Optimal Estimation of Snow and Ice Surface Parameters from Imaging Spectroscopy Measurements
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Guanter, Luis↗
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Optimal Estimation of Snow and Ice Surface Parameters from Imaging Spectroscopy Measurements
No abstract provided
Guanter, Luis↗
Spatially constrained atmosphere and surface retrieval for imaging spectroscopy
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Regina Eckert↗
Evaluation of infrared emission spectroscopy for mapping the Moon's surface composition from lunar orbit
Infrared thermal emission spectroscopy is evaluated for its possible application to compositional mapping of the Moon's surface from lunar orbit. Principles of the mid-IR (approximately 4-25 microns) technique, previous lunar ground-based observations, and laboratory studies of Moon samples are reviewed and summarized. A lunar thermal emission spectrometer experiment is described, patterned after a similar instrument on the Mars Observer spacecraft. Thermal emission spectrometry from a polar-orbiting lunar spacecraft could provide a valuable mapping tool to aid in exploration for lunar resources and help provide understanding of the origin of the Moon and history of lunar surface processes.
Nash, Douglas B.↗
Effect of Space Radiation Processing on Lunar Soil Surface Chemistry: X-Ray Photoelectron Spectroscopy Studies
Current understanding of the chemistry and microstructure of the surfaces of lunar soil grains is dominated by a reference frame derived mainly from electron microscopy observations [e.g. 1,2]. These studies have shown that the outermost 10-100 nm of grain surfaces in mature lunar soil finest fractions have been modified by the combined effects of solar wind exposure, surface deposition of vapors and accretion of impact melt products [1,2]. These processes produce surface-correlated nanophase Feo, host grain amorphization, formation of surface patinas and other complex changes [1,2]. What is less well understood is how these changes are reflected directly at the surface, defined as the outermost 1-5 atomic monolayers, a region not easily chemically characterized by TEM. We are currently employing X-ray Photoelectron Spectroscopy (XPS) to study the surface chemistry of lunar soil samples that have been previously studied by TEM. This work includes modification of the grain surfaces by in situ irradiation with ions at solar wind energies to better understand how irradiated surfaces in lunar grains change their chemistry once exposed to ambient conditions on earth.
Dukes, C.↗
Mars Observer: A global mapping mission
Mars Observer will be launched in September 1991, arrive at Mars in August 1993, and begin mapping in December 1993. Mapping will be conducted from a low-altitude (400 km) polar orbit over a period of one Martian year (687 days). Each of the seven instruments will be able to observe Mars continuously over this period. The scientific mission centers on global Geoscience and Climatology observations of the Mars atmosphere, surface, and interior. The seven experiments involve gamma-ray and neutron spectroscopy, magnetometry, surface and atmospheric imaging, atmospheric sounding, laser altimetry, gravity mapping, and thermal emission spectroscopy.
Palluconi, Frank K.↗
Laser Infrared Desorption Spectroscopy to Detect Complex Organic Molecules on Icy Planetary Surfaces
Laser Desorption-Infrared Spectroscopy (LD-IR) uses an IR laser pulse to desorb surface materials while a spectrometer measures the emission spectrum of the desorbed materials (Figure 1). In this example, laser desorption operates by having the incident laser energy absorbed by near surface material (~10 microns in depth). This desorption produces a plume that exists in an excited state at elevated temperatures. A natural analog for this phenomenon can be observed when comets approach the sun and become active and individual molecular emission spectra can be observed in the IR [1,2,3,4,5]. When this occurs in comets, the same species that initially emit radiation down to the ground state are free to absorb it, reducing the amount of detectable emission features. The nature of our technique results in absorption not occurring, because the laser pulse could easily be moved away form the initial desorption plume, and still have better spatial resolution then reflectance spectroscopy. In reflectance spectroscopy, trace components have a relatively weak signal when compared to the entire active nature of the surface. With LDIR, the emission spectrum is used to identify and analyze surface materials.
