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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Ion-Flow-Induced Excitation of Electrostatic Cyclotron Mode in Magnetized Dusty Plasma

The stability of electrostatic cyclotron mode is investigated in a flowing magnetized dusty plasma in the presence of strong ion–neutral collisions. In the high magnetic field limit, when the dust magnetization becomes important, it is expected that the collective behavior of magnetized dust grains suspended in the near-sheath region substantially influences the dispersion properties of electrostatic modes. The growth/damping of the collective excitation is significantly controlled by such parameters as the ion–neutral collision frequency, Mach number, and magnetic field strength. In our case, the explicit dependence of the Mach number on the magnetic field and collision frequency has been taken into account and possible implications on the stability of the mode is analyzed. Streaming instability of cyclotron modes may be important to understand issues related to the interaction mechanism between dust grains and other associated phenomena like Coulomb crystallization, phase behavior, transport properties, etc., in the relatively strong magnetic field limit, which is currently accessible in the DPD (Kiel University) and MDPX (PSL, Auburn University) experiments.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2020

A “Graft to” Electrospun Zwitterionic Bilayer Membrane for the Separation of Hydraulic Fracturing-Produced Water via Membrane Distillation

Simultaneous fouling and pore wetting of the membrane during membrane distillation (MD) is a major concern. In this work, an electrospun bilayer membrane for enhancing fouling and wetting resistance has been developed for treating hydraulic fracture-produced water (PW) by MD. These PWs can contain over 200,000 ppm total dissolved solids, organic compounds and surfactants. The membrane consists of an omniphobic surface that faces the permeate stream and a hydrophilic surface that faces the feed stream. The omniphobic surface was decorated by growing nanoparticles, followed by silanization to lower the surface energy. An epoxied zwitterionic polymer was grafted onto the membrane surface that faces the feed stream to form a tight antifouling hydration layer. The membrane was challenged with an aqueous NaCl solution containing sodium dodecyl sulfate (SDS), an ampholyte and crude oil. In the presence of SDS and crude oil, the membrane was stable and displayed salt rejection (>99.9%). Further, the decrease was much less than the base polyvinylidene difluoride (PVDF) electrospun membrane. The membranes were also challenged with actual PW. Our results highlight the importance of tuning the properties of the membrane surface that faces the feed and permeate streams in order to maximize membrane stability, flux and salt rejection.

omniphobic↗
NASA NTRS1987

Clark Lake microbursts - On a lower limit to type III burst brightness temperatures

Further observations of solar microbursts by the Clark Lake radioheliograph are reported. The microbursts have properties consistent with weak type III bursts, with the implication that type III's can have brightness temperatures as low as 1 million K. The importance of this result is explored. A single model to explain the stronger type III bursts and the weaker microbursts is sought. It is shown that none of the models for stabilizing the strongest type III electron streams can explain the observed microbursts: these models have threshold levels of Langmuir waves which imply emission (due to spontaneous scattering off ions) with brightness temperatures in excess of those observed. It appears that either some vital physics is still missing from models for type III bursts, or that microbursts should have properties significantly different from those of type III bursts. In the latter case further observations should allow important tests of type III models.

White, S. M.↗
NASA NTRS2013

Ice-Shelf Tidal Flexure and Subglacial Pressure Variations

We develop a model of an ice shelf-ice stream system as a viscoelastic beam partially supported by an elastic foundation. When bed rock near the grounding line acts as a fulcrum, leverage from the ice shelf dropping at low tide can cause significant (approx 1 cm) uplift in the first few kilometers of grounded ice.This uplift and the corresponding depression at high tide lead to basal pressure variations of sufficient magnitude to influence subglacial hydrology.Tidal flexure may thus affect basal lubrication, sediment flow, and till strength, all of which are significant factors in ice-stream dynamics and grounding-line stability. Under certain circumstances, our results suggest the possibility of seawater being drawn into the subglacial water system. The presence of sea water beneath grounded ice would significantly change the radar reflectivity of the grounding zone and complicate the interpretation of grounded versus floating ice based on ice-penetrating radar observations.

