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Stability analysis of a liquid fuel annular combustion chamber

High frequency combustion instability problems in a liquid fuel annular combustion chamber are examined. A modified Galerkin method was used to produce a set of modal amplitude equations from the general nonlinear partial differential acoustic wave equation in order to analyze the problem of instability. From these modal amplitude equations, the two variable perturbation method was used to develop a set of approximate equations of a given order of magnitude. These equations were modeled to show the effects of velocity sensitive combustion instabilities by evaluating the effects of certain parameters in the given set of equations.

Mcdonald, G. H.↗

The N.A.C.A. Apparatus for Studying the Formation and Combustion of Fuel Sprays and the Results from Preliminary Tests

Described here is an apparatus for studying the formation and combustion of fuel sprays under conditions closely simulating those in a high speed compression-ignition engine. The apparatus consists of a single-cylinder modified test engine, a fuel injection system so designed that a single charge of fuel can be injected into the combustion chamber, an electric driving motor, and a high-speed photographic apparatus. The cylinder head of the engine has a vertical disk form of combustion chamber whose sides are glass windows. When the fuel is injected into the combustion chamber, motion pictures at the rate of 2000 per second are taken of the spray formation by means of spark discharges. When combustion takes place, the light of combustion is recorded on the same photographic film as the spray photographs. Included here are the results of some tests to determine the effect of air temperature, air flow, and nozzle design on the spray formation. The results show that the compression temperature has little effect on the penetration of the fuel spray, but does not affect the dispersion, that air velocities of about 300 feet per second are necessary to destroy the core of the spray, and that the effect of air flow on the spray is controlled to a certain extent by the design of the injection nozzle. The results on the combustion of the spray show that when ignition does not take place until after spray cut-off, the ignition may start almost simultaneously throughout the combustion chamber or at different points throughout the chamber. When ignition takes place before spray cut-off, the combustion starts around the edge of the spray and then spreads throughout the chamber.

Rothrock, A M↗

Fuels and Combustion Technology for Advanced Aircraft Engines [Les Propergols et les Systèmes de Combustion pour les Moteurs d'Aéronefs]

The Conference Proceedings contains the 38 papers presented at the Propulsion and Energetics Panel 81st Symposium on "Fuels and Combustion Technology for Advanced Aircraft Engines" which was held from 10th-14th May 1993, in Fiuggi, Italy. The Technical Evaluation Report and the Keynote Address are included at the beginning, and discussions follow most papers. The Symposium was arranged in the following Sessions: Technology Overview Papers (2); Modelling: Pollutant Formation (4); Modelling: Combustor Design (5); High Temperature Fuels and Fuel Systems (6); Combustion Research: Performance (6); Combustion Research: Emissions (5); Fuel Atomization: Diagnostics and Modelling (5); and Combustion Research: Flowfleld and Mixing (4). The last paper is a contribution from Russia not allocated to a session. New technologies for low NOx combustors and advanced high-pressure/high temperature cycle engines result in unique problems in design and performance. There have been significant advances in modelling and diagnostics to aid the development of these technologies. The purpose of the Symposium was to bring together experts from industry, research establishments and universities to discuss fundamental and applied research in these areas as relevant to the development of advanced gas turbine engines, to exchange practical experience and to discuss the state of the art.

