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An instrument capable of remotely monitoring trace atmospheric constituents is described. The instrument, called a laser absorption spectrometer, can be operated from an aircraft or spacecraft to measure the concentration of selected gases in three dimensions. This device will be particularly useful for rapid determination of pollutant levels in urban areas.
The National Research Council's decadal survey on Earth Science and Applications from Space[1] recommended the Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS) mission for launch in 2013-2016 as a logical follow-on to the Orbiting Carbon Observatory (OCO) which is scheduled for launch in late 2008 [2]. The use of a laser absorption measurement technique provides the required ability to make day and night measurements of CO2 over all latitudes and seasons. As a demonstrator for an approach to meeting the instrument needs for the ASCENDS mission we have developed the airborne Carbon Dioxide Laser Absorption Spectrometer (CO2LAS) which uses the Integrated Path Differential Absorption (IPDA) Spectrometer [3] technique operating in the 2 micron wavelength region.. During 2006 a short engineering checkout flight of the CO2LAS was conducted and the results presented previously [4]. Several short flight campaigns were conducted during 2007 and we report results from these campaigns.
Continuous combustion product monitoring aboard manned spacecraft can prevent chronic exposure to hazardous compounds and also provides early detection of combustion events. As future missions extend beyond low-Earth orbit, analysis of returned environmental samples becomes impractical and safety monitoring should be performed in situ. Here, we describe initial designs of a five-channel tunable laser absorption spectrometer to continuously monitor combustion products with the goal of minimal maintenance and calibration over long-duration missions. The instrument incorporates dedicated laser channels to simultaneously target strong mid-infrared absorption lines of CO, HCl, HCN, HF, and CO2. The availability of low-power-consumption semiconductor lasers operating in the 2 to 5 micron wavelength range affords the flexibility to select absorption lines for each gas with maximum interaction strength and minimal interference from other gases, which enables the design of a compact and mechanically robust spectrometer with low-level sensitivity. In this paper, we focus primarily on absorption line selection based on the availability of low-power single-mode semiconductor laser sources designed specifically for the target wavelength range.
Measurements of tropospheric ozone have been made in the southern and middle California regions and over the Pacific Ocean during two series of flights in February and May 1977. The data were obtained by using a laser absorption spectrometer, a nadir-viewing instrument which remotely measures the ozone column abundance between ground level and aircraft altitude by interacting with ozone at specific wavelengths near 9.5 microns. The measurements indicate significantly lower ozone abundances above the Mojave Desert region as compared with farm, forest, and urban areas. The average tropospheric column density was found to be 0.0027 atm cm/km over the California region and 0.0035 atm cm/km over the Pacific Ocean region 1000-2000 km west of the coast of Mexico.
The air quality aboard manned spacecraft must be continuously monitored to ensure crew safety and identify equipment malfunctions. In particular, accurate real-time monitoring of carbon monoxide (CO) levels helps to prevent chronic exposure and can also provide early detection of combustion-related hazards. For long-duration missions, environmental monitoring grows in importance, but the mass and volume of monitoring instruments must be minimized. Furthermore, environmental analysis beyond low-Earth orbit must be performed in-situ, as sample return becomes impractical. Due to their small size, low power draw, and performance reliability, semiconductor-laser-based absorption spectrometers are viable candidates for this purpose. To reduce instrument form factor and complexity, the emission wavelength of the laser source should coincide with strong fundamental absorption lines of the target gases, which occur in the 3 to 5 micrometers wavelength range for most combustion products of interest, thereby reducing the absorption path length required for low-level concentration measurements. To address the needs of current and future NASA missions, we have developed a prototype absorption spectrometer using a semiconductor quantum cascade laser source operating near 4.6 micrometers that can be used to detect low concentrations of CO with a compact single-pass absorption cell. In this study, we present the design of the prototype instrument and report on measurements of CO emissions from the combustion of a variety of aerospace plastics.
As a precursor to and validation of the core technology necessary for NASA's Active Sensing of CO2 Emissions over Nights, Days,and Seasons (ASCENDS) mission, we flew JPL's Carbon Dioxide Laser Absorption Spectrometer (CO2LAS) in a campaign of five flights onboard NASA's DC-8 Airborne Laboratory in July 2010. This is the latest in a series of annual flight campaigns that began in 2006, and our first on the DC-8 aircraft.
Ozone data from the 1979 Southeastern Virginia Urban Study (SEV-UPS) field program are presented. The SEV-UPS was conducted for evaluation of an ozone remote sensor, the Laser Absorption Spectrometer. During the measurement program, remote-sensor evaluation was in two areas; (1) determination of the remote sensor's accuracy, repeatability, and operational characteristics, and (2) demonstration of the application of remotely sensed ozone data in air-quality studies. Data from six experiments designed to provide in situ ozone data for evaluation of the sensor in area 1, above, are presented. Experiments consisted of overflights of a test area with the remote sensor aircraft while in situ measurements with a second aircraft and selected surface stations provided correlative ozone data within the viewing area of the remote sensor.
