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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Precious metal oxygen-evolving anodes for electrolytic reduction of metal oxides in molten LiCl-Li 2 O electrolyte

Understanding the electrochemical stability of oxygen-evolving anode materials in molten salt electrolytes is essential to enable decarbonized electrolytic reduction of metal oxides (e.g., used nuclear oxide fuels). Here, this work investigated three precious metals (Ir, Ru, and Pt) as oxygen-evolving anodes in molten LiCl-Li 2 O (99.0-1.0 wt%) at 650 °C. For consistent measurements, this work employed a three-electrode cell comprised of a two-phase Li-Bi (65-35 at%) reference electrode and a NiO counter electrode. Anodic polarization behavior of each anode was investigated via cyclic voltammetry (CV) and chronoamperometry. The onset potential for oxygen evolution was observed at E > 2.9 V (vs. Li/Li + ) for the Ir and Ru anodes and anodic current density was as high as 1.0 A cm -2 at 3.23 V. The dimensional stability of each anode was evaluated from long-term electrolysis experiments (10.0-32.1 h) at 3.23 V. Rapid consumption of the Pt anode was observed after the application of 26,453 C cm -2 with a reduction in diameter of about 15.8% due to the formation of a non-protective Li 2 PtO 3 compound. The formation of this compound was also observed during CV measurements as additional anodic waves at potentials more negative than that of oxygen evolution. In contrast, both the Ir and Ru anodes exhibited excellent dimensional stability with a reduction in diameter or thickness of less than 1.5% even after applying greater charge density of ~41,100 C cm -2 , demonstrating superior stability during oxygen evolution in the LiCl-Li 2 O electrolyte.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS2015

Opportunities and Strategies for Testing and Infusion of ISRU in the Evolvable Mars Campaign

HE Evolvable Mars Campaign (EMC) is developing the plans and systems needed for a robust, evolutionary strategy to explore cis-lunar space, the Mars sphere of influence (including the moons of Mars), and the surface of Mars. Recently, the emphasis of NASA's plans has changed to focus on the prolonged pioneering of space, rather than focusing on a single crewed mission as the ultimate goal. A sustainable, pioneering vision of space would include in-situ resource utilization (ISRU) in multiple forms and at multiple destinations: atmospheric capture of Mars CO2 and/or volatiles for consumables and propellants, regolith for bulk and refined materials, and in-situ manufacturing at the Moon, Mars, and other bodies. These resources would enable a reduction in the logistical needs from Earth for future missions, thus preparing the way for a sustained presence on Mars. Although the EMC initially relies only on propellant production for the Mars ascent vehicle via ISRU, one of its primary objectives is to prospect at every EMC destination to understand the potential for ISRU; this will permit true pioneering to be enabled after the first crew arrives at Mars. Recent and ongoing analysis has considered the possible prospecting measurements that can be performed at the asteroid returned to cis-lunar space by the Asteroid Robotic Redirect Mission (ARRM), at the lunar surface, at Phobos and Deimos, and on the surface of Mars to identify available resources for future use. These opportunities will be available on missions currently in the Evolvable Mars Campaign construct, and will also facilitate the testing and demonstration of resource acquisition, processing, storage, and useage technologies that can play a role in later missions. This analysis has also led to the identification of several objectives that should be targeted during the missions building up to and including the initial crewed missions. These objectives are mapped to strategies for incorporating ISRU to support resource cycle closure and reduce mass requirements from Earth. This analysis has yielded engineering constraints, based on ISRU, that impact the evaluation of landing sites for missions to the surface of Mars. The terrain of a particular site must be sufficiently flat to permit ISRU systems, as well as ancillary systems such as power and propellant storage tanks, to be landed, moved into position, set up, and operated. Water must be accessible in a form that can be acquired via ISRU, in quantities that align with demands. The chosen method of acquiring and processing water should align with the available resources at a particular site, and that site must have sufficient quantities to meet the requirements (based on crew consumables and propellant demands). Lower altitude landing sites are preferred, as the increase in density can facilitate carbon dioxide acquisition from the atmosphere. Another preference is for sites with a greater ability to move regolith for civil engineering purposes; for example, this would be conducive to both bulk regolith uses (such as the manufacture of berms), and processed regolith uses (such as microwave sintering).