Fuels for aircraft↗

Fuel-rich catalytic combustion of a high density fuel

Fuel-rich catalytic combustion (ER is greater than 4) of the high density fuel exo-tetrahydrocyclopentadiene (JP-10) was studied over the equivalence ratio range 5.0 to 7.6, which yielded combustion temperatures of 1220 to 1120 K. The process produced soot-free gaseous products similar to those obtained with iso-octane and jet-A in previous studies. The measured combustion temperature agreed well with that calculated assuming soot was not a combustion product. The process raised the effective hydrogen/carbon (H/C) ratio from 1.6 to over 2.0, thus significantly improving the combustion properties of the fuel. At an equivalence ratio near 5.0, about 80 percent of the initial fuel carbon was in light gaseous products and about 20 percent in larger condensable molecules. Fuel-rich catalytic combustion has now been studied for three fuels with H/C ratios of 2.25 (iso-octane), 1.92 (jet-A), and 1.6 (JP-10). A comparison of the product distribution of these fuels shows that, in general, the measured concentrations of the combustion products were monotonic functions of the H/C ratio with the exception of hydrogen and ethylene. In these cases, data for JP-10 fell between iso-octane and jet-A rather than beyond jet-A. It is suggested that the ring cross-linking structure of JP-10 may be responsible for this behavior. All the fuels studied showed that the largest amounts of small hydrocarbon molecules and the smallest amounts of large condensable molecules occurred at the lower equivalence ratios. This corresponds to the highest combustion temperatures used in these studies. Although higher temperatures may improve this mix, the temperature is limited. First, the life of the present catalyst would be greatly shortened when operated at temperatures of 1300 K or greater. Second, fuel-rich catalytic combustion does not produce soot because the combustion temperatures used in the experiments were well below the threshold temperature (1350 K) for the formation of soot. Increasing the temperature above this value would remove the soot-free nature of the process. Since all the fuels studied show a similar breakdown of the primary fuel into smaller molecular combustion products, this technique can be applied to all hydrocarbon fuels.

Brabbs, Theodore A.↗

Experimental results with hydrogen fueled internal combustion engines

The paper focuses on the most important experimental findings for hydrogen-fueled internal combustion engines, with particular reference to the application of these findings to the assessment of the potential of hydrogen engines. Emphasis is on the various tradeoffs that can be made, such as between maximum efficiency, maximum power, and minimum NO emissions. The various possibilities for induction and ignition are described. Some projections are made about areas in which hydrogen engines may find their initial application and about optimum ways to design such engines. It is shown that hydrogen-fueled reciprocal internal combustion engines offer important advantages with respect to thermal efficiency and exhaust emissions. Problems arising from preignition can suitably be avoided by restricting the fuel-air equivalence ratio to values below about 0.5. The direct cylinder injection appears to be a very attractive way to operate the engine, because it combines a wide range of possible power outputs with a high thermal efficiency and very low NO emissions at part loads.

De Boer, P. C. T.↗

Plasma-based global pathway analysis to understand the chemical kinetics of plasma-assisted combustion and fuel reforming

The Global Pathway Analysis (GPA) algorithm helps analyze the chemical kinetics of complex combustion systems by identifying important global reaction pathways connecting a source species to a sink species through various important intermediate species (i.e., hub species). Here, the present work aims to extend GPA algorithm to plasma-assisted combustion and fuel reforming systems to identify the dominant global pathways in such systems at various conditions. In addition, the present study extends the ability of GPA algorithm to identify reaction cycles involving the excitation of high-concentration species (e.g., O 2 , N 2 , and fuel) to their vibrational and electronic states and the subsequent de excitation to their ground state, based on their significance on the reactivity of plasma-assisted systems in terms of gas heating and radical production. Provisions are made in the GPA algorithm to evaluate the reactivity of identified re action pathways and cycles based on the element-flux transfer (i.e., dominance), heat release, and radical production rate. The newly developed Plasma-based Global Pathway Analysis (PGPA) algorithm is then used to analyze the plasma assisted combustion of ammonia and reforming of methane. The PGPA analyses elucidated the significance of vibrational-translational cycles on the reactivity of NH 3 /air mixtures. Further, analyses on the production of NO ascribed the early reforming of NH 3 to N 2 and H 2 in impeding the production of NO during plasma-assisted NH 3 ignition. Lastly, the enhanced reforming of CH 4 /N 2 mixtures using plasma has been attributed to electron impact dissociation of CH 4 when compared to thermal reforming. In contrast, conventional path-Flux analysis (PFA) was found to require significant manual effort and pre-analysis intuitions from expert knowledge, making it arduous to provide valuable in sights into plasma chemistry. The user-friendly and automated nature of PGPA thus provides a valuable tool for assessing the kinetics of plasma-assisted systems helpful in analyzing and, further, a foundation in reducing plasma-assisted chemistry, without the needs of expert knowledge.

