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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

Effects of refractive index mismatch in optical CT imaging of polymer gel dosimeters

Purpose: Proposing an image reconstruction technique, algebraic reconstruction technique-refraction correction (ART-rc). The proposed method takes care of refractive index mismatches present in gel dosimeter scanner at the boundary, and also corrects for the interior ray refraction. Polymer gel dosimeters with high dose regions have higher refractive index and optical density compared to the background medium, these changes in refractive index at high dose results in interior ray bending. Methods: The inclusion of the effects of refraction is an important step in reconstruction of optical density in gel dosimeters. The proposed ray tracing algorithm models the interior multiple refraction at the inhomogeneities. Jacob’s ray tracing algorithm has been modified to calculate the pathlengths of the ray that traverses through the higher dose regions. The algorithm computes the length of the ray in each pixel along its path and is used as the weight matrix. Algebraic reconstruction technique and pixel based reconstruction algorithms are used for solving the reconstruction problem. The proposed method is tested with numerical phantoms for various noise levels. The experimental dosimetric results are also presented. Results: The results show that the proposed scheme ART-rc is able to reconstruct optical density inside the dosimeter better than the results obtained using filtered backprojection and conventional algebraic reconstruction approaches. The quantitative improvement using ART-rc is evaluated using gamma-index. The refraction errors due to regions of different refractive indices are discussed. The effects of modeling of interior refraction in the dose region are presented. Conclusions: The errors propagated due to multiple refraction effects have been modeled and the improvements in reconstruction using proposed model is presented. The refractive index of the dosimeter has a mismatch with the surrounding medium (for dry air or water scanning). The algorithm reconstructs the dose profiles by estimating refractive indices of multiple inhomogeneities having different refractive indices and optical densities embedded in the dosimeter. This is achieved by tracking the path of the ray that traverses through the dosimeter. Extensive simulation studies have been carried out and results are found to be matching that of experimental results.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2015

SU-C-204-04: Patient Specific Proton Stopping Powers Estimation by Combining Proton Radiography and Prior-Knowledge X-Ray CT Information

Purpose: The material relative stopping power (RSP) uncertainty is the highest contributor to the range uncertainty in proton therapy. The purpose of this work is to develop a robust and systematic method that yields accurate, patient specific, RSP by combining 1) pre-treatment x-ray CT and 2) daily proton radiograph of the patient. Methods: The method is formulated as a linear least-square optimization problem (min||Ax-B||2). The parameter A represents the pathlength crossed by the proton in each material. The RSPs for the materials (water equivalent thickness (WET)/physical thickness) are denoted by x. B is the proton radiograph expressed as WET crossed. The problem is minimized using a convex-conic optimization algorithm with xi<xi+1 constraint. The Gammex RMI-465 phantom, with 13 material inserts, is used to investigate the optimal RSPs. The proton radiograph (B) is produced using Geant4 simulation. The matrix A is computed by calculating proton trajectories through the CT with the cubic-spline approach. Geant4 RSPs are used as reference and the clinical HU-RSP calibration curve is used as comparison. The convergence is investigated as a function of the number of angles and protons used. The radiographs angle which yield the most accurate RSPs are investigated. Results: Optimization with 9 angles and 104 protons/angle yields precise RSP (<0.75%) for all materials, except plastic lung (1.5%). Average deviation relative to Geant4 RSP is 0.5% and 3.5% using HU-RSP. Using more than two angles or more than 4×103 proton does not further increase the RSP estimate accuracy. The insert distance to the beam initial plane is related to the RSP error for this insert material. Specific filters are applied on the proton angle and energy loss to remove nuclear interaction artefacts. Conclusion: The proposed formulation of the problem with prior knowledge x-ray CT demonstrates serious potential to increase the accuracy of present RSP estimates.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2021

Revealing the Nanostructure of Mesoporous Fuel Cell Catalyst Supports for Durable, High-Power Performance