Evolvable Mars Campaign↗
DOE OSTI2024

Tandem pyrolysis evolved gas–gas chromatography–mass spectrometry

Analysis of byproducts from thermal degradation of polymer materials provides a wealth of information about a materials’ composition, thermal stability, degradation mechanisms, and kinetics. However, regardless of the instrumentation used, only limited information is obtainable from a single experiment. Microfurnace technology, when interfaced to a gas chromatography-mass spectrometry (GC-MS), can be used to obtain both thermal and chemical information via evolved gas analysis-MS (EGA-MS) and GC-MS analysis modes. While both EGA-MS and Py-GC-MS are valuable when characterizing polymer materials, at least two experiments on distinct samples are required, which can be a liability for clear interpretation of results from inhomogeneous samples. Here, we seek to overcome this limitation by combining EGA-MS and Py-GC-MS modes in a single experimental setup. Further, this was done by developing new gas line modifications to allow for tandem Pyrolysis Evolved Gas-Gas Chromatography-Mass Spectrometry (Py/EG-GC-MS) analysis. Verification of Py/EG-GC-MS analysis was performed using a polystyrene standard. Results demonstrate successful Py/EG-GC-MS analysis for the first-time showing the potential of these modifications for application in areas where sample is limited or direct correlation of products to the thermal profile is desirable such as in forensics or product-specific kinetics.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Small-Molecule Models of Hydrogen-Evolving MX 2 (M = Mo, W; X = S, Se) Bulk Solids: Composition–Activity Relationships

Triangular metal chalcogenide clusters of the form [M 3 Q 7 L 3 ]An (M = Mo or W; Q = S or Se; L = i Bu 2 NCS 2 – , (CF 3 CH 2 ) 2 NCS 2 – , i Bu 2 NCSe 2 – , or i Bu 2 PS 2 – ; An = Cl – or I – ) have been investigated as molecular analogues of layered metal dichalcogenide (MX 2 ) H 2 -evolution catalysts. These clusters have been evaluated for their relative H 2 -evolving ability under a common photolysis protocol implementing [Ru(bpy) 3 ] 2+ as chromophore and Et 3 N as sacrificial electron donor. With M constant as Mo and with constant supporting ligand, clusters with an all-sulfide core enable greater H 2 -TON than clusters with an all-selenide core. A more active catalyst is produced by [Mo 3 S 7 (S 2 CN i Bu 2 ) 3 ] + I – than its W 3 analogue with the same core sulfide composition and supporting dithiocarbamate ligands. Dichalcogenocarbamate ligands provide more active catalysts than dialkyldithiophosphate ligated clusters, and within the dichalcogenocarbamate set, greater H 2 -turnovers correlate with more-electron-donating ligands (i.e., i Bu 2 NCS 2 – > (CF 3 CH 2 ) 2 NCS 2 – > i Bu 2 NCSe 2 – ). Cluster cations with Cl – as counteranion are very similar in activity H 2 -evolving levels to identical clusters with I – , ruling out any significant interfering effect by I – upon the electron transfer relay between Et 3 N and catalyst. In the aggregate, observations are consistent with a mechanism for H 2 evolution that involves reductive extrusion of H 2 from a metal hydride intermediate.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

On the Interplay Between Distributed Bulk Plasticity and Local Fault Slip in Evolving Fault Zone Complexity

Abstract We numerically investigate the role of plastic strain accumulation on the mechanical response of a planar strike‐slip fault. Our models show that fault‐zone strength significantly impacts the ensuing sequence of earthquakes. Weaker fault zones accumulating more plastic strain promote more complexity in the seismicity pattern through aperiodic earthquake occurrences and intermittent episodes of rupture and arrest. However, if the fault zone strength is high enough, the overall earthquake sequence is characterized by periodic fault‐spanning events. We find that both the fault normal stress and the fault geometric profile evolve throughout the earthquake sequence, suggesting a self‐roughening mechanism. Despite the significant impact of plasticity on the fault response, the width of the plastically deforming region in the fault zone is small compared to the fault length. Our results suggest a rich behavior in dynamically evolving fault zones and support the need for further high‐resolution studies of the highly non‐linear near‐fault region.

