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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

High-resolution observations of the spatial and velocity distribution of cometary hydrogen

We have obtained high velocity and spatial resolution long-slit H alpha spectra of comets Austin (1989c1) and Levy (1990c). Spectra of both comets clearly show the existence of a low velocity thermalized component of hydrogen gas. The amount of slow hydrogen is estimated for comet Austin. The Levy spectrum shows an unusual high-velocity spatially-confined blob of hydrogen emission of unknown origin.

Brown, Michael E.↗
NASA NTRS1991

Constitutive and damage material modeling in a high pressure hydrogen environment

Numerous components in reusable space propulsion systems such as the SSME are exposed to high pressure gaseous hydrogen environments. Flow areas and passages in the fuel turbopump, fuel and oxidizer preburners, main combustion chamber, and injector assembly contain high pressure hydrogen either high in purity or as hydrogen rich steam. Accurate constitutive and damage material models applicable to high pressure hydrogen environments are therefore needed for engine design and analysis. Existing constitutive and cyclic crack initiation models were evaluated only for conditions of oxidizing environments. The main objective is to evaluate these models for applicability to high pressure hydrogen environments.

Russell, D. A.↗
NASA NTRS1985

High spectral resolution Fabry-Perot interferometer measurements of Comet Halley at H-alpha and 6300 A

A 40.6-cm Newtonian telescope was interfaced to the Fabry-Perot interferometer at the Arecibo Observatory to make high-spectral-resolution measurements of Comet Halley emissions at 6562.72 A (H-alpha) and 6300.3 A (O I). The atomic hydrogen outflow velocity was found to be approximately 7.9 + or - 1.0 km/s. In general, the H-alpha spectra are highly structured, and indicative of a multiple component atomic hydrogen velocity distribution. For O (1D), implied production rates of 6.44 + or - 3.0 x 10 to the 28th/s and 5.66 + or - 2.7 x 10 to the 28th/s were found on March 15 and 17, respectively.

Kerr, R. B.↗
DOE OSTI2019

Controlled release of hydrogen from composite nanoparticles

Multi-functional materials for use in reversible, high-capacity hydrogen separation and/or storage are described. Also described are systems incorporating the materials. The multi-functional materials combine a hydrogen absorbing material with a high-efficiency and anon-contact energy absorbing material in a composite nanoparticle. The non-contact energy absorbing material include magnetic and/or plasmonic materials. The magnetic or plasmonic materials of the composite nanoparticles can provide localized heating to promote release of hydrogen from the hydrogen storage component of the composite nanoparticles.

08 HYDROGEN↗
DOE OSTI2026

Toward the application of the Risk-Based Maintenance approach to a hydrogen-fueled manufacturing plant

Safety, reliability, and maintenance of hydrogen-based equipment, including Risk-Based Maintenance (RBM), have recently gained increasing attention, as hydrogen, while key to decarbonizing hard-to-abate sectors, raises safety concerns. However, two literature gaps limit the development of risk-based strategies for hydrogen technologies. First, existing RBM methodologies do not account for hydrogen-specific components, such as electrolyzers, which differ from conventional equipment. Second, available studies on electrolyzer reliability remain largely qualitative or laboratory-scale. This study addresses these gaps by proposing an adapted RBM methodology tailored to hydrogen-fueled manufacturing facilities. Integrating qualitative tools (e.g., FMEA) with probabilistic models (e.g., Bayesian Networks) enables comprehensive hazardous scenarios identification and likelihood estimation. A conceptual layout of a glass furnace supplied by a 3 MW PEM electrolyzer is considered as a case study to demonstrate the feasibility of the adapted RBM framework in identifying high-risk components and enabling maintenance prioritization, potentially improving plant safety.

