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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

Nondetection of Helium in the Upper Atmospheres of Three Sub-Neptune Exoplanets

We present a search for helium in the upper atmospheres of three sub-Neptune-sized planets to investigate the origins of these ubiquitous objects. The detection of helium for a low-density planet would be strong evidence for the presence of a primary atmosphere accreted from the protoplanetary nebula because large amounts of helium are not expected in the secondary atmospheres of rocky planets. We used Keck+NIRSPEC to obtain high-resolution transit spectroscopy of the planets GJ 1214b, GJ 9827d, and HD 97658b around the 10833 Å He triplet feature. We did not detect helium absorption for any of the planets despite achieving a high level of sensitivity. We used the nondetections to set limits on the planets’ thermosphere temperatures and atmospheric loss rates by comparing grids of 1D models to the data. We also performed coupled interior structure and atmospheric loss calculations, which suggest that the bulk atmospheres (winds) of the planets would be at most modestly enhanced (depleted) in helium relative to their primordial composition. Our lack of detections of the helium triplet for GJ 1214b and GJ 9827d is highly inconsistent with the predictions of models for the present-day mass loss on these planets. Higher signal-to-noise data would be needed to detect the helium feature predicted for HD 97658b. We identify uncertainties in the extreme-ultraviolet fluxes of the host stars and the lack of detailed mass-loss models specifically for cool and metal-enhanced atmospheres as the main limitations to the interpretation of our results. Ultimately, our results suggest that the upper atmospheres of sub-Neptune planets are fundamentally different from those of gas giant planets.

79 ASTRONOMY AND ASTROPHYSICS↗

EEG and ocular correlates of circadian melatonin phase and human performance decrements during sleep loss

The aim of this study was to quantify the associations between slow eye movements (SEMs), eye blink rate, waking electroencephalogram (EEG) power density, neurobehavioral performance, and the circadian rhythm of plasma melatonin in a cohort of 10 healthy men during up to 32 h of sustained wakefulness. The time course of neurobehavioral performance was characterized by fairly stable levels throughout the first 16 h of wakefulness followed by deterioration during the phase of melatonin secretion. This deterioration was closely associated with an increase in SEMs. Frontal low-frequency EEG activity (1-7 Hz) exhibited a prominent increase with time awake and little circadian modulation. EEG alpha activity exhibited circadian modulation. The dynamics of SEMs and EEG activity were phase locked to changes in neurobehavioral performance and lagged the plasma melatonin rhythm. The data indicate that frontal areas of the brain are more susceptible to sleep loss than occipital areas. Frontal EEG activity and ocular parameters may be used to monitor and predict changes in neurobehavioral performance associated with sleep loss and circadian misalignment.

Non-NASA Center↗

The Effect of Clearance Distribution on the Performance of a Compression-ignition Engine with a Precombustion Chamber

The clearance distribution in a precombustion chamber cylinder head was varied so that for a constant compression ratio of 13.5 the spherical auxiliary chambers contained 20, 35, 50, and 70 per cent of the total clearance volume. Each chamber was connected to the cylinder by a single circular passage, flared at both ends, and of a cross-sectional area proportional to the chamber volume, thereby giving the same calculated air-flow velocity through each passage. Results of engine-performance tests are presented with variations of power, fuel consumption, explosion pressure, rate of pressure rise, ignition lag, heat loss to the cooling water, and motoring characteristics. For good performance the minimum auxiliary chamber volume, with the cylinder head design used, was 35 per cent of the total clearance volume; for larger volumes the performance improves but slightly. With the auxiliary chamber that contained 35 percent of the clearance volume there were obtained the lowest explosion pressures, medium rates of pressure rise, and slightly less than the maximum power. For all clearance distributions an increase in engine speed decreased the ignition lag in seconds and increased the rate of pressure rise.