Achieving high power performance and durability with low Pt loadings are critical challenges for proton exchange membrane fuel cells. PtCo catalysts developed on new carbon black supports show promise by simultaneously providing good oxygen reduction kinetics and local oxygen transport. We investigate the role of nanoscale morphology in the performance of these catalysts supported on accessible (HSC-e and HSC-f) and conventional (Ketjen Black) porous carbons using 3D electron tomography, nitrogen sorption, and electrochemical performance measurements. We find that the accessible porous carbons have hollow interiors with mesopores that are larger and more numerous than conventional porous carbons. However, mesopore-sized openings (>2 nm width) are too rare to account for significant oxygen transport. Instead we propose the primary oxygen transport pathway into the interior is through 1–2 nm microporous channels permeating the carbon. The increased mesoporosity in the accessible porous carbons results in a shorter diffusion pathlength through constrictive, tortuous micropores in the support shell leading to lower local oxygen transport resistance. In durability testing, the accessible porous carbons show faster rates of electrochemical surface area loss, likely from fewer constrictive pores that would mitigate coarsening, but maintain superior high current density performance at end of test from the improved local oxygen transport.

Electrochemistry↗
DOE OSTI2026

Design of a Molten Salt Flow Cell for Combined Absorbance and Laser-Induced Breakdown Spectroscopy for Online Measurements

A novel flow cell allowing for multiple optical spectroscopy measurements on flowing molten salts was designed, and demonstrative calibrations of impurities in aqueous samples were performed. Online compositional measurements of molten salts are of high interest to monitor the state of relevant solar and nuclear systems. Here, the Spectroscopic Configuration for Optical Real-Time Characterization of High-Temperature (SCORCH) fluids cell was designed to meet this need by providing optical access to a high-temperature molten salt sample stream without physical contact between the sample and window materials. Laser-induced breakdown spectroscopy (LIBS) was utilized to quantify Li, Cr, Fe, Ni, Sr, and Pr at concentrations ranging nominally from 0 to 315 mmol L −1 . Laser power, frequency, and plasma position were optimized to mitigate challenges associated with sample splashing. Univariate calibration models were built with R 2 > 0.98, percent root mean square error of cross-validation (%RMSECV) as low as 2.7%, and limits of quantification (LOQs) down to 4.1 mmol L −1 . Simultaneously, absorbance calibrations were developed for the applicable analytes (Cr, Ni, and Pr) using Beer’s law with a pathlength of 4.41 ± 0.10 mm. These models provide excellent quantification performance with R 2 > 0.999, %RMSECV as low as 0.6%, and LODs down to 0.08 mmol L −1 . Although these calibrations were performed for each spectroscopic technique separately, the two methods may be combined in the future through multivariate modeling and sensor fusion to provide more robust models with the benefits of both techniques (e.g., absorbance: oxidation state concentrations, LIBS: elemental concentration). Additionally, optimized spectrometers may be deployed to enhance sensitivity.

absorbance spectroscopy↗
DOE OSTI2020

Exploration of Water Jets in Supersonic Crossflow Using X-Ray Diagnostics

Here, near-field structures of pure- and aerated-liquid jets injected into Mach 2 crossflow environments were experimentally investigated at the 7-BM beamline of the Advanced Photon Source at Argonne National Laboratory using high-speed shadowgraph imaging, high-speed x-ray imaging, and pathlength-integrated x-ray fluorescence. Liquid was flush injected into a blowdown supersonic wind tunnel. Test section top and side windows were fitted with a polycarbonate plate for high x-ray transmittance. An axisymmetric aerated-liquid injector was fitted with an exchangeable nozzle adaptor to generate a liquid jet. Water and nitrogen, the gas used for aerated-liquid jets, were doped with specially selected dopants to facilitate x-ray measurements. Liquid column structures for a pure-liquid jet, typically masked by dense droplet clouds in a supersonic crossflow environment, were visualized with the present x-ray imaging setup. Surface-wave formation, movement, and transformation on the column windward surface of the pure-liquid jet, along with column deformation and breakup processes, were qualitatively characterized. We measured time-averaged line-of-sight (LOS) liquid mass distributions within the liquid jet near fields. Cross-sectional liquid column contours of pure-liquid jets at various deformation stages were reconstructed from LOS liquid mass distributions. The pure-liquid jet deformed liquid column reached a maximum width of 1.47 times the orifice diameter before exhibiting rapid mass removal. We also observed the plume-crossing phenomenon in the aerated-liquid jet.