Geology↗
DOE OSTI2025

Orthogonal replication with optogenetic selection evolves yeast JEN1 into a mevalonate transporter

Abstract The in vivo continuous evolution system OrthoRep (orthogonal replication) is a powerful strategy for rapid enzyme evolution inSaccharomyces cerevisiaethat diversifies genes at a rate exceeding the endogenous genome mutagenesis rate by several orders of magnitude. However, it is difficult to neofunctionalize genes using OrthoRep partly because of the way selection pressures are applied. Here we combine OrthoRep with optogenetics in a selection strategy we call OptoRep, which allows fine-tuning of selection pressure with light. With this capability, we evolved a truncated form of the endogenous monocarboxylate transporterJEN1 (JEN1t)into a de novo mevalonate importer. We demonstrate the functionality of the evolvedJEN1t(JEN1t Y180C/G ) in the production of farnesene, a renewable aviation biofuel, from mevalonate fed to fermentation media or produced by microbial consortia. This study shows that the light-induced complementation of OptoRep may improve the ability to evolve functions not currently accessible for selection, while its fine tunability of selection pressure may allow the continuous evolution of genes whose desired function has a restrictive range between providing effective selection and cellular viability.

Biochemistry & Molecular Biology↗
DOE OSTI2026

Heavy dark matter in rapidly evolving massive stars

We study the impact of heavy dark matter (DM) captured in massive stars via scattering(s) with the star constituents. We focus on the first stars and use stellar evolution simulations to track down how DM capture evolves over time from the zero-age main sequence to the late metal-rich stages of stellar evolution. During the early hydrogen-helium-dominated phase, the capture process is well described by scattering with two targets. As a star evolves, metal production leads to the formation of a dense core surrounded by a lighter envelope. The core significantly enhances the capture of ultra-heavy DM; in this case, three distinct nuclear species are required to accurately describe multiple-scattering capture. We use the Eddington inversion method to obtain a realistic DM velocity distribution, better suited when the star is near the center of a halo, than the widely used Maxwell-Boltzmann distribution. We find that heavy DM would be able to thermalize and achieve capture-annihilation equilibrium within a massive star's lifetime for regions of the parameter space not excluded by direct detection. For non-annihilating DM, because of the high amount of targets available for capture and despite massive stars being short-lived, it would even be possible for DM to achieve self-gravitation and collapse to a black hole, which eventually could swallow the star from within before the expected end of the star's life, for non-excluded regions of the parameter space. Our results highlight the dependence of DM capture on the stellar evolutionary stage, composition, and halo location, demonstrating that accurate modeling of massive stars is essential for constraining heavy DM with primordial stellar populations.

dark matter theory↗
DOE OSTI2025

The Milky Way and M31 orbital history: did the Local Group evolve in isolation?

ABSTRACT We use new measurements of the M31 proper motion to examine the Milky Way (MW) – M31 orbit and angular momentum. For Local Group (LG) mass consistent with measured values, and assuming the system evolves in isolation, we show a wide range of orbits is possible. We compare to a sample of LG-like systems in the Illustris simulation, and find that ∼13 per cent of these pairs have undergone a pericentric passage. Using the simulated sample, we examine how accurately an isolated, two-body model describes the MW–M31 orbit, and show that ∼10 per cent of the analogues in the simulation are well-modelled by such an orbit. Systems that evolve in isolation by this definition are found to have a lower rate of major mergers, and in particular have no major mergers since $z \approx 0.3$. For all systems, we find an increase in the orbital angular momentum which is fairly independent of the merger rate, and is possibly explained by the influence of tidal torques on the LG. Given the likely quiet recent major merger history of the MW, it is plausible that the isolated two-body model appropriately describes the orbit, though recent evidence for a major merger in M31 may complicate this interpretation.

Hartl, Odelia V. (ORCID:0000000202379726)↗
DOE OSTI2024

Evolve CAPP Final Report

The Evolve Central Appalachia (Evolve CAPP) project is investigating the rare earth and critical mineral resource potential of the Central Appalachian basin, spanning Virginia, West Virginia, Kentucky, and Tennessee. This initiative aims to advance clean energy technologies, strengthen sustainable industries critical to national security, and foster economic growth through downstream value-added industries. Innovative policy incentives, stakeholder collaboration, and responsible sourcing practices are identified as pivotal to overcoming barriers. The project seeks to align environmental stewardship with economic imperatives. These efforts aim to position the Central Appalachian region as a leader in responsible critical mineral sourcing, contributing to a resilient, secure, and future-ready supply chain for critical minerals.