tidal↗
DOE OSTI2018

Stability of Solutions of Initial Boundary-Balue Problems of Aerohydroelasticity

In designing structures and devices interacting with the flow of gas or liquid, it is necessary to solve the problems associated with the investigation of the stability required for their functioning and operational reliability. The definition of stability of an elastic body taken in the article corresponds to Lyapunov’s concept of stability of a dynamical system. On the base of the proposed nonlinear mathematical model the dynamic stability of the elastic aileron of the wing taking into account the incident subsonic flow of gas or liquid (in an ideal model of an incompressible environment) is investigated. Also a nonlinear mathematical model of the device relating to the vibration technique, which is intended for intensification of technological processes, for example, the process of mixing, is considered. The action of these devices is based on the oscillations of elastic elements during the gas or liquid flow. The dynamic stability of the elastic element located on one wall of the flow channel with the subsonic flow of gas or liquid (in an ideal model of a compressible environment) is investigated. Both models are described by a coupled nonlinear system of differential equations for the unknown functions — the potential of the gas velocity and deformation of the elastic element. On the basis of the construction of functionals, we obtain the sufficient conditions of the stability, the imposed restrictions on the free-stream velocity of the gas, the flexural stiffness of the elastic element, and other parameters of the mechanical system. The examples of construction of the stability regions for particular parameters of the mechanical system are presented.

42 ENGINEERING↗
NASA NTRS2003

Experimental Investigation of Centrifugal Compressor Stabilization Techniques

Results from a series of experiments to investigate techniques for extending the stable flow range of a centrifugal compressor are reported. The research was conducted in a high-speed centrifugal compressor at the NASA Glenn Research Center. The stabilizing effect of steadily flowing air-streams injected into the vaneless region of a vane-island diffuser through the shroud surface is described. Parametric variations of injection angle, injection flow rate, number of injectors, injector spacing, and injection versus bleed were investigated for a range of impeller speeds and tip clearances. Both the compressor discharge and an external source were used for the injection air supply. The stabilizing effect of flow obstructions created by tubes that were inserted into the diffuser vaneless space through the shroud was also investigated. Tube immersion into the vaneless space was varied in the flow obstruction experiments. Results from testing done at impeller design speed and tip clearance are presented. Surge margin improved by 1.7 points using injection air that was supplied from within the compressor. Externally supplied injection air was used to return the compressor to stable operation after being throttled into surge. The tubes, which were capped to prevent mass flux, provided 9.3 points of additional surge margin over the baseline surge margin of 11.7 points.

Skoch, Gary J.↗
NASA NTRS1987

Boundary-layer receptivity and laminar-flow airfoil design

Boundary-layer receptivity examines the way in which external disturbances generate instability waves in boundary layers. Receptivity theory is complementary to stability theory, which studies the evolution of disturbances that are already present in the boundary layer. A transition prediction method which combines receptivity with linear stability theory would directly account for the influence of free-stream disturbances and also consider the characteristics of the boundary layer upstream of the neutral stability point. The current e sup N transition prediction methods require empirical correlations for the influence of environmental disturbances, and totally ignore the boundary layer characteristics upstream of the neutral stability point. The regions where boundary-layer receptivity occurs can be separated into two classes, one near the leading edges and the other at the downstream points where the boundary layer undergoes rapid streamwise adjustments. Analyses were developed for both types of regions, and parametric studies which examine the relative importance of different mechanisms were carried out. The work presented here has focused on the low Mach number case. Extensions to high subsonic and supersonic conditions are presently underway.