47 OTHER INSTRUMENTATION↗
DOE OSTI2024

Investigation of Thermal Radiation under Pressurized Oxy-combustion Conditions

Thermal radiation of the gaseous and particle phases in a pilot-scale pressurized oxy-combustor is computationally studied. In particular, the radiation characteristics of gases and particles are estimated by employing the statistical narrow-band model and the large-particle model. It is found that thermal radiation of the particle cloud dominates in the combustor under a furnace temperature of 1500 K and when there is no substantial loss of particles to the walls. Another important observation is that radiation from the gas and particles can be approximately treated as a graybody under these conditions. More specifically, the results on the spectral radiation intensity of a gas comprising 40% (vol) H 2 O and 60% CO 2 show that when the pressure is increased to 15 bar, and the radiation pathlength is 100 cm, the spectral radiation profile of the gas phase approaches that of a blackbody at the respective temperature. In addition, the emissivity of the particulate cloud has been evaluated as a function of the particle concentration and diameter by employing the large-particle model. It is shown that the emissivity grows with the particle concentration but decreases with the particle size for the same mass of the particles. Finally, this outcome of the present study is expected to be used to validate the assumption of the gray-gas model adopted in the numerical simulations of pressurized oxy-combustion.

large-particle model↗
DOE OSTI2026

New measurement techniques for gear-changing research using DESIREE

In this work we cover some of the newer techniques developed to measure the effects of a gear changing system maintained in DESIREE at Stockholm University. Gear-changing is a collider synchronization method where two rings with different harmonic numbers in them maintain collisions through different velocities, pathlengths or a combination of the two. This system has been demonstrated using the low energy ion collider DESIREE at Stockholm university. We have not only continued our previous methods of studying the beam using a repeating pattern technique where one bucket in each ring is intentionally left empty, but we now also use recently installed pickups outside of the merger region to study the beams separately while they collide.

Accelerator Physics↗
DOE OSTI2018

Solution of the Generalized Linear Boltzmann Equation for Multidimensional Stochastic Media

The generalized linear Boltzmann equation is a recently developed framework based on non-classical transport theory for modeling the expected value of particle flux in an arbitrary stochastic medium. Provided with a non-classical cross-section for a given statistical description of a medium, any transport problem in that medium may be solved. Previous work has only considered one-dimensional media without finite boundary conditions and discrete binary mixtures of materials. In this work the solution approach for the GLBE in multidimensional media with finite boundaries is outlined. The discrete ordinates method with an implicit discretization of the pathlength variable is used to leverage sweeping methods for the transport operator. In addition, several convenient approximations for non-classical cross-sections are introduced. The solution approach is verified against random realizations of a Gaussian process medium in a square enclosure.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2025

A formaldehyde and nitrogen dioxide toxics monitor for environmental justice

DOE’s Integrated Field Laboratories (IFLs) require a vast array of measurements to measure urban air quality. Nitrogen dioxide (NO2) and formaldehyde (HCHO) are ubiquitous pollutants with numerous sources, most notably vehicle exhaust. High-spatial density measurements are critical to understanding how certain neighborhoods are more adversely impacted by pollutants. This report describes the results of a Phase I SBIR project to develop and demonstrate a rapid, affordable, low-power monitor to provide high spatial resolution mobile measurements of formaldehyde and nitrogen dioxide at street-level, where people live and walk. The spatial density will be achieved via rapid measurements on a mobile platform. This sensor will quantify spatial disparities in cities of the toxics, HCHO and NO2, as well as carbon monoxide and carbon dioxide for better source identification. These species are detected in the mid infrared by laser absorption spectroscopy, and fiberoptics are used. Tasks accomplished include identification and testing of the appropriate spectroscopic regions; coupling of laser light into a fiberoptic system; development of software to control miniature electronics to scan and control two lasers simultaneously; coupling of the mid infrared fiber into a multipass cell for enhanced pathlength and sensitivity; characterization of sources of instrument noise; and design work for a Phase II prototype.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

