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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Monte Carlo simulations of Cu/Ni–Si–Mn co-precipitation in duplex stainless steels

First-Passage Kinetic Monte Carlo (FPKMC) simulations of species migration in duplex stainless steels were performed in order to establish relationships between alloy content, segregation behavior, and the formation of Ni-Si-Mn rich particles in cast duplex stainless steels during thermal aging. The Ni-Si-Mn-rich second phase forms after extended aging at reactor operating temperatures and degrades alloy properties. Simulations of Ni-Si-Mn cluster formation were validated through comparison with experimental results obtained through Atom Probe Tomography (APT) on similar alloy compositions, identifying several trends. First, Cu promotes the formation of Ni-Si-Mn clusters, but only when Ni or Mn prefer segregation to the surface of Cu particles; without the segregation of these species, the critical composition for the clusters to form was not achieved. Second, the width of precipitate-denuded zones near ?/d interfaces increases with decreasing Cu content. This finding was in strong agreement with APT results, further validating our model. Finally, our model predicts that Ni-Si-Mn cluster formation will be the most extensive when the Si:Mn ratio is approximately 1:1 and the least extensive when one of these key elements is less concentrated (Mn = 0.5 at.% or Si = 0.5 at.%). The implications of these results on how to improve alloy properties are discussed.

Cu co-precipitation, Atom probe tomography (APT), ↗
DOE OSTI2025

Field intercomparison of ice nucleation measurements: the Fifth International Workshop on Ice Nucleation Phase 3 (FIN-03)

Abstract. The third phase of the Fifth International Ice Nucleation Workshop (FIN-03) was conducted at the Storm Peak Laboratory in Steamboat Springs, Colorado, in September 2015 to facilitate the intercomparison of instruments measuring ice-nucleating particles (INPs) in the field. Instruments included two online and four offline measurement systems for INPs, which are a subset of those utilized in the laboratory study that comprised the second phase of FIN (FIN-02). The composition of the total aerosols was characterized using the Particle Analysis by Laser Mass Spectrometry (PALMS) and Wideband Integrated Bioaerosol Sensor (WIBS) instruments, and aerosol size distributions were measured by a laser aerosol spectrometer (LAS). The dominant total particle compositions present during FIN-03 were composed of sulfates, organic compounds, and nitrates, as well as particles derived from biomass burning. Mineral-dust-containing particles were ubiquitous throughout and represented 67 % of supermicron particles. Total WIBS fluorescing particle concentrations for particles with diameters of > 0.5 µm were 0.04 ± 0.02 cm−3 (0.1 cm−3 highest; 0.02 cm−3 lowest), typical of the warm season in this region and representing ≈ 9 % of all particles in this size range as a campaign average. The primary focus of FIN-03 was the measurement of INP concentrations via immersion freezing at temperatures > −33 °C. Additionally, some measurements were made in the deposition nucleation regime at these same temperatures, representing one of the first efforts to include both mechanisms within a field campaign. INP concentrations via immersion freezing agreed within factors ranging from nearly 1 to 5 times on average between matched (time and temperature) measurements, and disagreements only rarely exceeded 1 order of magnitude for sampling times coordinated to within 3 h. Comparisons were restricted to temperatures lower than −15 °C due to the limits of detection related to sample volumes and very low INP concentrations. Outliers of up to 2 orders of magnitude occurred between −25 and −18 °C; a better agreement was seen at higher and lower temperatures. Although the 5–10 factor agreement of INP measurements found in FIN-03 aligned with the results of the FIN-02 laboratory comparison phase, giving confidence in progress of this measurement field, this level of agreement still equates to temperature uncertainties of 3.5 to 5 °C that may not be sufficient for numerical cloud modeling applications that utilize INP information. INP activity in the immersion-freezing mode was generally found to be an order of magnitude or more, making it more efficient than in the deposition regime at 95 %–99 % water relative humidity, although this limited data set should be augmented in future efforts. To contextualize the study results, an assessment was made of the composition of INPs during the late-summer to early-fall period of this study inferred through comparison to existing ice nucleation parameterizations and through measurement of the influence of thermal and organic carbon digestion treatments on immersion-freezing ice nucleation activity. Consistent with other studies in continental regions, biological INPs dominated at temperatures of > −20 °C and sometimes colder, while arable dust-like or other organic-influenced INPs were inferred to dominate below −20 °C.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1991

