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At least 91 records · Page 5

Life cycle analysis of dedicated energy crops for fuel production in the United States

Dedicated energy crops are promising feedstocks to make biofuels including jet fuels. This study applies life cycle analysis (LCA) to estimate direct well-to-wake (WTW) greenhouse gas (GHG) emissions (g CO 2 e/MJ) for jet fuel derived from five energy crops-biomass sorghum, miscanthus, switchgrass, poplar, and willow-via Fischer-Tropsch-to-Jet (FTJ) and Ethanol-to-Jet (ETJ) pathways. The WTW boundary includes direct emissions from biomass production, fuel production, and fuel combustion. The R&D GREET model is expanded to conduct the LCA, using national average biomass yields and farming inputs from the 2023 Billion-Ton Study. In addition, this study estimates emissions from market-mediated effects, including induced land-use change, induced other crop (non-feedstock) production changes, and induced livestock production changes using global economic and emissions factor models. On a per-dry U.S. ton basis, cultivation and harvest emissions are lowest for willow (51,565 g CO 2 e) and highest for biomass sorghum (104,488 g CO 2 e). Per-acre results show similarly high emissions for sorghum and lowest values for poplar and willow. Direct WTW emissions are substantially lower for FTJ (biomass sorghum: 5.5; miscanthus: 10.3; switchgrass: 11.7; poplar: 11.9; and willow: 8.7 g CO 2 e/MJ) than ETJ (33.2; 33.8; 34.8; 36.2; and 31.7 g CO 2 e/MJ, respectively). When market-mediated emissions are included, miscanthus exhibits the lowest total emissions across energy crop pathways. Although results are sensitive to modeling assumptions, they indicate that high-yielding perennial and woody crops, particularly when planted on marginal land, could significantly reduce WTW emissions for bio-jet fuels by combining low direct emissions with soil carbon gains and favorable market-mediated effects.

Billion-Ton Study↗

Imaging Zn and Ni distributions in leaves of different ages of the hyperaccumulator Noccaea caerulescens by synchrotron-based X-ray fluorescence

Mapping of leaves of hyperaccumulators can provide insights into the mechanisms these species utilize to accumulate high metal concentrations. We used synchrotron-based X-ray fluorescence (SXRF) to perform Zn and Ni imaging in leaves of different ages of Noccaea caerulescens. A mature leaf of the related non-hyperaccumulator Thlaspi arvense was also imaged. The concentrations of Zn, Ni, Co, and Cr in N. caerulescens grown on an ultramafic soil were 9-, 10-, 12-, and 3-fold higher than T. arvense. N. caerulescens showed an exceptional ability to accumulate Zn from the soil, posing a bioconcentration factor of 6.7. T. arvense had Zn and Ni distributed uniformly in the leaf blade with doubling fluorescence counts in the tip and margins, suggesting a strategy to excrete metals and avoid toxicity. On the other hand, N. caerulescens displayed distinctly different Zn and Ni accumulation patterns, regardless of the age or metal concentration in the leaves. Zinc was mainly distributed in the cells surrounding the central and secondary veins. Nickel accumulated in the margins and tips of the leaf blade. Finally, given the time required to image large leaves in synchrotron facilities, small leaves can be used to represent the leaf distribution of Zn and Ni in N. caerulescens.

36 MATERIALS SCIENCE↗

How profitable is switchgrass in Illinois, USA? An economic definition of marginal land

