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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Pelletized immobilized amine sorbent for CO2 capture

The disclosure describes a pelletized sorbent comprising a first component comprising Basic Immobilized Amine Sorbent, a second component comprising inorganic strength additive, and a third component comprising polymer binder, where the Basic Immobilized Amine Sorbent and solid inorganic strength additive are interconnected by the polymer binder. The pelletized sorbent is useful for removing CO2 from a gaseous mixture such as a post combustion gas stream.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Recovery of Rare Earths, Precious Metals and other Critical Materials from Geothermal Waters with Advanced Sorbent Structures - CRADA 355 (Abstract)

The ability to recover valuable trace level minerals from geothermal brines using high-performance solid-phase sorbents will be explored and developed. A compressive range of sorbent materials will be screened for application to metal extraction from geothermal brines. Preferred sorbents from extraction of trace levels of rare earths (REs), precious metals (PMs), and other critical/strategically valuable materials (CMs) such as Zn, Mn, Te, Sc, Se and U from geothermal brines will be identified. For the preferred sorbents PNNL will determine the volumes they are capable of providing efficient extraction from. The thermal and chemical limits (including, acid, sulfur, salt) for performance of the preferred sorbent materials will be determined; with a target of at least 125°C and perhaps as high as 400° C. Sorbent form factors (including, packed bed, membrane, mats) that can function efficiently and be installed cost effectively in geothermal energy plants will be assessed for chemical and economic viability. Material regeneration and cyclic utilization will be demonstrated, targeting hundreds to thousands of cycles. Options for recovery and purification (including, selective separation of heavy REs) of collected materials will be explored. A techno-economic analysis (TEA) will be performed to assess the best approach to provide a value-added extraction process for geothermal energy systems. The sorbent materials and engineering analysis will be applicable to other industrial processes in which secondary recovery of valuable materials could provide economic benefit.

15 GEOTHERMAL ENERGY↗
DOE OSTI2025

Direct Air Capture Case Studies: Sorbent System (Rev. 1)

In 2022, the National Energy Technology Laboratory published a techno-economic assessment (TEA) examining the performance and cost of a generic solid sorbent-based direct air capture (DAC) system, “Direct Air Capture Case Studies: Sorbent System”. Revision 1 of this report builds on the previous effort by updating assumptions to reflect the evolving industry and recent developments in the DAC research and development (R&D) portfolio. Revision 1 of the report also expands the case list to examine a variety of sorbent DAC system configurations. The objective of this series is to present transparent and independent TEAs that can serve as a guideline for sorbent DAC TEA development and highlight potential avenues for cost reductions that can inform R&D. The sorbent considered is not reflective of any one material type; rather, it represents an approximate average of reported material performance in the literature. The base cases presented in this series do not represent optimized systems due to the nascence of the technology and lack of publicly available information. The base cases serve as a reference for informative sensitivity analyses.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Dynamic structural and microstructural responses of a metal–organic framework type material to carbon dioxide under dual gas flow and supercritical conditions

The structural and microstructural responses of a model metal–organic framework material, Ni(3-methyl-4,4'-bipyridine)[Ni(CN) 4 ] (Ni-BpyMe or PICNIC-21), to CO 2 adsorption and desorption are reported for in situ small-angle X-ray scattering and X-ray diffraction measurements under different gas pressure conditions for two technologically important cases. These conditions are single or dual gas flow (CO 2 with N 2 , CH 4 or H 2 at sub-critical CO 2 partial pressures and ambient temperatures) and supercritical CO 2 (with static pressures and temperatures adjusted to explore the gas, liquid and supercritical fluid regimes on the CO 2 phase diagram). The experimental results are compared with density functional theory calculations that seek to predict where CO 2 and other gas molecules are accommodated within the sorbent structure as a function of gas pressure conditions, and hence the degree of swelling and contraction in the associated structure spacings and void spaces. Furthermore, these predictions illustrate the insights that can be gained concerning how such sorbents can be designed or modified to optimize the desired gas sorption properties relevant to enhanced gas recovery or to addressing carbon dioxide reduction through carbon mitigation, or even direct air capture of CO 2 .