08 HYDROGEN↗
DOE OSTI2020

Understanding the Structure and Dynamics of Complex Biomembrane Interactions by Neutron Scattering Techniques

The membrane is one of the key structural materials of biology at the cellular level. Composed predominantly of a bilayer of lipids with embedded and bound proteins, it defines the boundaries of the cell and many organelles essential to life and therefore is involved in almost all biological processes. Membrane-specific interactions, such as drug binding to a membrane receptor or the interactions of an antimicrobial compound with the lipid matrix of a pathogen membrane, are of interest across the scientific disciplines. Herein we present a review, aimed at nonexperts, of the major neutron scattering techniques used in membrane studies: small-angle neutron scattering, neutron membrane diffraction, neutron reflectometry, quasielastic neutron scattering, and neutron spin echo. Neutron scattering techniques are well suited to studying biological membranes. The nondestructive nature of cold neutrons means that samples can be measured for long periods without fear of beam damage from ultraviolet, electron, or X-ray radiation, and neutron beams are highly penetrating, thus offering flexibility in samples and sample environments. Most important is the strong difference in neutron scattering lengths between the two most abundant forms of hydrogen, protium and deuterium. Changing the relative amounts of protium/deuterium in a sample allows the production of a series of neutron scattering data sets, enabling the observation of differing components within complex membrane architectures. This approach can be as simple as using the naturally occurring neutron contrast between different biomolecules to study components in a complex by changing the solution H 2 O/D 2 O ratio or as complex as selectively labeling individual components with hydrogen isotopes. This review presents an overview of each experimental technique with the neutron instrument configuration, related sample preparation and sample environment, and data analysis, highlighted by a special emphasis on using prominent neutron contrast to understand structure and dynamics. This review gives researchers a practical introduction to the often enigmatic suite of neutron beamlines, thereby lowering the barrier to taking advantage of these large-facility techniques to achieve new understandings of membranes and their interactions with other molecules.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2021

Molecular-scale origins of solution nanostructure and excess thermodynamic properties in a water/amphiphile mixture

The molecular and nanoscale origins of nonideality in excess thermodynamic properties are essential to understanding cosolvent mixtures, yet they remain challenging to determine. Here, we consider a binary mixture of water and an amphiphile, N,N,N',N'-tetramethylmalonamide (TMMA), which is characterized by strong hydrogen bonding between the two components and no hydrogen bonding between amphiphiles. Using molecular dynamics simulation, validated with excess volume measurements and X-ray scattering, we identify three distinct solution regimes across the composition range of the binary mixture and find that the transition between two of these regimes, marked by the water percolation threshold, is closely correlated with minima in the excess volume and excess enthalpy. Structural analysis of the simulations reveals an interplay between local interactions and solution nanostructure, determined by the relative strength of the water–water and water–amphiphile hydrogen bonding interactions. By comparison with other amphiphiles, such as linear alcohols, the relative strength of like and unlike interactions between water and amphiphile affects the relationship between thermodynamics and structural regimes. This provides insight into how molecular forces of mutual solvation interact across length scales and how they manifest in excess thermodynamic properties.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2009

Chemochromic Hydrogen Leak Detectors

At NASA, hydrogen safety is a key concern for space shuttle processing. Leaks of any level must be quickly recognized and addressed due to hydrogen s lower explosion limit. Chemo - chromic devices have been developed to detect hydrogen gas in several embodiments. Because hydrogen is odorless and colorless and poses an explosion hazard, there is an emerging need for sensors to quickly and accurately detect low levels of leaking hydrogen in fuel cells and other advanced energy- generating systems in which hydrogen is used as fuel. The device incorporates a chemo - chromic pigment into a base polymer. The article can reversibly or irreversibly change color upon exposure to hydrogen. The irreversible pigment changes color from a light beige to a dark gray. The sensitivity of the pigment can be tailored to its application by altering its exposure to gas through the incorporation of one or more additives or polymer matrix. Furthermore, through the incorporation of insulating additives, the chemochromic sensor can operate at cryogenic temperatures as low as 78 K. A chemochromic detector of this type can be manufactured into any feasible polymer part including injection molded plastic parts, fiber-spun textiles, or extruded tapes. The detectors are simple, inexpensive, portable, and do not require an external power source. The chemochromic detectors were installed and removed easily at the KSC launch pad without need for special expertise. These detectors may require an external monitor such as the human eye, camera, or electronic detector; however, they could be left in place, unmonitored, and examined later for color change to determine whether there had been exposure to hydrogen. In one type of envisioned application, chemochromic detectors would be fabricated as outer layers (e.g., casings or coatings) on high-pressure hydrogen storage tanks and other components of hydrogen-handling systems to provide visible indications of hydrogen leaks caused by fatigue failures or other failures in those systems. In another type of envisioned application, chemochromic detectors of this type could be optoelectronically instrumented for monitoring to provide measured digital indications of color changes indicative of the presence of hydrogen.

