist static energy during the recharge and suppressed stages of MJO initiation and eastward propagation. The analyses will make use of cloud regimes from MODIS observations to provide a compositing technique that enables the identification of systematic connections between different cloud regimes and the larger scale environment. Within these cloud regimes, the relationship between the associated cloud-radiative effects observed by CERES, vertically-resolved and vertically-integrated thermodynamics using AIRS/AMSU-A observations, and atmospheric boundary layer fluxes will be demonstrated.

Roberts, J. Brent↗

NASA NTRS1994

Laboratory Investigation of the Growth and Crystal Structure of Nitric Acid Hydrates by Transmission Electron Microscopy (TEM)

A great deal of recent laboratory work has focussed on the characterization of the nitric acid hydrates, thought to be present in type I Polar Stratospheric Clouds (PSCs). Phase relationships and vapor pressure measurements (1-3) and infrared characterizations (4-5) have been made. However, the observed properties of crystalline solids (composition, melting point, vapor pressure, surface reactivity, thermodynamic stability, extent of solid solution with other components, etc.) are controlled by their crystal structure. The only means of unequivocal structural identification for crystalline solids is diffraction (using electrons, X-rays, neutrons, etc.). Other observed properties of crystalline solids, such as their infrared spectra, their vapor pressure as a function of temperature, etc. yield only indirect information about what phases are present, their relative proportions, or whether they are crystalline or amorphous.

Blake, David F.↗

NASA NTRS2010

Characterization of Cloud Water-Content Distribution

The development of realistic cloud parameterizations for climate models requires accurate characterizations of subgrid distributions of thermodynamic variables. To this end, a software tool was developed to characterize cloud water-content distributions in climate-model sub-grid scales. This software characterizes distributions of cloud water content with respect to cloud phase, cloud type, precipitation occurrence, and geo-location using CloudSat radar measurements. It uses a statistical method called maximum likelihood estimation to estimate the probability density function of the cloud water content.

Lee, Seungwon↗

NASA NTRS2001

The Green Ocean Over the Amazon: Implications for Cloud Electrification

A convective regime with distinct maritime characteristics (weak updraft, low CCN, prevalent coalescence and rainout, weak mixed phase reflectivity, low glaciation temperature, and little if any lightning) is documented over the Amazon basin of the South American continent, and dubbed the "green ocean". Radar, lightning, thermodynamic and AVHRR satellite observations are examined to shed light on the roles of updraft and aerosol in providing departures from the green ocean regime toward continental behavior. Extreme case studies are identified in which the updraft control is dominant and in which the aerosol control is dominant. The tentative conclusion gives importance to both updrafts and aerosol in shaping the electrification of tropical convection.

Williams, E.↗

NASA NTRS1986

Protostellar formation in rotating interstellar clouds. V - Nonisothermal collapse and fragmentation

Numerical calculations are presented for rigorous models spanning a four-dimensional parameter space of initial conditions of the three-dimensional collapse of rotating protostellar clouds, encompassing radiative transfer in the Eddington approximation and detailed thermodynamical relations. It is found that protostellar formation may involve a few stages of hierarchical fragmentation terminated by increased thermal pressure in the nonisothermal regime, that high thermal energy clouds remain nearly axisymmetric during the first dynamic collapse phase, and that very slowly rotating clouds can fragment. The presolar nebula was probably formed from a cloud with very little initial rotation.