36 MATERIALS SCIENCE↗
DOE OSTI2023

Emerging concepts in intermediate carbon dioxide emplacement to support carbon dioxide removal

Substantial upscaling of carbon dioxide capture is possible in the coming decades but existing solutions for storage are projected to be limited in annual capacity by as much as 2–10 GtCO 2 per year until mid-century. Temporary storage of CO 2 in a solid or liquid state could prove useful for filling this gap in capacity, until more permanent and ideally lucrative CO 2 sequestration options come online. There are several concepts for reversible solid-state and chemical CO 2 storage, but their advantages and limitations have yet to be reviewed in this context. This article focuses on the physical and chemical aspects of CO 2 storage via liquid and solid chemical carriers and sorbents, and gives an overview of the energetics around their use, as well as prospects for their future development. Exciting opportunities for coupling capture and medium to high maturity multi-year storage technologies could support carbon removal in the coming decades. Highlights of the analysis are the remarkable storage capacity of oxalic acid and formic acid (CO 2 -density of 1857 kg m –3 and 1152 kg m –3 , compared with condensed liquid CO 2 at 993–1096 kg m –3 , respectively), the relative scalability and compatibility of carbonate salts for stationary storage with direct air capture, and the potential promise of multiple carriers for CO 2 transportation. Solid sorbents do not achieve such ultra-high storage capacities, but could improve storage over compressed gas tanks on a capacity and energetics basis.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Harnessing the Hybridization of a Metal-Organic Framework and Superbase-Derived Ionic Liquid for High-Performance Direct Air Capture of CO 2

Direct air capture (DAC) of CO 2 has emerged as the most promising “negative carbon emission” technologies. Despite being state-of-the-art, sorbents deploying alkali hydroxides/amine solutions or amine-modified materials still suffer from unsolved high energy consumption and stability issues. Here, in this work, composite sorbents are crafted by hybridizing a robust metal-organic framework (Ni-MOF) with superbase-derived ionic liquid (SIL), possessing well maintained crystallinity and chemical structures. The low-pressure (0.4 mbar) volumetric CO 2 capture assessment and a fixed-bed breakthrough examination with 400 ppm CO 2 gas flow reveal high-performance DAC of CO 2 (CO 2 uptake capacity of up to 0.58 mmol g -1 at 298 K) and exceptional cycling stability. Operando spectroscopy analysis reveals the rapid (400 ppm) CO 2 capture kinetics and energy-efficient/fast CO 2 releasing behaviors. The theoretical calculation and small-angle X-ray scattering demonstrate that the confinement effect of the MOF cavity enhances the interaction strength of reactive sites in SIL with CO 2 , indicating great efficacy of the hybridization. The achievements in this study showcase the exceptional capabilities of SIL-derived sorbents in carbon capture from ambient air in terms of rapid carbon capture kinetics, facile CO 2 releasing, and good cycling performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Comparison of microwave and conventional heating for CO 2 desorption from zeolite 13X

In this study, we investigate microwave irradiation as an alternative to conventional heating for temperature swing adsorption processes. The performance of microwave and conventional heating during sorbent regeneration was evaluated by measuring CO 2 desorption from zeolite 13X at different temperatures. Experimentally, a fixed bed of zeolite 13X was saturated by a 150 sccm flow of 15 % CO 2 at room temperature followed by sorbent regeneration under nitrogen at 55, 100, or 150 °C by applying either microwave irradiation or conventional heating. Microwaves reduced sorbent regeneration times by at least half compared to regeneration by conventional heating. Under conventional regeneration, desorption curves were resolved into two peaks representing physisorbed CO 2 (mass diffusion limited) at low temperature and bicoordinated CO 2 (thermally limited) with increasing temperature. Under microwave regeneration, only one desorption peak was observed suggesting that CO 2 desorption was limited by mass diffusion through the porous zeolite 13X structure, rather than by temperature. Depending on microwave power, apparent activation energy of the microwave-assisted regeneration was 15.8–18.1 kJ/mol, compared to 41.5 kJ/mol for conventional regeneration. The reduction in apparent activation energy is mainly attributed to selective microwave heating of CO 2 adsorption sites (Na + sites) resulting in greater steady state temperatures of Na + relative to framework atoms, suggesting greater heating efficiency due to microwaves compared to conventional heat transfer. Due to rapid cycling and efficient heat transfer to CO 2 sites on zeolite 13X, microwave regeneration is found to increase adsorption/desorption cycling productivity and potentially reduce the energy penalty of temperature swing capture.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Progress in development of characterization capabilities to evaluate candidate materials for direct air capture applications