Roberson, Luke↗
NASA NTRS2008

Radiation Transport of Heliospheric Lyman-alpha from Combined Cassini and Voyager Data Sets

Heliospheric neutral hydrogen scatters solar Lyman-alpha radiation from the Sun with '27-day' intensity modulations observed near Earth due to the Sun's rotation combined with Earth's orbital motion. These modulations are increasingly damped in amplitude at larger distances from the Sun due to multiple scattering in the heliosphere, providing a diagnostic of the interplanetary neutral hydrogen density independent of instrument calibration. This paper presents Cassini data from 2003-2004 obtained downwind near Saturn at approximately 10 AU that at times show undamped '27-day' waves in good agreement with the single-scattering models of Pryor et al., 1992. Simultaneous Voyager 1 data from 2003- 2004 obtained upwind at a distance of 88.8-92.6 AU from the Sun show waves damped by a factor of -0.21. The observed degree of damping is interpreted in terms of Monte Carlo multiple-scattering calculations (e.g., Keller et al., 1981) applied to two heliospheric hydrogen two-shock density distributions (discussed in Gangopadhyay et al., 2006) calculated in the frame of the Baranov-Malama model of the solar wind interaction with the two-component (neutral hydrogen and plasma) interstellar wind (Baranov and Malama 1993, Izmodenov et al., 2001, Baranov and Izmodenov, 2006). We conclude that multiple scattering is definitely occurring in the outer heliosphere. Both models compare favorably to the data, using heliospheric neutral H densities at the termination shock of 0.085 cm(exp -3) and 0.095 cm(exp -3). This work generally agrees with earlier discussions of Voyager data in Quemerais et al., 1996 showing the importance of multiple scattering but is based on Voyager data obtained at larger distances from the Sun (with larger damping) simultaneously with Cassini data obtained closer to the Sun.

Pryor, W.↗
NASA NTRS1975

Economics

Tables covering the selling price of hydrogen as a function of each process temperature studied are presented. Estimated selling price, based on capital costs and operating and maintenance costs, is included. In all cases, no credit was given for the methane component of hydrogen.

Source record↗
DOE OSTI2013

Safety of Hydrogen Systems Installed in Outdoor Enclosures

The Hydrogen Safety Panel brings a broad cross-section of expertise from the industrial, government, and academic sectors to help advise the U.S. Department of Energy’s (DOE) Fuel Cell Technologies Office through its work in hydrogen safety, codes, and standards. The Panel’s initiatives in reviewing safety plans, conducting safety evaluations, identifying safety-related technical data gaps, and supporting safety knowledge tools and databases cover the gamut from research and development to demonstration and deployment. The Panel’s recent work has focused on the safe deployment of hydrogen and fuel cell systems in support of DOE efforts to accelerate fuel cell commercialization in early market applications: vehicle refueling, material handling equipment, backup power for warehouses and telecommunication sites, and portable power devices. This paper resulted from observations and considerations stemming from the Panel’s work on early market applications. This paper focuses on hydrogen system components that are installed in outdoor enclosures. These enclosures might alternatively be called “cabinets,” but for simplicity, they are all referred to as “enclosures” in this paper. These enclosures can provide a space where a flammable mixture of hydrogen and air might accumulate, creating the potential for a fire or explosion should an ignition occur. If the enclosure is large enough for a person to enter, and ventilation is inadequate, the hydrogen concentration could be high enough to asphyxiate a person who entered the space. Manufacturers, users, and government authorities rely on requirements described in codes to guide safe design and installation of such systems. Except for small enclosures used for hydrogen gas cylinders (gas cabinets), fuel cell power systems, and the enclosures that most people would describe as buildings, there are no hydrogen safety requirements for these enclosures, leaving gaps that must be addressed. This paper proposes that a technical basis be developed to enable code bodies to write requirements for the range of enclosures from the smallest to the largest.