Boss, Alan R.↗

NASA NTRS2006

Analysis of Rapidly Developing Low Cloud Ceilings in a Stable Environment

Forecasters at the Space Meteorology Group (SMG) issue 30 to 90 minute forecasts for low cloud ceilings at the Space Shuttle Landing Facility (TTS) to support Space Shuttle landings. Mission verification statistics have shown ceilings to be the number one forecast challenge for SMG. More specifically, forecasters at SMG are concerned with any rapidly developing clouds/ceilings below 8000 ft in a stable, capped thermodynamic environment. Therefore, the Applied Meteorology Unit (AMU) was tasked to examine archived events of rapid stable cloud formation resulting in ceilings below 8000 ft, and document the atmospheric regimes favoring this type of cloud development. The AMU examined the cool season months of November to March during the years of 1993-2003 for days that had low-level inversions and rapid, stable low cloud formation that resulted in ceilings violating the Space Shuttle Flight Rules. The AMU wrote and modified existing code to identify inversions from the morning (-10 UTC) Cape Canaveral, FL rawinsonde (XMR) during the cool season and output pertinent sounding information. They parsed all days with cloud ceilings below 8000 ft at TTS, forming a database of possible rapidly-developing low ceiling events. Days with precipitation or noticeable fog burn-off situations were excluded from the database. In the first phase of this work, only the daytime hours were examined for possible ceiling development events since low clouds are easier to diagnose with visible satellite imagery. Phase II of this work includes expanding the database to include nighttime cases which is underway as this abstract is being written. For the nighttime cases, the AMU will analyze both the 00 UTC soundings and the 10 UTC soundings to examine those data for the presence of a low-level inversion. The 00 UTC soundings will probably not have a surface-based inversion, but the presence of inversions or "neutral" layers aloft and below 8,000 ft will most likely help define the stable regime, being a thermodynamically "capped" environment. Occurrences of elevated low-level inversions or stable layers will be highlighted in conjunction with nights that experienced a possible development or onset of cloud ceilings below 8,000 ft. Using these criteria to narrow down the database, the AMU will then use archived IR satellite imagery for these possible events. This presentation summarizes the composite meteorological conditions for 20 daytime event days with rapid low cloud ceiling formation and 48 non-events days consisting of advection or widespread low cloud ceilings and describes two sample cases of daytime rapidly-developing low cloud ceilings. The authors will also summarize the work from the nighttime cases and describe a representative sample case from this data set.

Bauman, William H., III↗

NASA NTRS2004

Thermodynamic Conditions Favorable to Superlative Thunderstorm Updraft, Mixed Phase Microphysics and Lightning Flash Rate

Satellite observations of lightning flash rate have been merged with proximal surface station thermodynamic observations toward improving the understanding of the response of the updraft and lightning activity in the tropical atmosphere to temperature. The tropical results have led in turn to an examination of thermodynamic climatology over the continental United States in summertime and its comparison with exceptional electrical conditions documented in earlier studies. The tropical and mid-latitude results taken together support an important role for cloud base height in regulating the transfer of Convective Available Potential Energy (CAPE) to updraft kinetic energy in thunderstorms. In the tropics, cloud base height is dominated by the dry bulb temperature over the wet bulb temperature as the lightning-regulating temperature in regions characterized by moist convection. In the extratropics, an elevated cloud base height may enable larger cloud water concentrations in the mixed phase region, a favorable condition for the positive charging of large ice particles that may result in thunderclouds with a reversed polarity of the main cloud dipole. The combined requirements of instability and cloud base height serve to confine the region of superlative electrification to the vicinity of the ridge in moist entropy in the western Great Plains.

Williams, E.↗

NASA NTRS1994

H2-rich interstellar grain mantles: An equilibrium description

Experiments simulating the codeposition of molecular hydrogen and water ice on interstellar grains demonstrate that amorphous water ice at 12 K can incorporate a substantial amount of H2, up to a mole ratio of H2/H2O = 0.53. We find that the physical behavior of approximately 80% of the hydrogen can be explained satisfactorily in terms of an equilibrium population, thermodynamically governed by a wide distribution of binding site energies. Such a description predicts that gas phase accretion could lead to mole fractions of H2 in interstellar grain mantles of nearly 0.3; for the probable conditions of WL5 in the rho Ophiuchi cloud, an H2 mole fraction of between 0.05 and 0.3 is predicted, in possible agreement with the observed abundance reported by Sandford, Allamandola, & Geballe. Accretion of gas phase H2 onto grain mantles, rather than photochemical production of H2 within the ice, could be a general explanation for frozen H2 in interstellar ices. We speculate on the implications of such a composition for grain mantle chemistry and physics.

Dissly, Richard W.↗

NASA NTRS2018

Particle Size Calibration Testing in the NASA Propulsion Systems Laboratory

The particle size characterization portion of the 2017 Propulsion Systems Laboratory (PSL) Cloud Calibration is described. The work focuses on characterizing the particle size distribution of the icing cloud as a function of simulated atmospheric conditions.These results will aid in upcoming ice crystal and supercooled liquid icing tests in PSL. Measurements acquired with the Phase Doppler Interferometer and High Speed Imaging instruments are presented. Experimental results indicate that the particle size distribution is primarily a function nozzle air and water pressures, and that air speed is not a significant effect for ice crystal clouds in PSL and both thermodynamic conditions and air speed are not significant effects for supercooled liquid water clouds in PSL.

