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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Development and Validation of Two-Phase Flow Models in MOOSE and Application to Molten Salt Reactors

Two-phase flow in Molten Salt Reactors (MSRs) is important as it impacts reactivity evolution, reactor transient response, and the removal of species dissolved in the molten salt through gas phase transfer. Therefore, accurately predicting the gas distribution and the associated liquid-gas interface area in MSRs is essential for their design and operation. Recently, we integrated two new models into Idaho National Laboratory (INL)’s Multiphysics Object-Oriented Simulation Environment (MOOSE): a multi-D generalization of a mixture drift-flux model and a Euler-Euler model. The Euler-Euler model offers higher fidelity, while the mixture drift-flux model provides greater computational efficiency, which is typically preferred for modeling reactor transients. However, the mixture model's accuracy in capturing void distribution and interfacial area in MSRs still needs to be assessed. This article begins with a description of the mathematical framework for the two-phase models implemented in MOOSE. It then presents validation of these models against relevant experimental data. Finally, both models are applied to the Molten Salt Reactor Experiment case study, analyzing various operational conditions such as different rates of fission product volatilization and diverse cover gas entrainment scenarios at the reactor pump. The article concludes by assessing the suitability of both models for capturing the two-phase flow dynamics critical to MSR operations.

42 - ENGINEERING↗
DOE OSTI2024

Colloidal InAs Quantum Dot-Based Infrared Optoelectronics Enabled by Universal Dual-Ligand Passivation

Solution-processed low-bandgap semiconductors are crucial to next-generation infrared (IR) detection for various applications, such as autonomous driving, virtual reality, recognitions, and quantum communications. In particular, III–V group colloidal quantum dots (CQDs) are interesting as nontoxic bandgap-tunable materials and suitable for IR absorbers; however, the device performance is still lower than that of Pb-based devices. Herein, a universal surface-passivation method of InAs CQDs enabled by intermediate phase transfer (IPT), a preliminary process that exchanges native ligands with aromatic ligands on the CQD surface is presented. IPT yields highly stable CQD ink. In particular, desirable surface ligands with various reactivities can be obtained by dispersing them in green solvents. Furthermore, CQD near-infrared (NIR) photodetectors are demonstrated using solution processes. Careful surface ligand control via IPT is revealed that enables the modulation of surface-mediated photomultiplication, resulting in a notable gain control up to ≈10 with a fast rise/fall response time (≈12/36 ns). Considering the figure of merit (FOM), EQE versus response time (or –3 dB bandwidth), the optimal CQD photodiode yields one of the highest FOMs among all previously reported solution-processed nontoxic semiconductors comprising organics, perovskites, and CQDs in the NIR wavelength range.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Synthesis and Photophysical Properties of Light-Harvesting Gold Nanoclusters Fully Functionalized with Antenna Chromophores

The development of efficient light-harvesting systems is important to understand the key aspects of solar-energy conversion processes and to utilize them in various photonic applications. In this study, atomically well-defined gold nanoclusters are reported as a new platform to fabricate artificial light-harvesting systems. An efficient amide coupling method is developed to synthesize water-soluble Au 22 clusters fully protected with pyrene chromophores by taking advantage of their facile phase-transfer reaction. The synthesized Au 22 clusters with densely packed 18 pyrene chromophores (Au 22 –PyB 18 ) exhibit triple-emission in blue, green, and red wavelength regions arising respectively from pyrene monomer, pyrene excimer, and Au 22 emission, producing bright white light emission together. The photoluminescence of Au 22 is enhanced by more than tenfold, demonstrating that pyrenes at the periphery efficiently channel the absorbed energy to the luminescent Au 22 at the center. A combination of femtosecond transient absorption and anisotropy measurements of Au 22 –PyB 18 explicitly reveals three main decay components of 220 fs, 3.5 ps, and 160 ps that can be assigned to energy migration between pyrenes and energy transfer processes from pyrene monomer and excimer to the central Au 22 , respectively.

