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At least 91 records · Page 5

Extended active space CASSCF/MRSD CI calculations of the barrier height for the reaction O + H2 yields OH + H

The convergence of the barrier height for the O + H2 yields OH + H reaction is studied as a function of the size of the active space in the CASSCF calculation and the size of the basis set. The basis set employed in this study is described. The sources of the differences between the POL-CI and MRSD-CI calculations for barrier height are examined. It is observed that the barrier height is rapidly convergent with respect to the expansion of the active space. The effects of adding active orbitals on the barrier height are investigated. The barrier height estimated from corrected MRSD-CI data is 12.4 kcal/mol.

Walch, Stephen P.↗

Waveform analysis for Geosat day 96

A detailed model waveform function has been least-squares-fitted to 10-second averages of waveform sampler data from selected over-ocean portions of day 96 of the Geosat mission. The results confirm that the height corrections already applied in the routine Geosat data processing are generally good to well within 10 centimeters. Additional height corrections are provided that can refine height estimates to within the several-centimeter level.

Hayne, George S.↗

Upflowing ionospheric ions in the auroral region

Observations of upflowing ionospheric ions are obtained nearly simultaneously by DE 1 and DE 2 over the nightside auroral regions. At low altitudes, the mean value of the net upward ion number flux is of the order of 10 exp 9/sq cm per sec. The ionosphere is predominantly O(+), and the flux of ions with energy greater than 5 eV is a very small fraction (less than 1 percent) of the total ion flux. At high altitudes, the upflowing ions are accelerated by a parallel electric field and heated (with characteristic energies of hundreds of electron volts). Comparing upflowing fluxes at high and low altitudes yields an estimated height of the bottom of the auroral acceleration region of 1400-1700 km for the region of peak potential drop. This low-altitude acceleration could either be from a parallel electric field or from perpendicular acceleration. The fluxes at the edges of the arc are mostly H(+) thus implying a higher-altitude base of the acceleration region at the edges where the potential drop is lower.

Lu, G.↗

Estimating Elevation Angles From SAR Crosstalk

Scheme for processing polarimetric synthetic-aperture-radar (SAR) image data yields estimates of elevation angles along radar beam to target resolution cells. By use of estimated elevation angles, measured distances along radar beam to targets (slant ranges), and measured altitude of aircraft carrying SAR equipment, one can estimate height of target terrain in each resolution cell. Monopulselike scheme yields low-resolution topographical data.

Freeman, Anthony↗

Estimating Slopes In Images Of Terrain By Use Of BRDF

Proposed method of estimating slopes of terrain features based on use of bidirectional reflectivity distribution function (BRDF) in analyzing aerial photographs, satellite video images, or other images produced by remote sensors. Estimated slopes integrated along horizontal coordinates to obtain estimated heights; generating three-dimensional terrain maps. Method does not require coregistration of terrain features in pairs of images acquired from slightly different perspectives nor requires Sun or other source of illumination to be low in sky over terrain of interest. On contrary, best when Sun is high. Works at almost all combinations of illumination and viewing angles.

Scholl, Marija S.↗

Measurement of Geopotential Heights by GPS Radio Occultation

Geopotential heights of constant pressure surfaces are retrieved from global positioning system (GPS) radio occultation data. In order to assess accuracy a subset of data obtained by GPS/MET during spring 1995 and summer 1995 are compared to the output of the European Centre for Medium-Range Weather Forecasts (ECMWF) global model. The root-mean-square measurement error is 20 m throughout the upper troposphere and lower stratosphere. Furthermore, the ECMWF global model contains enhanced errors in the southeast Pacific. In probing the data for potential utility in climate studies, a Bayesian interpolation technique is used to map the geopotential height fields in the upper troposphere during the summer. Despite limitations of the GPS/MET data set the global average 300-mbar geopotential height over a 2-week period in summer 1995 is determined with an accuracy of 7 m. By obtaining greater coverage and partially resolving synoptic variability, a future constellation of 16 orbiting receivers could obtain global average geopotential height estimates in the upper troposphere with an accuracy of 1 m each day. Accuracy would be somewhat worse for regional studies, except in the tropics where synoptic variability is depressed.

Leroy, Stephen S.↗

Polarimetric SAR Interferometry Evaluation in Mangroves

TanDEM-X (TDX) enables to generate an interferometric coherence without temporal decorrelation effect that is the most critical factor for a successful Pol-InSAR inversion, as have recently been used for forest parameter retrieval. This paper presents mangrove forest height estimation only using single-pass/single-baseline/dual-polarization TDX data by means of new dual-Pol-InSAR inversion technique. To overcome a lack of one polarization in a conventional Pol- InSAR inversion (i.e. an underdetermined problem), the ground phase in the Pol-InSAR model is directly estimated from TDX interferograms assuming flat underlying topography in mangrove forest. The inversion result is validated against lidar measurement data (NASA's G-LiHT data).

