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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS2007

Alfven Waves in the Solar Wind, Magnetosheath, and Outer Magnetosphere

Alfven waves Propagating outward from the Sun are ubiquitous in the solar wind and play a major role in the solar wind-magnetosphere interaction. The passage of the waves generally occurs in the form of a series of discrete steepened discontinuities, each of which results in an abrupt change in the interplanetary magnetic field direction. Some orientations of the magnetic field permit particles energized at the Earth's bow shock to gain access to the foreshock region immediately upstream from the Earth's bow shock. The thermal pressure associated with these particles can greatly perturb solar wind plasma and magnetic field parameters shortly prior to their interaction with the Earth's bow shock and magnetosphere. The corresponding dynamic pressure variations batter the magnetosphere, driving magnetopause motion and transient compressions of the magnetospheric magnetic field. Alfven waves transmit information concerning the dynamic pressure variations applied to the magnetosphere to the ionosphere, where they generate the traveling convection vortices (TCVs) seen in high-latitude ground magnetograms. Finally, the sense of Alfvenic perturbations transmitted into the magnetosheath reverses across local noon because magnetosheath magnetic field lines drape against the magnetopause. The corresponding change in velocity perturbations must apply a weak torque to the Earth's magnetosphere.

Sibeck, D. G.↗
NASA NTRS2021

Compact Thermal Imager (CTI) for Atmospheric Remote Sensing

The demonstration of a newly developed compact thermal imager (CTI) on the International Space Station (ISS) has provided not only a technology advancement but a rich high-resolution dataset on global clouds, atmospheric and land emissions. This study showed that the free-running CTI instrument could be calibrated to produce scientifically useful radiance imagery of the atmosphere, clouds, and surfaces with a vertical resolution of ~460 m at limb and a horizontal resolution of ~80 m at nadir. The new detector demonstrated an excellent sensitivity to detect the weak limb radiance perturbations modulated by small-scale atmospheric gravity waves. The CTI’s high-resolution imaging was used to infer vertical cloud temperature profiles from a side-viewing geometry. For nadir imaging, the combined high-resolution and high-sensitivity capabilities allowed the CTI to better separate cloud and surface emissions, including those in the planetary boundary layer (PBL) that had small contrast against the background surface. Finally, based on the ISS’s orbit, the stable detector performance and robust calibration algorithm produced valuable diurnal observations of cloud and surface emissions with respect to solar local time during May–October 2019, when the CTI had nearly continuous operation.

thermal imager↗
DOE OSTI2021

Semicomputational calculation of Bragg shift in stratified materials

The fiber Bragg grating (FBG) may be viewed as a one dimensional photonic band-gap crystal by virtue of the periodic spatial perturbation imposed on the fiber core dielectric material. Similar to media supporting Bloch waves, the engraved weak index modulation, presenting a periodic “potential” to an incoming guided mode photon of the fiber, yields useful spectral properties that have been the basis for sensing applications and emerging quantum squeezing and solitons. The response of an FBG sensor to arbitrary external stimuli represents a multiphysics problem without a known analytical solution despite the growing use of FBGs in classical and quantum sensing and metrology. Here, we study this problem by first presenting a solid mechanics model for the thermal and elastic states of a stratified material. Additionally, the model considers an embedded optical material domain that represents the Bragg grating, here in the form of an FBG. Using the output of this model, we then compute the optical modes and their temperature- and stress-induced behavior. The developed model is applicable to media of arbitrary shape and composition, including soft matter and materials with nonlinear elasticity and geometric nonlinearity. Finally, we employ the computed surface stress and temperature distributions along the grating to analytically calculate the Bragg shift, which is found to be in reasonable agreement with our experimental measurements.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2006

Studies of acoustic-electric feed-throughs for power transmission through structures