Infrared heterodyne spectroscopy is a passive technique employing coherent optical detection for the study of spectral features in remote sources. It employs optical components such as mirrors and lenses normally associated with incoherent optics, but because of it's coherent nature, it offers the advantages of ultrahigh spectral resolving power, high frequency precision, and diffraction limited field-of-view. Attention is given to the development of an ultrahigh resolution diode laser heterodyne spectrometer for observational and laboratory use. The instrument is designed for operation in the spectral range from 7.5 to 8.5 microns. A PbSe tuneable diode laser (TDL) is employed as local oscillator. A closed-cycle cooler is employed to keep the oscillator at operating temperatures in the range from 12 to 60 K. Attention is given to factors determining the TDL heterodyne sensitivity, the spectrometer design, and a survey of 8 micron observations, SiO could be detected in the sunspot spectrum.
Monitoring of specific combustion products can provide early-warning detection of accidental fires aboard manned spacecraft and also identify the source and severity of combustion events. Furthermore, quantitative in situ measurements are important for gauging levels of exposure to hazardous gases, particularly on long-duration missions where analysis of returned samples becomes impractical. Absorption spectroscopy using tunable laser sources in the 2 to 5 micrometer wavelength range enables accurate, unambiguous detection of CO, HCl, HCN, HF, and CO2, which are produced in varying amounts through the heating of electrical components and packaging materials commonly used aboard spacecraft. Here, we report on calibration and testing of a five-channel laser absorption spectrometer designed to accurately monitor ambient gas-phase concentrations of these five compounds, with low-level detection limits based on the Spacecraft Maximum Allowable Concentrations. The instrument employs a two-pass absorption cell with a total optical pathlength of 50 cm and a dedicated infrared semiconductor laser source for each target gas. We present results from testing the five-channel sensor in the presence of trace concentrations of the target compounds that were introduced using both gas sources and oxidative pyrolysis (non-flaming combustion) of solid material mixtures.
Extensive data from large regions are needed as a basis for the study of anthropogenic trace gases in the troposphere. The need arises, therefore, for an instrument which is capable to monitor rapidly the atmosphere in a region. The present investigation is concerned with the results of efforts to develop an instrument which is capable of remotely measuring gases in the troposphere. The Laser Absorption Spectrometer (LAS) was designed for use in aircraft, and was employed to measure tropospheric ozone distribution since 1977. Attention is given to a description of the LAS instrument, the theoretical basis of instrument operation, LAS measurement programs, the results of the LAS development program, and future work.
Understanding the earth's carbon cycle is essential for diagnosing current and predicting future climates, which requires precise global measurements of atmospheric CO2 through space missions. The Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS) space mission will provide accurate global atmospheric CO2 measurements to meet carbon science requirements. The joint team of NASA Langley Research Center and ITT Exelis, Inc. proposes to use the intensity-modulated, continuous-wave (IM-CW) laser absorption spectrometer (LAS) approach for the ASCENDS mission. Prototype LAS instruments have been developed and used to demonstrate the power, signal-to-noise ratio, precision and accuracy, spectral purity, and stability of the measurement and the instrument needed for atmospheric CO2 observations from space. The ranging capability from laser platform to ground surfaces or intermediate backscatter layers is achieved by transmitted range-encoded IM laser signals. Based on the prototype instruments and current lidar technologies, space LAS systems and their CO2 column measurements are analyzed. These studies exhibit a great potential of using IM-CW LAS system for the active space CO2 mission ASCENDS.
An instrument has been designed for the measurement of stratospheric trace species which utilizes tunable infrared diode lasers as sources for sensitive in situ absorption spectroscopy in selected wavelength regions. This instrument, the Balloon-Borne Laser In Situ Sensor (BLISS), is a high-resolution absorption spectrometer designed to provide measurements of the concentrations of stratospheric species and their diurnal variations. The instrument employs second-harmonic detection of the absorption of tunable diode laser (TDL) radiation (3-30 microns) in a 1 km path length defined by a retroreflector lowered 0.5 km below the BLISS gondola. Retroreflector tracking under microprocessor control is obtained using a He-Ne laser and coaligned TV camera with CID imaging. Simultaneous measurements of molecular species in the 20-40 km altitude range will be performed using four TDLs, with the predicted minimum-detectable mixing ratio at 30 km being typically less than or equal to 0.1 ppbv.
We report on the design of a six-channel tunable laser absorption spectroscopy instrument for measuring ambient gas-phase concentrations of CO, HCl, HCN, HF, CO2, and O2 in spacecraft environments. Monitoring of these compounds can provide early warning detection of fire events while also indicating what materials have been exposed to heating. Continued post-fire monitoring of these hazardous gases can also facilitate safe and effective cleanup. The sensor is a miniaturized version of a five-channel prototype that was previously validated in ground-based oxidative pyrolysis tests. Here, we describe absorption line selection and theoretical detection limits for a sensor with reduced absorption pathlengths for each detection channel, which allows for a substantial reduction in overall instrument footprint. Ultimately, the new instrument is designed to be used in fire safety tests conducted by NASA, where various materials will undergo oxidative pyrolysis in an unmanned spacecraft returning from low Earth orbit.