Moore, C. S.↗

Developing High Performance Space Networking Capabilities for the International Space Station and Beyond

A performance optimized implementation of Delay Tolerant Networking (DTN) with the capacity of gigabit-per second rates is developed for the International Space Station (ISS) and missions demanding large amounts of communications bandwidth. An overview of the High-rate Delay Tolerant Networking (HDTN) architecture and support for different convergence layers is provided. This paper then presents an overview of the testing and integration efforts to evaluate interoperability and capability in relevant environments. The first was interoperability testing with DTN Marshall Enterprise (DTNME) which resulted in near-gigabit per second data rates. This was followed by ISS emulation testing with the Software Development and Integration Laboratory (SDIL) at the Lyndon B. Johnson Space Center (JSC) and local testing based on the ISS DTN network topology. The local tests resulted in the discovery of potential sources of performance loss in the network and demonstrated near-gigabit rates between HDTN and DTNME.

Daniel Raible↗

Hybrid Analytics Solution for Power Plant Operations

Expert Microsystems, Inc., MapEx Software Inc. and XMPLR Energy LLC have teamed to submit a proposal to the US Department of Energy’s Office of Fossil Energy to improve the efficiency, reliability and flexibility of existing coal-based power plants. The project, titled Hybrid Analytics Solution to Improve Coal Power Plant Operations (the “Hybrid Analytics” project), will develop, demonstrate and commercialize a novel approach that integrates two proven real-time monitoring techniques. The Hybrid Analytics approach integrates into a single, integrated solution: a) an established, advanced data-driven analytics solution that includes artificial intelligence, advanced pattern recognition and machine-learning techniques and b) a well-proven, first principle thermal heat balance model solution. The future role of coal plants will depend on the ability to cycle and follow loads to meet marginal power demands, accommodate renewables and support the grid. Essential to success in this new role is a plant’s ability to maintain high reliability, efficiency and flexibility. However, these changing operational demands put significant stresses on power plant components that directly impact the ability to deliver these requirements. In the past, plants have independently monitored performance using physics-based solutions (heat rate, boiler losses, etc.) and reliability using data-driven analytics (advanced pattern recognition). The Hybrid Analytics solution integrates both approaches to enhance fault detection, provide automated diagnostics and estimates of remaining time to act, and provide critical, enhanced and accurate real-time information to coal plant operators. As a result, coal plants can improve efficiency, reliability, and flexibility and can cost-effectively maintain their key role in the power delivery system.

01 COAL, LIGNITE, AND PEAT↗

Inhibition of the ablation rate of graphite by gaseous chlorine.

Investigation of the inhibiting effect of gaseous chlorine on the ablation rate of graphite. It is shown that small amounts of chlorine gas, when present in a supersonic high-temperature air environment, can inhibit the ablation rate of graphite and depress its surface temperature below that measured in pure air. The ablation inhibition performance of chlorine is presented in graphs in terms of mass loss rate and surface temperature depression as a function of chlorine concentration.

Maahs, H. G.↗

Impact of electrode porosity architecture on electrochemical performances of 1 mm-thick LiFePO4 binder-free Li-ion electrodes fabricated by Spark Plasma Sintering

Thick electrodes with high active material loadings have been intensively studied over the last couple of decades in pursuit of achieving high energy density systems. To optimize and enhance the electrochemical performance of such electrodes, one has to control the pore morphology by, for example, varying the pore size and shape, and the level of porosity. In the present work, the fabrication of thick binder-free LiFePO4 (LFP) electrodes with two different pore sizes (12 and 20 mu m) and porosities (21 vol% and 44 vol%) using Spark Plasma Sintering (SPS) and templating approach is reported. The well-controlled porous architecture inside the thick electrodes is realized by fine-tuning experimental parameters. The impact of porosity architecture on electrochemical performance is quantified and correlated with the 3D tortuosity values determined from both micro-computed tomography and electrochemical impedance-based experimental methods. Based on the micro-computed tomography data analysis, estimated tortuosity values along X, Y, and Z axes reveal an anisotropic effect perpendicularly to the SPS compression axis (Z-direction). This is particularly profoundly observed in the samples with larger pores (20 mu m). The correlation between morphological properties and the rate capability performance is established indicating that the capacity loss happens mainly due to the Li-ion diffusion limitations.

