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NASA NTRS1977

Consideration of encapsulants for photovoltaic arrays in terrestrial applications

Long-term survivability of photovoltaic arrays and components in terrestrial environments will require development of adequate protective systems. Highly considered are polymeric encapsulants, a method which was successfully employed in space and aerospace applications to protect critical electrical circuitry. To be employable, however, the polymer encapsulants must themselves be chemically and mechanically resistant to failure in terrestrial service. Chemical resistance includes stability to the degrading actions of ultraviolet light, oxygen, moisture and elevated temperatures in sun rich areas. Programs are underway to identify and develop chemically stable encapsulant candidates. Chemical considerations aside, mechanical failures of the encapsulants must also be avoided in array designs. This paper discusses design considerations for avoiding mechanical failures of polymeric encapsulants, with emphasis on biaxial properties, thermal fatigue, and anisotropy and nonhomogeneity of material properties. The general principles to be presented evolved from actual failures of polymeric materials in engineering applications. Also included are brief remarks on the permeability of polymer materials to atmospheric gases.

Cuddihy, E. F.↗

NASA NTRS1993

On wave-CISK and the evaporation-wind feedback for the Madden-Julian oscillation

The combined effects of Kelvin wave-CISK and the evaporation-wind (E-W) feedback are proposed as a possible mechanism for the Madden-Julian oscillation. A very simple single vertical mode model has been employed to examine the effects of both these processes on moist Kelvin waves. The effects of wave-induced moisture convergence is parameterized by reducing the moist static stability, and CISK occurs when the moist static stability becomes negative. The E-W feedback in the presence of mean easterlies leads to unstable Kelvin modes. The presence of mean westerlies leads to decaying Kelvin modes. When CISK and the E-W feedback work in concert, an unstable Kelvin mode develops that has phase speeds of propagation between 5 m/s and 10 m/s for a large range of parameter values. On the other hand, the E-W feedback mechanism alone, in the case when CISK is not operating, produces the phase speeds of the observed Madden-Julian oscillation for only a very limited range of parameter values.

Kirtman, B.↗

NASA NTRS2001

Quasi-Equilibrium States in the Tropics Simulated by a Cloud-Resolving Model: Specific Features and Budget Analysis - Part 1

A series of long-term integrations using the two-dimensional Goddard Cumulus Ensemble (GCE) model were performed by altering imposed environmental components to produce various quasi-equilibrium thermodynamic states. Model results show that the genesis of a warm/wet quasi-equilibrium state is mainly due to either strong vertical wind shear (from nudging) or large surface fluxes (from strong surface winds), while a cold/dry quasi-equilibrium state is attributed to a remarkably weakened mixed-wind shear (from vertical mixing due to deep convection) along with weak surface winds. In general, latent heat flux and net large-scale temperature forcing, the two dominant physical processes, dominate in the beginning stage of the simulated convective systems, then considerably weaken in the final stage, which leads to quasi-equilibrium states. A higher thermodynamic regime is found to produce a larger rainfall amount, as convective clouds are the leading source of rainfall over stratiform clouds even though the former occupy much less area. Moreover, convective clouds are more likely to occur in the presence of strong surface winds (latent heat flux), while stratiform clouds (especially the well-organized type) are favored in conditions with strong wind shear (large-scale forcing). The convective systems, which consist of distinct cloud types due to the variation in horizontal winds, are also found to propagate differently. Accordingly, convective systems with mixed-wind shear generally propagate in the direction of shear, while the system with strong (multidirectional) wind shear propagates in a more complex way. Based on the results from the temperature (Q1) and moisture (Q2) budgets, cloud-scale eddies are found to act as a hydrodynamic 'vehicle' that cascades the heat and moisture vertically. Several other specific features such as atmospheric stability, CAPE, and mass fluxes are also investigated and found to be significantly different between diverse quasi-equilibrium states. Detailed comparisons between the various states are presented.