There are numerous engineering design problems where the use of wires to transfer power and communicate data thru the walls of a structure is prohibitive or significantly difficult that it may require a complex design. Using physical feedthroughs in such systems may make them susceptible to leakage of chemicals or gasses, loss of pressure or vacuum, as well as difficulties in providing adequate thermal or electrical insulation. Moreover, feeding wires thru a wall of a structure reduces the strength of the structure and makes the structure prone to cracking due to fatigue that can result from cyclic loading and stress concentrations. One area that has already been identified to require a wireless alternative to electrical feedthroughs is the container of the Mars Sample Return Mission, which will need wireless sensors to sense a pressure leak and to avoid potential contamination. The idea of using elastic or acoustic waves to transfer power was suggested recently by [Y. Hu, et al., July 2003]. This system allows for the avoidance of cabling or wiring. The technology is applicable to the transfer of power for actuation, sensing and other tasks inside any sealed container or vacuum/pressure vessel. An alternative approach to the modeling presented previously [Sherrit et a., 2005] used network analysis to solve the same problem in a clear and expandable manner. Experimental tests on three different designs of these devices were performed. The three designs used different methods of coupling the piezoelectric element to the wall. In the first test the piezoelectric material was bolted using a backing structure. In the second test the piezoelectric was clamped after the application of grease and finally the piezoelectric element was attached using a conductive epoxy. The mechanical clamp with grease produced the highest measured efficiency of 53% however this design was the least practical from a fabrication viewpoint. The power transfer efficiency of conductive epoxy joint was 40% and the stress bolts (12%).

ultrasonics↗
NASA NTRS1987

The acceleration of winds by MHD waves in open magnetic structures

It has become increasingly clear in recent years that the available models describing the acceleration of high speed streams in solar coronal holes are inadequate. Thermal models do not result in winds with the proper thermal speed and density. In addition models which assume acceleration by Alfven waves, though promising, are not self-consistent when applied low in coronal holes where the acceleration of the wind takes place. An Alfven wave in the corona with a period of a few hundred seconds will have a wavelength of the order of 10 cm. This is of the order of the diameter of a coronal hole in the low corona, and therefore it is expected that the MHD waves are guided in some sense by the coronal hole in which they propagate. This basic idea led to the development of a leaky waveguide theory to describe MHD wave propagation in coronal holes. Recent efforts were concentrated in two areas: the development of numerical codes to properly describe the hydrodynamics of the flow, and more realistic models of the coronal hole properties such as density gradients and spherical divergence of the flux tube. Some of the important aspects of the theory are discussed, including the effect of density inhomogeneities and smooth transverse density gradients. In addition it is hoped that some early results from the numerical models will be presented. The acceleration of cool winds is a problem of interest in cool supergiants also. Some work was done on the development of wind models for these stars as well.

Davila, Joseph M.↗
NASA NTRSDate not supplied

IceCube: Demonstration of an 883 GHz Radiometer for Ice Cloud Remote Sensing

IceCube was a technology demonstration of an 883 GHz heterodyne radiometer on a 3U CubeSat for ice cloud characterization. The project was a collaboration between Goddard Space Flight Center, Virginia Diodes Inc., and Wallops Flight Facility. IceCube was launched to the International Space Station (ISS) in April 2017, and was deployed to the orbit in May 2017. The radiometer measured ice cloud emissions from an ISS orbit for over 15 months. IceCube generated the first 883 GHz cloud map over a large operation temperature range of (5 ºC—37 ºC). Cloud ice plays a major role in the cloud precipitation process and Earth’s energy budget. Ice clouds are used in global circulation models as tuning parameters to achieve model agreement with observation at the top of the atmosphere in the radiation budget and at the bottom for precipitation, however, due to a lack of accurate ice cloud measurements large uncertainties exist in these models. Submillimeter wave remote sensing is capable of addressing this issue by measuring cloud ice mass and microphysical properties in the middle-to-upper troposphere. This fills the sensitivity gap not covered by the visible/infrared and microwave sensors [1]. The goal of IceCube was to increase the TRL of a heterodyne 883 GHz radiometer (using commercial parts) from 5 to 7 by validating the performance in a relevant spaceflight environment. The design of the radiometer was driven by frequency of operation, bandwidth, calibration, available power, and thermal environment requirements. The design included a 15 mm aperture off-axis parabolic reflector with a Potter feed horn, an 883 GHz 2nd-harmonic mixer that is fed by a local oscillator chain with a 24.3 GHz dielectric resonator (MLA), followed by a 6 GHz bandwidth centered at 9 GHz intermediate frequency assembly (IFA), receiver interface card, and power distribution unit. The IFA included an internal noise diode calibration to separate the MLA performance from the rest of the system. For this the radiometer had four operational states: antenna, antenna + noise, reference, and reference + noise; each state’s duration was 10 ms. The total power dissipation of the instrument was 5.6 W. The spacecraft had spinning capabilities to provide a cold sky view for calibration. We present the instrument design, ground test results, challenges, and highlight some of the flight measurements.

