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Surface States and Effective Surface Area on Photoluminescent P-Type Porous Silicon

The present study is motivated by the possibility of utilizing porous silicon for spectral sensors. Pulse measurements on the porous-Si/electrolyte system are employed to determine the surface effective area and the surface-state density at various stages of the anodization process used to produce the porous material. Such measurements were combined with studies of the photoluminescence spectra. These spectra were found to shift progressively to the blue as a function of anodization time. The luminescence intensity increases initially with anodization time, reaches a maximum and then decreases with further anodization. The surface state density, on the other hand, increases with anodization time from an initial value of about 2 x 10(exp 12)/sq cm surface to about 1013 sq cm for the anodized surface. This value is attained already after -2 min anodization and upon further anodization remains fairly constant. In parallel, the effective surface area increases by a factor of 10-30. This behavior is markedly different from the one observed previously for n-type porous Si.

Weisz, S. Z.

Lunar and Planetary Science XXXV: Mars: Surface Coatings, Mineralogy, and Surface Properties

The session "Mars: Surface Coatings, Mineralogy, and Surface Properties" contained the following reports:High-Silica Rock Coatings: TES Surface-Type 2 and Chemical Weathering on Mars; Old Desert Varnish-like Coatings and Young Breccias at the Mars Pathfinder Landing Site; Analyses of IR-Stealthy and Coated Surface Materials: A Comparison of LIBS and Reflectance Spectra and Their Application to Mars Surface Exploration; Contrasting Interpretations of TES Spectra of the 2003 Rover:Opportunity-Landing Site: Hematite Coatings and Gray Hematite; A New Hematite Formation Mechanism for Mars; Geomorphic and Diagenetic Analogs to Hematite Regions on Mars: Examples from Jurassic Sandstones of Southern Utah, USA; The Geologic Record of Early Mars: A Layered, Cratered, and "Valley-"ed: Volume; A Simple Approach to Estimating Surface Emissivity with THEMIS; A Large Scale Topographic Correction for THEMIS Data; Thermophysical Properties of Meridiani Planum, Mars; Thermophysical and Spectral Properties of Gusev, the MER-Spirit Landing Site on Mars; Determining Water Content of Geologic Materials Using Reflectance Spectroscopy; and Global Mapping of Martian Bound Water at 6.1 Microns Based on TES Data: Seasonal Hydration.

Source record

Pickup Ion Mass Spectrometry for Surface Bounded Exospheres and Composition Mapping of Lunar and Planetary Surfaces

Many of the small to medium sized objects in the solar system can be characterized as having surface bounded exospheres, or atmospheres so tenuous that scale lengths for inter-particle collisions are much larger than the dimensions of the objects. The atmospheres of these objects are the product of their surfaces, both the surface composition and the interactions that occur on them and also their interiors when gases escape from there. Thus by studying surface bounded exospheres it is possible to develop insight into the composition and processes that are taking place on the surface and interiors of these objects. The Moon and Mercury are two examples of planetary bodies with surface bounded exospheres that have been studied through spectroscopic observations of sodium, potassium, and, on the moon, mass spectrometric measurements of lunar gases such as argon and helium.

Keller, J. W.

Enhanced Surface Spray Cooling with Embedded and Compound Extended Surface Structures

Experiments were conducted to study the effects of enhanced surface structures on heat flux using spray cooling. The surface enhancements consisted of embedded structures (dimples, pores, and tunnels) and compound extended surface enhancements (straight fins, cubic pin fins and dimples) machined on and within the top surface of copper heater blocks. Each copper block had a projected cross-sectional area of 2.0 sq cm. Measurements were also obtained on a heater block with a flat surface for baseline comparison purposes. A 2x2 nozzle array was used with PF-5060 as the working fluid. Thermal performance data was obtained under nominally degassed (chamber pressure of 41.4 kPa) and gassy conditions (chamber with N2 gas at 101 kPa) with a bulk fluid temperature of 20.5 C. Results for both the nominally degassed and gassy cases show that the highest critical heat flux (CHF) was attained using straight fins and porous tunnels. For the nominally degassed case, both had a CHF of approx.: 142 W/sq cm while for the gassy case their CHF values increased to 175 W/sq cm. This gave an enhancement relative to the nominally degassed flat surface case of approx. 77% and 119% respectively.

Silk, Erie A.