33 ADVANCED PROPULSION SYSTEMS↗

The NACA Apparatus for Studying the Formation and Combustion of Fuel Sprays and the Results from Preliminary Tests

This report describes the apparatus as designed and constructed at the Langley Memorial Aeronautical Laboratory, for studying the formation and combustion of fuel sprays under conditions closely simulating those occurring in a high-speed compression-ignition engine. The apparatus consists of a single-cylinder modified test engine, a fuel-injection system so designed that a single charge of fuel can be injected into the combustion chamber of the engine, an electric driving motor, and a high-speed photographic apparatus. The cylinder head of the engine has a vertical-disk form of combustion chamber whose sides are glass windows. When the fuel is injected into the combustion chamber, motion pictures at the rate of 2,000 per second are taken of the spray formation by means of spark discharges. When combustion takes place the light of the combustion is recorded on the same photographic film as the spray photographs. The report includes the results of some tests to determine the effect of air temperature, air flow, and nozzle design on the spray formation.

Rothrock, A M↗

A comparison of European and American microgravity combustion experimental techniques

The European and the NASA microgravity combustion programs are complementary in many aspects. Differences appear in the technical approaches and cooperative efforts are beneficial. Droplet combustion gaseous fuel studies and the study of solid-fuel combustion are areas of common interest. It is recognized that the progress that can be made in low gravity combustion investigations, depends on advanced diagnostic tools, developed for normal gravity laboratories. The benefits of combustion experiments in reduced gravity, the ground-based low gravity facilities and the NASA microgravity combustion program are also considered.

Sacksteder, Kurt↗

CFD Analysis of the 24-inch JIRAD Hybrid Rocket Motor

A series of multispecies, multiphase computational fluid dynamics (CFD) analyses of the 24-inch diameter joint government industry industrial research and development (JIRAD) hybrid rocket motor is described. The 24-inch JIRAD hybrid motor operates by injection of liquid oxygen (LOX) into a vaporization plenum chamber upstream of ports in the hydroxyl-terminated polybutadiene (HTPB) solid fuel. The injector spray pattern had a strong influence on combustion stability of the JIRAD motor so a CFD study was initiated to define the injector end flow field under different oxidizer spray patterns and operating conditions. By using CFD to gain a clear picture of the flow field and temperature distribution within the JIRAD motor, it is hoped that the fundamental mechanisms of hybrid combustion instability may be identified and then suppressed by simple alterations to the oxidizer injection parameters such as injection angle and velocity. The simulations in this study were carried out using the General Algorithm for Analysis of Combustion SYstems (GALACSY) multiphase combustion codes. GALACSY consists of a comprehensive set of droplet dynamic submodels (atomization, evaporation, etc.) and a computationally efficient hydrocarbon chemistry package built around a robust Navier-Stokes solver optimized for low Mach number flows. Lagrangian tracking of dispersed particles describes a closely coupled spray phase. The CFD cases described in this paper represent various levels of simplification of the problem. They include: (A) gaseous oxygen with combusting fuel vapor blowing off the walls at various oxidizer injection angles and velocities, (B) gaseous oxygen with combusting fuel vapor blowing off the walls, and (C) liquid oxygen with combusting fuel vapor blowing off the walls. The study used an axisymmetric model and the results indicate that the injector design significantly effects the flow field in the injector end of the motor. Markedly different recirculation patterns are observed in the vaporization chamber as the oxygen velocity and/or spray pattern is varied. The ability of these recirculation patterns to stabilize the diffusion flame above the surface of the solid fuel gives a plausible explanation for the experimentally determined combustion stability characteristics of the JIRAD motor, and suggests how combustion stability can be assured by modifications to the injector design.