Mangrove↗

Multi-Parameter Nonlinear Gain Correction of X-Ray Transition Edge Sensors for the X-Ray Integral Field Unit

With its array of 3840 Transition Edge Sensors (TESs), the Athena X-ray Integral Field Unit (X-IFU) will provide spatially resolved high-resolution spectroscopy (2.5 eV up to 7 keV) from 0.2 to 12 keV, with an absolute energy scale accuracy of 0.4 eV. Slight changes in the TES operating environment can cause significant variations in its energy response function, which may result in systematic errors in the absolute energy scale. We plan to monitor such changes at pixel level via onboard X-ray calibration sources and correct the energy scale accordingly using a linear or quadratic interpolation of gain curves obtained during ground calibration. However, this may not be sufficient to meet the 0.4 eV accuracy required for the XIFU. In this contribution, we introduce a newtwo-parameter gain correction technique, based on both the pulse-height estimate of a fiducial line and the baseline value of the pixels. Using gain functions that simulate ground calibration data, we show that this technique can accurately correct deviations in detector gain due to changes in TES operating conditions such as heat sink temperature, bias voltage, thermal radiation loading and linear amplifier gain. We also address potential optimisations of the onboard calibration source and compare the performance of this new technique with those previously used.

Cucchetti, E.↗

Mangrove Mapping with the Freeman-Durden Polarimetric Decomposition and Insar Coherence from ALOS-2

We map mangrove extents in Pongara National Park, Gabon using the Freeman-Durden Decomposition and InSAR Coherence derived from ALOS-2 imagery. Specifically, we obtain a land cover map derived from both this polarimetric decom-position and a 14-day repeat-pass coherence. Our classification model and results are highly interpretable based on a depth 2 decision tree. We further illustrate the correlation between InSAR coherence and height obtaining rough man-grove height estimates from TanDEM-X data. From our results, we observe that repeat-pass interferometric coherence provides invaluable information about mangrove extents and coastal forests. The clear identification of mangrove extents presents a significant opportunity for NISAR, which will pro-vide 12-day repeat pass images over coastal areas globally.

Tien-Hao Liao↗

Mangrove Mapping With the Freeman-Durden Polarimetric Decomposition and InSAR Coherence From ALOS-2

We map mangrove extents in Pongara National Park, Gabon using the Freeman-Durden Decomposition and InSAR Coherence derived from ALOS-2 imagery. Specifically, we obtain a land cover map derived from both this polarimetric decomposition and a 14-day repeat-pass coherence. Our classification model and results are highly interpretable based on a depth 2 decision tree. We further illustrate the correlation between InSAR coherence and height obtaining rough mangrove height estimates from TanDEM-X data. From our results, we observe that repeat-pass interferometric coherence provides invaluable information about mangrove extents and coastal forests. The clear identification of mangrove extents presents a significant opportunity for NISAR, which will provide 12-day repeat pass images over coastal areas globally.

Thomas, Nathan↗

PBL Thermodynamic Characterization and Its Variability From NAST-I During the Wh2yMSIE Field Campaign

The National Airborne Sounder Testbed-Interferometer (NAST‑I) suborbital system (<2.6 km IFOV; 0.25 cm-1 within 645–2700 cm‑1) serves as a spaceborne instrument simulator and pathfinder for future satellite capabilities and airborne science experiments. The NAST‑I measurements are made to advance understanding of science critical for weather, climate, chemistry, and radiation applications. Here we present some groundbreaking capabilities of NAST-I measurements and corresponding geophysical retrievals and their potential benefits toward improved atmospheric state and composition characterizations needed for science applications of particular importance toward enhancing characterization and understanding of the Planetary Boundary Layer (PBL). Initial results of PBL height estimation and thermodynamic characterization and their time evolution from NAST-I measurements during the WH2yMSIE field campaign are presented.

Daniel K Zhou↗

Capacity Building Engagement for Estimating Forest Stand Height Utilizing the SAR Handbook

Utilizing Synthetic Aperture Radar (SAR) which provides information such as vegetation structure and moisture content, independently of weather conditions is a powerful tool that can be employed to more effectively monitor deforestation and estimate biomass which is of paramount concern, especially in South and Southeast Asia which contain nearly 15% of all tropical forests. SERVIR, a NASA-USAID initiative, works in partnership with regional hubs around the world building capacity through promoting the use of Earth observations and geospatial technologies. The SERVIR Global network and the Silva Carbon program collaboratively developed the SAR Handbook: Comprehensive Methodologies for Forest Monitoring and Biomass Estimation which set out to reduce the barriers associated with leveraging SAR and increase the capacity of researchers and practitioners globally to use SAR for monitoring. In particular, utilizing SAR to estimate Forest Stand Height (FSH) is crucial for greenhouse gas emissions reporting and estimating carbon storage. Programs such as Reducing Emissions from Deforestation and Forest Degradation (REDD) rely on parameters such as these for their monitoring efforts. This talk will showcase the collaborative efforts, emergent geospatial technology leveraged, and capacity building approaches utilized by our team to conduct a South and Southeast Asia focused in-person training event located at SERVIR-Mekong, a SERVIR hub lead by the Asian Disaster Preparedness Center (ADPC) in Bangkok.