Kerschen, Edward J.↗
DOE OSTI2019

Mercury Speciation and Stabilization in Saltstone - 19103

Mercury is a contaminant of concern in Savannah River Site (SRS) high level waste (HLW). For five decades elemental mercury was used in the catalytic dissolution of aluminum cladding from the enriched-alloy uranium recovery process. Over 60,000 kg of mercury are now distributed in the SRS HLW tanks. The mercury speciation in the liquid waste streams resulting from conditioning HLW sludge for vitrification and in the decontaminated low activity sodium salt solution removed from the tanks was initially thought to be primarily ionic with a minor amount of elemental mercury. Recent sampling detected organic mercury, primarily methylmercury, HgCH{sub 3}{sup +} (MeHg{sup +}), and a trace amount of ethylmercury (EtHg) in these streams in addition to the ionic and elemental forms of mercury. The objective of this work was to identify the fate of the organic mercury in saltstone, a waste form containing portland cement, slag cement, and Class F fly ash. This information is needed to evaluate total mercury and organic mercury limits for the saltstone Waste Acceptance Criteria to assure regulatory compliance with mixed waste disposal requirements and to evaluate opportunities to enhance the waste form performance. Results to date indicate that the MeHg{sup +} reacts with sulfide in the cementitious reagents, slag in particular, to form nanoparticles of β-HgS, meta cinnabar, which is very insoluble and has a solubility product in water, pK{sub sp}, at 25 deg. C of 53. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1983

A kinetic cross-field streaming instability

In a high-beta plasma the so-called modified-two-stream instability, which results from strongly magnetized electrons drifting relative to unmagnetized ions across a homogeneous magnetic field, is misnamed because the mode is highly kinetic, particularly when the relative streaming velocity exceeds the Alfven speed of the plasma. This kinetic cross-field streaming instability is investigated in detail, examining the effect of the electromagnetic terms and the stability boundaries in both low- and high-beta plasmas. An approximate dispersion relation showing the relation of this mode to the whistler is derived and solutions of it are compared with those obtained from the exact dispersion relation. The kinetic mode, unlike the usual modified-two-stream instability, is not stabilized by electromagnetic effects when the relative electron-ion drift speed exceeds the Alfven speed.

Wu, C. S.↗
DOE OSTI2019

The Preparation and Characterization of Co–Ni Nanoparticles and the Testing of a Heterogenized Co–Ni/Alumina Catalyst for CO Hydrogenation

Samples of well-controlled nanoparticles consisting of alloys of cobalt and nickel of different atomic ratios were synthesized using wet chemical methods with oleylamine as the solvent and the reducing agent. These materials were characterized by a variety of techniques, including high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM), X-ray energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). Small amounts of heterogenized catalysts were prepared using alumina as the support. However, the potential for use of Co–Ni catalysts in CO hydrogenation was explored using a larger amount of Co–Ni/alumina catalyst prepared from standard aqueous impregnation methods and tested in a continuously stirred tank reactor (CSTR) for Fischer–Tropsch synthesis (FTS). Results are compared to a reference catalyst containing only cobalt. The heterogenized catalysts were characterized using synchrotron methods, including temperature programmed reduction with extended X-ray absorption fine structure spectroscopy and X-ray absorption near edge spectroscopy (TPR-EXAFS/XANES). The characterization results support intimate contact between Co and Ni, strongly suggesting alloy formation. In FTS testing, drawbacks of Ni addition included decreased CO conversion on a per gram catalyst basis, although Ni did not significantly impact the turnover number of cobalt, and produced slightly higher light gas selectivity. Benefits of Ni addition included an inverted induction period relative to undoped Co/Al2O3, where CO conversion increased with time on-stream in the initial period, and the stabilization of cobalt nanoparticles at a lower weight % of Co.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1993

Inviscid instability of streamwise corner flow

Linear stability of the incompressible flow along a stream wise corner is studied by solving the two-dimensional eigenvalue problem governed by partial differential equations. It is found that this fully three-dimensional flow is subject to inviscid instability due to the inflectional nature of the stream wise velocity profile. The higher growth rates for the inviscid instability mode, which is symmetric about the corner bisector, as compared to the viscous Tollmien-Schlichting instability operative away from the corner is consistent with the experimental findings that the corner flow transitions to turbulence earlier than the two-dimensional Blasius flow away from the corner.