Liang, Pak-Yan↗

Biogenic carbon capture at pulp mills via sodium spiking and oxy-fuel calcination

Over 13 million metric tons of biogenic carbon dioxide (CO 2 ) are mineralized yearly in United States (US) pulp mill recovery boilers as molten sodium carbonate. The mineralized CO 2 is released downstream in the rotary lime kiln where it can be captured at a relatively low cost for permanent sequestration. The use of biocarbon and bioenergy at pulp mills enables the possibility for atmospheric carbon removal when biogenic CO2 is captured and sequestered. We demonstrate the feasibility of capturing biogenic CO 2 via sodium spiking coupled with oxy-fuel calcination in the rotary lime kiln at existing kraft pulp mills. Sodium (Na) spiking elevates the Na ion loading in the kraft chemical looping process by replacing chlorine-based bleaching with a highly alkaline bleaching sequence. Chemical pulping processes are modeled and simulated to understand the technical limits of implementing sodium spiking in existing pulp mills. Each 1 % of sodium added to the bleaching operations increases the rate of CO 2 mineralization by 4 %, and the maximum increase in sodium content in the kraft process is 9 %. Without sodium spiking, estimated CO 2 capture costs are $131 and $107/mt CO 2 for air and oxy-fuel combustion, respectively. With the implementation of sodium spiking, the cost of CO 2 captured decreases by 27 % and 31 %, showing costs of $96 and $74/mt CO 2 for air and oxy-fuel combustion, respectively. Oxy-fuel combustion reduces the costs of CO 2 capture compared to air combustion, but merged deployment with sodium spiking seems to be the most cost-effective pathway to integrate carbon capture.

60 APPLIED LIFE SCIENCES↗

Numerical Simulation of the Combustion of Fuel Droplets: Finite Rate Kinetics and Flame Zone Grid Adaptation (CEFD)

The NASA Nebraska Space Grant (NSGC) & EPSCoR programs have continued their effort to support outstanding research endeavors by funding the Numerical Simulation of the Combustion of Fuel Droplets study at the University of Nebraska at Lincoln (UNL). This team of researchers has developed a transient numerical model to study the combustion of suspended and moving droplets. The engines that propel missiles, jets, and many other devices are dependent upon combustion. Therefore, data concerning the combustion of fuel droplets is of immediate relevance to aviation and aeronautical personnel, especially those involved in flight operations. The experiments being conducted by Dr. Gogos and Dr. Nayagam s research teams, allow investigators to gather data for comparison with theoretical predictions of burning rates, flame structures, and extinction conditions. The consequent improved hndamental understanding droplet combustion may contribute to the clean and safe utilization of fossil hels (Williams, Dryer, Haggard & Nayagam, 1997, 72). The present state of knowledge on convective extinction of he1 droplets derives fiom experiments conducted under normal gravity conditions. However, any data obtained with suspended droplets under normal gravity are grossly affected by gravity. The need to obtain experimental data under microgravity conditions is therefore well justified and addresses one of the goals of NASA s Human Exploration and Development of Space (HEDS) microgravity combustion experiment.

Gogos, George↗

Droplet Combustion Experiment

Liquid fuel combustion provides a major portion of the world's energy supply. In most practical combustion devices, liquid burns after being separated into a droplet spray. Essential to the design of efficient combustion systems is a knowledge of droplet combustion behavior. The microgravity environment aboard spacecraft provides an opportunity to investigate the complex interactions between the physical and chemical combustion processes involved in droplet combustion without the complications of natural buoyancy. Launched on STS-83 and STS-94 (April 4 and July 1, 1997), the Droplet Combustion Experiment (DCE) investigated the fundamentals of droplet combustion under a range of pressures (0.25 to 1 atm), oxygen mole fractions (<0.5), and droplet sizes (1.5 to 5 mm). Principal DCE flight hardware features were a chamber to supply selected test environments, the use of crew-inserted bottles, and a vent system to remove unwanted gaseous combustion products. The internal apparatus contained the droplet deployment and ignition mechanisms to burn single, freely deployed droplets in microgravity. Diagnostics systems included a 35-mm high-speed motion picture camera (see the following sequence of photos) with a backlight to photograph burning droplets and a camcorder to monitor experiment operations. Additional diagnostics included an ultraviolet-light-sensitive CCD (charge couple discharge) camera to obtain flame radiation from hydroxyl radicals (see the final figure) and a 35-mm SLR (single-lens-reflex) camera to obtain color still photographs of the flames.