Shie, C.-L.↗

NASA NTRS2000

Nutritional Evaluation of NASA's Rodent Food Bar Diet

Tests are being conducted on NASA's rodent Food Bar in preparation for long-term use as the rat and mouse diet aboard the International Space Station. Nutritional analyses are performed after the bars are manufactured and then repeated periodically to determine nutritional stability. The primary factors analyzed are protein, ash, fat, fiber, moisture, amino acids, fatty acids, and minerals. Nutrient levels are compared to values published in the National Research Council's dietary requirements for rodents, and also to those contained in several commonly used commercial rodent lab diets. The Food Bar is manufactured from a powdered diet to which moisture is added as it is processed through an extruder. The bars are dipped into potassium sorbate, vacuum-sealed, and irradiated. In order to determine nutrient changes during extrusion and irradiation, the powdered diet, the non-irradiated bars, and the irradiated bars are all analyzed. We have observed lower values for some nutrients (iodine, vitamin K, and iron) in the Food Bars compared with NRC requirements. Many nutrients in the Food Bars are contained at a higher level than levels in the NRC requirements. An additional factor we are investigating is the 26% moisture level in the Food Bars, which drops to about 15% within a week, compared to a stable 10% moisture in many standard lab chow diets. In addition to the nutritional analyses, the food bar is being fed to several strains of rats and mice, and feeding study and necropsy results are being observed (Barrett et al, unpublished data). Information from the nutritional analyses and from the rodent studies will enable us to recommend the formulation that will most adequately meet the rodent Food Bar requirements for long-term use aboard the Space Station.

Barrett, Joyce E.↗

NASA NTRS2016

Investigation of Desiccants and CO2 Sorbents for Advanced Exploration Systems 2015-2016

Advanced Exploration Systems are integral to crewed missions beyond low earth orbit and beyond the moon. The long-term goal is to reach Mars and return to Earth, but current air revitalization systems are not capable of extended operation within the mass, power, and volume requirements of such a mission. Two primary points are the mechanical stability of sorbent pellets and recovery of sorbent productivity after moisture exposure in the event of a leak. In this paper, we discuss the present efforts towards screening and characterizing commercially-available sorbents for extended operation in desiccant and CO2 removal beds.

Knox, James C.↗

NASA NTRS2000

Aging Effects of Environmentally-Friendly Cleaners on Adhesive Bond Integrity

Because of the 1990 Clean Air Act Amendment many chlorinated solvents are being phased out of use in manufacturing industries. Replacement of the ODC (ozone- depleting chemicals) with less volatile, non-ozone depleting cleaners has been extensively studied over the past nine years at Thiokol Propulsion, Cordant Technologies. Many of the non-ODC cleaners contain compounds that can potentially degrade over time under conditions of high temperature, humidity and exposure to light. The chemical composition of environmentally conditioned cleaners and the subsequent effect on aluminum/amine-cured epoxy bond integrity as measured by Tapered Double Cantilever Beam were evaluated. From this study it is observed that moisture content increases for those cleaners containing polar compounds. Non-volatile residue content increases as stabilizers are depleted and the chemical compound limonene is oxidized. A change in aluminum/ amine-cured epoxy bond fracture toughness is observed as some of these cleaners age with increases in moisture and NVR content.

Biegert, L. L.↗

NASA NTRS1990

Additives Lower Dielectric Constants Of Polyimides

Dielectric constants as low as 2.43 make polyimides more attractive for electronic applications. Process makes aromatic condensation polyimide films and coatings with dielectric constants lowered by incorporation of diamic acid additives. Materials provide better electrical insulation without sacrificing temperature stability of polyimide binders. Applicable whenever high temperature, low absorption of moisture, and high electrical-insulation properties needed. Applications include semiconductors and printed-circuit boards for computer industry and possibly automotive industry.

Stoakely, Diane M.↗

NASA NTRS2000

Preservation Methods Utilized for Space Food

Food for manned space flight has been provided by NASA-Johnson Space Center since 1962. The various mission scenarios and space craft designs dictated the type of food preservation methodologies required to meet mission objectives. The preservation techniques used in space flight include freeze-dehydration, thermostabilization, irradiation, freezing and moisture adjustment. Innovative packaging material and techniques enhanced the shelf-stability of the food items. Future space voyages may include extended duration exploration missions requiring new packaging materials and advanced preservation techniques to meet mission goals of up to 5-year shelf-life foods.

Vodovotz, Yael↗

NASA NTRS2003

A Variational Analysis of Divergence Profiles Based upon Column-Integrated Mass, Moisture and Energetic Constraints with Satellite-Derived Boundary Fluxes

A diagnostic study is made of the mean global divergent circulation based upon a constrained least action principle that minimizes column-integrated divergent kinetic energy subject to constraints on mass, moisture, available potential energy (ape) and total kinetic energy. The concept of gross moist stability was incorporated in the prescription of Lagrange weight function associated with the ape constraint in order to simulate the net effects of cumulus convective heating in the tropics. The variational analyses were validated satisfactorily with the original NCEP/NCAR-reanalysis divergence fields for the Septembers of 1987 and 1988. Further analyses show that in the tropical ascending regions, the analyzed divergences are dominated by the mass and ape constraints; the moisture constraint is implicitly satisfied while the kinetic energy constraint is highly dependent on the ape constraint. In the subtropical descending regions, the analyzed divergences are dominated by the mass, moisture and kinetic energy constraints; the ape constraint is implicitly satisfied. When the constraint integrals were blended with the satellite-derived boundary flux data from GPCP precipitation and ERBE/SRB radiation estimates, the newly analyzed divergences are significantly stronger than the reanalysis divergences in the areas where the estimates of precipitation rates are higher. With few exceptions, the increases in upper-layer divergences are coupled with nearly equal increases in lower-layer convergences.