Engine icing↗

NASA NTRS2019

Particle Size Calibration Testing in the NASA Propulsion Systems Laboratory

Engine Icing↗

NASA NTRS1990

Liquid-Vapor Equilibrium of Multicomponent Cryogenic Systems

Liquid-vapor and solid-vapor equilibria at low to moderate pressures and low temperatures are important in many solar system environments, including the surface and clouds of Titan, the clouds of Uranus and Neptune, and the surfaces of Mars and Triton. The familiar cases of ideal behavior are limiting cases of a general thermodynamic representation for the vapor pressure of each component in a homogeneous multicomponent system. The fundamental connections of laboratory measurements to thermodynamic models are through the Gibbs-Duhem relation and the Gibbs-Helmholtz relation. Using laboratory measurements of the total pressure, temperature, and compositions of the liquid and vapor phases at equilibrium, the values of these parameters can be determined. The resulting model for vapor-liquid equilibrium can then conveniently and accurately be used to calculate pressures, compositions, condensation altitudes, and their dependencies on changing climatic conditions. A specific system being investigated is CH4-C2H6-N2, at conditions relevant to Titan's surface and atmosphere. Discussed are: the modeling of existing data on CH4-N2, with applications to the composition of Titan's condensate clouds; some new measurements on the CH4-C2H6 binary, using a high-precision static/volumetric system, and on the C2H6-N2 binary, using the volumetric system and a sensitive cryogenic flow calorimeter; and describe a new cryogenic phase-equilibrium vessel with which we are beginning a detailed, systematic study of the three constituent binaries and the ternary CH4-C2H6-N2 system at temperatures ranging from 80 to 105 K and pressures from 0.1 to 7 bar.

Thompson, W. Reid↗

NASA NTRS1999

The Lightning Imaging Sensor

The Lightning Imaging Sensor (LIS) is a NASA Earth Observing System (EOS) instrument on the Tropical Rainfall Measuring Mission (TRMM) platform designed to acquire and investigate the distribution and variability of total lightning (i.e., cloud-to-ground and intracloud) between q35' in latitude. Since lightning is one of the responses of the atmosphere to thermodynamic and dynamic forcing, the LIS data is being used to detect deep convection without land-ocean bias, estimate the precipitation mass in the mixed phased region of thunderclouds, and differentiate storms with strong updrafts from those with weak vertical motion.

Christian, Hugh J.↗

NASA NTRS2022

Impact of Meteorological Factors on the Mesoscale Morphology of Cloud Streets during a Cold-Air Outbreak over the Western North Atlantic

Postfrontal clouds (PFC) are ubiquitous in the marine boundary layer, and their morphology is essential to estimating the radiation budget in weather and climate models. Here we examine the roles of sea surface temperature (SST) and meteorological factors in controlling the mesoscale morphology and evolution of shallow clouds associated with a cold-air outbreak that occurred on 1 March 2020 during phase I of the Aerosol Cloud Meteorology Interactions over the Western Atlantic Experiment (ACTIVATE). Our results show that the simulated PFC structure and ambient conditions by the Weather Research and Forecasting (WRF) Model are generally consistent with observations from GOES-16 and dropsonde measurements. We also examine the thermodynamical and dynamical influences in the cloud mesoscale morphology using WRF sensitivity experiments driven by two meteorological forcing datasets with different domain-mean SST and spatial gradients, which lead to dissimilar values of hydrometeor water path and cloud core fraction. The SST from ERA5 leads to weaker stability and higher inversion height than the SST from FNL does. In addition, the use of large-scale meteorological forcings from ERA5 yields a distinctive time evolution of wind direction shear in the inner domain, which favors the formation and persistence of longer cloud rolls. Both factors contribute to a change in the time evolution of domain-mean water path and cloud core fraction of cloud streets. Our study takes advantage of the simulation driven by the differences between two large-scale forcing datasets to illustrate the importance of SST and wind direction shear in the cloud street morphology in a realistic scenario

Jingyi Chen↗

NASA NTRS1977

Optical polarimetry: Instrumentation and applications; Proceedings of the Seminar, San Diego, Calif., August 23, 24, 1977

Instrumentation used in optical polarimetry is discussed with reference to high-resolution spectropolarimetry, an orbiter cloud photopolarimeter, X-ray polarimeters, and the design of a self-nulling ellipsometer. Consideration is given to surface and thin-film ellipsometry noting studies of electrochemical surface layers, surface anisotropy, polish layers on infrared window materials, and anodic films. Papers on biological, chemical, and physical polarimetry are presented including birefringence in biological materials, vibrational optical activity, and the optical determination of the thermodynamic phase diagram of a metamagnet. Remote sensing is discussed in terms of polarization imagery, the optical polarimetry of particulate surfaces, and techniques and applications of elliptical polarimetry in astronomy and atmospheric studies.