N Ehsan↗
NASA NTRS1989

Using passive, thermal remote sensing techniques for detecting subsurface gravel accumulations in vegetated, unconsolidated sedimentary terrains

Multiband radiometric data from an airborne imaging thermal scanner are being studied for use in finding buried gravel deposits. The techniques are based on measuring relative differences in the thermal properties between gravel-laden targets and the surrounding gravelless background. These properties are determined from modeling the spectral radiant emittance recorded over both types of surfaces in conjunction with ground measurements of the most significant heat flows above and below the surface. Thermodynamic properties of sampled materials from control sites are determined, and diurnal and annual subsurface heat waves are recorded. Thermal models that account for heat exchange at the surface, as well as varying levels of soil moisture, humidity, and vegetation, are needed for adaptation and modification to simulate the physical and radiative environments of this region.

Burns, Gregory S.↗
NASA NTRS1997

Application of Laser Based Ultrasound for NDE of Damage in Thick Stitched Composites

As design engineers implement new composite systems such as thick, load bearing composite structures, they must have certifiable confidence in structure s durability and worthiness. This confidence builds from understanding the structural response and failure characteristics of simple components loaded in testing machines to tests on full scale sections. Nondestructive evaluation is an important element which can provide quantitative information on the damage initiation, propagation, and final failure modes for the composite structural components. Although ultrasound is generally accepted as a test method, the use of conventional ultrasound for in-situ monitoring of damage during tests of large structures is not practical. The use of lasers to both generate and detect ultrasound extends the application of ultrasound to in- situ sensing of damage in a deformed structure remotely and in a non-contact manner. The goal of the present research is to utilize this technology to monitor damage progression during testing. The present paper describes the application of laser based ultrasound to quantify damage in thick stitched composite structural elements to demonstrate the method. This method involves using a Q-switched laser to generate a rapid, local linear thermal strain on the surface of the structure. This local strain causes the generation of ultrasonic waves into the material. A second laser used with a Fabry-Perot interferometer detects the surface deflections. The use of fiber optics provides for eye safety and a convenient method of delivering the laser over long distances to the specimens. The material for these structural elements is composed of several stacks of composite material assembled together by stitching through the laminate thickness that ranging from 0.5 to 0.8 inches. The specimens used for these nondestructive evaluation studies had either impact damage or skin/stiffener interlaminar failure. Although little or no visible surface damage existed, internal damage was detected by laser based ultrasound.

Anastasi, Robert F.↗
NASA NTRS2009

High Spectral Resolution Infrared Studies of Titan: Winds, Temperature and Composition

Results from the most recent analyses of resolved ethane Line emission profiles from the stratosphere of Titan, measured before (2003) [1, 2], near the time of (2005) [3, 4], and after (2008) Huygens descent, will be presented. Wind velocity, temperature and ethane abundance are retrieved from 11.7 micron measurements at spectral resolving, powers > 1000000 using the NASA Goddard Space Flight Center Heterodyne Instrument for Planetary Wind And Composition (HIPWAC) interfaced with the 8.2 meter Subaru telescope of the National Astronomical Observatory of Japan. Retrieved wind velocities (approx.190 m/s at 230 km) from Doppler shifts of measured emission lines are compared to previous infrared heterodyne studies and compared to results front either direct wired measurements - Huygens Doppler Wind Experiment [5], Doppler shifts of reflected visible radiation [6], and mm-wave investigations [7]. Comparison to indirect wind retrievals from stellar occultation [8] observations and Cassini CIRS thermal maps [9] is also made, An empirical altitude-dependent wired model will be presented. The narrow ethane emission lines are analyzed to retrieve the ethane mole fraction and an attempt is made to evaluate the altitude distribution of ethane in the stratosphere for thermal profiles derived from measurements from Cassini and Huygens. Resultant ethane altitude distributions will be discussed and comparison to results front earlier HIPWAC and other remote sensing measurements and from contemporaneous Cassini/Huygens investigations [10, 11] will be made. Preliminary comparison suggests temporal or spatial variability in the line emission and retrieved ethane abundance in Titan's stratosphere:. Possible detection of minor hydrocarbon constituents and evidence of possible probing of Titan's mesosphere and of mesospheric wind shear will be discussed.