Balachandar, S.↗
NASA NTRS1987

Prediction of transition on a flat plate under the influence of free-stream turbulence using low-Reynolds-number two-equation turbulence models

The prediction characteristics and capabilities of two popular two-equation low-Reynolds-number turbulence models (Jones, Launder 1972; Lam, Bremhorst 1981) have been evaluated with respect to the prediction of transition of a flat plate under the influence of free-stream turbulence. The sensitivity of the predictions to free-stream turbulence intensity, initial starting location of the calculation, and the assumed initial starting profiles for k and epsilon has been determined and presented. Although both models predict the correct qualitative characteristics of transition, they also exhibit significant quantitative deficiencies with regard to both the predicted location and the length of transition. A modification to the production term in the turbulent kinetic energy equation is proposed which is based on a simple stability criterion and correlated to the free-stream turbulence level. The modification becomes inactive in the fully turbulent regime, but is shown to improve both the qualitative and quantitative characteristics of the transition predictions.

Schmidt, Rodney C.↗
NASA NTRS1988

Spatial stability of a compressible mixing layer

Presented are the results of a study of the inviscid spatial stability of a parallel compressible mixing layer. The parameters of this study are the Mach number of the moving stream, the ratio of the temperature of the stationary stream to that of the moving stream, the frequency and the direction of propagation of the disturbance wave. Stability characteristics of the flow as a function of these parameters are given. It is shown that if the Mach number exceeds a critical value there are always two groups of unstable waves. One of these groups is fast with phase speeds greater than 1/2, and the other is slow with speeds less than 1/2. Phase speeds for the neutral and unstable modes are given, as well as growth rates for the unstable modes. It is shown that three dimensional modes have the same general behavior as the two dimensional modes but with higher growth rates over some range of propagation direction. Finally, a group of very low frequency unstable modes was found for sufficiently large Mach numbers. These modes have very low phase speeds but large growth rates.

Jackson, T. L.↗
NASA NTRS1989

Inviscid spatial stability of a compressible mixing layer

Presented are the results of a study of the inviscid spatial stability of a parallel compressible mixing layer. The parameters of this study are the Mach number of the moving stream, the ratio of the temperature of the stationary stream to that of the moving stream, the frequency and the direction of propagation of the disturbance wave. Stability characteristics of the flow as a function of these parameters are given. It is shown that if the Mach number exceeds a critical value there are always two groups of unstable waves. One of these groups is fast with phase speeds greater than 1/2, and the other is slow with speeds less than 1/2. Phase speeds for the neutral and unstable modes are given, as well as growth rates for the unstable modes. It is shown that three-dimensional modes have the same general behavior as the two-dimensional modes but with higher growth rates over some range of propagation direction. Finally, a group of very low frequency unstable modes was found for sufficiently large Mach numbers. These modes have very low phase speeds but large growth rates.

Jackson, T. L.↗
DOE OSTI2025

Structural Evolution and Stability of Rh/TiO 2 Catalysts under CO 2 Hydrogenation Conditions: Influence of the Initial Rh Structure

Characterizing catalyst stability by identifying the predominant mechanisms, timescales and driving forces of catalyst reconstruction under relevant reaction conditions is necessary for the design and commercialization of new catalysts. Here, in this paper, we study Rh/TiO 2 catalysts under CO 2 hydrogenation conditions (773 K, 75% H 2 , 25% CO 2 ) at high conversion and utilize reactivity studies along with ex-situ and in-situ spectroscopy and microscopy to characterize changes in catalyst activity and structure as a function of time on stream and the initial catalyst structure. This is a prototypical catalyst for CO 2 hydrogenation where Rh structure and Rh-TiO 2 interactions have been proposed to explain reactivity, selectivity (between CO and CH 4 formation) and catalyst stability. The influence of the initial Rh structure (varying from Rh single atoms to Rh nanoparticles), support stability, regeneration and pretreatment(s), and the chemical potential(s) of the reaction environment on reaction selectivity and catalyst stability were explored. The product selectivity between CO and CH 4 was determined to be dependent on the relative fraction of Rh single atoms and Rh nanoparticle-TiO 2 interfacial sites under reaction conditions, each exhibiting distinct stability under prolonged time on stream. Surprisingly, Rh single atoms exhibited stability for the duration of 90 h reactivity measurements, even at high Rh density (≥ 1.8 Rh atoms/nm 2 ) on the support, while Rh nanoparticles sintered under reaction conditions. As a result, all catalysts exhibited increasing selectivity to CO with increasing time on stream (> 10 h). We conclude the distribution of Rh structures evolved over time under reaction conditions through three distinct reconstruction mechanisms (Rh particle fragmentation, Ostwald ripening, and particle migration and coalescence) that occurred on varying timescales. Catalyst stability on the ~90 h time scale was ultimately controlled by the initial Rh structure.

