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EOS Science Plan and EOS Science Plan Executive Summary

Remote sensing of aerosol properties from space is reviewed both for present and planned national and international satellite sensors. Techniques that are being used to enhance our ability to characterize the global distribution of aerosol properties include well-calibrated multispectral radiometers, multispectral polarimeters, and multi-angle spectroradiometers. Though most of these sensor systems rely primarily on visible to mid-infrared spectral channels, the availability of thermal channels to aid in cloud screening is an important additional piece of information that is not always incorporated into the sensor design. In this paper, we describe the various satellite sensor systems being developed by Europe, Japan, and the U.S., and highlight the advantages and disadvantages of each of these systems for aerosol applications. An important underlying theme is that the remote sensing of aerosol properties, especially aerosol size distribution and single scattering albedo, is exceedingly difficult. As a consequence, no one sensor system is capable of providing totally unambiguous information, and hence a careful intercomparison of derived products from different sensors, together with a comprehensive network of ground-based sunphotometer and sky radiometer systems, are required to advance our quantitative understanding of global aerosol characteristics.

King, Michael D.

Constraining the Global, Cloud-Free Reflected Solar Radiation Flux (RSRF) with Earth Observing System (EOS) Instruments

Variations in the top-of-atmosphere reflected solar radiation flux, and in the factors that determine its value, are among the most important diagnostic indicators of changes in Earth's energy balance. Data from the MISR (Multi-angle Imaging SpectroRadiometer), MODIS (Moderate-resolution Imaging Spectroradiometer), SAGE-3 (Stratospheric Aerosol and Gas Experiment), and CERES (Clouds and Earth's Radiant Energy System), all of which are spacecraft instruments scheduled for launch in 1999, will each constrain pieces of the RSRF budget. Prior to launch, we are performing studies to determine the sensitivity of these instruments to key factors that influence the cloud-free RSRF: aerosol optical depth, aerosol scattering properties, and surface visible bidirectional reflectance distribution function (BRDF). We are also assessing the ability of the aggregate of instruments to constrain the overall RSRF budget under natural conditions over the globe. Consider the MISR retrieval of aerosols: according to simulations over cloud-free, calm ocean, for pure particles with natural ranges of optical depth, particle size, and indices of refraction, MISR can retrieve column aerosol optical depth for all but the darkest particles, to an uncertainty of at most 0.05 or 20%, whichever is larger, even if the particle properties are poorly known. For one common particle type, soot, constraints on the optical depth over dark ocean are very poor. The simulated measurements also allow us to distinguish spherical from non-spherical particles, to separate two to four compositional groups based on indices of refraction, and to identify three to four distinct size groups between 0. 1 and 2.0 microns characteristic radius at most latitudes. Based on these results, we expect to distinguish air masses containing different aerosol types, routinely and globally, with multiangle remote sensing data. Such results far exceed current satellite aerosol retrieval capabilities, which provide only total optical depth for assumed particle properties; the new information will complement in situ data, which give details about aerosol size and composition locally. In addition, our team is using climatologies that reflect the constraints each instrument is expected to provide, along with ERBE (Earth Radiation Budget Experiment) data and a radiative transfer code, to study overall sensitivity to RSRF, helping us prepare for similar studies with new data from the EOS-era instruments.

Kahn, Ralph

Monitoring Earth's Ecosystems

Partnered with Goddard Space Flight Center, Sensit Technologies Inc. developed a third-generation Portable Apparatus for Rapid Acquisitions of Bidirectional Observations of Land and Atmosphere, or PARABOLA III for short. Now commercially available, PARABOLA III is designed to measure the reflected signature of a variety of Earth surface types, from rangeland vegetation to ice and snow. It can rapidly acquire data for almost the complete sky and ground-looking hemispheres, with no missing data and sufficient dynamic range to measure direct solar radiance. The instrument was actively used in the Boreal Ecosystem- Atmosphere Study which provided useful information in designing a Multi-angle Imaging SpectroRadiometer, a small satellite being built by the Jet Propulsion Laboratory that will measure sunlight reflected by the Earth into space.

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Level 2 Top-of-Atmosphere Albedo Algorithm Theorectical Basis

This Algorithm Theoretical Basis (ATB) document describes the algorithms used to retrieve the albedo parameters of the Multi-angle Imaging SpectroRadiometer (MISR) Level 2 Top-of-Atmosphere (TOA)/Cloud Product.

Top-of-Atmosphere albedo algorithm

Global Geographic Database in Support of EOS MISR Data Processing

This paper will describe the production of the Ancillary Geographic Product (AGP) in support of the Earth Observing System (EOS) Multi-angle Imaging SpectroRadiometer (MISR) instrument data processing. The AGP is essentially a global database of geographic properties, tailored to the needs of the MISR mission.

ancillary geographic product earth observing syste

Measurement of the Depolarization of Reflected Light From Spectralon

Light reflected from Spectralon, the material chosen for on-board radiometric calibration of the Multi-angle Imaging SpectroRadiometer (MISR) is quantified in terms of the fraction of the reflected intensity that has the same polarization as the incident light.

Spectralon Radiometric Calibration

A Spectralon BRF Data Base for MISR Calibration Application

The Multi-angle Imaging SpectroRadiometer (MISR) is an Earth observing sensor which will provide global retrievals of aerosols, clouds, and land surface parameters. Instrument specifications require high accuracy absolute calibration, as well as accurate camera-to-camera, band-to-band and pixel-to-pixel relative response determinations.

spectralon MISR spectroradiometer remote sensing

Geometric Retrieval of Cloud Top Height from MISR Imagery

This paper presents the above three processing steps starting from an accurate and efficient project of multi-angle MISR image data to the ellipsoid surface, followed by a mathematical derivation which separates the cloud motion and height, and finally an automatic image matching and ray intersection algorithm for high resolution cloud top height retrieval.

Image

Aqueous Self‐Assembly of Cylindrical and Tapered Bottlebrush Block Copolymers

The self‐assembly of amphiphilic bottlebrush block copolymers (BCPs), featuring backbones densely grafted with two types of side chains, is less well understood compared to linear BCPs. In particular, the solution self‐assembly of tapered bottlebrush BCPs—cone‐shaped BCPs with hydrophilic or hydrophobic tips—remains unexplored. This study investigates eight tapered and four cylindrical bottlebrush BCPs with varied ratios of hydrophobic polystyrene (PS) and hydrophilic poly(acrylic acid) (PAA) side chains, synthesized via sequential addition of macromonomers using ring‐opening metathesis polymerization (SAM‐ROMP). Self‐assembled nanostructures formed in water were analyzed using cryogenic transmission electron microscopy, small‐angle neutron scattering, and dynamic light scattering. Most BCPs generated multiple nanostructures with surface protrusions, including spherical micelles, cylindrical micelles, and vesicles, alongside transitional forms like ellipsoids and semi‐vesicles. Coarse‐grained molecular dynamics simulations supported the experimental findings, which revealed two distinct self‐assembly pathways. The first involved micelle fusion, producing elliptical and cylindrical aggregates, sometimes forming Y‐junctions. The second pathway featured micelle maturation into semivesicles, which developed into vesicles or large compound vesicles. This work provides the first experimental evidence of vesicle formation via semivesicles in bottlebrush BCPs and demonstrates the significant influence of cone directionality on self‐assembly behavior in these cone‐shaped polymeric amphiphiles.

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