08 HYDROGEN↗
DOE OSTI2018

Kelvin probe force microscopy for high-resolution imaging of hydrogen in steel alloys [Poster]

Kelvin probe force microscopy (KPFM) was used to image and co-locate the presence of hydrogen in stainless steel (SS) with microstructure. Various SS samples were investigated, including forged, welded, LENS® fabricated, and pinch welded materials. KPFM images the local work function of a surface as a function of spatial position using atomic force microscopy. KPFM is capable of delivering high spatial (~10 nm) and potential (~5mV) resolution maps characterizing the microstrucure and the locally varying work function of surfaces. Hydrogen segregated at the surface of SS increases the local work function by either reducing tensile strain or by reducing the chemical potential of surface species. In a process known as hydrogen embrittlement, hydrogen segregates to and becomes trapped at extended defects (e.g. dislocations, boundaries, pores) which leads to the initiation of cracking and can result in structural failure. Hydrogen storage necessitates a proper understanding of the mechanisms of hydrogen embrittlement in SS. Developing advanced characterization techniques for hydrogen embrittlement is critical to identify long term solutions for materials exposed to hydrogen. Current techniques of observing hydrogen embrittlement involve mechanical testing, and optical microscopy with low resolution. Advance microstructural imaging techniques capable of resolving features down to the nanometer scale are needed. KPFM provides high resolution imaging for the characterization and development of SS components for hydrogen storage.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2019

Investigation of Thermolytic Production of Hydrogen Applicable to Savannah River Site High Level Waste - 19443

Several experiments have been performed to measure the generation rates of hydrogen gas due to reaction (thermolysis) of organic compounds in both simulated and radioactive waste. Initial measurements of hydrogen generation rates at 100 deg. C were made to downselect molecules and functional groups that produce significant amounts of hydrogen for subsequent kinetic determination. A statistically-designed test matrix was employed to quantitatively determine chemical conditions of highest reactivity at 100 deg. C. Additional experiments were performed at 100 deg. C to determine the impact of specific chemical components on hydrogen generation rates for relevant organic compounds. A semi-empirical model for thermolytic hydrogen generation rate from glycolate at 100 deg. C was developed and compared to results from radioactive waste and literature reports. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1972

Conceptual design study of a six-man solid electrolyte system for oxygen reclamation

A six-man solid electrolyte oxygen regeneration system (SEORS) that will produce 12.5 lbs/day of oxygen has been designed. The SEORS will simultaneously electrolyze both carbon dioxide and water vapor and be suitable for coupling with a carbon dioxide concentration system of either molecular sieve, solid amine or hydrogen depolarized electrochemical type. The total system will occupy approximately 19 cu ft (34.5 in. x .26 in. x 36 in. high) and will weigh approximately 500 pounds. It is estimated that the total electrical power required will be 1783 watts. The system consists of three major components; electrolyzer, hydrogen diffuser, and carbon deposition reactor. There are 108 electrolysis stacks of 12 cells each in the electrolyzer. Only 2/3 of the 108 stacks will be operated at a time; the remainder will be held in reserve. The design calls for 96 palladium membranes for hydrogen removal to give 60 percent redundancy. Four carbon deposition reactors are employed. The iron catalyst tube in each reactor weighs 7.1 lb and 100 percent redundancy is allowed.

Morris, J. P.↗
NASA NTRS1984

On the magnetic field in the white dwarf Grw + 70.8247 deg

Greenstein (1984) has estimated a 3.5 x 10 to the 8th gauss magnetic field strength for the case of a sharp absorption feature near 1345 A, from the white dwarf Grw + 70.8247 deg that is interpreted as a component of hydrogen Lyman-alpha in a strong magnetic field. A highly accurate multiparameter variational method is the basis of the present deduction of a maximum Lyman-alpha obtainable wavelength of 1342.6 A, with a magnetic field of 5.6 x 10 to the 8th gauss. Alternative explanations of the 1345 A line as H-alpha or H-beta components, or a combination of the two, are given.