Nayagam, Vedha↗

Theory of Influence of a Low-Volatility, Soluble Impurity on Spherically-Symmetric Combustion of Fuel Droplets

Analyses are given for the evolution of liquid-phase mass fraction profiles and temperature during combustion of fuel droplets composed of binary miscible mixtures of low-volatility and high-volatility constituents, with small initial mass fractions of the low-volatility material, or slow introduction of low-volatility material into the liquid phase by absorption from the gas phase. The gas phase is assumed to remain quasi-steady and the liquid temperature spatially uniform. The ratio of the liquid-phase diffusion coefficient to the initial burning-rate constant is treated as a small parameter. Asymptotic analyses in this parameter are developed, and the conservation equations are integrated numerically in obtaining descriptions of the combustion history. It is shown that at the surface of the droplet a boundary layer arises in which the mass fraction of the low-volatility component increases with time. The results are used to explain qualitatively some observed conditions of flame contraction and liquid disruption in droplet combustion.

Shaw, B. D.↗

Fuel-rich catalytic combustion of Jet-A fuel-equivalence ratios 5.0 to 8.0

Fuel-rich catalytic combustion (E.R. greater than 5.0) is a unique technique for preheating a hydrocarbon fuel to temperatures much higher than those obtained by conventional heat exchangers. In addition to producing very reactive molecules, the process upgrades the structure of the fuel by the formation of hydrogen and smaller hydrocarbons and produces a cleaner burning fuel by removing some of the fuel carbon from the soot formation chain. With fuel-rich catalytic combustion as the first stage of a two stage combustion system, enhanced fuel properties can be utilized by both high speed engines, where time for ignition and complete combustion is limited, and engines where emission of thermal NO sub x is critical. Two-stage combustion (rich-lean) has been shown to be effective for NO sub x reduction in stationary burners where residence times are long enough to burn-up the soot formed in the first stage. Such residence times are not available in aircraft engines. Thus, the soot-free nature of the present process is critical for high speed engines. The successful application of fuel-rich catalytic combustion to Jet-A, a multicomponent fuel used in gas turbine combustors, is discusssed.

Brabbs, Theodore A.↗

High-speed phase contrast imaging of spray breakup of jet fuels under combusting conditions

X-ray phase contrast imaging is conducted at 90,517 Hz on a fuel spray to characterize the breakup of the bulk fuel into ligaments and individual droplets in a single-sector, swirl-stabilized combustor under reacting conditions. Phase contrast imaging is used to qualitatively assess spray breakup for two fuels: Jet-A, which represents a normal viscosity fuel, and a blend of JP-5 (64%) and farnesane (36% by volume), which represents a high-viscosity fuel, at three fuel-flow rates and two air inlet temperatures. Time-series images of the fuels show that atomization occurs much more rapidly at higher fuel pressure with thinner ligaments being rapidly shredded. The high-viscosity fuel is qualitatively observed to have markedly longer, thicker ligaments and larger droplet diameters after the primary breakup than the normal viscosity fuel. Using an image processing and droplet quantification strategy, the mean droplet velocity magnitudes were found to decrease with decreasing fuel pressure and fuel-flow rate. The increase in preheat temperature from 323 to 370 K results in an increase in the mean droplet velocity magnitude and a decrease in numerical average and Sauter mean diameter, indicating improved atomization. The high-viscosity fuel was found to have larger average droplet diameters at each condition than the normal viscosity fuel. The increased preheat is found to enhance the combustion efficiency, which is hypothesized to couple with the improved atomization due to the higher combustion temperatures. This indicates the importance of examining spray atomization and breakup under realistic combusting conditions for relevant fuels as the heat release directly couples with the atomization process.