Cathode material↗

Optical PAyload for Lasercomm Science (OPALS) link validation

Recently several day and nighttime links under diverse atmospheric conditions were completed using the Optical Payload for Lasercomm Science (OPALS) flight system on-board the International Space Station (ISS). In this paper we compare measured optical power and its variance at either end of the link with predictions that include atmospheric propagation models. For the 976 nm laser beacon mean power transmitted from the ground to the ISS the predicted mean irradiance of 10's of microwatts per square meter close to zenith and its decrease with range and increased air mass shows good agreement with predictions. The irradiance fluctuations sampled at 100 Hz also follow the expected increase in scintillation with air mass representative of atmospheric coherence lengths at zenith at 500 nm in the 3-8 cm range. The downlink predicted power of 100's of nanowatts was also reconciled within the uncertainty of the atmospheric losses. Expected link performance with uncoded bit-error rates less than 1E-4 required for the Reed-Solomon code to correct errors for video, text and file transmission was verified. The results of predicted and measured powers and fluctuations suggest the need for further study and refinement.

ISS↗

Chemical Reactor Network Modeling of Ammonia Rich-Quench-Lean Combustion Using a Partially Stirred Reactor Approach

Ammonia is a promising alternative fuel, but its use is challenging due to low flammability and high nitrogen oxide (NOx) emissions. Two-stage rich-quench-lean (RQL) combustion strategies have shown promise in reducing NOx emissions. This approach involves two stages: a rich stage that oxidizes part of the fuel and decomposes ammonia into hydrogen, and a lean stage that burns out the hydrogen and residual ammonia. Researchers used a chemical reactor network model to study the effects of heat loss and mixing on emissions performance. They found that heat loss and reduced mixing rates can lead to increased NOx emissions and N2O formation. The results will inform the development of optimized two-stage RQL combustors for ammonia, with a focus on minimizing NOx emissions and improving overall efficiency.

ammonia combustion↗

Mechanism-Informed Breakdown: Understanding Degradation by Controlling Voltage-Hold Patterns in Proton Exchange Membrane Water Electrolyzers

Low catalyst loadings pose challenges to performance stability in proton exchange membrane (PEM) water electrolysis over extended operation. To study the impact of degradation mechanisms and voltage loss rates, different stress tests are applied to membrane electrode assemblies. Potential cycling conditions were observed to induce higher degrees of iridium (Ir) oxide crystallization, ionomer degradation, and catalyst layer (CL) thinning, which likely contributed to higher kinetic loss rates. On the other hand, while Ir migrating into the PEM (Ir band) generally impairs performance, the interconnected and more uniform Ir band formed under a constant 2 V hold may allow for Ir at the catalyst/membrane interface to remain electronically connected and kinetically accessible, as well as indicate greater Ir site access during the applied stressor. The 2 V hold also demonstrates improved kinetic durability through a lower Tafel slope, faster polarization kinetics, and reduced charge transfer resistance. In contrast, potential cycling caused the migration of disconnected Ir agglomerates into the membrane bulk and created a steady increase in charge transfer resistance, a more dramatic decrease in capacitance (46.7% loss), and significant damage to the surrounding ionomer, indicating a decline in both the quality and quantity of active sites in the anode CL. This work underscores the distinct degradation pathways associated with load holds versus cycling, highlighting the role of catalyst-ionomer interactions in kinetic performance and long-term stability. These insights can inform operational strategies for PEM electrolyzers powered by intermittent energy sources, aiming to minimize efficiency losses over extended operation.

36 MATERIALS SCIENCE↗

Investigation of Different Constituent Encoders in a Turbo-code Scheme for Reduced Decoder Complexity

A large number of papers have been published attempting to give some analytical basis for the performance of Turbo-codes. It has been shown that performance improves with increased interleaver length. Also procedures have been given to pick the best constituent recursive systematic convolutional codes (RSCC's). However testing by computer simulation is still required to verify these results. This thesis begins by describing the encoding and decoding schemes used. Next simulation results on several memory 4 RSCC's are shown. It is found that the best BER performance at low E(sub b)/N(sub o) is not given by the RSCC's that were found using the analytic techniques given so far. Next the results are given from simulations using a smaller memory RSCC for one of the constituent encoders. Significant reduction in decoding complexity is obtained with minimal loss in performance. Simulation results are then given for a rate 1/3 Turbo-code with the result that this code performed as well as a rate 1/2 Turbo-code as measured by the distance from their respective Shannon limits. Finally the results of simulations where an inaccurate noise variance measurement was used are given. From this it was observed that Turbo-decoding is fairly stable with regard to noise variance measurement.