The Sample Analysis at Mars (SAM) investigation of the Mars Science Laboratory (MSL) addresses the chemical and isotopic composition of the atmosphere and volatiles extracted from solid samples. The SAM investigation is designed to contribute substantially to the mission goal of quantitatively assessing the habitability of Mars as an essential step in the search for past or present life on Mars. SAM is a 40 kg instrument suite located in the interior of MSL's Curiosity rover. The SAM instruments are a quadrupole mass spectrometer, a tunable laser spectrometer, and a 6-column gas chromatograph all coupled through solid and gas processing systems to provide complementary information on the same samples. The SAM suite is able to measure a suite of light isotopes and to analyze volatiles directly from the atmosphere or thermally released from solid samples. In addition to measurements of simple inorganic compounds and noble gases SAM will conduct a sensitive search for organic compounds with either thermal or chemical extraction from sieved samples delivered by the sample processing system on the Curiosity rover's robotic arm,
The Sample Analysis at Mars (SAM) suite of instruments on the Curiosity Rover of Mars Science Laboratory Mission is designed to provide chemical and isotopic analysis of organic and inorganic volatiles for both atmospheric and solid samples. The goals of the science investigation enabled by the gas chromatograph mass spectrometer and tunable laser spectrometer instruments of SAM are to work together with the other MSL investigations is to quantitatively assess habitability through a series of chemical and geological measurements. We describe the multi-column gas chromatograph system employed on SAM and the approach to extraction and analysis of organic compounds that might be preserved in ancient martian rocks.
Creare Incorporated and NASA Goddard Space Flight Center developed and space qualified two wide range pumps (WRPs) that were included in the Sample Analysis at Mars (SAM) instrument. This instrument was subsequently integrated into the Mars Science Laboratory (MSL) "Curiosity Rover," launched aboard an Atlas V rocket in 2011, and landed on August 6, 2012, in the Gale Crater on Mars. The pumps have now operated for more than 18 months in the Gale Crater and have been evacuating the key components of the SAM instrument: a quadrupole mass spectrometer, a tunable laser spectrometer, and six gas chromatograph columns. In this paper, we describe the main design challenges and the ways in which they were solved. This includes the custom design of a miniaturized, high-speed motor to drive the turbo drag pump rotor, analysis of rotor dynamics for super critical operation, and bearing/lubricant design/selection.
The Sample Analysis at Mars (SAM) instrument suite is the largest scientific payload on the Mars Science Laboratory (MSL) Curiosity rover, which landed in Mars׳ Gale Crater in August 2012. As a miniature geochemical laboratory, SAM is well-equipped to address multiple aspects of MSL׳s primary science goal, characterizing the potential past or present habitability of Gale Crater. Atmospheric measurements support this goal through compositional investigations relevant to martian climate evolution. SAM instruments include a quadrupole mass spectrometer, a tunable laser spectrometer, and a gas chromatograph that are used to analyze martian atmospheric gases as well as volatiles released by pyrolysis of solid surface materials (Mahaffy et al., 2012). This report presents analytical methods for retrieving the chemical and isotopic composition of Mars׳ atmosphere from measurements obtained with SAM׳s quadrupole mass spectrometer. It provides empirical calibration constants for computing volume mixing ratios of the most abundant atmospheric species and analytical functions to correct for instrument artifacts and to characterize measurement uncertainties. Finally, we discuss differences in volume mixing ratios of the martian atmosphere as determined by SAM (Mahaffy et al., 2013) and Viking (Owen et al., 1977, Oyama and Berdahl, 1977) from an analytical perspective. Although the focus of this paper is atmospheric observations, much of the material concerning corrections for instrumental effects also applies to reduction of data acquired with SAM from analysis of solid samples.
The Saturn PRobe Interior and aTmosphere Explorer (SPRITE) mission concept targets high-priority Planetary Science Decadal Survey science objectives. This mission concept would deliver the SPRITE entry probe into the Saturn atmosphere to obtain in situ measurements of elemental abundances and isotopic ratios, which would help distinguish the role Saturn played in the solar system formation and co-evolution of other planets. An Atmospheric Structure Investigation sensor package on the entry probe would provide in situ measurements of the pressure/temperature and wind structure below the cloud-tops, and a Quadrupole Mass Spectrometer and Tunable Laser Spectrometer suite would determine the composition of Saturn’s atmosphere. The SPRITE mission concept described in this paper uses a solar-powered carrier-relay spacecraft to deliver the battery-powered entry probe to Saturn after a 10-year Venus-Earth-Earth gravity-assist trajectory, and then relays the probe data back to Earth during the carrier-relay spacecraft Saturn flyby. A high-heritage design approach is implemented for the flight elements to minimize technical risk and enable successful return of this high-value science data.