42 ENGINEERING↗

Experimental Investigation of Air-Fuel Equivalence Ratio Effects on Advanced Dual-fuel Diesel/Ammonia Combustion on a Single-Cylinder Medium-Duty Diesel Engine at High Load

Ammonia (NH3) has gathered a lot of interest as a low-lifecycle-carbon fuel in sectors with high weight and distance requirements, such as shipping. The International Maritime Organization (IMO) mandates a 70-80% greenhouse gas (GHG) reduction by 2040, which is only possible with advanced engine technologies and fuels like NH3. Prior research studies at the US Department of Energy’s Oak Ridge National Laboratory have shown strong performance with NH3 under dual-fuel mode using conventional diesel combustion (CDC) manifold air pressure (MAP) settings. Diesel airflow was initially used to simplify retrofitting (no turbocharger modification), which resulted in air-fuel equivalence ratios (λ) greater than 1.5. To characterize potential improvements in dual-fuel NH3 combustion performance at richer in-cylinder conditions, a global λ sweep using a diesel pilot ignition (DPI) strategy with diesel fuel injected near top-dead center (TDC) and a reactivity-controlled compression ignition (RCCI) injection strategy with diesel fuel injected earlier during the compression stroke were compared. The experiments were conducted at 1200 RPM and 12.6 bar (75% load), and λ was varied by decreasing the commanded air flow to the engine at greater than 90% ammonia energy substitution (AES) level. A diesel injection timing sweep was conducted for both the combustion modes at fixed λ, and the timing with the lowest engine-out N2O emissions was identified. The results indicated an optimal balance between CO2, eq and thermal efficiency benefits for both DPI and RCCI injection strategy cases compared to CDC at a λ of 1.4. The indicated N-based emissions exhibited a strong correlation to the ratio of CA5–50 and ignition delay for DPI, but no apparent trend emerged for the RCCI injection strategy at the tested boundary conditions.

Tyrewala, Daanish [ORNL] (ORCID:0000000208599324)↗

Assessing outdoor air quality and public health impact attributable to residential black carbon emissions in rural China

Black carbon (BC) is a significant component of particulate matter (PM) that relates to air pollution, climate forcing, and further implications for public health. BC is predominantly released from the combustion of solid fuels. Combustion of low-quality fuels in rural China may induce severe respiratory and cardiopulmonary health outcomes for residents, which have however been inadequately assessed. One major reason for the limited understanding is the lack of a high-resolution inventory. An improved method of estimating the BC-associated public health burden is needed. This work quantified premature mortalities due to residential BC emissions in rural China. Domestic BC emissions at 1×1 km resolution were compiled based on previous field investigation, which were further configured for air quality simulation. A chemistry transport model, WRF–CMAQ v5.2, was employed for simulating BC concentrations. The consequent premature mortalities were quantified by a BC-specific concentration-response function (CRF) derived from an epidemiological study. Results show that residential combustion of solid fuel in rural China emitted 648.0 Gg (95%CI: 361.0–965.9) BC in 2014, after dispersion, accounting for 51.8% of annual mean ground-level BC concentration in China. Such impact was most severe in North and Northeast China, and the Sichuan Basin. The further investigation estimated 171,000 (95%CI: 69,000–387,000) premature mortalities that were attributable to exposure to rural residential BC. These findings reveal the major contribution of rural residential BC emissions to air pollution formation and public health impacts. Our findings are anticipated to provide useful information for enacting the next-stage environmental strategy for the residential sector in China.

63 RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTAN↗