Decisions regarding the conversion of land from an existing crop to bioenergy crops are critical for the sustainable production of both food and fuels. This study seeks to establish criteria for delineating land as “economically marginal”, and thus suited for growing switchgrass. In this case study of an Illinois agricultural field, the profitability of switchgrass, with farmgate prices of $\$44$ Mg –1 , $\$66$ Mg –1 , or $\$88$ Mg –1 , was compared to corn and soybean crop prices. Further, the study also evaluates the profitability of switchgrass when replacing corn-based yield estimates from the Soil Productivity Index (SPI) of Illinois. Based on a dry-matter yield of 10.45 Mg ha –1 , switchgrass can compete with soybeans only at the high price of $\$88$ Mg –1 , but depending on location, can compete with corn at $\$66$ Mg –1 . Across Illinois, at $\$88$ ha –1 , all Illinois land with SPI < 100% and 95% of land under SPI class C (SPI 100–116) is profitable under switchgrass. Switchgrass may not be profitable relative to corn grown in the SPI class A (SPI > 133) and only 7% of class B (SPI 117–132). Our results show that land with drainage and erosion limitations is economically marginal when corn and soybean yields are low, and the farmgate price for switchgrass is greater than $\$66$ Mg –1 . However, this may not be possible on land where switchgrass is replacing frequent soybean rotations (corn–soybean ratio ≤ 1). Land used to produce only soybeans may only be marginal at the farmgate price of $\$88$ Mg –1 . Further studies need to be conducted to identify how much land can be converted to switchgrass without harming corn production.

09 BIOMASS FUELS↗

Hurricanes and turbulent floods threaten arsenic-contaminated coastal soils and vulnerable communities

Coastal environments, particularly those adjacent to Superfund sites, are at increased risk of contaminant release during natural disasters, posing serious threats to nearby communities. To investigate this issue, we employed an advanced laboratory flood simulator to impose arsenic-contaminated sediments to turbulent flooding events. We further monitored changes in arsenic collocation and solid-phase speciation using advanced synchrotron radiation-based techniques to understand the impacts of flooding on arsenic mobility. Our results demonstrate that turbulent conditions significantly enhance the resuspension of arsenic-rich sediments, resulting in increased arsenic release into the water. This mobilization is driven by the erosion of the reduced sediments and the redox-mediated transformation and dissolution of Fe and Mn (oxyhydr) oxides, which promote the release of As(III). We found that arsenic speciation on resuspended particles is closely tied to shear stress, with As(V) prevailing at low stress and the more toxic As(III) dominating at higher stress levels. In the post-erosion phase, solid-phase As(III) decreased while dissolved As(III) increased, indicating ongoing desorption. The persistence of multiple arsenic species on resuspended particles marks them as potential long-range transport vectors. Thus, the environmental impact of flooding and sediment resuspension extends beyond the event itself, raising longer-term concerns for arsenic mobility. Our comprehensive geospatial analysis revealed substantial overlap between arsenic-contaminated soils and regions at high risk of flooding and hurricanes across the conterminous United States. This overlap disproportionately impacts economically disadvantaged and marginalized communities. Approximately 40 million Americans reside within 10 kilometers of these high-risk contaminated zones, with nearly 28 million exposed to hurricane threats and around 18 million vulnerable to flooding risks. Alarmingly, over 40% of those affected by hurricanes and 33% of those impacted by flooding belong to underrepresented minority and low-income populations. These findings highlight the urgent need for targeted mitigation strategies to protect public health and address environmental justice concerns.

54 ENVIRONMENTAL SCIENCES↗

Measurements of water vapor in Mars' antarctic

A complete Mars year of measurements of atmospheric water vapor in the south arctic have been obtained from the Viking Orbiters. Analysis of the observations indicates that, except for the south remnant cap, the southern hemisphere of Mars is devoid of any substantial reservoirs of water in contact with the atmosphere, and that, in the summer time, the top layer of soil is desiccated. Small amounts of water ice are incorporated into the annual CO2 cap; this water is released at the cap margin when it retreats in the spring. The first global dust storm resulted in heating of the south arctic atmosphere and a transport of water in from the equatorial region. The second global dust storm had a negligible effect on atmospheric water vapor; the dust contained little water.