Henry, R. J. W.↗
NASA NTRS1998

The Local ISM and its Interaction with the Winds of Nearby Late-type Stars

We present new Goddard High-Resolution Spectrograph (GHRS) observations of the Ly-alpha and Mg II absorption lines seen toward the nearby stars 61 Cyg A and 40 Eri A. We use these data to measure interstellar properties along these lines of sight and to search for evidence of circumstellar hydrogen walls, which are produced by collisions between the stellar winds and the Local InterStellar Medium (LISM). We were able to model the Ly-alpha lines of both stars without hydrogen-wall absorption components, but for 61 Cyg A the fit required a stellar Ly-alpha, line profile with an improbably deep self-reversal, and for 40 Eri A the fit required a very low deuterium-to-hydrogen ratio that is inconsistent with previous GHRS measurements. Since these problems could be rectified simply by including stellar hydrogen-wall components with reasonable attributes, our preferred fits to the data include these components. We have explored several ways in which the hydrogen-wall properties measured here and in previous work can be used to study stellar winds and the LISM. We argue that the existence of a hydrogen wall around 40 Eri A and a low H I column density along that line of sight imply that either the interstellar density must decrease toward 40 Eri A or the hydrogen ionization fraction (chi) must increase. We find that hydrogen-wall temperatures are larger for stars with faster velocities through the LISM. The observed temperature-velocity relation is consistent with the predictions of hydromagnetic shock jump conditions. More precise comparison of the data and the jump conditions suggests crude upper limits for both chi and the ratio of magnetic to thermal pressure in the LISM (alpha): chi less than 0.6 and alpha less than 2. The latter upper limit corresponds to a limit on the LISM magnetic field of B less than 5 micro G. These results imply that the plasma Mach number of the interstellar wind flowing into the heliosphere is M(sub A) greater than 1.3, which indicates that the collision is supersonic and that there should therefore be a bow shock outside the heliopause in the upwind direction. Finally, we estimate stellar wind pressures (P sub wind) from the measured hydrogen-wall column densities. These estimates represent the first empirical measurements of wind properties for late-type main-sequence stars. The wind pressures appear to be correlated with stellar X-ray surface fluxes, F(x), in a manner consistent with the relation P(wind) varies as F(x)(exp -1/2), a relation that is also consistent with the variations of P(sub wind) and F(sub x) observed during the solar activity cycle. If this relation can in fact be generalized to solar-like stars, as is suggested by our data, then it is possible to estimate stellar wind properties simply by measuring stellar X-rays. One implication of this is that stellar wind pressures and mass-loss rates are then predicted to increase with time, since F(sub x) is known to decrease with stellar age.

Wood, Brian E.↗
DOE OSTI2012

METALLICITIES, DUST, AND MOLECULAR CONTENT OF A QSO-DAMPED Ly{alpha} SYSTEM REACHING log N(H I) = 22: AN ANALOG TO GRB-DLAs

We present the elemental abundance and H{sub 2} content measurements of a damped Ly{alpha} (DLA) system with an extremely large H I column density, log N(H I) (cm{sup -2}) = 22.0 {+-} 0.10, at z{sub abs} = 3.287 toward the QSO SDSS J081634+144612. We measure column densities of H{sub 2}, C I, C I*, Zn II, Fe II, Cr II, Ni II, and Si II from a high signal-to-noise and high spectral resolution VLT-UVES spectrum. The overall metallicity of the system is [Zn/H] = -1.10 {+-} 0.10 relative to solar. Two molecular hydrogen absorption components are seen at z = 3.28667 and 3.28742 (a velocity separation of Almost-Equal-To 52 km s{sup -1}) in rotational levels up to J = 3. We derive a total H{sub 2} column density of log N(H{sub 2}) (cm{sup -2}) = 18.66 and a mean molecular fraction of f = 2N(H{sub 2})/[2N(H{sub 2}) + N(H I)] = 10{sup -3.04{+-}0.37}, typical of known H{sub 2}-bearing DLA systems. From the observed abundance ratios we conclude that dust is present in the interstellar medium of this galaxy, with an enhanced abundance in the H{sub 2}-bearing clouds. However, the total amount of dust along the line of sight is not large and does not produce any significant reddening of the background QSO. The physical conditions in the H{sub 2}-bearing clouds are constrained directly from the column densities of H{sub 2} in different rotational levels, C I and C I*. The kinetic temperature is found to be T Almost-Equal-To 75 K and the particle density lies in the range n{sub H} = 50-80 cm{sup -3}. The neutral hydrogen column density of this DLA is similar to the mean H I column density of DLAs observed at the redshift of {gamma}-ray bursts (GRBs). We explore the relationship between GRB-DLAs and the high column density end of QSO-DLAs finding that the properties (metallicity and depletion) of DLAs with log N(H I) > 21.5 in the two populations do not appear to be significantly different.

79 ASTRONOMY AND ASTROPHYSICS↗