Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “evaporation”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Mixed-state entanglement and information recovery in thermalized states and evaporating black holes

We study the universal behavior of quantum information-theoretic quantities in thermalized isolated quantum many-body systems and evaporating black holes. In particular, we study a genuine mixed-state entanglement measure called the logarithmic negativity, other correlation measures including the Renyi negativities and the mutual information, and a signature of multipartite entanglement called the reflected entropy. We also probe the feasibility of recovering quantum information from subsystems of a thermalized quantum many-body system or from the radiation of an evaporating black hole, using quantities such as relative entropy and Petz map fidelity. A recently developed technique called the equilibrium approximation allows us to probe these quantities at finite temperature. We find striking qualitative differences from the infinite temperature case, which has been the topic of previous studies using Haar-random states. In particular, we find regimes where the logarithmic negativity is extensive but the mutual information is sub-extensive, indicating a large amount of undistillable, bound entanglement in thermalized states. For evaporating black holes at finite temperature, both the logarithmic negativity and the Petz map fidelity reveal an important new time scale t b , which is earlier than the Page time t p by a finite fraction of the total evaporation time. We find that t b , as opposed to t p , is the time scale at which quantum entanglement between different parts of the radiation becomes extensive, and the fidelity of information recovery for a large diary thrown into the black hole starts to grow.

2D Gravity↗
DOE OSTI2021

Replica wormholes for an evaporating 2D black hole

Quantum extremal islands reproduce the unitary Page curve of an evaporating black hole. This has been derived by including replica wormholes in the gravitational path integral, but for the transient, evaporating black holes most relevant to Hawking’s paradox, these wormholes have not been analyzed in any detail. In this paper we study replica wormholes for black holes formed by gravitational collapse in Jackiw-Teitelboim gravity, and confirm that they lead to the island rule for the entropy. The main technical challenge is that replica wormholes rely on a Euclidean path integral, while the quantum extremal islands of an evaporating black hole exist only in Lorentzian signature. Furthermore, the Euclidean equations for the Schwarzian mode are non-local, so it is unclear how to connect to the local, Lorentzian dynamics of an evaporating black hole. We address these issues with Schwinger-Keldysh techniques and show how the non-local equations reduce to the local ‘boundary particle’ description in special cases.

2D gravity↗
DOE OSTI2020

Simple holographic models of black hole evaporation

Several recent papers have shown a close relationship between entanglement wedge reconstruction and the unitarity of black hole evaporation in AdS/CFT. The analysis of these papers however has a rather puzzling feature: all calculations are done using bulk dynamics which are essentially those Hawking used to predict information loss, but applying ideas from entanglement wedge reconstruction seems to suggest a Page curve which is consistent with information conservation. Why should two different calculations in the same model give different answers for the Page curve? In this note we present a new pair of models which clarify this situation. Our first model gives a holographic illustration of unitary black hole evaporation, in which the analogue of the Hawking radiation purifies itself as expected, and this purification is reproduced by the entanglement wedge analysis. Moreover a smooth black hole interior persists until the last stages the evaporation process. Our second model gives an alternative holographic interpretation of the situation where the bulk evolution leads to information loss: unlike in the models proposed so far, this bulk information loss is correctly reproduced by the entanglement wedge analysis. This serves as an illustration that quantum extremal surfaces are in some sense kinematic: the time-dependence of the entropy they compute depends on the choice of bulk dynamics. In both models no bulk quantum corrections need to be considered: classical extremal surfaces are enough to do the job. We argue that our first model is the one which gives the right analogy for what actually happens to evaporating black holes, but we also emphasize that any complete resolution of the information problem will require an understanding of non-perturbative bulk dynamics.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2020

Thin-Film Solar Cells with 19% Efficiency by Thermal Evaporation of CdSe and CdTe

CdTe-based solar cells exhibiting 19% power conversion efficiency were produced using widely available thermal evaporation deposition of the absorber layers on SnO2-coated glass with or without a transparent MgZnO buffer layer. Evaporating CdSe and CdTe sequentially by thermal evaporation and subsequent CdCl2 annealing establishes efffective CdSeTe band grading as well as dense, large-grain films. These results show that high-performance II-VI photovoltaics can be made by inexpensive, commercially available evaporation systems without the need to build customized equipment, enabling CdTe photovoltaics research and manufacturing to be more accessible to the broader photovoltaics community.