Lu, Huei-Lin↗

NASA NTRS1990

Thermally stable, low dielectric polyquinolines for aerospace and electronics applications

Four new high molecular weight, linear chain polyquinolines have been synthesized and fabricated into high quality free standing films. These polymers are characterized by moderate to high glass transition temperatures, excellent thermal and thermooxidative stability, extremely low dielectric constants and good planarizing characteristics. The polymers absorb very low quantities of moisture. As a consequence, the dielectric constant of one new polyquinoline has been shown to be quite insensitive to exposure to warm/wet conditions. Isothermal aging of one new derivative in air has been carried out at elevated temperatures (250 C to 345 C). The results demonstrate truly outstanding thermooxidative stability. Additional characterizations include molecular weight determinations, solubilities and film-forming characteristics, density measurements, and UV-Vis spectroscopy. The data acquired to date suggest that the polymers may find use as refractive films and coatings and as interlevel planarizers in microelectronics applications.

Hendricks, Neil H.↗

NASA NTRS2010

NASA's Soil Moisture Active and Passive (SMAP) Mission

The Soil Moisture Active-Passive (SMAP) Mission is one of the first Earth observation satellites being formulated by NASA in response to the 2007 National Research Council s Decadal Survey. SMAP will make global measurements of soil moisture at the Earth's land surface and its freeze-thaw state. These measurements will allow significantly improved estimates of water, energy and carbon transfers between the land and atmosphere. Soil moisture measurements are also of great importance in assessing flooding and monitoring drought. Knowledge gained from SMAP observations can help mitigate these natural hazards, resulting in potentially great economic and social benefits. SMAP observations of soil moisture and freeze/thaw timing over the boreal latitudes will also reduce a major uncertainty in quantifying the global carbon balance and help to resolve an apparent missing carbon sink over land. The SMAP mission concept will utilize an L-band radar and radiometer sharing a rotating 6-meter mesh reflector antenna flying in a 680 km polar orbit with an 8-day exact ground track repeat aboard a 3-axis stabilized spacecraft to provide high-resolution and high-accuracy global maps of soil moisture and freeze/thaw state every two to three days. In addition, the SMAP project will use these surface observations with advanced modeling and data assimilation to provide estimates of deeper root-zone soil moisture and net ecosystem exchange of carbon. SMAP recently completed its Phase A Mission Concept Study Phase for NASA and transitioned into Phase B (Formulation and Detailed Design). A number of significant accomplishments occurred during this initial phase of mission development. The SMAP project held several open meetings to solicit community feedback on possible science algorithms, prepared preliminary draft Algorithm Theoretical Basis Documents (ATBDs) for each mission science product, and established a prototype algorithm testbed to enable testing and evaluation of the performance of candidate algorithms. SMAP conducted an Applications Workshop in September 2009 to coordinate with potential application users interested in the mission data. A draft Applications Plan describing the Project s planned outreach to potential applications users has been prepared and will be updated during Phase B. SMAP made a significant evaluation of the potential terrestrial radio frequency interference (RFI) source environment and established radiometer and radar flight hardware and ground processing mitigation approaches. SMAP finalized its science orbit and orbit injection approach to optimize launch mass and prepared launch and commissioning scenarios and timeline. A science data communications approach was developed to maximize available science data volume to improve science margins while maintaining moderately short data product latencies to support many potential applications using existing ground assets and with minimum impact to the flight system. SMAP developed rigid multi-body and flexible body dynamics and control models and system designs for the 6-meter rotating instrument reflector-boom assembly (RBA) and flight system to confirm pointing and control performance, and devised strategies to efficiently implement on-orbit balancing if needed. Industry partners were selected for the spin mechanism assembly (SMA) and RBA. Preliminary designs for the radar and radiometer were initiated, including constructing breadboards of key assemblies.