Kostiuk, T.↗
NASA NTRS2023

Dynamical Core Damping of Thermal Tides in Martian Atmosphere

Atmospheric oscillations with daily periodicity are observed in in-situ near-surface pressure, temperature, and winds observations, and also in remotely sensed temperature and pressure observations of the Martian atmosphere. Such oscillations are interpreted as thermal tides driven by the diurnal cycle of solar radiation and occur at various frequencies, with the most prominent being the diurnal, semidiurnal, terdiurnal and quadiurnal tides. Mars global circulation models reproduce these tides with varying levels of success. Until recently, both the MarsWRF and newly developed MarsMPAS models were able to produce realistic diurnal and semidiurnal tide amplitudes but predicted higher-order mode amplitudes that were significantly weaker than observed. We use linear wave analysis to show that the divergence damping applied within both MarsWRF and MarsMPAS is responsible for suppressing the amplitude of thermal tides with frequency greater than 2 per sol, despite being designed to suppress only acoustic wave modes. Decreasing the strength of the divergence damping in MarsWRF and MarsMPAS allows for excellent prediction of the higher order tidal modes. This finding demonstrates that care must be taken when applying numerical dampers and filters that may eliminate some desired dynamical features in planetary atmospheres.

Yuan Lian↗
DOE OSTI2023

Technology Maturation of Wireless Harsh Environment Sensors For Improved Condition Based Monitoring Of Coal Fired Power Generation

The overall goal of this project was to demonstrate and develop the usage of high-temperature (HT) harsh-environment (HE) wireless surface acoustic wave resonator (SAWR) sensor technology to promote reliable maintenance through condition-based maintenance (CBM) for field applications in harsh service conditions associated with power plant environments. The project aimed to advance the HT HE wireless SAWR sensor technology from TRL 5 to TRL 7. In addition to HT HE wireless temperature sensing, efforts were dedicated during this project to investigate, develop and increase the TRL from 3 to 5 for the following technologies: (a) HT HE strain sensors to address additional CBM monitoring needs, such as boiler tube mechanical / thermal stresses, which can provide early indications for boiler tube cracking and failure; and (b) HT aluminum nitride (AlN) and scandium aluminum nitride (ScAlN) based piezoelectric thin film fabrication and implementation of SAW sensors, with the goal of releasing the need to use single crystal piezoelectric materials for SAWRs and thus broaden possible technology applications to non-planar and harder to modify surfaces. To achieve the goals mentioned above, UMaine and its partner, Environetix Technologies Corporation, established partnerships with the following power plants: Longview Power (Maidsville, WV), a coal-fired power plant; Penobscot Energy Recovery Corp (PERC, Orrington, ME), a waste-to-energy power plant; and the UMaine Steam Plant (Orono, ME), an oil / natural gas power plant. To realize wireless HT HE SAWR sensor systems in these harsh service conditions, the University of Maine research team worked with Environetix and these power plants to define, design, fabricate, test and validate a mature prototype wireless temperature SAWR sensor system for boiler tube applications within the HT HE of the reheater pass damper chamber to directly and wirelessly monitor the temperature at eighteen independent boiler tube locations. The system included three levels, or “tiers”, of wireless communication to enable remote monitoring: Tier 1, the wireless link in the reheater pass damper chamber directly accessing the sensors on the boilers; Tier 2, the wireless local area network link, transmitting processed sensor information within the power plant to the Tier 3, a commercial wireless signal carrier company for secure remote data monitoring outside of the power plant. Regarding the wireless sensor system installed at Longview Power, temperature information from the boilers was continuously transmitted from the Longview boilers at Maidsville, WV, to Environetix headquarters, Orono, ME, over a 34 month period, when the system was finally decommissioned. Strain sensors and piezoelectric ScAlN thin film sensors were successfully installed on the exhaust duct at the UMaine Steam Power plant. The advances in wireless strain sensors and thin film piezoelectric film fabrication and testing were performed mostly in UMaine laboratories and field tested at the UMaine Steam Plant, due to its close proximity to UMaine/Environetix, access to the plant facility, and due to difficulties in accessing the other power plants during the COVID shut-down period. The project accomplished the TRL level increase of the targeted CBM technologies through the successful fabrication, installation, test, and validation of dedicated and commercial wireless sensor systems, utilizing the three different power plants. The outcomes of this project, including the wireless sensor data capability, are expected to yield an advance for CBM in harsh power plant environments. The reduction of maintenance costs, improved safety during plant operation, and increased power plant efficiency will lead to increased revenues (i.e., fewer forced outages) due to better process monitoring enabled by the wireless HT HE SAWR temperature sensor technology.