As part of U.S. national efforts to combat the detrimental effect of global climate change, the National Institute of Standards and Technology (NIST) was recently tasked to support efforts in direct air capture (DAC) of carbon dioxide research and deployment. In order to develop test procedures, materials, and documentary standards, key characterization methods relevant to DAC materials have been investigated and used to identify desirable properties for a potential Standard Reference Material (SRM). Select amine-supported materials that previously showed potential for DAC applications have been characterized using commonly available laboratory methods. Further insights into the adsorption characteristics have been gained from developing and applying more specialized characterization tools ideal for probing low concentrations of carbon dioxide. A broad suite of capabilities that examine relevant properties under appropriate conditions gives the most profound insights into a material's specific performance. We advocate for even more specialized capabilities to be developed and standardized to quantitatively monitor the interactions of CO 2 with molecular species in complex and often disordered systems to advance DAC and support carbon dioxide reduction (CDR) in general.

carbon dioxide↗
DOE OSTI2025

Experimental and Theoretical Thermokinetic Analysis of the Na 3 VO 4 –CO 2 Reaction System under Different Physicochemical Conditions

Sodium vanadate (Na 3 VO 4 ) was synthesized, structural and microstructurally characterized as well as tested as possible carbon dioxide (CO 2 ) captor through thermodynamic calculations in addition to thermogravimetric dynamic and isothermal analyses. Ceramic structural characterization evidenced the formation of the Na 3 VO 4 crystal phase, while microstructural features evidenced dense agglomerates with a poor specific surface area, although synthesis temperature (600 °C) was not as high as that for other sodium ceramics. Na 3 VO 4 was investigated for the CO 2 capture process through dynamic and isothermal experiments, in the presence or absence of oxygen. All these experiments showed that Na 3 VO 4 possesses interesting CO 2 capture properties in a specific temperature range (520 and 600 °C). Isothermal products characterization allowed to elucidate the reaction pathway, implying the Na 4 V 2 O 7 formation, as possible reactive intermediate. In fact, reaction path evolution was supported with theoretical thermodynamic data. Moreover, the kinetic analysis, performed using the Avrami-Erofeev mathematical model and subsequent thermodynamic data obtention, probed the positive influence of the temperature, in both CO 2 superficial and bulk chemical sorption processes, while oxygen addition did not enhance the superficial process. Additionally, as it would be expected, kinetics were enhanced as a function of the CO 2 concentration.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

CO 2 Capture Characteristics of Hyperbranched Poly(alkylene imine): A Molecular Dynamics Simulation Approach

This study explores the CO 2 capture characteristics of hyperbranched poly(ethylenimine) (HB-PEI) and poly- (propyleneimine) (HB-PPI) through molecular dynamics simulations using density functional theory-calibrated force fields. Key features such as density, free volume, glass transition temperature, CO 2 /H 2 O distribution, and molecular diffusion are systematically investigated to elucidate structure−function relationships under dry and hydrated conditions. HB-PEI demonstrates a slightly higher density and lower free volume compared to HB-PPI yet shows superior CO 2 capture due to the high amine concentration. Glass transition analysis indicates a higher thermal mobility in HBPEI, enhancing the CO 2 diffusivity. Pair correlation and coordination analyses confirm a stronger affinity of CO 2 with primary and secondary amines, particularly in hydrated environments where water competes with CO 2 for binding sites. Despite its more compact structure, HB-PEI outperformed HB-PPI in CO 2 and H 2 O transport, as confirmed by higher diffusion coefficients across all hydration levels. These findings highlight a critical balance among polymer architecture, amine accessibility, and hydration in designing next-generation solid amine sorbents for efficient direct air capture applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Model-Based Energy and Cost Analysis of Direct Air Capture Using ePTFE-Based Laminate-Structured Gas–Solid Contactors

Carbon dioxide removal (CDR) technologies will play a significant role in limiting global warming if implemented on a large scale. Direct air capture (DAC) is a scalable approach for removing atmospheric carbon, yet the true scope of its scalability remains unclear due to the early stage of technology development and high first plant costs. This study provides groundwork for understanding the technoeconomic trade-offs in developing DAC systems using laminate-structured gas–solid contactors, encompassing the analysis of both contactor and process design spaces. The robust mass transfer and process models outlined in this study provide tools for evaluating DAC processes and designing DAC plants based on cost and energy analysis. First, the key contactor geometrical parameters are identified to understand the CO 2 productivity–energy demand trade-offs, where geometries yielding higher mass transfer rates can achieve higher CO 2 productivities at the expense of energy consumption by fans and steam use. Next, a detailed process parametric study is conducted for DAC systems coupled with steam-assisted temperature-vacuum swing adsorption (S-TVSA) to visualize the trade-offs in the multidimensional design space. The main cost driver dramatically changes over different process conditions, but the operating cost prevailed on the Pareto front, with potential to operate as low as 150 $/tonne-CO 2 (within the cost range of 148–504 $/tonne-CO 2 in this study where the DAC system is coupled with industrial facilities for steam production).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Energy Performance Validation of a Gaseous Air Cleaning Technology for Commercial Buildings