25 ENERGY STORAGE↗
DOE OSTI2023

Multi-functionalized basic immobilized amine sorbents for removal of metal contaminants from wastewater

This disclosure provides polyamine sorbent compositions for the separation of metals from aqueous solutions. The polyamine sorbent compositions comprise a silica support, an aminosilane bound to the silica support, an epoxysilane bound to the silica support, and a polyamine where the polyamine is chemically tethered onto a solid silica support through via the epoxysilane. The polyamine may be further stabilized within the bulk sorbent through hydrogen bonding interactions with the aminosilane. The sorbent compositions resist leaching by H 2 O in an aqueous stream containing heavy oxyanion-based (and other) metals and demonstrate stability over a pH range of 2-14. The sorbent compositions are useful for the separation of metals from aqueous solutions. The cationic heavy metals are captured by the co-existing amine groups (—NH 2 , —NH, —N) from the polymeric network while additional metal capture capacity is derived from the introduction of a secondary silane linker.

Gray, McMahan L.↗
NASA NTRS1993

Thermal control of ice-stream margins

The thermal balance at the base of an ice sheet near an ice-stream margin was investigated theoretically. Specifically, conditions such that the base of the ice sheet would be frozen in the absence of heat generated by the ice motion were investigated. The base of the ice stream is maintained at melting as a result of high dissipation of heat at the base associated with its fast motion over the bed. Heat dissipation in the inter-ice-stream ridge ice is presumed to be too small to maintain melting conditions on the bed there. Two opposing effects can be identified near the shear margin separating the fast and slow motions. Because the velocity of an ice stream falls off toward its margin, there is a near margin heat deficit zone where the heat generated at the bed is not, by itself, sufficient to maintain melting conditions. Without some counteracting process, the base could freeze inward toward the ice stream and cause it to narrow. The marginal shearing generates heat within the ice above the bed. This heat produces a thermal shielding effect that tends to warm the bed on both sides of the boundary between the fast and slow motion. This shielding effect, if strong enough, could produce a thawed zone beyond the fast/slow boundary. If melting at the bed by itself allows fast motion, then the ice stream would be free to widen. A coupled mass and heat flow model is being developed to examine these competing processes. Preliminary calculations using available information for boundary conditions appropriate for Ice Stream B predict that the shielding effect is most important. This tentative result suggests that thermal conditions are such that the ice stream could widen unstably. Other constraints would be required to stabilize the width. Possible factors could be bed morphology beneath ridges that does not allow fast motion even in thawed conditions, or inward advection of cold ice from the ridges across the margin and into the ice stream, which suppresses the shielding effect. The unknown geothermal heat flow beneath ice streams and inter ice-stream ridges is a major uncertainty in doing these calculations.

Raymond, Charles F.↗
NASA NTRS1993

Transition prediction and control in subsonic flow over a hump

The influence of a surface roughness element in the form of a two-dimensional hump on the transition location in a two-dimensional subsonic flow with a free-stream Mach number up to 0.8 is evaluated. Linear stability theory, coupled with the N-factor transition criterion, is used in the evaluation. The mean flow over the hump is calculated by solving the interacting boundary-layer equations; the viscous-inviscid coupling is taken into consideration, and the flow is solved within the separation bubble. The effects of hump height, length, location, and shape; unit Reynolds number; free-stream Mach number, continuous suction level; location of a suction strip; continuous cooling level; and location of a heating strip on the transition location are evaluated. The N-factor criterion predictions agree well with the experimental correlation of Fage; in addition, the N-factor criterion is more general and powerful than experimental correlations. The theoretically predicted effects of the hump's parameters and flow conditions on transition location are consistent and in agreement with both wind-tunnel and flight observations.

Masad, Jamal A.↗