14 SOLAR ENERGY↗
DOE OSTI2022

Revisiting the K-edge X-ray absorption fine structure of Si, Ge–Si alloys, and the isoelectronic series: CuBr, ZnSe, GaAs, and Ge

Extended X-ray absorption fine structure (EXAFS) has evolved into an unprecedented local-structure technique that is routinely used to study materials’ problems in the biological, chemical, and physical sciences. Like many other experimental techniques, EXAFS also requires that several key atomic parameters must be known a priori before structural information can be quantitatively determined. Utilizing current analytical methods, we revisit the isoelectronic series CuBr, ZnSe, GaAs, and Ge originally studied by Stern et al. during the early development of EXAFS. We demonstrate that the ab initio EXAFS code FEFF accurately predicts the atomic phase shifts and backscattering amplitudes that are primarily functions of the sum of atomic numbers Z along an EXAFS scattering path. We also investigate quantitative fitting and first- and second-shell phase transferability together with problems that arise if a backscattering atom is identified incorrectly in an EXAFS fitting model. Features in the near-edge region, on the other hand, are shown to require a comprehensive treatment of the band structure and density-of-states, including effects of the screened Coulomb interaction between the photoelectron and core hole. Here, we demonstrate that the Bethe–Salpeter equation (BSE) accurately captures the NEXAFS (or XANES) portion of the spectrum for the isoelectronic series in addition to Si and Ge–Si alloys, including within a few eV of the absorption edge, where band structure and excitonic effects are most important.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Baseband Digital Network Analyzer Upgrade for LLRF Controllers

Digital Network Analyzers (DNA) have been implemented in many Low-Level Radio Frequency (LLRF) systems, notably NSLS-II and CERN, to help tune feedback loops. DNA characterizes feedback loops by measuring the frequency-dependent magnitude and phase transfer functions. It enables the measurement of open loop gains, gain/phase margins, and loop delays to help fine-tune feedback loops. An FPGA-based DNA has been developed and integrated into the current Relativistic Heavy Ion Collider (RHIC) LLRF infrastructure. Its performance has been tested with an implementation of one-turn delay feedback (OTFB) on the bench to maximize gain and stability. The DNA has been used to characterize a RHIC 28 MHz cavity in a RHIC Accelerator Physics Experiment (APEX) to test transient beam loading compensation strategies.

43 PARTICLE ACCELERATORS↗
NASA NTRS1968

Study of cryogenic container thermodynamics during propellant transfer

Study of thermodynamic phenomena occurring during transfer of cryogenic liquids from dewar to receiver tank reveals that the basic cause of tank implosion is evaporation rate of droplets entering the tank in the early transfer phase. Analyses of the thermodynamics involved and implosion prevention techniques are included.

Brogan, J. J.↗
NASA NTRS1984

OTV fluid mangement systems

Design, performance, and technology issues associated with reduced gravity propellant management for orbital transfer vehicles (OTV's) are reviewed. The in-space cryogenic management state-of-technology significantly affects the overall confidence level associated with a resupply mission and propulsion performance. Cryogen resupply sequences, timelines, controls, and associated crew involvement are all affected by the technology state. Additionally, OTV propellant tankage configurations, tankage thermodynamic conditions, acceleration environment, propulsion interfaces, and instrumentation are significant factors. Basic propellant transfer phases examined that drive orbital servicing requirements include: (1) tankage preconditioning; (2) tankage chilldown; and (3) propellant fill. Propellant management support of the OTV propulsion phases includes engine restart requirements and orbital coast between engine burns. Technology activities in support of identified technology issues are reviewed.

Hastings, L.↗
NASA NTRS1989

Millisecond radio pulsars in globular clusters

It is shown that the number of millisecond radio pulsars, in globular clusters, should be larger than 100, applying the standard scenario that all the pulsars descend from low-mass X-ray binaries. Moreover, most of the pulsars are located in a small number of clusters. The prediction that Teran 5 and Liller 1 contain at least about a dozen millisecond radio pulsars each is made. The observations of millisecond radio pulsars in globular clusters to date, in particular the discovery of two millisecond radio pulsars in 47 Tuc, are in agreement with the standard scenario, in which the neutron star is spun up during the mass transfer phase.