T-1075: Large Area Fast Timing Beam Time of Flight (LAFTBToF) for ProtoDUNE

Large-area Picosecond Photodetectors (LAPPDs), developed at Argonne National Laboratory (ANL), present an opportunity to provide identification of charged particles in the 2-10 GeV/c range. Traditional methods using ionization or Cherenkov detectors require large amounts of material or pathlength for the particle to traverse in order to get a clean measurement, and are ill suited for particle beam identification in fixed-target experiments. The 6x6 cm 2 LAPPD uses mm-thick borosilicate glass micro-channel plates with a resistive surface coating added via atomic layer deposition. An electrical connection schematic of the LAPPD is shown in Figure 1. Electrons emitted by the photocathode are accelerated through the MCPs, which have µm-sized capillaries, and an avalanche of electrons is created as the electrons collide against the walls of the capillaries of the MCPs. The resulting electron avalanche is collected on anode strip lines and the signal may be read out on both ends of the stipline. The resistive coating of the thin MCPs and the short path length of the electrons to the readout results in fast rise times, gains of greater than 10 6 and typical timing resolutions of 50 ps. Differential timing on the ends of the strip lines can provide mm-level position measurements. The material of the bare LAPPD presents less than 0.05 of an interaction length and approximately 0.12 of a radiation length for a charged particle of I GeV/c. In our application, two large-area photodetectors separated by 5-10 meters can be used in a time-of-flight (ToF) measurement for 3σ separation of2-7 GeV/c charged pions, kaons and protons with minimal impact on the particle's trajectory and momentum.

43 PARTICLE ACCELERATORS↗
DOE OSTI2023

Analysis of thermal radiation of a gas-particulate-cloud in a pressurized oxy-coal combustor

Pressurized oxy-combustion (POC) aims to reduce carbon emissions from coal-fired power plants. In the POC process, pulverized coal is burned at elevated pressure in an O2-CO2 environment. The elevated pressure and high CO2 and H2O concentrations strongly impact thermal radiation, thereby significantly distinguishing POC system from conventional atmospheric-pressure air-fired and oxy-fuel combustion. Consequently, a thorough understanding of thermal radiation in POC is required to promote the development of novel combustors. The present computational work analyzes thermal radiation of the gaseous and particle phases in the pilot-scale POC combustor in Washington University in St. Louis. Particularly, the radiation characteristics of the gaseous and particulate cloud were estimated by employing the statistical narrow band model and the large-particle model. It is found that thermal radiation of a particulate cloud dominates in the combustor under the conditions of a furnace temperature of 1500 K and no substantial particle loss. Another important result is that the gas-and-particulate cloud can be approximately treated as a graybody under the same conditions. To be more specific, the results of spectral radiation intensity of a gas comprised of 40% (vol) H2O and 60% CO2 show that when the pressure is increased to 15 bar, and the radiation pathlength to 100 cm, the spectral radiation profile of the gas phase approaches that of a blackbody at the respective temperature. In addition, the emissivity of the particulate cloud has been evaluated as a function of the particle concentration and diameter by means of the large particle model. It is shown that the emissivity grows with the particle concentration but decreases with the particle size for the same mass of a particulate cloud. The emissivity of a particulate cloud in oxy- combustion exceeds that in air-fired combustion. This work could be used to validate the assumption of the gray gas model adopted in numerical simulations.

Li, Lei↗
DOE OSTI2021

Improving Prediction of Peroxide Value of Edible Oils Using Regularized Regression Models

We present four unique prediction techniques, combined with multiple data pre-processing methods, utilizing a wide range of both oil types and oil peroxide values (PV) as well as incorporating natural aging for peroxide creation. Samples were PV assayed using a standard starch titration method, AOCS Method Cd 8-53, and used as a verified reference method for PV determination. Near-infrared (NIR) spectra were collected from each sample in two unique optical pathlengths (OPLs), 2 and 24 mm, then fused into a third distinct set. All three sets were used in partial least squares (PLS) regression, ridge regression, LASSO regression, and elastic net regression model calculation. While no individual regression model was established as the best, global models for each regression type and pre-processing method show good agreement between all regression types when performed in their optimal scenarios. Furthermore, small spectral window size boxcar averaging shows prediction accuracy improvements for edible oil PVs. Best-performing models for each regression type are: PLS regression, 25 point boxcar window fused OPL spectral information RMSEP = 2.50; ridge regression, 5 point boxcar window, 24 mm OPL, RMSEP = 2.20; LASSO raw spectral information, 24 mm OPL, RMSEP = 1.80; and elastic net, 10 point boxcar window, 24 mm OPL, RMSEP = 1.91. The results show promising advancements in the development of a full global model for PV determination of edible oils.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