Kellogg, Kent↗

NASA NTRS1998

Cyclic Fiber Push-In Test Monitors Evolution of Interfacial Behavior in Ceramic Matrix Composites

SiC fiber-reinforced ceramic matrix composites are being developed for high-temperature advanced jet engine applications. Obtaining a strong, tough composite material depends critically on optimizing the mechanical coupling between the reinforcing fibers and the surrounding matrix material. This has usually been accomplished by applying a thin C or BN coating onto the surface of the reinforcing fibers. The performance of these fiber coatings, however, may degrade under cyclic loading conditions or exposure to different environments. Degradation of the coating-controlled interfacial behavior will strongly affect the useful service lifetime of the composite material. Cyclic fiber push-in testing was applied to monitor the evolution of fiber sliding behavior in both C- and BN-coated small-diameter (15-mm) SiC-fiber-reinforced ceramic matrix composites. The cyclic fiber push-in tests were performed using a desktop fiber push-out apparatus. At the beginning of each test, the fiber to be tested was aligned underneath a 10- mm-diameter diamond punch; then, the applied load was cycled between selected maximum and minimum loads. From the measured response, the fiber sliding distance and frictional sliding stresses were determined for each cycle. Tests were performed in both room air and nitrogen. Cyclic fiber push-in tests of C-coated, SiC-fiber-reinforced SiC showed progressive increases in fiber sliding distances along with decreases in frictional sliding stresses for continued cycling in room air. This rapid degradation in interfacial response was not observed for cycling in nitrogen, indicating that moisture exposure had a large effect in immediately lowering the frictional sliding stresses of C-coated fibers. These results indicate that matrix cracks bridged by C-coated fibers will not be stable, but will rapidly grow in moisture-containing environments. In contrast, cyclic fiber push-in tests of both BN-coated, SiC-fiber-reinforced SiC and BNcoated, SiC-fiber-reinforced barium strontium aluminosilicate showed no significant changes in fiber sliding behavior with continued short-term cycling in either room air or nitrogen. Although the composites with BN-coated fibers showed stable short-term cycling behavior in both environments, long-term (several-week) exposure of debonded fibers to room air resulted in dramatically increased fiber sliding distances and decreased frictional sliding stresses. These results indicate that although matrix cracks bridged by BNcoated fibers will show short-term stability, such cracks will show substantial growth with long-term exposure to moisture-containing environments. Newly formulated BN coatings, with higher moisture resistance, will be tested in the near future.

Eldridge, Jeffrey I.↗

NASA NTRS1990

Acetylene-chromene terminated resins as high temperature thermosets

A novel phase transfer catalyzed process for the preparation of propargyl ethers has been developed. The propargyl ethers serve as precursors to a new class of thermosetting resins called acetylene-chromene terminated (ACT) resins. Heat treatment of a solution of propargyl ethers with various catalysts, followed by removal of solvent leads to the ACT resins via partial conversion of the propargyl ether groups to chromenes. This process reduces the energy content of the resin systems and reduces the amount of shrinkage found during cure. Due to the presence of the solvent the process is safe and gives rise to low viscosity products suitable for resin transfer molding and filament winding type applications. Due to the high glass transition temperature, high modulus, and low moisture uptake the cured resins display better than 232 C/wet performance. The thermal stability of the ACT resins in air at 204 C is superior to that of conventional bismaleimide resins. The resins also display excellent electrical properties.

Godschalx, J. P.↗

NASA NTRS1999

Response to CO2 Transient Increase in the GISS Coupled Model: Regional Coolings in a Warming Climate

The (GISS) Goddard Institute for Space Studies coupled atmosphere-ocean model is used to investigate the effect of increased atmospheric CO2 by comparing a compounded 1 percent CO2 increase experiment with a control simulation. After 70 years of integration, the global surface air temperature in the 1 percent CO2 experiment is 1.43 C warmer. In spite of this global warming, there are two distinct regions, the northern Atlantic Ocean and the southern Pacific Ocean, where the surface air temperature is up to 4 C cooler. This situation is maintained by two positive feedbacks: a local effect on convection in the South Pacific and a non-local impact on the meridional circulation in the North Atlantic. The poleward transport of latent energy and dry static energy by the atmosphere is greater in the 1 percent CO2 experiment, caused by warming and therefore increased water vapor and greater greenhouse capacity at lower latitudes. The larger atmospheric transports tend to reduce upward vertical fluxes of heat and moisture from the ocean surface at high latitudes, which has the effect of stabilizing the ocean, reducing both convection and the thermohaline circulation. With less convection, less warm water is brought up from below, and with a reduced North Atlantic thermohaline circulation (by 30 percent at time of CO2 doubling), the poleward energy transport by the oceans decreases. The colder water then leads to further reductions in evaporation, decreases of salinity at high latitudes, continued stabilization of the ocean, and maintenance of reduced convection and meridional overturning. Although sea ice decreases globally, it increases in the cooling regions which reduces the overall climate sensitivity; its effect is most pronounced in the Southern Hemisphere. Tropical warming has been observed over the past several decades; if modeling studies such as this and others which have produced similar effects are valid, these processes may already be beginning.

