Additive Manufacturing of Refractory Metallic Materials
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Nonmetallic materials development - cryogenic insulation, adhesives research, and membrane diffusion theory
Creep tests with titanium alloys, precipitation hardening stainless steels, and maraging steels
Cratering in basalt and pumice targets by hypervelocity impact of aluminum projectiles
Impact tests on samples of volcanic pumice and basalt
Flammability tests of guidance and navigation nonmetallic materials in pure oxygen atmosphere
The special skills developed during the Saturn S-2 Program are documented to enable qualified personnel to carry out efficient operations in future S-2 production. Skills covered include: acceptance testing of fusion-welding equipment, weld operators and inspector certification, machine certification, preweld operations, and repair weld certification.
Vacuum stability screening tests were performed on the Apollo 15 Scientific Instrument Module (SIM) bay nonmetallic materials in accordance with the NASA document SP-R-0022. The testing was necessary to support the evaluation to determine the effect material outgassing contamination would have on the SIM bay optical lenses and sensing devices. The Apollo 15 SIM experiments were highly successful, therefore, it is assumed that contamination due to the outgassing of nonmetallic materials did not affect equipment operation. A related problem, the reversion of a silicone rubber grommet which affected an electrical motor switch operation is also reported.
Analysis of a wide variety on nonmetallic materials for offgassing products, including carbon monoxide and total hydrocarbons in 5 psia oxygen are reported. A general method as described in MSFC-SPEC-101B Offgassing Support Combustion.
Calibration data are presented for heat flux and pressure profiles, model temperature histories, and model weight and thickness changes.
Multiple physical and chemical techniques including mass spectroscopy, atomic absorption spectroscopy, gas chromatography, electron microscopy, optical microscopy, electronic spectroscopy for chemical analysis (ESCA), infrared spectroscopy, nuclear magnetic resonance (NMR), X-ray analysis, conductivity, and isotopic labeling were used in investigating the atomic interactions between organic environments and titanium and titanium oxide surfaces. Key anhydrous environments studied included alcohols, which contain hydrogen; carbon tetrachloride, which does not contain hydrogen; and mixtures of alcohols and halocarbons. Effects of dissolved salts in alcohols were also studied. This program emphasized experiments designed to delineate the conditions necessary rather than sufficient for initiation processes and for propagation processes in Ti SCC.
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Cyclic creep response was investigated and design methods applicable to thermal protection system structures were developed. The steady-state (constant temperature and load) and cyclic creep response characteristics of four alloys were studied. Steady-state creep data were gathered through a literature survey to establish reference data bases. These data bases were used to develop empirical equations describing creep as a function of time, temperature, and stress and as a basis of comparison for test data. Steady-state creep tests and tensile cyclic tests were conducted. The following factors were investigated: material thickness and rolling direction; material cyclic creep response under varying loads and temperatures; constant stress and temperature cycles representing flight conditions; changing stresses present in a creeping beam as a result of stress redistribution; and complex stress and temperature profiles representative of space shuttle orbiter trajectories. A computer program was written, applying creep hardening theories and empirical equations for creep, to aid in analysis of test data. Results are considered applicable to a variety of structures which are cyclicly exposed to creep producing thermal environments.
A method of analysis was developed for predicting permanent cyclic creep deflections in stiffened panel structures. This method uses creep equations based on cyclic tensile creep tests and a computer program to predict panel deflections as a function of mission cycle. Four materials were investigated - a titanium alloy (Ti-6Al-4V), a cobalt alloy (L605), and two nickel alloys (Rene'41 and TDNiCr). Steady-state and cyclic creep response data were obtained by testing tensile specimens fabricated from thin gage sheet (0.025 and 0.63 cm nominal). Steady-state and cyclic creep equations were developed which describe creep as a function of time, temperature and load. Tests were also performed on subsize (6.35 x 30.5 cm) rib and corrugation stiffened panels. These tests were used to correlate creep responses between elemental specimens and panels. The panel response was analyzed by use of a specially written computer program.
Ten materials were evaluated for mechanical and dielectric properties following long term vacuum exposure. Data obtained for these materials is presented in tabular form.
The effects of prolonged spacecraft materials were determined and the results compared with predicted behavior. The adhesion and dielectric properties of poly-thermaleze and therm-amid magnet wire insulation were studied. The tensile properties of Lexan, polyurethane, polyethelyne, lucite, and nylon were studied well as the flexure and tensile characteristic of Adlock 851, a phenolic laminate. The volume resistivity of Cho-seal, a conductive elastomer was also a examined. Tables show the time exposed at thermal vacuum, and the high, low, and average MPA and KSI.
A PDP 11/23 quadrupole mass spectrometer system was coupled to a nondiscriminating gas inlet system permitting gases at atmospheric pressure to be admitted into a high vacuum chamber containing the ion source of the mass spectrometer without separation of the gaseous components. The resolution of related software problems has resulted in a convenient computer-mass spectrometer system capable of generating masses, relative intensities and related data on the gaseous products resulting from the atmospheric thermal decomposition of nonmetallic materials.
Predictive modeling of environmental conditions on nonmetallic materials was studied. The in-flight data of the atomic oxygen reaction with carbon and osmium, the laboratory and in-flight data of the atomic oxygen reaction with polymeric films and the effect of electron irradiation on the rates of oxidation are discussed. No information is found that can be used to model such effects on composites. The effects of the space environment on thermal control coatings and its effect on the space station are examined.