Verbunt, Frank↗
NASA NTRS1989

Millisecond radio pulsars in globular clusters

It is shown that the number of millisecond radio pulsars, in globular clusters, should be larger than 100, applying the standard scenario that all the pulsars descend from low-mass X-ray binaries. Moreover, most of the pulsars are located in a small number of clusters. The prediction that Teran 5 and Liller 1 contain at least about a dozen millisecond radio pulsars each is made. The observations of millisecond radio pulsars in globular clusters to date, in particular the discovery of two millisecond radio pulsars in 47 Tuc, are in agreement with the standard scenario, in which the neutron star is spun up during the mass transfer phase.

Verbunt, Frank↗
NASA NTRS1990

15 GHz space VLBI observations using an antenna on a TDRSS satellite

A 4.9 m diameter antenna in earth orbit, part of the Tracking and Data Relay Satellite System, was previously used for space VLBI observations at 2.3 GHz. It has now been used successfully with two ground antennas for VLBI measurements at 15 GHz. Although the sensitivity (gain/system temperature) of the orbiting antenna was a factor of 6 poorer at 15 GHz than at 2.3 GHz, 11 out of 22 extragalactic sources were detected on space-ground baselines, up to a maximum baseline of 1.63 earth diameters. The results suggest that the distribution of source visibilities at 15 and 2.3 GHz are similar for these baseline lengths. Model-dependent brightness temperatures of 1-2.5 x 10 to the 12th K were derived for six sources. This suggests that sources with brightness temperatures in this range are as common at 15 GHz as at 2.3 GHz. The coherence on space-ground baselines (this includes effects due to the phase transfer from the ground to the satellite and the reconstruction of the spacecraft orbit) was 0.76 for 340 s integrations.

Linfield, R. P.↗
NASA NTRS1990

A merger model for SN 1987 A

It is proposed that the progenitor of SN 1987A was the product of the merger of two binary components in a common envelope that formed as a result of a dynamically unstable mass-transfer phase. Two cases are considered, one in which the primary (presupernova) star is on the first red-giant branch, and one in which it is on the asymptotic giant branch, when the common-envelope phase commences. While in the first case the merger would always have been completed before the supernova event, it is possible in the second case that the supernova progenitor exploded while the stars were still in the process of spiraling into the center of the common envelope. It is shown how the latter scenario might lead to an exotic postsupernova binary with properties that could account for the 8 hr periodicity in the 2 kHz pulse frequency of the supernova pulsar (Kristian et al., 1989). It is also shown how both scenarios may explain all of the major observational features of this supernova event, including its most striking anomalies (particularly the blue color of the apparent progenitor Sk -69 deg 202).

Podsiadlowski, P.↗
NASA NTRS1990

Acetylene-chromene terminated resins as high temperature thermosets

A novel phase transfer catalyzed process for the preparation of propargyl ethers has been developed. The propargyl ethers serve as precursors to a new class of thermosetting resins called acetylene-chromene terminated (ACT) resins. Heat treatment of a solution of propargyl ethers with various catalysts, followed by removal of solvent leads to the ACT resins via partial conversion of the propargyl ether groups to chromenes. This process reduces the energy content of the resin systems and reduces the amount of shrinkage found during cure. Due to the presence of the solvent the process is safe and gives rise to low viscosity products suitable for resin transfer molding and filament winding type applications. Due to the high glass transition temperature, high modulus, and low moisture uptake the cured resins display better than 232 C/wet performance. The thermal stability of the ACT resins in air at 204 C is superior to that of conventional bismaleimide resins. The resins also display excellent electrical properties.

Godschalx, J. P.↗
NASA NTRS1994

Space VLBI telecommunication characteristics, protection criteria, and frequency sharing

A brief description of the technical characteristics of space VLBI is made, emphasizing the VLBI cross-correlation process. The signal-to-noise ratio of the cross-correlation process should be maintained as large as possible for the duration of the observation. Protection of this process from unwanted interference is a primary objective. The telecommunication radio links required in a space VLBI system are identified and characterized. Maximum bandwidths are suggested, as well as the minimum carrier frequencies required for the telemetering and the phase-transfer radio links. Planned space VLBI system models-Radioastron (Russia), VLBI Space Observatory Project (VSOP) (Japan), and the DSN orbiting VLBI subnet. (United States)--are taken as a baseline to determine the interference criteria. It is concluded that existing interference criteria for near-Earth research satellites are suitable for the protection of the space VLBI systems planned.