Davies, D. W.↗

Quantitative analysis of planetary reflectance spectra with principal components analysis

A technique is presented for quantitative analysis of planetary reflectance spectra as mixtures of particles on microscopic and macroscopic scales using principal components analysis. This technique allows for determination of the endmembers being mixed, their abundance, and the scale of mixing, as well as other physical parameters. Eighteen lunar telescopic reflectance spectra of the Copernicus crater region, from 600 nm to 1800 nm in wavelength, are modeled in terms of five likely endmembers: mare basalt, mature mare soil, anorthosite, mature highland soil, and clinopyroxene. These endmembers were chosen from a similar analysis of 92 lunar soil and rock samples. The models fit the data to within 2 percent rms. It is found that the goodness of fit is marginally better for intimate mixing over macroscopic mixing.

Johnson, P. E.↗

Estimating Snow Water Storage in North America Using CLM4, DART, and Snow Radiance Data Assimilation

This paper addresses continental-scale snow estimates in North America using a recently developed snow radiance assimilation (RA) system. A series of RA experiments with the ensemble adjustment Kalman filter are conducted by assimilating the Advanced Microwave Scanning Radiometer for Earth Observing System (AMSR-E) brightness temperature T(sub B) at 18.7- and 36.5-GHz vertical polarization channels. The overall RA performance in estimating snow depth for North America is improved by simultaneously updating the Community Land Model, version 4 (CLM4), snow/soil states and radiative transfer model (RTM) parameters involved in predicting T(sub B) based on their correlations with the prior T(sub B) (i.e., rule-based RA), although degradations are also observed. The RA system exhibits a more mixed performance for snow cover fraction estimates. Compared to the open-loop run (0.171m RMSE), the overall snow depth estimates are improved by 1.6% (0.168m RMSE) in the rule-based RA whereas the default RA (without a rule) results in a degradation of 3.6% (0.177mRMSE). Significant improvement of the snow depth estimates in the rule-based RA as observed for tundra snow class (11.5%, p < 0.05) and bare soil land-cover type (13.5%, p < 0.05). However, the overall improvement is not significant (p = 0.135) because snow estimates are degraded or marginally improved for other snow classes and land covers, especially the taiga snow class and forest land cover (7.1% and 7.3% degradations, respectively). The current RA system needs to be further refined to enhance snow estimates for various snow types and forested regions.

snow depth↗

Quantifying Variability and Controls of Riverine Dissolved Organic Carbon Exported to Arctic Coastal Margins of North America (Final Report)

This project involved implementation and application of a coupled permafrost hydrology and dissolved organic carbon process models to investigate how spatial and seasonal variations in terrestrial hydrology and soil freeze/thaw dynamics influence the mobilization, loading, and export of organic carbon to the stream network for selected arctic basins across northern Alaska and northwest Canada. The model simulations were constrained by detailed observations of in- stream chemistry, soil active layer profile moisture and temperature dynamics, streamflow, soil carbon inventories and satellite microwave remote sensing based assessments of surface soil freeze-thaw dynamics. We developed and applied the numerical modeling and data analysis, incorporating observed data for calibration and validation, in order to investigate the terrestrial hydrology, permafrost dynamics, and associated DOC production and loading to rivers across a region encompassing watersheds draining to the coast. The project produced six publications and three datasets archived in public repositories.

54 ENVIRONMENTAL SCIENCES↗

HCMM: Soil moisture in relation to geologic structure and lithology, northern California

The author has identified the following significant results. Empirical observations on the ground and examination of aerial color IR photographs indicate that in grassland terrain, the vegetation overlying sandstone tends to become less vigorous sooner in the late spring season than does the area overlain by an adjacent shale unit. The reverse relationship obtains in the fall. These relationships are thought to be a reflection of the relative porosity of each of the units and hence of their ability to retain or lose soil moisture. A comparison of the optically enlarged day and nite IR imagery of the Late Mesozoic interbedded sandstone and shale units along the western margin of the Sacramento Valley, California, taken at seasonally critical times of the year (late spring/early summer and late fall/early winter) reveals subtle seasonal variations of graytone which tend to support the empirical observations after consideration of Sun angle and azimuth, and the internal consistency of the data on each set of satellite imagery.