14 SOLAR ENERGY↗
DOE OSTI2020

Climate change will affect global water availability through compounding changes in seasonal precipitation and evaporation

Both seasonal and annual mean precipitation and evaporation influence patterns of water availability impacting society and ecosystems. Existing global climate studies rarely consider such patterns from non-parametric statistical standpoint. Here, we employ a non-parametric analysis framework to analyze seasonal hydroclimatic regimes by classifying global land regions into nine regimes using late 20th century precipitation means and seasonality. These regimes are used to assess implications for water availability due to concomitant changes in mean and seasonal precipitation and evaporation changes using CMIP5 model future climate projections. Out of 9 regimes, 4 show increased precipitation variation, while 5 show decreased evaporation variation coupled with increasing mean precipitation and evaporation. Increases in projected seasonal precipitation variation in already highly variable precipitation regimes gives rise to a pattern of “seasonally variable regimes becoming more variable”. Regimes with low seasonality in precipitation, instead, experience increased wet season precipitation.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Solar-driven evaporators for water treatment: challenges and opportunities

Solar-driven evaporation is an emerging process to acquire freshwater from saline water or wastewater, in which photothermal materials play a crucial role. Additionally, significant effort has been devoted to promoting energy conversion efficiency by material and device design. In the current review, we discuss the major factors affecting evaporator efficiency and long-term performance, including selection of photothermal materials, promotion of evaporation efficiency, and solutions to the problem of scaling. Both the material components and structure will affect the absorption and reflection of the incident light, and the evaporation efficiency can be enhanced by reducing heat loss, enlarging surface area, and recycling latent heat. Scaling can be addressed by tailoring surface properties and structure.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2026

Mass spectral molecular mapping shows benefits of thermal evaporation in prelithiated silicon-based electrodes

Silicon based composites have become increasingly popular as potential anodes for lithium-ion batteries due to their large storage capacity and potential ability to generate batteries with energy densities greater than 350 Wh kg −1 . These anodes often see reduced initial columbic efficiency (ICE) due to disruptive volume expansionup to 300% and continuous solid electrolyte interphase (SEI) layer formation. Prelithiation, where an excess reservoir of Li is added to the electrode to compensate for irreversible SEI formation losses during their sample preparation, has proven to solve the issue of immediate capacity loss. Thermal evaporation is a prelithiation technique with limited studies on its effectiveness. In this study, time-of-flight secondary ion mass spectrometry (ToF-SIMS) is used to highlight the benefits of prelithiation via thermal evaporation. ToF-SIMS provides chemical mapping and spatial information in 2D and 3D visualizing the deposition of lithium, identifying Li x Si y alloy and Li x Si y O z silicate formation, and the distribution of lithium passivation into the electrodes. Passivation under different atmospheric conditions, such as inert Argon (Ar) and Ar/ carbon dioxide (CO 2 ), highlights the impact of the environment on the passivation effectiveness and formation of Li x Si y alloy and Li x Si y O z silicate. The ToF-SIMS molecular imaging and depth profiling results indicate that prelithiation via thermal evaporation effectively distributes lithium throughout the depth profile thickness of several hundred nanometers. It induces a greater degree of Li x Si y O z silicate formation over Li x Si y alloy. Our ToF-SIMS characterization results show the effectiveness of thermal evaporation in producing a more stable electrode and an electrode with an effective lithium reserve that can preserve its capacity.

Parker, Gabriel D. [Oak Ridge National Laboratory ↗
DOE OSTI2024

Transmission interference fringe ( TIF ) technique for the dynamic visualization of evaporating droplet