Russell, Gary L.↗

NASA NTRS2011

The Sensitivity of African Easterly Waves to Eastern Tropical Atlantic Sea-Surface Temperatures

The results of two regional atmospheric model simulations are compared to assess the influence of the eastern tropical Atlantic sea-surface temperature maximum on local precipitation, transient easterly waves and the West African summer monsoon. Both model simulations were initialized with reanalysis 2 data (US National Center for Environmental Prediction and Department of Energy) on 15 May 2006 and extended through 6 October 2006, forced by synchronous reanalysis 2 lateral boundary conditions introduced four times daily. One simulation uses 2006 reanalysis 2 sea-surface temperatures, also updated four times daily, while the second simulation considers ocean forcing absent the sea-surface temperature maximum, achieved here by subtracting 3 K at every ocean grid point between 0 and 15 N during the entire simulation. The simulation with 2006 sea-surface temperature forcing produces a realistic distribution of June-September mean precipitation and realistic westward propagating swaths of maximum rainfall, based on validation against Tropical Rainfall Measuring Mission (TRMM) estimates. The simulation without the sea-surface temperature maximum produces only 57% of the control June-September total precipitation over the eastern tropical Atlantic and about 83% of the Sahel precipitation. The simulation with warmer ocean temperatures generates generally stronger circulation, which in turn enhances precipitation by increasing moisture convergence. Some local precipitation enhancement is also attributed to lower vertical thermal stability above the warm water. The study shows that the eastern tropical Atlantic sea-surface temperature maximum enhances the strength of transient easterly waves and broadens the spatial extent of associated precipitation. However, large-scale circulation and its interaction with the African continent, and not sea-surface temperatures, control the timing and trajectories of the waves.

Druyan, Leonard M.↗

NASA NTRS1988

Moisture adsorption in optical coatings

The thin film filter is a very large aperture component which is exceedingly useful because of its small size, flexibility and ease of mounting. Thin film components, however, do have defects of performance and especially of stability which can cause problems in systems, particularly where long-term measurements are being made. Of all of the problems, those associated with moisture absorption are the most serious. Moisture absorption occurs in the pore-shaped voids inherent in the columnar structure of the layers. Ion-assisted deposition is a promising technique for substantially reducing moisture adsorption effects in thin film structures.

Macleod, H. Angus↗

NASA NTRS2001

A Methodology for Surface Soil Moisture and Vegetation Optical Depth Retrieval Using the Microwave Polarization Difference Index

A methodology for retrieving surface soil moisture and vegetation optical depth from satellite microwave radiometer data is presented. The procedure is tested with historical 6.6 GHz brightness temperature observations from the Scanning Multichannel Microwave Radiometer over several test sites in Illinois. Results using only nighttime data are presented at this time, due to the greater stability of nighttime surface temperature estimation. The methodology uses a radiative transfer model to solve for surface soil moisture and vegetation optical depth simultaneously using a non-linear iterative optimization procedure. It assumes known constant values for the scattering albedo and roughness. Surface temperature is derived by a procedure using high frequency vertically polarized brightness temperatures. The methodology does not require any field observations of soil moisture or canopy biophysical properties for calibration purposes and is totally independent of wavelength. Results compare well with field observations of soil moisture and satellite-derived vegetation index data from optical sensors.

Owe, Manfred↗

NASA NTRS1979

Numerical simulation of VTPR temperature retrievals in a severe storm environment

Environmental conditions prior to convective development on the Great Plains of the U.S. on one case study day were investigated using the high-resolution infrared radiation sounder (HIRS) on Nimbus 6. A dual-retrieval scheme was developed to retrieve both lower tropospheric moisture and temperature parameters from the HIRS radiances. Total precipitable water, surface dew point temperatures, and stability indices were analyzed at a resolution of up to 30 Km on this day. Correlations with interpolated NES rawinsonde values were high and intrinsic noise levels were low. The true quality of the mesoscale analyses, however, is only seen by examining the small scale features at a scale of approximately 100 Km. Perturbations on the dry line feature for this day were seen in the satellite data, although the dry line position was just as easily picked up by surface observations. Convective development 2 1/2 hours later did seem to correlate well with the local maxima of moisture and instability seen in the satellite analyses.

Vonderhaar, T. H.↗