20 FOSSIL-FUELED POWER PLANTS↗
NASA NTRS1980

Structure and meteorology of the middle atmosphere of Venus Infrared remote sensing from the Pioneer orbiter

The results of the Pioneer Venus orbiter radiometric temperature-sounding experiment are presented with examples of each of the primary data products. The measured temperature field is used to model the dynamics of the middle atmosphere from 60 to 140 km, and the thermal and solar fluxes are used to calculate the planetary radiation budget. The data for the diurnal variation of temperature at a given height show fairly small amplitudes up to an altitude of about 95 km, above which the day to night contrast increases rapidly with height. At the equator the dependence of temperature in the stratosphere on solar longitude is dominated by a wave number 2 solar tide with an amplitude of about 10 K. The equator to pole gradients are larger than expected, and the stratosphere is typically 15 to 20 K warmer at the pole than at the equator. The most significant discovery concerning the cloud morphology is a dipole structure consisting of two clearings in the cloud at locations straddling the pole and rotating around it every 2.7 days.

Taylor, F. W.↗
NASA NTRS1995

Applications of GOES-8/9 data to hurricane analysis

GOES-8 was successfully launched in 1994, and has performed up to expeditions and in some cases has actually exceeded pre-launch specifications. A similar geostationary satellite, GOES-9, was launched in May of 1995. This new generation of NOAA's geostationary satellites carry a superior design and instrumentation package that allow for greater detection of meteorological features and parameters. The new GOES imager has a 5 band multispectral capability with high spatial resolution, while the sounder contains 18 thermal infrared (IR) bands plus a low resolution visible band. The imager carries a visible channel with 1 10-bit quantization and increased sampling frequency, a short-wave and long-wave window channel, and a water vapor band with a twofold increase in spatial resolution and a factor of 3 improvement in signal-to-noise over that obtained from previous GOES sensors. The advances in observing the earth's atmospheric system anticipated from these improvements are outlined in Menzel and Purdom (1994). The specific impact of this improved remote sensing capability on the analysis of tropical cyclones is discussed here.

Velden, Christopher S.↗
NASA NTRSDate not supplied

Science Objectives of the ACCP/AOS Millimeter- and Submillimeter-Wave Radiometers

Passive microwave radiometers provide highly useful information regarding the Earth system by measuring thermal emission (from the surface and atmosphere) that is reflected, absorbed, and scattered by the surface and the atmosphere. As such, radiometers have been instrumental across Earth-observing concepts with heritage tracing back to the Nimbus era, and clouds and precipitation have been key geophysical phenomena these sensors have targeted. As millimeter-wave (particularly ≥85 GHz) and submillimeter-wave technologies have advanced, the applicability of microwave radiometers has expanded to encompass falling snow and ice clouds, respectively. Given the strong heritage of microwave radiometry and the emergence of submillimeter-wave sensors for sensing falling snow and ice clouds, the National Academies’ 2017 Decadal Survey for Earth Science and Applications from Space recommended passive sensors covering these wavelengths be included in observing systems that address the Aerosols, Clouds, Convection, and Precipitation (ACCP) combined designated observable. To showcase the capabilities for addressing the ACCP science objectives, we will provide an overview of the passive microwave capabilities envisioned for the Atmosphere Observing System (AOS, part of the recently unveiled NASA Earth System Observatory), including descriptions of the radiometers for the inclined and polar orbits and the primary geophysical variables of interest related to ice-phase clouds and precipitation. We will also discuss secondary science objectives, such as precipitation mapping, that can be achieved with the ACCP/AOS radiometers. Examples from the analyses performed for the ACCP/AOS architecture study and subsequent sensor definition exercises will be presented, outlining the basis for the radiometer configuration within the context of the overarching ACCP/AOS goals to elucidate the connections between atmospheric dynamics, weather (including extreme events), air quality, and climate.

Ian S Adams↗
NASA NTRS1999

Observations of Convective and Dynamical Instabilities in Tropopause Folds and their Contribution to Stratosphere-Troposphere Exchange

With aircraft-mounted in-situ and remote sensing instruments for dynamical, thermal. and chemical measurements, we studied two cases of tropopause folding. In both folds we found Kelvin-Helmholtz billows with horizontal wavelength of about 900 m and thickness of about 120 m. In one case the instability was effectively mixing the bottomside of the fold, leading to the transfer of stratospheric air into the troposphere. Also we discovered in both cases small-scale secondary ozone maxima shortly after the aircraft ascended past the topside of the fold that corresponded to regions of convective instability. We interpreted this phenomenon as convectively breaking gravity waves. Therefore, we posit that convectively breaking gravity waves acting on tropopause folds must be added to the list of important irreversible mixing mechanisms leading to stratosphere-troposphere exchange.