Kwatra, S. C.↗

Automating Detection and Diagnosis of Faults, Failures, and Underperformance in PV Plants

The project developed hybrid physics-based and machine-learning methods for near-real-time detection of balance-of-system faults (e.g., string, combiner, and tracker outages) in utility-scale Photovoltaic plants, achieving over 50% true positive rates with under 10% false positives and significantly reducing engineering setup time. In the extended phase, the scope expanded to plant-level underperformance analysis and industry benchmarking through the SUPER.epri.com platform. SUPER standardizes data processing and performance metrics across more than 9 GWac and 120+ plants, enabling robust comparisons and insights into loss rates, inverter downtime, and capacity degradation.

14 SOLAR ENERGY↗

Hubble Space Telescope Star Tracker ad Two-Gyro Control Law Design, Implementation, and On-Orbit Performance

The Hubble Space Telescope (HST) normally requires three gyroscopes for three-axis rate control. The loss of the Space Shuttle Columbia on STS-107 resulted in the cancellation of a shuttle-based HST Servicing Mission 4. Therefore, HST must operate using the on-board hardware until an alternate means of servicing can be accomplished. The probability of gyro failure indicates that fewer than three gyros will be operable before any servicing mission can be performe& To mitigate this, and to extend the HST life expectancy, a rate estimation and control algorithm was developed that requires two gyros to measure rate about two axes, with the remaining axis rate estimated using one of three alternate sensors. Three-axis magnetometers (MSS) are used for coarse rate estimation during large maneuvers and during occultations of other sensors. Fixed-Head Star Trackers (FHSTs) are used for rate estimation during safe mode recovery and during transition to science operations. Fine rate estimation during science operations is performed using the Fine Guidance Sensors (FGSs). The FHST mode (T2G) relies on star vectors as measured by the FHSTs to estimate vehicle rate about the axis not measured by the gyros. Since the FHSTs were not designed to estimate body rate, this method involves a unique set of problems that had to be overcome in the final design, such as the effect of FHST break tracks and moving targets on rate estimation. The solutions to these problems, as well as a detailed description of the design and implementation of the rate estimation are presented Also included are the time domain and frequency domain analysis of the T2G control law. A high fidelity HST simulator (HSTSIM) was used to verify T2G performance prior to on-orbit use. Results of these simulations are also presented. Finally, analysis of actual T2G on-orbit test results is presented for design validation.

VanArsdall, John C.↗

Interleaver design for trellis-coded differential 8-PSK modulation with non-coherent detection

The effect of finite interleaver size on bit error rate (BER) performance of coded 8-DPSK is determined by means of computer simulations. The losses evaluated in this way include the SNR degradation due to the timing and frequency errors of the symbol synchronizer and the automatic frequency control (AFC) of the receiver. BER measurements are presented using a conventional 2/3 rate convolutional 8-state trellis-code for typical Rayleigh and Rician fading channels. It is shown that for a Rician channel with a Rician parameter of 7 dB, a Doppler spread of 100 Hz and a data rate of 2400 bps, an interleaver with size 16 x 16 symbols performs nearly as well as a very large interleaver. It is also shown that for very fast Rayleigh channels, the BER-curves flatten out at large SNR.

Edbauer, Franz↗

Levenberg–Marquardt multi-classification using hinge loss function

Incorporating higher-order optimization functions, such as Levenberg-Marquardt (LM) have revealed better generalizable solutions for deep learning problems. However, these higher-order optimization functions suffer from very large processing time and training complexity especially as training datasets become large, such as in multi-view classification problems, where finding global optima is a very costly problem. To solve this issue, we develop a solution for LM-enabled classification with, to the best of knowledge first-time implementation of hinge loss, for multiview classification. Hinge loss allows the neural network to converge faster and perform better than other loss functions such as logistic or square loss rates. Here we prove our method by experimenting with various multiclass classification challenges of varying complexity and training data size. The empirical results show the training time and accuracy rates achieved, highlighting how our method outperforms in all cases, especially when training time is limited. Our paper presents important results in the relationship between optimization and loss functions and how these can impact deep learning problems.