Light scattering by lunar-like particle size distributions

A fundamental input to models of light scattering from planetary regoliths is the mean phase function of the regolith particles. Using the known size distribution for typical lunar soils, the mean phase function and mean linear polarization for a regolith volume element of spherical particles of any composition were calculated from Mie theory. The two contour plots given here summarize the changes in the mean phase function and linear polarization with changes in the real part of the complex index of refraction, n - ik, for k equals 0.01, the visible wavelength 0.55 micrometers, and the particle size distribution of the typical mature lunar soil 72141. A second figure is a similar index-phase surface, except with k equals 0.1. The index-phase surfaces from this survey are a first order description of scattering by lunar-like regoliths of spherical particles of arbitrary composition. They form the basis of functions that span a large range of parameter-space.

Goguen, Jay D.↗
NASA NTRS1978

Radio evidence on the particle distribution functions in the corona following flares

This paper summarizes results of radio studies of the distribution functions (number, energy distribution, and pitch-angle distribution) of the energetic particles that are produced at the time of solar flares. The clues and constraints they impose on the mechanisms of acceleration are considered, bearing in mind that radio evidence implies that there are at least two stages of acceleration in many flares. The distribution functions of the particles resulting from first-phase acceleration, first- and/or second-phase, and second-phase acceleration are discussed.

Dulk, G. A.↗
NASA NTRS1984

Electrical conductivity studies on CuBr containing Al2O3 particles

The conductivity of CuBr was studied and the role of a second phase, Al2O3, dispersed in CuBr was tested. CuBr melts at 493 C and exhibits three phases in the solid state. CuBr is a good ionic conductor with a transport number for copper ions of virtually unity with weighed proportions of the appropriate chemicals used. The CuBr materials were heated above melting point of CuBr, and the samples were sandwiched between copper electrodes. The ac conductivity, was determined at 1 kHz between 25 and 440 C depending on the sample. It was shown that at low temperatures, the conductivity for CuBr (Al2O3) increased by as much as 100, whereas in the beta phase the conductivity of CuBr containing Al2O3 decreased. The electrical conductivity studies are in agreement with earlier data.

Dubec, P. M.↗
NASA NTRS2022

Probing the High-energy Gamma-Ray Emission Mechanism in the Vela Pulsar via Phase-resolved Spectral and Energy-dependent Light-curve Modeling

Recent kinetic simulations sparked a debate regarding the emission mechanism responsible for pulsed GeV γ-ray emission from pulsars. Some models invoke curvature radiation, while other models assume synchrotron radiation in the current sheet. We interpret the curved spectrum of the Vela pulsar as seen by H.E.S.S. II (up to ∼100 GeV) and the Fermi Large Area Telescope to be the result of curvature radiation due to primary particles in the pulsar magnetosphere and current sheet. We present phase-resolved spectra and energy-dependent light curves using an extended slot gap and current-sheet model, invoking a step function for the accelerating electric field as motivated by kinetic simulations. We include a refined calculation of the curvature radius of particle trajectories in the lab frame, impacting the particle transport, predicted light curves, and spectra. Our model reproduces the decrease of the flux of the first peak relative to the second one, evolution of the bridge emission, near-constant phase positions of peaks, and narrowing of pulses with increasing energy. We can explain the first of these trends because we find that the curvature radii of the particle trajectories in regions where the second γ-ray light-curve peak originates are systematically larger than those associated with the first peak, implying that the spectral cutoff of the second peak is correspondingly larger. However, an unknown azimuthal dependence of the E field, as well as uncertainty in the precise spatial origin of the GeV emission, precludes a simplistic discrimination of emission mechanisms.