Laser Desorption-Infrared Spectroscopy↗
A new technique for Auger analysis of surface species subject to electron-induced desorption
A method is presented to observe surface species subject to electron-induced desorption by Auger electron spectroscopy. The surface to be examined is moved under the electron beam at constant velocity, establishing a time independent condition and eliminating the time response of the electron spectrometer as a limiting factor. The dependence of the Auger signal on the surface velocity, incident electron current, beam diameter, and desorption cross section are analyzed. The method is illustrated by the Auger analysis of PTFE, in which the fluorine is removed by electron induced desorption.
Pepper, S. V.↗
A new technique for Auger analysis of surface species subject to electron-induced desorption.
A method is presented to observe surface species subject to electron-induced desorption by Auger electron spectroscopy. The surface to be examined is moved under the electron beam at constant velocity, establishing a time-independent condition and eliminating the time response of the electron spectrometer as a limiting factor. The dependence of the Auger signal on the sample velocity, incident electron current, beam diameter, and desorption cross section is analyzed. It is shown that it is advantageous to analyze the moving sample with a high beam current, in contrast to the usual practice of using a low beam current to minimize desorption from a stationary sample. The method is illustrated by the analysis of a friction transfer film of PTFE, in which the fluorine is removed by electron-induced desorption. The method is relevant to surface studies in the field of lubrication and catalysis.
Pepper, S. V.↗
Mars Observer - The next Mars mission
The next mission to Mars, called Mars Observer, will be launched in September 1992. After the capture of the spacecraft by the planet and the adjustment into a low, sun-synchronous, polar-mapping orbit in late 1993, observations will continue for a Mars year (687 days). The scientific mission centers around global geoscience and climatology observations of the Mars atmosphere, surface, and interior. The seven experiments carried by the spacecraft involve gamma-ray spectroscopy, magnetometry, surface and atmospheric imaging, atmospheric sounding, laser altimetry, gravity mapping, and thermal emission spectroscopy. All experiments contain microprocessors, which will be controlled remotely from the investigator's home institution. The long planned period of continuous 24 h/day observation promises a rich harvest of global and seasonal information. Mars Observer stands between the initial exploration of Mars and the more intensive explorations, possibly involving human beings, that are only now being planned.
Albee, Arden L.↗
Mars Observer - Ready for launch
The main objectives of the Mars Observer Mission are reviewed. The activity of the mission focuses on geoscience and climatology, with observations to be made of the Mars atmosphere, surface, and interior. The mission will include seven scientific experiments involving gamma-ray spectroscopy, magnetometry, surface and atmospheric imaging, atmospheric sounding, laser altimetry, gravity mapping, and thermal emission spectroscopy. The mission plan and mapping operations are briefly discussed.
Albee, A. L.↗
Thermal stability of electron-irradiated poly(tetrafluoroethylene) - X-ray photoelectron and mass spectroscopic study
Polytetrafluoroethylene (PTFE) was subjected to 3 keV electron bombardment and then heated in vacuum to 300 C. The behavior of the material as a function of radiation dose and temperature was studied by X-ray photoelectron spectroscopy (XPS) of the surface and mass spectroscopy of the species evolved. Lightly damaged material heated to 300 C evolved saturated fluorocarbon species, whereas unsaturated fluorocarbon species were evolved from heavily damaged material. After heating the heavily damaged material, those features in the XPS spectrum that were associated with damage diminished, giving the appearance that the radiation damage had annealed. The observations were interpreted by incorporating mass transport of severed chain fragments and thermal decomposition of severely damaged material into the branched and cross-linked network model of irradiated PTFE. The apparent annealing of the radiation damage was due to covering of the network by saturated fragments that easily diffused through the decomposed material to the surface region upon heating.
Wheeler, Donald R.↗
X-ray photoelectron and mass spectroscopic study of electron irradiation and thermal stability of polytetrafluoroethylene
Polytetrafluoroethylene (PTFE) was subjected to 3 keV electron bombardment and then heated in vacuum to 300 C. The behavior of the material as a function of radiation dose and temperature was studied by X-ray photoelectron spectroscopy (XPS) of the surface and mass spectroscopy of the species evolved. A quantitative comparison of the radiation dose rate with that in other reported studies showed that, for a given total dose, the damage observed by XPS is greater for higher dose rates. Lightly damaged material heated to 300 C evolved saturated fluorocarbon species, whereas unsaturated fluorocarbon species evolved from heavily damaged material. After heating the heavily damaged material, those features in the XPS that were associated with damage diminished, giving the appearance that the radiation damage annealed. The apparent annealing of the radiation damage was found to be due to the covering of the network by saturated fragments that easily diffused through the decomposed material to the surface region upon heating.