Here, the transmission interference fringe (TIF) technique was developed to visualize the dynamics of evaporating droplets based on the Reflection Interference Fringe (RIF) technique for micro-sized droplets. The geometric formulation was conducted to determine the contact angle (CA) and height of macro-sized droplets without the need for the prism used in RIF. The TIF characteristics were analyzed through experiments and simulations to demonstrate a wider range of contact angles from 0 to 90°, in contrast to RIF's limited range of 0–30°. TIF was utilized to visualize the dynamic evaporation of droplets in the constant contact radius (CCR) mode, observing the droplet profile change from convex-only to convex-concave at the end of dry-out from the interference fringe formation. The TIF also observed the contact angle increase from the fringe radius increase. This observation is uniquely reported as the interference fringe (IF) technique can detect the formation of interference fringe between the reflection from the center convex profile and the reflection from the edge concave profile on the far-field screen. Unlike general microscopy techniques, TIF can detect far-field interference fringes as it focuses beyond the droplet-substrate interface. The formation of the convex-concave profile during CCR evaporation is believed to be influenced by the non-uniform evaporative flux along the droplet surface.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

Evaporation barrier for dark matter in celestial bodies

The minimum testable dark matter (DM) mass for almost all DM signatures in celestial bodies is determined by the rate at which DM evaporates. DM evaporation has previously been calculated assuming a competition between the gravitational potential of the object, and thermal kicks from the celestial-body matter. We point out a new effect, where mediators with a range larger than the interparticle spacing induce a force proportional to the density gradient of celestial objects, forming an evaporation barrier for the DM. This effect can be so significant that evaporation does not occur even for sub-MeV DM, in stark contrast to previous calculations. This opens up a wide range of new light DM searches, many orders of magnitude in DM mass below the sensitivity of direct detection.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2024

Local models of two-temperature accretion disc coronae – II. Ion thermal conduction and the absence of disc evaporation

We use local stratified shearing-box simulations with magnetic field-aligned thermal conduction to study an idealized model of the coupling between a cold, radiatively efficient accretion disc, and an overlying, hot, two-temperature corona. Evaporation of a cold disc by conduction from the hot corona has been proposed as a means of mediating the soft-to-hard state transitions observed in X-ray binary systems. We model the coronal plasma in our local disc patch as an MHD fluid subject to both free-streaming ion conduction and a parametrized cooling function that captures the collisional transfer of energy from hot ions to colder, rapidly cooling leptons. In all of our models, independent of the initial net vertical magnetic flux (NF) threading the disc, we find no evidence of disc evaporation. The ion heat flux into the disc is radiated away before conduction can heat the disc’s surface layers. When an initial NF is present, steady-state temperature, density, and outflow velocities in our model coronae are unaffected by conduction. Instead of facilitating disc evaporation, thermal conduction is more likely to feed the disc with plasma condensing out of the corona, particularly in flows without NF. Our work indicates that uncertainties in the amount of NF threading the disc hold far greater influence over whether or not the disc will evaporate into a radiatively inefficient accretion flow compared to thermal conduction. We speculate that a change in net flux mediates disc truncation/evaporation.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Prediction of the Inter-Tube Flow Mode Transitions in the Evaporators of Multi-Effect Thermal Desalination Plants

Water is one of the most stressed resources on the planet. The limited availability of fresh water and the high cost of transportation have led to an increased interest in water desalination technologies. The two main categories of desalination techniques are membrane desalination and thermal desalination. Membrane technologies include pressure driven and electrical driven membranes. On the other hand, thermal desalination includes: multi-effect desalination (MED), multi-stage flash (MSF) desalination, and mechanical vapor compression desalination. Multi-effect desalination plants are usually made of a series of evaporators (also known as effects). In each effect, hot steam flows inside the tubes and evaporates the seawater that falls on the outside of the tubes. The vapor formed at each effect flows to the next effect and acts as the heating medium for the falling seawater. The prevailing flow mode of the falling seawater (i.e. droplet, jet, or sheet) influences heat and mass transfer as well as dry out in the evaporators of Multi-Effect Desalination (MED) plants. The objective of this paper is to predict and discuss the prevailing falling film flow modes in the evaporators of MED plants, under different operating conditions. The paper demonstrates the transitional Reynolds numbers between the main falling film modes for seawater. This closes a gap in the literature where there is a dearth of mode transition data for seawater. The effect of fluid properties and tube geometry on the transitions is discussed in details. As a result, the accuracy of the predicted transitional Reynolds numbers is evaluated via uncertainty quantification techniques.

availability↗
DOE OSTI2020

Calculation of Glycolate Concentration Factors Across the 242-25H (3H) Evaporator System