Surface charging and x-ray emission from insulator surfaces induced by collisions with highly charged ions : relevance to cometary and planetary sp

Characteristic X-ray emission lines are detected from simulants of comet surfaces as they undergo collisions with highly charged ions (HCIs). The HCI projectiles are O+2-O+7. Ion energies are varied in the range (2-7)q keV, where q is the ion charge state. The targets are the insulator minerals olivine, augite, and quartz. It is found that the emission of characteristic K-L, K-M X-rays appears to proceed during positive charging of the surface by the HCI beam. When one uses low-energy, flood-gun electrons to neutralize the surface charge, the X-ray emission is eliminated or greatly reduced, depending on the flood-gun current. Acceleration of background electrons onto the charged surface results in excitation of elemental transitions, including the K-L2 and K-L3 target X-ray emission lines of Mg and Si located spectroscopically at 1253.6 and 1739.4 eV, respectively. Also observed are emission lines from O, Na, Ca, Al, and Fe atoms in the target and charge-exchange lines via surface extraction of electrons by the O+q electric field. Good agreement is found in the ratio of the measured X-ray yields for Mg and Si relative to the ratio of their electron-impact K-shell ionization cross sections. The present study may serve as a guide to astronomers as to specific observing X-ray energies indicative of solar/stellar wind or magnetospheric ion interactions with a comet, planetary surface, or circumstellar dust.

comets

Particle-Surface Interaction Model and Method of Determining Particle-Surface Interactions

A method and model of predicting particle-surface interactions with a surface, such as the surface of a spacecraft. The method includes the steps of: determining a trajectory path of a plurality of moving particles; predicting whether any of the moving particles will intersect a surface; predicting whether any of the particles will be captured by the surface and/or; predicting a reflected trajectory and velocity of particles reflected from the surface.

Hughes, David W.

An Approach for the Long-Term 30-m Land Surface Snow-Free Albedo Retrieval from Historic Landsat Surface Reflectance and MODIS-based A Priori Anisotropy Knowledge

Land surface albedo has been recognized by the Global Terrestrial Observing System (GTOS) as an essential climate variable crucial for accurate modeling and monitoring of the Earth's radiative budget. While global climate studies can leverage albedo datasets from MODIS, VIIRS, and other coarse-resolution sensors, many applications in heterogeneous environments can benefit from higher-resolution albedo products derived from Landsat. We previously developed a "MODIS-concurrent" approach for the 30-meter albedo estimation which relied on combining post-2000 Landsat data with MODIS Bidirectional Reflectance Distribution Function (BRDF) information. Here we present a "pre-MODIS era" approach to extend 30-m surface albedo generation in time back to the 1980s, through an a priori anisotropy Look-Up Table (LUT) built up from the high quality MCD43A BRDF estimates over representative homogenous regions. Each entry in the LUT reflects a unique combination of land cover, seasonality, terrain information, disturbance age and type, and Landsat optical spectral bands. An initial conceptual LUT was created for the Pacific Northwest (PNW) of the United States and provides BRDF shapes estimated from MODIS observations for undisturbed and disturbed surface types (including recovery trajectories of burned areas and non-fire disturbances). By accepting the assumption of a generally invariant BRDF shape for similar land surface structures as a priori information, spectral white-sky and black-sky albedos are derived through albedo-to-nadir reflectance ratios as a bridge between the Landsat and MODIS scale. A further narrow-to-broadband conversion based on radiative transfer simulations is adopted to produce broadband albedos at visible, near infrared, and shortwave regimes.We evaluate the accuracy of resultant Landsat albedo using available field measurements at forested AmeriFlux stations in the PNW region, and examine the consistency of the surface albedo generated by this approach respectively with that from the "concurrent" approach and the coincident MODIS operational surface albedo products. Using the tower measurements as reference, the derived Landsat 30-m snow-free shortwave broadband albedo yields an absolute accuracy of 0.02 with a root mean square error less than 0.016 and a bias of no more than 0.007. A further cross-comparison over individual scenes shows that the retrieved white sky shortwave albedo from the "pre-MODIS era" LUT approach is highly consistent (R(exp 2) = 0.988, the scene-averaged low RMSE = 0.009 and bias = −0.005) with that generated by the earlier "concurrent" approach. The Landsat albedo also exhibits more detailed landscape texture and a wider dynamic range of albedo values than the coincident 500-m MODIS operational products (MCD43A3), especially in the heterogeneous regions. Collectively, the "pre-MODIS" LUT and "concurrent" approaches provide a practical way to retrieve long-term Landsat albedo from the historic Landsat archives as far back as the 1980s, as well as the current Landsat-8 mission, and thus support investigations into the evolution of the albedo of terrestrial biomes at fine resolution.