Wheeler, Donald R.↗
Surface photovoltage due to photo-thermo-ionization of surface states - GaAs
Surface photovoltage spectroscopy was employed for studying the mechanism of subbandgap photoionization transitions from surface states in GaAs surfaces. It was found that the photoionization cross-section exhibits a maximum for a photon energy of about 0.9 eV. This finding indicates a photo-thermal mechanism of photovoltage, i.e., photo-induced transitions between surface state levels and the subsequent thermal ejection of electrons from the upper level into the conduction band.
Morawski, A.↗
Adhesion of various metals to a clean iron /011/ surface studied with LEED and Auger emission spectroscopy
Adhesion of single crystal metals to clean iron surface studied by emission spectroscopy
Buckley, D. H.↗
Surface-Enhanced X-Ray Fluorescence
Surface-enhanced x-ray fluorescence (SEn-XRF) spectroscopy is a form of surface- enhanced spectroscopy that was conceived as a means of obtaining greater sensitivity in x-ray fluorescence (XRF) spectroscopy. As such, SEn-XRF spectroscopy joins the ranks of such other, longer-wavelength surface-enhanced spectroscopies as those based on surface-enhanced Raman scattering (SERS), surface-enhanced resonance Raman scattering (SERRS), and surfaceenhanced infrared Raman absorption (SEIRA), which have been described in previous NASA Tech Briefs articles. XRF spectroscopy has been used in analytical chemistry for determining the elemental compositions of small samples. XRF spectroscopy is rapid and quantitative and has been applied to a variety of metal and mineralogical samples. The main drawback of XRF spectroscopy as practiced heretofore is that sensitivity has not been as high as required for some applications. In SEn-XRF as in the other surface-enhanced spectroscopies, one exploits several interacting near-field phenomena, occurring on nanotextured surfaces, that give rise to local concentrations of incident far-field illumination. In this case, the far-field illumination comes from an x-ray source. Depending on the chemical composition and the geometry of a given nanotextured surface, these phenomena could include the lightning-rod effect (concentration of electric fields at the sharpest points on needlelike surface features), surface plasmon resonances, and grazing incidence geometric effects. In the far field, the observable effect of these phenomena is an increase in the intensity of the spectrum of interest - in this case, the x-ray fluorescence spectrum of chemical elements of interest that may be present within a surface layer at distances no more than a few nanometers from the surface.
Anderson, Mark↗
Evidence of alloy formation during reduction of platinized tin oxide surfaces
Ion scattering spectroscopy, Auger electron spectroscopy, and electron spectroscopy for chemical analysis have been used to examine a platinized tin oxide catalyst surface before, during, and after reduction by annealing under vacuum at 250 to 450 C. These techniques were then used to examine the reduced surface after a room-temperature, low-pressure oxygen exposure. The spectral results and the behavior of the reduced surface toward oxygen exposure both indicate that a Pt/Sn alloy is produced during reduction.
Gardner, Steven D.↗
Surface Analysis Evaluation of Handwipe Cleaning for the Space Shuttle RSRM
In this paper we discuss the role of surface-sensitive spectroscopy (electron spectroscopy for chemical analysis, or ESCA) in the selection of solvents to replace 1,1,1-trichloroethane in handwipe cleaning of bonding surfaces on NASA's Space Shuttle Reusable Solid Rocket Motor (RSRM). Removal of common process soils from a wide variety of metallic and polymeric substrates was characterized. The cleaning efficiency was usually more dependent on the type of substrate being cleaned and the specific process soil than on the solvent used. A few substrates that are microscopically rough or porous proved to be difficult to clean with any cleaner, and some soils were very tenacious and difficult to remove from any substrate below detection limits. Overall, the work showed that a wide variety of solvents will perform at least as well as 1,1,1-trichloroethane.
Lesley, Michael W.↗