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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Reshaping the Quantum Arrow of Time

While the microscopic laws of physics are often symmetric under time reversal, most natural processes that we observe are not. The emergent asymmetry between typical and time-reversed processes is referred to as the arrow of time. In quantum physics, an arrow of time emerges when a sequence of measurements is performed on a system. We introduce quantum control tools that can yield dynamics more consistent with time flowing backward than forward. The control tools are based on the explicit construction of a Hamiltonian that can replicate the stochastic trajectories of a monitored quantum system. Such a Hamiltonian can reverse the effect of monitoring and, via a feedback process, generate trajectories consistent with a reversed arrow of time. It can also be used to simulate the backward-in-time dynamics of an open quantum system. Finally, we design a feedback-driven continuous measurement engine powered by the energy pumped into the system by the monitoring process. We show that the engine can operate under experimentally realizable conditions with feedback delay and finite-efficiency measurements.

Entropy production↗
NASA NTRS1984

Reversibility and stability of information processing systems

Classical and quantum models of dynamically reversible computers are considered. Instabilities in the evolution of the classical 'billiard ball computer' are analyzed and shown to result in a one-bit increase of entropy per step of computation. 'Quantum spin computers', on the other hand, are not only microscopically, but also operationally reversible. Readoff of the output of quantum computation is shown not to interfere with this reversibility. Dissipation, while avoidable in principle, can be used in practice along with redundancy to prevent errors.

Zurek, W. H.↗
DOE OSTI2024

High-order harmonics and the reverse of the squaring up process in the triangular-lattice magnet HoPdAl 4 ⁢Ge 2

We uncover high-order harmonics and the reverse of the squaring-up process, in terms of analyzing the evolution of magnetic orders in a centrosymmetric layered triangular-lattice magnet HoPdAl 4 ⁢Ge 2 , based on a detailed study of the crystal structure, magnetic susceptibility, magnetization, heat capacity, and magnetic structure. Temperature dependencies of magnetic susceptibility and heat capacity show two magnetic transitions at T N = 10.5 K and T t = 5.5 K. Below T N , Ho 3+ spins order antiferromagnetically as a transverse spin-density wave with the propagation vector k 1 = (001.5 – δ) with δ ≈ 0.18. Upon further cooling through T t , the high-order harmonics with k n = (001.5 – nδ), n = 3, 5, 7 develop, suggesting a squaring-up process. It is surprising that the squaring-up process does not continue down to 0 K but reverses the trend below 3 K. Magnetic-field-induced metastable transitions were observed in M⁡(H) curves with the fields applied both parallel and perpendicular to the triangular-lattice plane. Neutron-diffraction results suggest that the magnetization process in HoPdAl 4 ⁢Ge 2 involves the conversion of k n = (001.5 – n⁢δ) with n = 1, 3, 5, 7, to a ferromagnetic k F = (000) component. It is worth noting that the already weak seventh harmonic magnetic peak is enhanced by applying a small magnetic field in the ab plane at 1.5 K or warming up to 3 K, accompanied by a slight decrease of δ.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2023

Fluid power circuit having switch-mode power transformer and methods

A fluid power circuit with a switch-mode power transformer used to transfer power while keeping the pressure of power source and reverse osmosis processes relatively decoupled. The switch-mode power transformer uses the inertia of a hydraulic motor driven electric generator and switching of a hydraulic motor inlet between high and low-pressure ends to decrease the pressure at which power is being transmitted to a reverse osmosis process.

Simmons, II, Jeremy W.↗
DOE OSTI2020

Correlating dynamic microstructure to observed color in electrophoretic displays via in situ small-angle x-ray scattering

Electrophoretic deposition (EPD) is an industrially relevant and scalable technique used to form particle deposits from colloidal suspensions. Highly concentrated particle suspensions generally prevent real-time in situ microscopy observations which limit the characterization of EPD films to ex situ, or postprocessed, laboratory techniques. For dynamic systems, such as tunable amorphous photonic crystals (APCs), only reversible deposits are formed during the EPD process. Since reversible deposits cannot be characterized with standard ex situ methods, the particle-particle and particle-field interactions that govern the displayed color and crystallinity of these systems are not well understood. In this paper, we present in situ small-angle x-ray scattering and UV-Vis techniques for measuring both the structural and optical response of an APC under applied electric fields. Furthermore, we also develop a computational model based on colloidal interactions to explain the observed change in the interparticle spacing of APCs due to the applied electric field which correlates to displayed color. Ultimately, this work provides a new in situ characterization method that could be expanded for other dynamic, tunable colloidal systems.

36 MATERIALS SCIENCE↗
NASA NTRS1987

Reverse time migration: A seismic processing application on the connection machine

The implementation of a reverse time migration algorithm on the Connection Machine, a massively parallel computer is described. Essential architectural features of this machine as well as programming concepts are presented. The data structures and parallel operations for the implementation of the reverse time migration algorithm are described. The algorithm matches the Connection Machine architecture closely and executes almost at the peak performance of this machine.