Cho, John Y. N.↗
NASA NTRSDate not supplied

The Nature of Space Weathering in Samples From Asteroid (162173) Ryugu Revealed By Coordinated Analysis

Space weathering, driven primarily by micrometeorite bombardment and solar wind ion irradiation, alters the morphology, microstructure, and chemistry of the surface regolith on airless bodies. The accumulation of microstructural and chemical space weathering features, including melt deposits, amorphous rims, and nanophase iron-bearing particles (npFe), are associated with alterations of the spectral properties of the regolith. In particular, space weathering changes the spectral slope and reflectance of surface materials, and causes the attenuation of characteristic absorption bands in the visible to near-infrared wave-lengths, as well as a shift towards longer wavelengths of the Christiansen feature (CF)in thermal infrared spectra. Previous studies of space weathering characteristics have focused on siliceous bodies like the Moon and S-type asteroid Itokawa. However, observations of asteroid Ryugu by the JAXA Hayabusa2 spacecraft and subsequent analyses of returned samples revealed carbonaceous and hydrated materials. These samples provided our first opportunity to constrain the effects of space weathering processes on primitive, C-type asteroids. Analyses of returned samples to understand the space weathering of carbonaceous materials are important for accurately interpreting remote sensing observations of carbonaceous asteroids. In addition, the analysis of Hayabusa2 samples from Ryugu paved the way for the analysis of samples from the asteroid Bennu, re-turned by the NASA OSIRIS-REx mission. As space weathering impacts the microstructure, chemistry, and spectral characteristics of asteroidal surfaces, here we report the results of a coordinated analytical study of the micro-and nano-scale signatures of space weathering in samples returned from Ryugu.

L E Melendez↗
DOE OSTI2025

A Conjugated Oligoelectrolyte Exhibiting Room Temperature Spin-Correlated Radical Pair Character for Biological Sensing

We report a water-soluble conjugated oligoelectrolyte (COE) composed of carbazole-benzophenone, COE-CbzBP, that exhibits photogenerated spin-correlated radical pair (SCRP) behavior sensitive to static electric fields from DNA but not from lipid bilayers. The SCRP forms from a thermally activated, spin-polarized state enabled by partial π-conjugation disruption at the donor–acceptor (carbazole-benzophenone) nitrogen–carbon (N–C) junction, which facilitates a twisted intramolecular charge-transfer (TICT) geometry. This state minimizes the singlet–triplet energy gap (ΔE ST = 0.12 eV), radical–pair exchange coupling (J RP ∼ ΔE ST /2), and charge separation free energy (ΔG CS ) in both DNA (−0.19 eV) and lipid bilayers (−0.55 eV). Room-temperature continuous-wave electron paramagnetic resonance (CW-EPR) reveals a photogenerated spin-polarized singlet for COE-CbzBP that splits upon DNA association, consistent with modulation of J RP and hyperfine coupling (A x ), presumably via electric field-spin coupling. No spin-polarized signal was observed under dark, cryogenic conditions, or in liposomes, but was quenched by the spin trap 4-POBN. Transient absorption and spectroelectrochemistry confirmed magnetic-field sensitive long-lived excited-state absorption features attributed to charge-separated states 3 [Cbz •+ -BP •– ]*, which were lengthened by DNA, and quenched in lipid bilayers and 4-POBN. Quantum chemical simulations show that planar geometries (lipid-like) increase ΔE ST by 0.31 eV compared to TICT-optimized structures. This geometry-dependent modulation explains the absence of SCRP signatures in rigid environments, underscoring the importance of TICT states, minimized ΔE ST , and favorable ΔG CS for achieving room-temperature SCRP generation. These findings establish design principles for TICT-enabled molecules exhibiting qubit-like behavior that operate under ambient and biologically relevant conditions, with direct implications for quantum information science (QIS).

Aromatic compounds↗
NASA NTRS1979

Thermal compensator for closed-cycle helium refrigerator

The wave length of an infrared, semiconductor laser diode having an output frequency that is dependent on the diode temperature is maintained substantially constant by maintaining the diode temperature constant. The diode is carried by a cold tip of a closed cycle helium refrigerator. The refrigerator has a tendency to cause the temperature of the cold tip to oscillate. A heater diode and a sensor diode are placed on a thermal heat sink that is the only highly conductive thermal path between the laser diode and the cold tip. The heat sink has a small volume and low thermal capacitance so that the sensing diode is at substantially the same temperature as the heater diode and substantially no thermal lag exists between them. The sensor diode is connected in a negative feedback circuit with the heater diode so that the tendency of the laser diode to thermally oscillate is virtually eliminated.

Jennings, D. E.↗