97 MATHEMATICS AND COMPUTING↗

Grooved electrodes for high-power-density fuel cells

Proton exchange membrane fuel cells (PEMFCs) are leading candidates to decarbonize the transport sector, but widespread deployment will require improvements in lifetime, fuel economy and cost. Here we present the grooved electrode, an alternative electrode structure that enhances PEMFC performance and durability by coupling high ionomer (ion-conducting binder) content for improved H + transport with grooves for rapid O 2 transport. Grooved electrodes provide up to 50% higher performance than state-of-the-art conventional electrodes under standard operating conditions. Fuel cell diagnostics combined with multiphysics modelling demonstrate that grooved electrodes provide facile O 2 transport despite their high ionomer content, enabling improved reaction rate uniformity. Grooved electrodes also provide improved durability, with less performance loss after carbon corrosion compared with baseline electrodes. Machine learning analysis demonstrates the potential to further optimize grooved structures for next-generation PEMFCs with enhanced performance and durability, enabling smaller and cheaper fuel cell stacks with higher fuel efficiency.

25 ENERGY STORAGE↗

Improved performance of a digital phase-locked loop combined with a frequency/frequency-rate estimator

When a digital phase-locked loop with a long loop update time tracks a signal with high Doppler, the demodualtion losses due to frequency mismatch can become very significant. One way of reducing these Doppler-related losses is to compensate for the Doppler effect using some kind of frequency-rate estimator. The performance of the fixed-window least-squares estimator and the Kalman filter is investigated; several Doppler compensating techniques are proposed. It is shown that the variance of the frequency estimator can be made as small as desired, and with this, the Doppler effect can be effectively compensated. The remaining demodulation losses due to phase jitter in the loop can be less than 0.1 dB.

Mileant, A.↗

Characterizing the Influence of Organic Polymers on the Specific Reactivity of Particulate Remedial Amendments

Commercially available particulate amendments demonstrate high reactivity for effective treatment of water soluble organic and inorganic contaminants in laboratory studies; however, transport of these particles is constrained in the subsurface. In many field applications, particulate amendments are mixed with organic polymers to enhance mobility for direct push applications or stabilize suspensions for high mass loadings. As such, the interactions between particulate amendments, organic polymers and contaminant species need to be systematically investigated to properly understand mechanistic processes that facilitate predictive performance metrics for specific applications in situ . In this study, batch experiments were conducted to quantify the effects of organic polymers (xanthan gum, guar gum, and sodium alginate), polymer concentration (800 and 4,000 mg/L), and aging (up to 28 days) on chromate treatment rate and capacity by two classes of amendments: reductants [granular zero-valent iron (gZVI), micron-ZVI (mZVI), sulfur modified iron (SMI)], and an adsorbent (bismuth sub-nitrate). When particulate amendments were suspended in polymer solutions, reductants retained between 84–100% of the amendment treatment capacity. Conversely, the adsorbent maintained 63–97% relative treatment capacity of the no-polymer control. Polymer solutions had a more pronounced impact on the rate of chromate removal; first order rates of chemical reduction decreased by as much as 70% and adsorption by up to 81% relative to the no-polymer controls. Polymer–amendment aging experiments also showed decreased Cr(VI) treatment capacity; reductants decreased by as much as 24% and adsorption decreased by as much as 44% after 28 days of incubation. While polymer suspensions are needed to aid the injection of particulate amendments into the subsurface, the results from this study indicate potential losses of treatment capacity and a decrease in the rate of remedial performance due to the physical and chemical interactions between polymer suspensions and reactive particulate amendments. Simple batch systems provide baseline characterization of tripartite interactions for the removal of Cr(VI). Additional work is needed to quantify the full impact of polymers on remedial outcomes under site relevant conditions at field scale.

54 ENVIRONMENTAL SCIENCES↗