Fiebrich, Rolf-Dieter↗
DOE OSTI2024

Growth of Nanocrystal Superlattices from Liquid Crystals

The growth of superlattices (SLs) made from self-assembled nanocrystals (NCs) is a powerful method for creating new materials and gaining insight into fundamental molecular dynamics. Previous explorations of NCSL syntheses have mostly compared them to crystallization. However, NCSL synthesis has not broadly shown cooling crystallization from saturated solutions as a reversible crystallization–dissolution process. We demonstrate the reversible growth of NCSLs by dispersing NCs in liquid crystal (LC) “smart solvents,” and harnessing the transitions between the isotropic and nematic phases of the LCs. The growth mode and morphology can be tuned. Furthernore, this process is a model platform for studying crystallization and demonstrates great potential in manufacturing NCSLs as colloidal crystals through liquid-phase epitaxy or colloidal synthesis.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
NASA NTRS1991

Numerical, experimental, and theoretical study of convective instability of flows over pointed bodies at incidence

A study is conducted to investigate whether the behavior of the asymmetric mean flow observed on pointed bodies of revolution at incidence remains consistent with the presence of a convective instability of an original symmetric flow, even in the incidence range where virtually bistable behavior of the asymmetric flow is observed. By means of a retractable wire located near the tip, it is determined experimentally that for all angles of attack tested (30 to 60 degs), changing the size or location of the controlled disturbance results in a finite change in the asymmetric flow field, even to the extent of reversing the sign of the side force or becoming almost symmetric. The process is reversible; returning the wire to an original position likewise restores the corresponding flow field and mean side force. The effect of wire location (roll angle and distance from the tip) as well as angle of attack and flow conditions are evaluated experimentally by means of flow visualization and side-force measurements for a generic ogive-cylinder model in a low-speed wind tunnel. Evaluation of the results in the light of computational observations and theoretical considerations yields an affirmative answer to the question posed.

Degani, David↗
NASA NTRS1992

Experimental study of controlled tip disturbance effect on flow asymmetry

The effect on the asymmetric mean flow observed on pointed bodies of revolution at incidence of changing the size and location of a controlled disturbance as well as changes in angle of attack and flow conditions are evaluated experimentally. Flow visualization and side-force measurements are carried out for a generic ogive-cylinder body inclined at high angle of attack in a low-speed wind tunnel. For all angles of attack tested (30-60 deg), minute changes in the size or location of the controlled disturbance result in finite changes in the asymmetric flow field, even to the extent of reversing the sign of the side force or becoming almost symmetric. The process is reversible; returning the wire to an original position likewise restores the corresponding flow field and mean side force. The variation of side force with continuous variation of a perturbation's size or location remains continuous and single valued, even in the incidence range of 50 to 60 deg, where 'bistable' behavior of the asymmetric flow field is observed.

Degani, David↗
NASA NTRS2012

Mars in Situ Resource Utilization Technology Evaluation

We have examined the technologies required to enable Mars In-Situ Resource Utilization (ISRU) because our understanding of Mars resources has changed significantly in the last five years as a result of recent robotic missions to the red planet. Two major developments, (1) confirmation of the presence of near-surface water in the form of ice in very large amounts at high latitudes by the Phoenix Lander and (2) the likely existence of water at lower latitudes in the form of hydrates or ice in the top one meter of the regolith, have the potential to change ISRU technology selection. A brief technology assessment was performed for the most promising Mars atmospheric gas processing techniques: Reverse Water Gas Shift (RWGS) and Methanation (aka Sabatier), as well as an overview of soil processing technology to extract water from Martian soil.

Muscatello, Anthony C.↗
NASA NTRS1972

Stabilization of porous glass reverse-osmosis membranes

Application of porous glass in form of capillary tubes for low capacity ion exchange in hyperfiltration experiments is discussed. Efficiency of desalination by process of reverse osmosis is described. Stabilization of porous glass membrane by presence of aluminum chloride is analyzed.

Ballou, E. V.↗
DOE OSTI2021

Calcium-Ion Binding Mediates the Reversible Interconversion of Cis and Trans Peroxido Dicopper Cores

Coupled dinuclear copper oxygen cores (Cu 2 O 2 ) featured in type III copper proteins (hemocyanin, tyrosinase, catechol oxidase) are vital for O 2 transport and substrate oxidation in many organisms. μ-1,2-cis peroxido dicopper cores ( C P) have been proposed as key structures in the early stages of O 2 binding in these proteins; their reversible isomerization to other Cu 2 O 2 cores are directly relevant to enzyme function. Furthermore, despite the relevance of such species to type III copper proteins and the broader interest in the properties and reactivity of bimetallic C P cores in biological and synthetic systems, the properties and reactivity of C P Cu 2 O 2 species remain largely unexplored. Herein, we report the reversible interconversion of μ-1,2-trans peroxido ( T P) and C P dicopper cores. Ca II mediates this process by reversible binding at the Cu 2 O 2 core, highlighting the unique capability for metal-ion binding events to stabilize novel reactive fragments and control O 2 activation in biomimetic systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Calcium‐Ion Binding Mediates the Reversible Interconversion of Cis and Trans Peroxido Dicopper Cores