Albedo algorithm

An Approach to Retrieve BRDF from Satellite and Airborne Measurements of Surface-Reflected Radiance Based on Decoupling of Atmospheric Radiative Transfer and Surface Reflection

Bi-directional Reflection Distribution Function (BRDF) defines anisotropy of the surface reflection. It is required to specify the boundary condition for radiative transfer (RT) modeling. Measurements of reflected radiance by satellite- and air-borne sensors provide information about anisotropy of surface reflection. Atmospheric correction needs to be performed to derive BRDF from the reflected radiance. Common approach for BRDF retrievals consists of the use of kernel-based BRDF and RT modeling that needs to be done anew at every step of the iterative process. The kernels’ weights are obtained by minimization of the difference between measured and modeled radiance. This study develops a new method of retrieving kernel-based BRDF that requires RT calculations to be done only once. The method employs the exact analytical expression of radiance at any atmospheric level through the solutions of two auxiliary atmosphere-only RT problems and the surface-reflected radiance at the surface level. The latter is related to BRDF and solutions of the auxiliary RT problems by a Fredholm integral equation of the second kind. The approach requires to perform RT calculations one time before the iterations. It can use observations taken at different atmospheric conditions assuming that surface conditions remain unchanged during the time span of observations. The algorithm accurately catches zero weights of the kernels that may be a concern if the number of kernels is greater than 3 in current mainstream approaches. The study presents numerical tests of the BRDF retrieval algorithm for various surface and atmospheric conditions.

Radkevich, Alexander

Demonstration of Portable X-ray Fluorescence Spectroscopy for High-Throughput In-Situ Quantification of Surface Lunar Dust for Testing and Future Surface Missions

In this paper, we present a new method of quantification for surface concentrations of lunar dust and lunar simulant for use and deployment for development testing and potential eventual use for verification and development testing and lunar surface missions. This technique demonstrates the use of portable X-ray fluorescence spectroscopy (pXRF) to quantify lunar dust loading on surfaces using an adaption of existing pXRF techniques. This paper shows the background in current methodologies for quantification of lunar dust in tests as well as current and potential future techniques for lunar surface missions, as well as current applications of commercial off-the-shelf (COTS) pXRF technology. The methodology for adapting current pXRF techniques is presented, followed by a demonstration of this new method on a variety of materials related to spaceflight or lunar surface missions. This technique shows high fidelity for immediate utilization as well as a demonstration of high potential for future surface missions.

Spectroscopy

LANDO: Developing Autonomous Surface Operations for Planetary Surfaces

The Lightweight Surface Manipulation System (LSMS) AutoNomy capabilities Development for surface Operations and construction (LANDO) project is an Early Career Initiative (ECI) selected for funding by the Space Technology Mission Directorate (STMD) beginning in fiscal year 2022. Over the two-year project duration, the LANDO project will deliver a general-purpose autonomy framework applicable to serial and tension-actuated manipulation agents, that has been validated using an existing prototype of the LSMS-L35 (35-kg wrist lift capacity on the lunar surface, sized for a Commercial Lunar Payload Services (CLPS) mission). Specific to the LANDO project, the autonomous LSMS-L35 will be used to demonstrate autonomous payload handling capabilities for Lunar and other planetary surfaces, directly addressing STMD capability gaps in autonomous surface construction (ASC) operations, advanced robotics and spacecraft autonomy technologies, and technologies supporting emerging space industries including the On-orbit Servicing, Assembly and Manufacturing (OSAM) National Initiative. In this paper, an overview of the LANDO ECI project is presented.

autonomy

LANDO: Developing autonomous surface operations for planetary surfaces

The Lightweight Surface Manipulation System (LSMS) AutoNomy capabilities Development for surface Operations and construction (LANDO) project is an Early Career Initiative (ECI) selected for funding by the Space Technology Mission Directorate (STMD) beginning in fiscal year 2022. Over the two-year project duration, the LANDO project will deliver a general-purpose autonomy framework applicable to serial and tension-actuated manipulation agents, that has been validated using an existing prototype of the LSMS-L35 (35-kg wrist lift capacity on the lunar surface, sized for a Commercial Lunar Payload Services (CLPS) mission). Specific to the LANDO project, the autonomous LSMS-L35 will be used to demonstrate autonomous payload handling capabilities for Lunar and other planetary surfaces, directly addressing STMD capability gaps in autonomous surface construction (ASC) operations, advanced robotics and spacecraft autonomy technologies, and technologies supporting emerging space industries including the On-orbit Servicing, Assembly and Manufacturing (OSAM) National Initiative. In this paper, an overview of the LANDO ECI project is presented.

autonomy

Microwave Remote Sensing Modeling of Ocean Surface Salinity and Winds Using an Empirical Sea Surface Spectrum

Active and passive microwave remote sensing techniques have been investigated for the remote sensing of ocean surface wind and salinity. We revised an ocean surface spectrum using the CMOD-5 geophysical model function (GMF) for the European Remote Sensing (ERS) C-band scatterometer and the Ku-band GMF for the NASA SeaWinds scatterometer. The predictions of microwave brightness temperatures from this model agree well with satellite, aircraft and tower-based microwave radiometer data. This suggests that the impact of surface roughness on microwave brightness temperatures and radar scattering coefficients of sea surfaces can be consistently characterized by a roughness spectrum, providing physical basis for using combined active and passive remote sensing techniques for ocean surface wind and salinity remote sensing.