Monica Barnard↗
NASA NTRS1987

Growth process of gamma'-particles in a liquid-quenched Ni-15 at percent Al alloy

The growth of gamma-prime particles in a supersaturated Ni-15 at% Al alloy prepared by the liquid-quench method was studied using a magnetic mass balance, transmission electron microscopy, and field ion microscopy. Three stages in the precipitation and growth of these particles are demonstrated. In the first phase, the gamma-prime phase was produced by nucleation of spinodal decomposition of the alloy. In the second stage, spherical gamma-prime particles were arranged at random in the matrix with the size independent of aging time. Then, the Al concentration in the matrix decreased with the -1/3 power of the aging time. These results suggest that the degree of ordering increases with aging time. In the third stage, the particles were coarsened with aging time. They were arranged in the matrix (100) zone and were cubic, with the cube face lying on (100). The interfacial free energy was 28.4 mJ/sq m at 873 K and 22.4 mJ/sq m at 973 K.

Tachikake, A.↗
NASA NTRS1990

The 27-28 October 1986 FIRE IFO cirrus case study - Comparison of radiative transfer theory with observations by satellite and aircraft

Observations of cirrus and altocumulus clouds during the FIRE are compared to theoretical models of cloud radiative properties. Three tests are performed. First, radiances are used to compare the relationship between nadir reflectance ot 0.83 micron and beam emittance at 11.5 microns with that predicted for model calculations using spherical and nonspherical phase functions. Good agreement is found between observations and theory when water droplets dominate. Poor agreement is found when ice particles dominate, especially using spherical-particle phase functions (SPPFs). Even when compared to a laboratory-measured ice-particle phase function (IPPF), the observations show great side-scattered radiation than the theoretical calculations. Second, the anisotropy of conservatively scattered radiation is examined using simultaneous multiple angle views of the cirrus from Landsat and ER-2 aircraft radiometers. Observed anisotropy gives good agreement with theoretical calculations using the laboratory IPPF and poor agreement with an SPPF. Third, Landsat radiances at 0.83, 1.65, and 2.21 microns are used to infer particle phase and size. For water droplets, good agreement is found with particle-probe measurements in the cloud. For ice particles, the Landsat radiance observations predict an effective radius of 60 microns versus aircraft observations of about 200 microns. It is suggested that this discrepancy may be explained by uncertainty in the imaginary index of ice and by inadequate measurements of small ice particles by microphysical probes.

Wielicki, Bruce A.↗
NASA NTRS1979

Energetic particles in solar flares

The principal properties of energetic particles accelerated in solar flares are reviewed. Particular emphasis is placed on the high-energy flare component whose acceleration is often referred to as second-phase acceleration. Stochastic Fermi acceleration is treated analytically, and the results of the computation are compared with particle and gamma-ray data to deduce information on the timing of the acceleration, the spectrum of the particles, and the energy content of the nucleonic component. A discussion of He-3 and heavy element abundances is also presented.

Ramaty, R.↗
NASA NTRS1976

Light scattering by tenuous particles - A generalization of the Rayleigh-Gans-Rocard approach

We consider scattering by arbitrarily shaped particles that satisfy two conditions: (1) that the polarizability of the particle relative to the ambient medium be small compared to 1 and (2) that the phase shift introduced by the particle be less than 2. We solve the integro-differential equation proposed by Shifrin by using the method of successive iterations and then applying a Fourier transform. For the second iteration, results are presented that accurately describe scattering by a broad class of particles. The phase function and other elements of the scattering matrix are shown to be in excellent agreement with Mie theory for spherical scatterers.

Acquista, C.↗
NASA NTRS1982

Second-stage acceleration in a limb-occulted flare

From radio observations it is known that two distinct groups of phenomena occur in large solar flares. The phenomena are related to an impulsive phase of approximately 100 s duration in the early stage of a flare and a following second phase lasting for tens of minutes. A study is presented of the limb-occulted flare event of July 22, 1972, giving particular attention to the second stage particle acceleration. The study takes into account hard X-ray, energetic particle, and radio observations. The conducted analysis shows that second stage acceleration is physically distinct from the impulsive phase, and is characterized by continuous and widespread electron acceleration to high energies, most likely by the type II burst shock wave.