Gutierrez-Luaces, B. O.↗
NASA NTRS1995

HINCOF-1: a Code for Hail Ingestion in Engine Inlets

One of the major concerns during hail ingestion into an engine is the resulting amount and space- and time-wise distribution of hail at the engine face for a given geometry of inlet and set of atmospheric and flight conditions. The appearance of hail in the capture streamtube is invariably random in space and time, with respect to size and momentum. During the motion of a hailstone through an inlet, a hailstone undergoes several processes, namely impact with other hailstones and material surfaces of the inlet and spinner, rolling and rebound following impact; heat and mass transfer; phase change; and shattering, the latter three due to friction and impact. Taking all of these factors into account, a numerical code, designated HINCOF-I, has been developed for determining the motion hailstones from the atmosphere, through an inlet, and up to the engine face. The numerical procedure is based on the Monte-Carlo method. The report presents a description of the code, along with several illustrative cases. The code can be utilized to relate the spinner geometry - conical or, more effective, elliptical - to the possible diversion of hail at the engine face into the bypass stream. The code is also useful for assessing the influence of various hail characteristics on the ingestion and distribution of hailstones over the engine face.

Gopalaswamy, N.↗
NASA NTRS2001

High Earth Orbit Design for Lunar-Assisted Medium Class Explorer Missions

This study investigates the application of high-Earth orbit (HEO) trajectories to missions requiring long on-target integration times, avoidance of the Earth's radiation belt, and minimal effects of Earth and Lunar shadow periods which could cause thermal/mechanical stresses on the science instruments. As used here, a HEO trajectory is a particular solution to the restricted three-body problem in the Earth-Moon system with the orbit period being either 1/2 of, or 1/4 of, the lunar sidereal period. A primary mission design goal is to find HEO trajectories where, for a five-year mission duration, the minimum perigee radius is greater than seven Earth radii (R(sub E)). This minimum perigee radius is chosen so that, for the duration of the mission, the perigee is always above the relatively heavily populated geosynchronous radius of 6.6 R(sub E). A secondary goal is to maintain as high an ecliptic inclination as possible for the duration of the mission to keep the apsis points well out of the Ecliptic plane. Mission design analysis was completed for launch dates in the month of June 2003, using both direct transfer and phasing loop transfer techniques, to a lunar swingby for final insertion into a HEO. Also provided are analysis results of eclipse patterns for the trajectories studied, as well as the effects of launch vehicle errors and launch delays.

McGiffin, Daniel A.↗
NASA NTRS2002

Slow Light in Coupled Resonator Optical Waveguides

Recently, we discovered that a splitting of the whispering gallery modes (WGMs) occurs in coupled resonator optical waveguides (CROWs), and that these split modes are of a higher Q than the single-resonator modes, leading to enormous circulating intensity magnification factors that dramatically reduce thresholds for nonlinear optical (NLO) processes. As a result of the enhancements in Q, pulses propagating at a split resonance can propagate much slower (faster) for over (under)-coupled structures, due to the modified dispersion near the split resonance. Moreover, when loss is considered, the mode-splitting may be thought of as analogous to the Autler-Townes splitting that occurs in atomic three-level lambda systems, i.e., it gives rise to induced transparency as a result of destructive interference. In under- or over-coupled CROWs, this coupled resonator induced transparency (CRIT) allows slow light to be achieved at the single-ring resonance with no absorption, while maintaining intensities such that NLO effects are maximized. The intensity magnification of the circulating fields and phase transfer characteristics are examined in detail.

Chang, Hongrok↗
NASA NTRS2004

Theoretical Considerations on the Properties of Accreting Millisecond Pulsars

We examine a number of evolutionary scenarios for the recently discovered class of accretion-powered millisecond X-ray pulsars in ultracompact binaries, including XTE JO929-314 and XTE J1751-305. These systems have very short orbital periods of Porb = 43.6 and 42.4 minutes, respectively, and extremely small mass functions. We focus on a particular scenario that can naturally explain the present-day properties of these systems. This model invokes a donor star that was either very close to the main-sequence turnoff at the onset of mass transfer or had sufficient time to evolve during the mass-transfer phase. We have run a systematic set of binary evolution calculations with a wide range of initial conditions.

Nelson, Lorne A.↗