Sea surface spectrum

TM surface wave diffraction by a truncated dielectric slab recessed in a perfectly conducting surface

The diffraction of a TM sub o surface wave by a terminated dielectric slab which is flush mounted in a perfectly conducting surface is studied. The incident surface wave gives rise to waves reflected and diffracted by the termination; these reflected and diffracted fields may be expressed in terms of the geometrical theory of diffraction by introducing surface wave reflection and diffraction coefficients which are associated with the termination. In this investigation, the surface wave reflection and diffraction coefficients have been deduced from a formally exact solution to this canonical problem. The solution is obtained by a combination of the generalized scattering matrix technique and function theoretic methods.

Pathak, P. H.

Relationship between hurricane surface winds and L-band radar backscatter from the sea surface

High-altitude, airborne, L-band synthetic aperture radar (SAR) data were collected in Hurricane Gloria on 28 and 30 September 1976. The backscattered power levels (proportional to the surface scattering coefficient) averaged over a few square kilometers of surface area were found to vary with surface wind speed and the angle of the wind relative to the radar. Comparisons between the backscatter from the eye and eye-wall regions of the hurricane were made with low-level aircraft wind measurements that were nearly coincident in space and time. The SAR has the potential advantage over other radar types because of its higher spatial resolution. It also appears to have the ability to penetrate rainfall, with a reduction in the echo from the surface. One difference when compared with higher frequency microwave radars is a decrease in the sensitivity of the backscatter to changes in wind speed. This dependence of L-band radar backscatter on surface winds suggests that the winds associated with hurricanes can be measured with airborne or spaceborne radars.

Weissman, D. E.

Surface wave diffraction by a truncated dielectric slab recessed in a perfectly conducting surface

The diffraction of a TM sub 0 surface wave by a terminated dielectric slab which is flush mounted in a perfectly conducting surface is studied. The incident surface wave gives rise to waves reflected and diffracted by the termination; these reflected and diffracted fields may be expressed in terms of the geometrical theory of diffraction by introducing surface wave reflection and diffraction coefficients which are associated with the termination. In this investigation the surface wave reflection and diffraction coefficients have been deduced from a formally exact solution to this canonical problem. The solution is obtained via a combination of the generalized scattering matrix technique and the Wiener-Hopf procedure. Expressions for the reflection and diffraction coefficients contain integrals which can be evaluated numerically.

Pathak, P. H.

Preliminary analytical results using surface current integration for predicting effects of surface pillows on RF performance

An overview of the fast integral RF evaluation (FIRE) program is presented. This program uses surface current integration to evaluate RF performance of antenna systems. It requires modeling of surfaces in X, Y, Z coordinates along equally spaced X and Y grids with Z in the focal directon. The far field contribution of each surface point includes the effects of the Z-component of surface current which is not included in the aperture integration technique. Because of this, surface current integration is the most effective and inclusive technique for predicting RF performance on non-ideal reflectors. Results obtained from use of the FIRE program and an aperture integration program to predict RF performance of a LSS antenna concept are presented.

Farrell, C. E.

Influence of mineral oil and additives on microhardness and surface chemistry of magnesium oxide (001) surface

X-ray photoelectron spectroscopy analyses and hardness experiments were conducted with cleaved magnesium oxide /001/ surfaces. The magnesium oxide bulk crystals were cleaved into specimens along the /001/ surface, and indentations were made on the cleaved surface in laboratory air, in nitrogen gas, or in degassed mineral oil with and without an additive while not exposing specimen surface to any other environment. The various additives examined contained sulfur, phosphorus, chlorine, or oleic acid. The sulfur-containing additive exhibited the highest hardness and smallest dislocation patterns evidencing plastic deformation; the chlorine-containing additive exhibited the lowest hardness and largest dislocation patterns evidencing plastic deformation. Hydrocarbon and chloride (MgCl2) films formed on the magnesium oxide surface. A chloride film was responsible for the lowest measured hardness.

Miyoshi, K.

A numerical method for approximating antenna surfaces defined by discrete surface points

A simple numerical method for the quadratic approximation of a discretely defined reflector surface is described. The numerical method was applied to interpolate the surface normal of a parabolic reflector surface from a grid of nine closest surface points to the point of incidence. After computing the surface normals, the geometrical optics and the aperture integration method using the discrete Fast Fourier Transform (FFT) were applied to compute the radiaton patterns for a symmetric and an offset antenna configurations. The computed patterns are compared to that of the analytic case and to the patterns generated from another numerical technique using the spline function approximation. In the paper, examples of computations are given. The accuracy of the numerical method is discussed.

Lee, R. Q.