Hudson, H. S.↗
DOE OSTI2022

Microstructural modification of a high-pressure die-cast A380 alloy through friction stir processing and its effect on mechanical properties

Aluminum alloy A380 is one of the major high-pressure die-cast (HPDC) alloys fabricated in the die casting sector. However, microstructural features such as shrinkage and gas porosity, entrapped oxide inclusions, change in the morphology of eutectic Si particles as a function of casting location, and the presence of multiple second phase particulates, especially Fe-bearing phases in HPDC A380 alloy results in limited ductility, thus, affecting its structural application. However, through proper modification of the as-cast microstructure, it is possible to improve the mechanical performance of alloy A380. In this study, we report the effect of friction stir processing (FSP), a well-known severe plastic deformation (SPD) and thermomechanical processing tool for selective microstructural modification, on A380. FSP effectively refines the as-cast microstructure and breaks down the coarse Si particles, creating a homogenized distribution of equiaxed Si particles in the aluminum matrix. Additionally, FSP eliminates porosity that acts as crack initiation sites, leading to improved mechanical strength and ductility.

Friction stir processing, Aluminum alloys, Mechani↗
DOE OSTI2023

An examination of the precipitation behavior of proton irradiated dual phase 308L weldment filler materials

Voids, G phase particles, and Ni-Si rich clusters in proton irradiated dual phase 308L groove filler of a SA508–304 L dissimilar metal weldment are analyzed using advanced characterization techniques. These weldments are often used in light water nuclear reactors and are subject to enhanced corrosion and associated stress corrosion cracking (SCC). Radiation damage is known to accelerate SCC. Ni-Si enriched clusters were observed in proton irradiated γ austenite, while G phase M 6 Ni 16 Si 7 (where M transition metal element) precipitates were observed in proton irradiated δ ferrite. Compositional analysis of the G phase precipitates and Ni-Si clusters from STEM-EDS and APT are compared. Unlike G phase particles in proton irradiated δ ferrite, Ni-Si clusters in proton irradiated γ austenite are not rich in Mn. Both STEM-EDS and APT line-scan profiles of the Ni-Si clusters show that the Fe and Cr concentration gradient between matrix γ austenite and the Ni-Si clusters is not as sharp as those between matrix δ ferrite and G phase. Further, HR-STEM imaging indicates that the lattice parameter of the Ni-Si clusters is commensurate with γ austenite and the clusters do not represent the precipitation of a second phase. Finally, our analysis demonstrates the density and volume fraction of G phase particles and the density of voids scales with proton irradiation damage and the energy to recoils.

308L groove filler↗
NASA NTRS1985

The energy spectra of solar flare electrons

A survey of 50 electron energy spectra from .1 to 100 MeV originating from solar flares was made by the combination of data from two spectrometers onboard the International Sun Earth Explorer-3 spacecraft. The observed spectral shapes of flare events can be divided into two classes through the criteria of fit to an acceleration model. This standard two step acceleration model, which fits the spectral shape of the first class of flares, involves an impulsive step that accelerates particles up to 100 keV and a second step that further accelerates these particles up to 100 MeV by a single shock. This fit fails for the second class of flares that can be characterized as having excessively hard spectra above 1 MeV relative to the predictions of the model. Correlations with soft X-ray and meter radio observations imply that the acceleration of the high energy particles in the second class of flares is dominated by the impulsive phase of the flares.

Evenson, P. A.↗
DOE OSTI2021

Intentional Uranium Tagging for Material Provenance and Pathway Forensics (LA19-Intentional-Forensics-NDD3Bb) (Annual Report for FY21)