An HST/COS survey of the low-redshift intergalactic medium. I. Survey, methodology, and overall results

We use high-quality, medium-resolution Hubble Space Telescope/Cosmic Origins Spectrograph (HST/COS) observations of 82 UV-bright active galactic nuclei (AGNs) at redshifts z{sub AGN} < 0.85 to construct the largest survey of the low-redshift intergalactic medium (IGM) to date: 5138 individual extragalactic absorption lines in H i and 25 different metal-ion species grouped into 2611 distinct redshift systems at z{sub abs} < 0.75 covering total redshift pathlengths Δz{sub H i} = 21.7 and Δz{sub O vi} = 14.5. Our semi-automated line-finding and measurement technique renders the catalog as objectively defined as possible. The cumulative column density distribution of H i systems can be parametrized dN(>N)/dz = C{sub 14}(N/10{sup 14}cm{sup −2}){sup −(β−1)}, with C{sub 14} = 25 ± 1 and β = 1.65 ± 0.02. This distribution is seen to evolve both in amplitude, C{sub 14}∝(1+z){sup 2.3±0.1}, and slope β(z) = 1.75–0.31 z for z ≤ 0.47. We observe metal lines in 418 systems, and find that the fraction of IGM absorbers detected in metals is strongly dependent on N{sub HI}. The distribution of O vi absorbers appears to evolve in the same sense as the Lyα forest. We calculate contributions to Ω{sub b} from different components of the low-z IGM and determine the Lyα decrement as a function of redshift. IGM absorbers are analyzed via a two-point correlation function in velocity space. We find substantial clustering of H i absorbers on scales of Δv = 50–300 km s{sup −1} with no significant clustering at Δv ≳ 1000 km s{sup −1}. Splitting the sample into strong and weak absorbers, we see that most of the clustering occurs in strong, N{sub H i} ≳ 10{sup 13.5} cm{sup −2}, metal-bearing IGM systems. The full catalog of absorption lines and fully reduced spectra is available via the Mikulski Archive for Space Telescopes (MAST) as a high-level science product at http://archive.stsci.edu/prepds/igm/.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1971

Large-scale reflection and absorption of solar radiation by clouds as influencing earth radiation budgets - New aircraft measurements.

Discussion of the first results of extensive recent aircraft measurements, in the short wavelengths, of the reflection and absorption properties of clouds and their impact on radiation budget studies. From the data obtained, the albedo of typical cloud types was determined integrally and spectrally. Some preliminary results are also offered for short-wave absorption and the apparent transmission of clouds. The effect of the atmospheric pathlength between sensor and target, exhibited through molecular scattering and aerosol scattering and absorption, is included in the data analysis. Results are also presented on vertical (short-wave) radiative flux profiles, within specific wavelength intervals, from near sea level to altitudes of about 40,000 ft over relatively short time intervals.

Drummond, A. J.↗
NASA NTRS1973

The calculation of proportional counter energy-deposition spectra from experimental data.

The experimental approach considered requires the measurement of energy-absorption distributions for a set of pathlengths which define a biological volume. A suitable folding procedure is necessary to produce composite energy-absorption distributions. The investigation is concerned with the quality of the prediction of energy-deposition distributions, taking into account distributions measured with a proportional counter.

Steigerwalt, J. E.↗
NASA NTRS1972

Temperature measurements behind reflected shock waves in air

A radiometric method for the measurement of gas temperature in self-absorbing gases has been applied in the study of shock tube generated flows. This method involves making two absolute intensity measurements at identical wavelengths, but for two different pathlengths in the same gas sample. Experimental results are presented for reflected shock waves in air at conditions corresponding to incident shock velocities from 7 to 10 km/s and an initial driven tube pressure of 1 torr. These results indicate that, with this technique, temperature measurements with an accuracy of + or - 5 percent can be carried out. The results also suggest certain facility related problems.

Bader, J. B.↗