01 COAL, LIGNITE, AND PEAT↗
NASA NTRS1986

Mass return to the interstellar medium from highly-evolved carbon stars

Data produced by the Infrared Astronomy Satellite (IRAS) was surveyed at the mid- and far-infrared wavelengths. Visually-identified carbon stars in the 12/25/60 micron color-color diagram were plotted, along with the location of a number of mass-losing stars that lie near the location of the carbon stars, but are not carbon rich. The final sample consisted of 619 objects, which were estimated to be contaminated by 7 % noncarbon-rich objects. The mass return rate was estimated for all evolved circumstellar envelopes. The IRAS Point Source Catalog (PSC) was also searched for the entire class of stars with excess emission. Mass-loss rates, lifetimes, and birthrates for evolved stars were also estimated.

Latter, W. B.↗
NASA NTRS1989

On the efficacy of cinema, or what the visual system did not evolve to do

Spatial displays, and a constraint that they do not place on the use of spatial instruments are discussed. Much of the work done in visual perception by psychologists and by computer scientists has concerned displays that show the motion of rigid objects. Typically, if one assumes that objects are rigid, one can then proceed to understand how the constant shape of the object can be perceived (or computed) as it moves through space. The author maintains that photographs and cinema are visual displays that are also powerful forms of art. Their efficacy, in part, stems from the fact that, although viewpoint is constrained when composing them, it is not nearly so constrained when viewing them. It is obvious, according to the author, that human visual systems did not evolve to watch movies or look at photographs. Thus, what photographs and movies present must be allowed in the rule-governed system under which vision evolved. Machine-vision algorithms, to be applicable to human vision, should show the same types of tolerance.

Cutting, James E.↗
NASA NTRS1990

Dust obscuration by an evolving galaxy population

The effect of an evolving luminosity function (LF) on the ability of foreground galaxies to obscure background sources is discussed, using the Press-Schechter/CDM standard evolving LF model. Galaxies are modeled as simplified versions of local spirals and Poisson statistics are used to estimate the fraction of sky covered by intervening dusty galaxies and the mean optical depths due to these galaxies. The results are compared to those obtained in the case of nonevolving luminosity function in a low-density universe. It is found that evolution of the galaxy LF does not allow the quasar dust obscuration hypothesis to be sustained for dust disks with plausible sizes. Even in a low-density universe, where evolution at z = less than 10 is unimportant, large disk radii are needed to achieve the desired obscuring effect. The mean fraction of sky covered is presented as a function of the redshift z along with adequate diagram illustrations.

Najita, Joan↗
NASA NTRS1991

OFMspert: An architecture for an operator's associate that evolves to an intelligent tutor

With the emergence of new technology for both human-computer interaction and knowledge-based systems, a range of opportunities exist which enhance the effectiveness and efficiency of controllers of high-risk engineering systems. The design of an architecture for an operator's associate is described. This associate is a stand-alone model-based system designed to interact with operators of complex dynamic systems, such as airplanes, manned space systems, and satellite ground control systems in ways comparable to that of a human assistant. The operator function model expert system (OFMspert) architecture and the design and empirical validation of OFMspert's understanding component are described. The design and validation of OFMspert's interactive and control components are also described. A description of current work in which OFMspert provides the foundation in the development of an intelligent tutor that evolves to an assistant, as operator expertise evolves from novice to expert, is provided.

Mitchell, Christine M.↗
NASA NTRS1991

Evolving the SP-100 reactor in order to boost large payloads to GEO and to low lunar orbit via nuclear-electric propulsion

In striving to reduce exploration cost and exploration risks, a crucial aspect of the plans is program continuity, i.e., the continuing application of a given technology over a long period so that experience will accumulate from extended testing here on Earth and from a diversity of applications in space. An integrated view needs to be formed of the missions SEI will carry out, near term as well as far, and of the ways in which these missions can mutually support one another. Near term programs should be so constituted as to provide for the long term missions both the enabling technologies and the accumulation of experience they need. In achieving this, missions in Earth orbit should both evolve and show the technologies crucial to long term missions on the lunar surface, and the program for the lunar labs should evolve and show the enabling technologies for exploration of the surface of Mars and for flights of human beings to Mars and return. In the near term, the program for the Space Station should be directed and funded to develop and demonstrate the solar Brayton power plant that will be most useful as the power generator for the SP-100 nuclear reactor.