The U.S. Department of Energy (DOE) Building Technologies Office Commercial Building Integration group conducts evaluations of new energy efficiency technologies as part of the High Impact Technology Catalyst program. The subject of this field validation project is an air cleaning technology that removes gaseous contaminants from indoor air to reduce outdoor air ventilation requirements. Reducing the volume of outdoor air required reduces heating, ventilating, and air conditioning (HVAC) loads and can provide significant energy savings for some buildings in certain climates. The technology, called the HLR (HVAC Load Reduction), was developed by enVerid. The technology uses a solid regenerable sorbent material that was developed by DOE's National Energy Technology Laboratory and licensed to the vendor for this application. The sorbent material was originally developed to adsorb carbon dioxide (CO2); the vendor continued to develop the sorbent and the overall system so that it can also remove volatile organic compounds (including aldehydes), carbon monoxide, ozone, and particulate matter 2.5 micrometers in diameter or smaller (PM2.5) from the air. This material has low regeneration temperature requirements, and its sorption properties are unaffected by humidity levels, both of which are beneficial for building applications.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2023

Evaluation of Technologies for Destruction of LDR Organics in Hanford Tank Waste

Aqueous Hanford tank wastes contain soluble organics and some tanks contain small amounts (<100 mg/L) of organics that are regulated under the Land Disposal Restrictions (LDR) portions of the Resource Conservation and Recovery Act (RCRA). Most of these organics can be removed by evaporation, but some are not. Methods to destroy/remove organics that are regulated by the LDR section of the RCRA and that are not removed by evaporation may be needed if ambient temperature waste treatment processes are used to immobilize aqueous Hanford tank wastes. To identify viable and compatible organic removal or destruction pretreatment methods an evaluation was performed by a team of researchers. The team utilized a Systems Engineering Approach that examines all aspects of the technology, based on information available in the literature and the experience of the team members. That evaluation led to recommendations by the team to perform testing on technologies to determine efficacy in destroying organics in Hanford tank waste liquids. The primary technologies recommended are chemical oxidants, including permanganate, peroxymonosulfate or peroxydisulfate (PMS/PDS), hydrogen peroxide, and ozone. Ultraviolet light irradiation of the stream with a solid catalyst sorbent is also recommended for testing. A generalized description of the test program is also included.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2024

Synthesizing Lithium Sorbents Using Acid Mine Drainage Solids

In this study, we prepared HMO from coal mine drainage (CMD) solids and examined the practicability of recovering Li from oil and gas produced waters and geothermal brines. We aim to innovate high-value added products from the existing extract REEs and CMs processing chain of legacy byproducts associated with coal production. CMD solids, which are precipitates collected from exhausted limestone gravels of passive CMD treatment beds, are enriched in rare earth elements (REEs) and other critical minerals (CMs), and therefore, considered as a viable alternative source for REEs/CMs to supply the Nation’s demands. A patented extraction process developed by NETL (TREE) has been demonstrated as a cost-effective and efficient approach to recover REEs/CMs from CMD solids. Here, we selected residuals of CMD solids from the TREE process that are enriched in manganese (Mn) (&gt;20% w/w) and successfully prepared LMO using a solid-state method modified from Yoshizuka et al. (2002).

Cheng, Chin-Min↗
DOE OSTI2023

Direct air capture of CO2: from insights into the current and emerging approaches to future opportunities

The rapid development of direct air capture (DAC) technologies has become critical in order to remove CO 2 from the atmosphere and limit global warming to a maximum of 1.5°C. In this perspective, we provide a mini review of the current research on the emerging liquid- and solid-based sorbent materials to capture CO 2 , summarize the existing challenges of DAC technologies, and suggest future research directions to accelerate the development of DAC systems. In particular, the desired properties for a breakthrough sorbent that efficiently captures CO 2 from the air and releases it for sequestration are described.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