Abstract Coupled dinuclear copper oxygen cores (Cu 2 O 2 ) featured in type III copper proteins (hemocyanin, tyrosinase, catechol oxidase) are vital for O 2 transport and substrate oxidation in many organisms. μ ‐1,2‐ cis peroxido dicopper cores ( C P ) have been proposed as key structures in the early stages of O 2 binding in these proteins; their reversible isomerization to other Cu 2 O 2 cores are directly relevant to enzyme function. Despite the relevance of such species to type III copper proteins and the broader interest in the properties and reactivity of bimetallic C P cores in biological and synthetic systems, the properties and reactivity of C P Cu 2 O 2 species remain largely unexplored. Herein, we report the reversible interconversion of μ ‐1,2‐ trans peroxido ( T P ) and C P dicopper cores. Ca II mediates this process by reversible binding at the Cu 2 O 2 core, highlighting the unique capability for metal‐ion binding events to stabilize novel reactive fragments and control O 2 activation in biomimetic systems.

Vargo, Natasha P.↗
NASA NTRS1981

Effect of fuel injector type on performance and emissions of reverse-flow combustor

The combustion process in a reverse-flow combustor suitable for a small gas turbine engine was investigated to evaluate the effect of fuel injector type on performance and emissions. Fuel injector configurations using pressure-atomizing, spill-flow, air blast, and air-assist techniques were compared and evaluated on the basis of performance obtained in a full-scale experimental combustor operated at inlet conditions corresponding to takeoff, cruise, low power, and idle and typical of a 16:1-pressure-ratio turbine engine. Major differences in combustor performance and emissions characteristics were experienced with each injector type even though the aerodynamic configuration was common to most combustor models. Performance characteristics obtained with the various fuel injector types could not have been predicted from bench-test injector spray characteristics. The effect of the number of operating fuel injectors on performance and emissions is also presented.

Norgren, C. T.↗
DOE OSTI2020

Role of Intact Hydrogen-Bond Networks in Multiproton-Coupled Electron Transfer

The essential role of a well-defined hydrogen-bond network in achieving chemically reversible multiproton translocations triggered by one-electron electrochemical oxidation/reduction is investigated by using pyridylbenzimidazole–phenol models. The two molecular architectures designed for these studies differ with respect to the position of the N atom on the pyridyl ring. In one of the structures, a hydrogen-bond network extends uninterrupted across the molecule from the phenol to the pyridyl group. Experimental and theoretical evidence indicates that an overall chemically reversible two-protoncoupled electron-transfer process (E2PT) takes place upon electrochemical oxidation of the phenol. This E2PT process yields the pyridinium cation and is observed regardless of the cyclic voltammogram scan rate. In contrast, when the hydrogen-bond network is disrupted, as seen in the isomer, at high scan rates (~1000 mV s –1 ) a chemically reversible process is observed with an E 1/2 characteristic of a one-proton-coupled electron-transfer process (E1PT). At slow cyclic voltammetric scan rates (<1000 mV s –1 ) oxidation of the phenol results in an overall chemically irreversible two-proton-coupled electron-transfer process in which the second proton-transfer step yields the pyridinium cation detected by infrared spectroelectrochemistry. In this case, we postulate an initial intramolecular proton-coupled electron-transfer step yielding the E1PT product followed by a slow, likely intermolecular chemical step involving a second proton transfer to give the E2PT product. Insights into the electrochemical behavior of these systems are provided by theoretical calculations of the electrostatic potentials and electric fields at the site of the transferring protons for the forward and reverse processes. Furthermore, this work addresses a fundamental design principle for constructing molecular wires where protons are translocated over varied distances by a Grotthuss-type mechanism.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1994

Differential rotation and turbulent convection: A new Reynolds stress model and comparison with solar data

In most hydrodynamic cases, the existence of a turbulent flow superimposed on a mean flow is caused by a shear instability in the latter. Boussinesq suggested the first model for the turbulent Reynolds stresses bar-(u(sub i)u(sub j)) in which the mean shear S(sub ij) is the cause (or source) of turbulence represented by the stress bar-(u(sub i)u(sub j)). In the case of solar differential rotation, exactly the reverse physical process occurs: turbulence (which must pre-exist) generates a mean flow which manifests itself in the form of differential rotation. Thus, the Boussinesq model is wholly inadequate because in the solar case, cause and effect are reversed. Since the Boussinesq model is inadequate, one needs an alternative model for the Reynolds stresses. We present a new dynamical model for the Reynolds stresses, convective fluxes, turbulent kinetic energy, and temperature fluctuations. The complete model requires the solution of 11 differential equations. We then introduce a set of simplifying assumptions which reduce the full dynamical model to a set of algebraic Reynolds stress models. We explicitly solve one of these models that entails only one differential equation. The overall agreement with the data is obtained with a model that is neither phenomenological nor one that requires a full numerical simulation, since it is algebraic in nature. The new model can play an important role in understanding the complex physics underlying the interplay between solar differential rotation and convection, as many physical processes can naturally be incorporated into the model.

Canuto, V. M.↗