Rich, E. I.↗

Quantifying spatial and vertical variations in soil C:N relationships in permafrost-affected landscapes

Permafrost regions are experiencing rapid changes that affect carbon (C) and nitrogen (N) cycles, with implications for vegetation dynamics and gas exchanges with the atmosphere. Soil C:N ratio is a key indicator of organic matter quality, yet spatial estimates of N stocks and C:N ratios lag behind those for C. We used quantile regression forests to compare direct and indirect digital soil mapping approaches for predicting soil C:N ratios at 0–30, 30–60, and 60–100 cm depths across a latitudinal transect in Alaska. The indirect approach – deriving C:N from separately predicted C and N stocks – outperformed direct mapping for the surface layer (0–30 cm), while direct mapping was marginally better at greater depths. However, prediction accuracy decreased with depth for both methods. Temperature and topography were the most important predictors. Both approaches overestimated low and underestimated high C:N ratios, with direct mapping showing greater bias. Our results underscore the challenges of modeling C:N ratios in heterogeneous, data-sparse permafrost soils, but also suggest that indirect mapping holds promise if supported by more extensive datasets.

54 ENVIRONMENTAL SCIENCES↗

Hydraulically‐vulnerable trees survive on deep‐water access during droughts in a tropical forest

Summary Deep‐water access is arguably the most effective, but under‐studied, mechanism that plants employ to survive during drought. Vulnerability to embolism and hydraulic safety margins can predict mortality risk at given levels of dehydration, but deep‐water access may delay plant dehydration. Here, we tested the role of deep‐water access in enabling survival within a diverse tropical forest community in Panama using a novel data‐model approach. We inversely estimated the effective rooting depth (ERD, as the average depth of water extraction), for 29 canopy species by linking diameter growth dynamics (1990–2015) to vapor pressure deficit, water potentials in the whole‐soil column, and leaf hydraulic vulnerability curves. We validated ERD estimates against existing isotopic data of potential water‐access depths. Across species, deeper ERD was associated with higher maximum stem hydraulic conductivity, greater vulnerability to xylem embolism, narrower safety margins, and lower mortality rates during extreme droughts over 35 years (1981–2015) among evergreen species. Species exposure to water stress declined with deeper ERD indicating that trees compensate for water stress‐related mortality risk through deep‐water access. The role of deep‐water access in mitigating mortality of hydraulically‐vulnerable trees has important implications for our predictive understanding of forest dynamics under current and future climates.

54 ENVIRONMENTAL SCIENCES↗

Monitoring sediment transfer processes on the desert margin

LANDSAT Thematic Mapper and Multispectral Scanner data have been used to construct change detection images for three playas in south-central Tunisia. Change detection images have been used to analyze changes in surface reflectance and absorption between wet and dry season (intra-annual change) and between different years (inter-annual change). Change detection imagery has been used to examine geomorphological changes on the playas. Changes in geomorphological phenomena are interpreted from changes in soil and foliar moisture levels, differences in reflectances between different salt and sediments and the spatial expression of geomorphological features. Intra-annual change phenomena that can be detected from multidate imagery are changes in surface moisture, texture and chemical composition, vegetation cover and the extent of aeolian activity. Inter-annual change phenomena are divisible into those restricted to marginal playa facies (sedimentation from sheetwash and alluvial fans, erosion from surface runoff and cliff retreat) and these are found in central playa facies which are related to the internal redistribution of water, salt and sediment.