Azzam, R. M. A.↗

NASA NTRS2023

A 1D Model for Nucleation of Ice From Aerosol Particles: An Application to a Mixed-Phase Arctic Stratus Cloud Layer

Mixed-phase clouds (MPCs) have been identified as significant contributors to uncertainties in climate projections, attributable to model representation of processes controlling the formation and loss of supercooled water droplets and ice particles from the atmosphere. Arctic MPCs are commonly widespread and long-lived, with sustained ice crystal formation processes that challenge current understanding. This study examines the ice-nucleating particle (INP) reservoir dynamics governing immersion-mode heterogeneous freezing in an observed case of Arctic MPCs using a simplified 1D aerosol-cloud model. The model setup includes prescribed dynamical forcings and thermodynamic profiles, and represents INPs as multicomponent and polydisperse particle size distributions. Diagnostic and prognostic approaches to immersion freezing parameterization are compared, including time-independent (singular) number- and surface area-based descriptions and a time-dependent description following classical nucleation theory (CNT). The choice of freezing parameterization defines the size of the INP reservoir. The CNT-based description yields an orders of magnitude larger INP reservoir than the singular parameterizations, which is the dominant factor for sustained ice crystal formation. The efficiency of the freezing process and cloud cooling are of secondary importance. A diagnostic treatment neglecting INP loss is only accurate when the INP reservoir size is large and INP depletion weak. Since a larger INP reservoir sustains ice crystal formation substantially longer, and ice water path scales with ice crystal concentrations for the conditions considered, resolving the source of differences in INP reservoir dynamics due to model implementation is a high priority for advancing climate model physics.

aerosol↗

NASA NTRS1973

Chemistry in interstellar space

The particular characteristics of chemistry in interstellar space are determined by the unique environmental conditions involved. Interstellar matter is present at extremely low densities. Large deviations from thermodynamic equilibrium are, therefore, to be expected. A relatively intense ultraviolet radiation is present in many regions. The temperatures are in the range from 5 to 200 K. Data concerning the inhibiting effect of small activation energies in interstellar clouds are presented in a table. A summary of measured activation energies or barrier heights for exothermic exchange reactions is also provided. Problems of molecule formation are discussed, taking into account gas phase reactions and surface catalyzed processes.

Donn, B.↗

NASA NTRS1995

Freezing Behavior of Stratospheric Sulfate Aerosols Inferred from Trajectory Studies

Based on the trajectory analysis presented in this paper, a new mechanism is described for the freezing of the stratospheric sulfate aerosols. Temperature histories based on 10-day back trajectories for six ER-2 flights during AASE-I (1989) and AAOE (1987) are presented. The mechanism requires, as an initial step, the cooling of a H2SO4/H2O aerosol to low temperatures. If a cooling cycle is then followed up by a warming to approximately 196-198 K, the aerosols may freeze due to the growth of the crystallizing embryos formed at the colder temperature. The HNO3 absorbed at colder temperatures may increase the nucleation rate of the crystalling embryos and therefore influence the crystallization of the supercooled aerosols upon warming. Of all the ER-2 flights described, only the polar stratospheric clouds (PSC), observed on the flights of January 24, and 25, 1989 are consistent with the thermodynamics of liquid ternary solutions of H2SO4/HNO3/H2O (type Ib PSCs). For those two days, back trajectories indicate that the air mass was exposed to sulfuric acid tetrahydrate (SAT) melting temperatures about 24 hours prior to being sampled by the ER-2. Temperature histories, recent laboratory measurements, and the properties of glassy solids suggest that stratospheric H2SO4 aerosols may undergo a phase transition to SAT upon warming at approximately 198 K after going through a cooling cycle to about 194 K or lower.

Tabazadeh, A.↗

NASA NTRS1981

Vibrational disequilibrium in low pressure clouds

Steady state vibrational populations of SiO and CO in several dilute blackbody radiation fields have been calculated as a function of total pressure, kinetic temperature, and chemical composition of the gas. An approximate calculation for polyatomic molecules has also been carried out. Vibrational disequilibrium becomes increasingly significant as the total pressure and radiation density decrease. Many regions of postulated grain formation are found to be far out of thermal equilibrium before the onset of condensation. The use of classical nucleation theory and equilibrium thermodynamics to predict the onset of condensation and the composition of the solids or the molecular composition of the gas phase in such regions therefore is very questionable and needs to be examined for each case.

Nuth, J. A.↗