AGU↗

Estimating Scaled Cloud Height in Pulse Jet Mixed Vessels

To suspend and mix radioactive slurries without pumps or impellers, the performance of pulsed jet mixed vessels has been investigated. The slurry in the pulse tubes is expelled impinging upon the vessel floor and lifting solids to a “cloud height” in a cyclic process. Experiments measuring cloud height for a variety of waste simulants have been conducted for vessel configurations that varied vessel diameter, fill height and pulse tube number, volume, and nozzle diameter. The elevation to which suspended particles rise is termed the cloud height and derives from a balance between the fluid forces of the jet and the gravitational forces acting on the particle ensemble. Here we use scaling to estimate the cloud height based on conservation of mass and momentum and jet similarity. We find that the cloud height varies with the nozzle exit velocity to the 2/3 power in agreement with observations.

cloud height, effective cleaning radius, effective↗

Recent Advances on INSAR Temporal Decorrelation: Theory and Observations Using UAVSAR

We review our recent advances in understanding the role of temporal decorrelation in SAR interferometry and polarimetric SAR interferometry. We developed a physical model of temporal decorrelation based on Gaussian-statistic motion that varies along the vertical direction in forest canopies. Temporal decorrelation depends on structural parameters such as forest height, is sensitive to polarization and affects coherence amplitude and phase. A model of temporal-volume decorrelation valid for arbitrary spatial baseline is discussed. We tested the inversion of this model to estimate forest height from model simulations supported by JPL/UAVSAR data and lidar LVIS data. We found a general good agreement between forest height estimated from radar data and forest height estimated from lidar data.

polarimetric SAR interferometry↗

Use of Satellite, Surface Observations and Numerical Weather Prediction Model Data to Improve Cloud Base Height and Cloud Base Vertical Velocity Estimation

Cloud base height (CBH) and cloud base vertical velocity (CBVV) are important variables that impact the overall climate in a region as they influence the formulation, longevity, and evolution of clouds. Retrieval of both parameters have long used ground instrumentation (e.g., Doppler lidar (DL), ground base radar); however, retrieving CBH from satellites is particularly challenging given that space-based instruments only observe cloud tops. In this manuscript, CBH is retrieved using a multi-linear regression equation, while CBVV used a random forests model. Both retrievals combine satellite and numerical weather prediction data. The satellite data used are the Visible Infrared Imaging Radiometer Suite imagery, while measurements of CBH and CBVV include DL and radiosonde data at the Southern Great Plains (SGP) Atmospheric Radiation Measurement observatory. Data from 83 summer days (May-August) in 2018–2021 featuring cumulus clouds forced by solar heating were examined and used to train the models, with years 2022–2023 used for validation. Various spatial domains were defined with one large (2.4° longitude by 2.0° latitude) SGP domain being split into smaller sections (smallest being 0.99° and 0.61° longitude and latitude respectably). CBH and CBVV values obtained from the DL as compared to the models show root mean square errors between 150 and 200 m, with CBVV values between 0.45 and 1 ms -1 . Finally, it was found that the CBH formulation performs well over all domains, while the CBVV retrievals become less accurate due to more turbulence being introduced into the observations as the number of DL stations decreases in the smaller domains.

54 ENVIRONMENTAL SCIENCES↗

Estimating Planetary Boundary Layer Heights from NOAA Profiler Network Wind Profiler Data

An algorithm was developed to estimate planetary boundary layer (PBL) heights from hourly archived wind profiler data from the NOAA Profiler Network (NPN) sites located throughout the central United States. Unlike previous studies, the present algorithm has been applied to a long record of publicly available wind profiler signal backscatter data. Under clear conditions, summertime averaged hourly time series of PBL heights compare well with Richardson-number based estimates at the few NPN stations with hourly temperature measurements. Comparisons with clear sky reanalysis based estimates show that the wind profiler PBL heights are lower by approximately 250-500 m. The geographical distribution of daily maximum PBL heights corresponds well with the expected distribution based on patterns of surface temperature and soil moisture. Wind profiler PBL heights were also estimated under mostly cloudy conditions, and are generally higher than both the Richardson number based and reanalysis PBL heights, resulting in a smaller clear-cloudy condition difference. The algorithm presented here was shown to provide a reliable summertime climatology of daytime hourly PBL heights throughout the central United States.

Wind Profiler↗

Comparisons of techniques for measurement of D-region electron densities

This paper reviews the ground-based and rocket techniques that are presently being used to determine electron density profiles in the ionospheric D region. Ground-based techniques include VLF, LF, and MF sounding; differential absorption and differential phase measurements using partial reflections; wave interaction; and incoherent scatter. Rocket techniques include differential absorption and Faraday rotation in association with high-resolution dc probes calibrated by means of the radio measurements. The characteristics of the aforementioned techniques are presented, including time and height resolution, accuracy estimates, preferred height ranges, and problems encountered. Electron density profiles obtained with these techniques are presented for comparable solar zenith angles and undisturbed solar and geophysical conditions.

Sechrist, C. F., Jr.↗