Millington, Andrew C.↗

Miscanthus: An Environmental Choice for Marginal Lands

Miscanthus x giganteus, or Giant Miscanthus, is a tall, perennial grass originally from Asia. It is considered a sterile hybrid that has been bred to not produce viable seeds. Instead, rhizomes are planted to establish the crop. Here, the rhizome is an underground modified stem mass that puts out shoots and roots supporting new growth each year. This perennial crop takes two to three years to reach maturity, but established stands can reach upwards of 12 ft. tall with a very thick canopy (Pyter, 2007). Miscanthus has shown potential for high dry matter yields compared to other biomass crops, which could in turn lead to more efficient land use especially when applied to a bioenergy and bioproduct supply chain. In one study, switchgrass (Panicum virgatum) yielded 10.3 Mg/ha of biomass on average, while miscanthus yielded 22.4 Mg/ha (Heaton et al., 2004). Additionally, miscanthus production has been associated with many environmental benefits, including benefits to water quality, nutrient load removal, soil stabilization, and soil health (Bhardwaj et al., 2011; Hussain et al., 2019). Many of the possible practical and environmental benefits that are associated with miscanthus production may be attractive to stakeholders who are interested in alternative land use options, particularly in areas considered to be marginal in productivity.

54 ENVIRONMENTAL SCIENCES↗

Emissivity of Frozen Regions Retrieved from Aquarius Measurements

The land emissivity model used in the Aquarius data processing has been updated for the latest data release (V5.0). In order to improve the estimates of the brightness temperatures of frozen regions, the new model uses values of surface emissivity that have been estimated from the Aquarius measurements averaged over the entire duration of the mission. The retrieved emissivities depend on the geographic location, but they depend only marginally on time, temperature and snow cover.

Aquarius↗

Available land for cellulosic biofuel production: a supply chain centered comparison

The land that is potentially available to produce dedicated cellulosic bioenergy crops, often referred to as 'marginal' land, depends heavily on the underlying assumptions used to classify and identify it. In this study we compare three definitions and types of marginal land to identify the interactions between the bioenergy landscape and the logistics networks needed for the biofuel supply chain. Typical studies of the scale, cost, and greenhouse gas (GHG) mitigation potential of cellulosic biofuel take a land-centered approach which may neglect to account for the trade-offs between establishing bioenergy crops and the supply chain design decisions needed to allow those crops to be converted to liquid fuel. A mathematical programming approach is used to minimize the total annualized cost of a large-scale field-to-product system producing bioethanol in the USA midwest. Results show that a high concentration of marginal land leads to efficient systems and that the bioenergy landscape design becomes increasingly important with a higher emphasis on GHG mitigation. Additionally, targeted landscape design (including fertilization) with a focus on fields with high soil carbon sequestration potential can greatly reduce the system-wide GHG emissions for only a small increase in the unit cost of biofuel.

09 BIOMASS FUELS↗

Climate Induced Birch Mortality in Trans-Baikal Lake Region, Siberia

The Trans-Baikal (or Zabailkal'e) region includes the forest-steppe ecotones south and east of Lake Baikal in Russia and has experienced drought for several years. The decline and mortality of birch (Betula pendula) stands within the forest-steppe ecotone Trans-Baikal region was studied based on a temporal series of satellite data, ground measurements, and tree ring analysis. During the first decade of the 21st century birch stands decline and mortality were observed on )about 5% of the total area of stands within our 1250 km(exp 2 study area. Birch forest decline and mortality occurs mainly at the margins of stands, within the forest-steppe ecotone on slopes with direct insolation. During the first decade of the 21st century summer (June-August) precipitation was about 25% below normal. Soil water content measurements were lowest within dead stands and highest within healthy stands and intermediate within damaged stands. Drought impact on stands was amplified by an increase in summer air temperatures (+0.9 C) in comparison with the previous decade. Tree ring data of ''surviving'' and ''dead'' tree groups showed a positive correlation with summer/annual precipitation and negative correlation with summer air temperatures. Temperature and precipitation extreme anomalies tend to occur in the region with a period of about 27 years. The observed anomaly was the most severe since the beginning of meteorological observations in the year 1900. Data for the other sites showed a positive climate impact on the growth and expansion of Siberian forests. That is, the same species (B. pendula) showed considerable increase (1.4 times both in height and stem volume) during 20th-21st centuries as temperature increased but precipitation remained at adequate levels.

Forest die-off↗