English, Robert E.↗
NASA NTRS1990

A two-step iterative method for evolving nonlinear acoustic systems to a steady-state

A new approach for evolving two-dimensional nonlinear acoustic systems with flow to a steady state is presented. The approach is a two-step iterative method which is tested on a benchmark acoustic problem for which an exact analytical solution is available. Results are also calculated for a nonlinear acoustic problem for which an exact analytical solution is not known. Results indicate that the two-step method represents a powerful, efficient, and stable method for evolving two-dimensional acoustic systems to a steady state, and that the method is applicable to any number of spatial dimensions and to other hyperbolic systems. It is noted that for the benchmark problem only a single iteration on the method is required when the transient and steady-state field are of the same order of magnitude; however, four iterations are required when the steady-state field is several orders of magnitude smaller than the transient field. This method requires six iterations before achieving a steady state for the nonlinear test problem.

Watson, Willie R.↗
NASA NTRS1991

Evolving the SP-100 reactor in order to boost large payloads to GEO and to low lunar orbit via nuclear-electric propulsion

In striving to reduce exploration cost and exploration risks, a crucial aspect of the plans is program continuity, i.e., the continuing application of a given technology over a long period so that experience will accumulate from extended testing here on earth and from a diversity of applications in space. An integrated view needs to be formed of the missions SEI will carry out, near term as well as far, and of the ways in which these missions can mutually support one another. Near term programs should be so constituted as to provide for the long term missions both the enabling technologies and the accumulation of experience they need. In achieving this, missions in earth orbit should both evolve and show the technologies crucial to long term missions on the lunar surfaces, and the program for the lunar labs should evolve and show the enabling technologies for exploration of the surface of Mars and for flights of human beings to Mars and return. In the near term, the program for the Space Station should be directed and funded to develop and demonstrate the solar Brayton power plant that will be most useful as the power generator for the SP-100 nuclear reactor.

English, Robert E.↗
NASA NTRS1992

A mapping closure for turbulent scalar mixing using a time-evolving reference field

A general mapping-closure approach for modeling scalar mixing in homogeneous turbulence is developed. This approach is different from the previous methods in that the reference field also evolves according to the same equations as the physical scalar field. The use of a time-evolving Gaussian reference field results in a model that is similar to the mapping closure model of Pope (1991), which is based on the methodology of Chen et al. (1989). Both models yield identical relationships between the scalar variance and higher-order moments, which are in good agreement with heat conduction simulation data and can be consistent with any type of epsilon(phi) evolution. The present methodology can be extended to any reference field whose behavior is known. The possibility of a beta-pdf reference field is explored. The shortcomings of the mapping closure methods are discussed, and the limit at which the mapping becomes invalid is identified.

Girimaji, Sharath S.↗
NASA NTRS1994

Transportation of volatile elements in thermally evolving planetesimals: An important role of metallic iron

Ordinary chondrites are considered to have experienced thermal metamorphism in small bodies. We are interested in behaviors of volatile elements in such a kind of thermally evolving planetesimals. Volatile elements generally have high vapor pressures at high temperature. In porous bodies, with a high gas permeability, volatile elements are transported efficiently over a long range. Behavior of volatile elements transported by permeable gas flow can be handled by an equation whose form is similar to that of the equation of thermal diffusion. We can follow transportation of heats and volatile elements in planetesimals, when parameters in these equations, initial conditions and chemical behavior of volatile elements are given. Recently, we discovered that nitrogen in equilibrated H-chondrites is mainly trapped in taenite (f.c.c. Fe-Ni), probably dissolved in interstitial sites. Fegley suggests that metallic iron cannot trap nitrogen in the solar nebula gas due to its very low nitrogen partial pressure. Approximately 1 bar of nitrogen pressure is required to explain the nitrogen content in taenite. We may expect high nitrogen gas partial pressure (possibly produced by vaporization of nitrogen-bearing solids such as organic materials) at the interior of thermally evolving planetesimals. Kinetic behavior of nitrogen in taenite suggests that it can easily be equilibrated with the ambient nitrogen gas at temperatures of approximately 500 C or higher. We consider that nitrogen is trapped in taenite through a nitrogen redistribution process occurred during the thermal metamorphic event.

Hashizume, K.↗