This report describes the outcomes of the third and final year of a project to research the feasibility of tagging uranium materials, especially nuclear fuels. The experimental focus remained on metallic uranium forms under prospective surface and bulk tagging scenarios. Overall, the results showed that the tags could be successfully imparted and characterized in both as-built and degraded conditions. This was in line with expectations coming into this project, indicating promise for both surface and bulk tagging of metallic forms of uranium. Multiple surface tagging techniques and detection strategies were explored in FY21, with an emphasis on improving tag quality, readability, and detection in the field. Non-radioactive materials were used as a testbed. Selective deposition via laser beam was determined to be successful in imparting a readable titanium deposit on a stainless steel base plate, and can be read with high resolution characterization techniques (e.g., scanning electron microscopy) and field capable tools (e.g., eddy current testing). Other deposition techniques, such as selective deposition via electron beam and photoluminescent tags, were explored in FY21, and while success for these techniques would be dependent on additional work, these techniques showed potential for surface tagging applications. To survey bulk taggant elements for bulk uranium metal, 16 tagging elements were spread among 18 depleted uranium castings (4 baseline, 3 mix, 1 dilution, and 10 recycle). Most of these were made and characterized in FY21. Taggant acceptability was based upon manufacturability, detectability, and persistence from the standpoint of two detection options: bulk chemical analysis (for “chemical taggants”) and microstructural analysis (for “second phase taggants”). Taggant detection in both up-front manufacturing and in the face of “degradations” such as dilution, mixing, and recycling was generally good. Two independent laboratories carried out chemical analysis on most of the castings, and often at several locations within a casting, and the results are discussed. Scanning electron microscopy+EDS microanalysis revealed the second phases mostly contained the expected tagging elements. The shapes and 2 spatial distributions of these micron-sized carbides, oxides, and intermetallic particles offers opportunities for further science-based investigation and tagging optimization. Overall, V and Co currently appear as the best choices for chemical taggants while Al, Ti, Mn, Co, Pd, and Tb all look good as second phase taggants. The other elements considered here – Sc, Ni, Ge, Nb, Ce, Ta, W, Ir, and Au – while not being ruled out, require more study to become viable options. It is of special note that in the recycling study only one of the 12 elements fell out of detection even after 10 meltings, demonstrating their persistence. An Appendix tabulates all chemical analysis results to enable more quantitative and statistical studies of detection opportunities and limitations, as a part of a related project.

36 MATERIALS SCIENCE↗
DOE OSTI2021

The Tracking Machine Learning challenge : Throughput phase

This paper reports on the second "Throughput" phase of the Tracking Machine Learning (TrackML) challenge on the Codalab platform. As in the first "Accuracy" phase, the participants had to solve a difficult experimental problem linked to tracking accurately the trajectory of particles as e.g. created at the Large Hadron Collider (LHC): given O($10^5$) points, the participants had to connect them into O($10^4$) individual groups that represent the particle trajectories which are approximated helical. While in the first phase only the accuracy mattered, the goal of this second phase was a compromise between the accuracy and the speed of inference. Both were measured on the Codalab platform where the participants had to upload their software. The best three participants had solutions with good accuracy and speed an order of magnitude faster than the state of the art when the challenge was designed. Although the core algorithms were less diverse than in the first phase, a diversity of techniques have been used and are described in this paper. The performance of the algorithms are analysed in depth and lessons derived.

Amrouche, Sabrina↗
NASA NTRSDate not supplied

CFD Comparisons with Updated NASA Juncture Flow Data

The purpose of the NASA Juncture Flow experiment is to acquire high-quality flowfield details deep in the corner of a wing-body junction specifically for the purpose of CFD validation. A second phase of testing was recently completed, which includes both laser doppler velocimetry and particle image velocimetry measurements. This paper describes the recent experiment and its results. It also makes detailed comparisons between the experimental data and a new version of a widely-used CFD turbulence model for Reynolds-averaged Navier-Stokes, which was recently developed to improve separated corner flow predictions. The CFD results generally produce very good qualitative agreement with the experiment, although they are less accurate inside of the separation region, as expected.

Experimental Data↗
NASA NTRS1991

Optical properties of aggregate particles whose outer diameter is comparable to the wavelength

Results are described of numerical calculations of the optical properties (extinction efficiency, single-scattering albedo, phase function, and linear polarization) of aggregate particles whose outer diameter is comparable with the wavelength. Results are presented for two types of particle, one composed of monomers whose radius is small compared with the wavelength and a second containing monomers with larger radii. The shape of the forward-scattered lobe of the phase function is diagnostic of the mean projected area (but differs from that for an equal-area sphere), while the linear polarization, phase function at large scattering angles, and single-scattering albedo depend on the monomer diameter. The wavelength dependence of the extinction efficiency differs markedly from that for equal-area spheres. These results can be used to infer particle properties from remotely sensed data.

West, Robert A.↗