Two models were developed to predict glycolate concentration factors across the 242-25H (3H) Evaporator system. The first model, identified as the Unrestricted Evaporation Model, was designed to evaluate concentration of typical 3H feed material to relatively high densities in order to calculate the concentration factor of glycolate in a given feed stream. This model may be used to understand the potential of glycolate to concentrate from a generic feed material through the 3H system. The second model, identified as the Holistic Evaporation Model, was designed to evaluate the evaporation of dilute, glycolate-containing Defense Waste Processing Facility (DWPF) waste with the requirement that high silicon concentrations typical of recycle material require dilution to adhere to current technical safety requirements. This model may be used to understand the potential of glycolate from DWPF recycle material to concentrate as a result of feeding through the 3H system.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Evaporative chilling systems and methods using a selective transfer membrane

Compact membrane evaporative chillers, methods for cooling a process fluid (e.g., air) using a compact membrane evaporative chiller, and air conditioning systems and methods that include a compact membrane evaporative chiller are disclosed herein. Compact membrane evaporative chillers as disclosed herein can advantageously reduce or eliminate power consumption needed to circulate a working fluid.

Johnson, Brian↗
DOE OSTI2025

A comprehensive modeling of falling film evaporators subject to vapor flow, pass arrangements, and refrigerants

Improving the heat transfer performance of falling film evaporators is a crucial step for improving the energy efficiency of the heat pump or refrigeration systems. This study conducts a numerical investigation for the practical-scale falling film evaporator based on the epsilon–NTU method with an updated heat transfer correlation. The algorithm was validated with lab-scale and real-scale falling film evaporator experimental results, and the prediction reaches a mean absolute deviation of 12.5%. Here, the parametric study encompasses eight refrigerants: R-134a, R-410A, R-600a, R-717, R-1270, R-152a, R-1234yf, and R-1234ze(E). The results indicate that vaporization enthalpy of refrigerant is a key property in selecting an appropriate working fluid because it helps minimize severe heat transfer degradation caused by dry-out. Additionally, the vapor-flow–induced heat transfer degradation can be predicted using the critical Weber number. Furthermore, the trade-off between extending the tube length and increasing the number of tubes for heat transfer improvement is discussed. Finally, different two-pass arrangements show deviations of less than 4 %.

Dry-out↗
DOE OSTI2021

Chromium evaporation and oxidation characteristics of alumina-forming austenitic stainless steels for balance of plant applications in solid oxide fuel cells

The chromium (Cr) evaporation behavior of several different types of iron (Fe)-based AFA alloys and benchmark Cr 2 O 3 -forming Fe-based 310 and Ni-based 625 alloys was investigated for 500 h exposures at 800 °C to 900 °C in air with 10% H 2 O. The Cr evaporation rates from alumina-forming austenitic (AFA) alloys were ~5 to 35 times lower than that of the Cr 2 O 3 -forming alloys depending on alloy and temperature. The Cr evaporation behavior was correlated with extensive characterization of the chemistry and microstructure of the oxide scales, which also revealed a degree of quartz tube Si contamination during the test. As a result, long-term oxidation kinetics were also assessed at 800 to 1000 °C for up to 10,000 h in air with 10% H 2 O to provide further guidance for SOFC BOP component alloy selection.

08 HYDROGEN↗
DOE OSTI2024

CFD unified approach under Eulerian–Lagrangian framework for methanol and gasoline direct injection sprays in evaporative and flash boiling conditions

Innovative synthetic fuels for advanced propulsion systems, such as methanol and ammonia, and synthetic blended fuels (E00, E10, and E30), known for their high volatility, are often injected directly into combustion chambers. It follows that Eulerian–Lagrangian spray models need to accurately capture the spray collapse as a consequence of flash boiling onset and be capable of proficiently handling the preferential evaporation of multi-component fuels in evaporative scenarios. So, we performed the assessment of an Eulerian–Lagrangian CFD code for simulating methanol and E00 gasoline blend sprays in both early and late injection conditions involving flash boiling conditions and preferential evaporation. The adoption of an effervescent breakup model and of a non-equilibrium phase transition model for the discrete phase allows the adoption of a setup that is almost completely free from specific constant tuning, especially for what concerns the breakup model. We validated the simulations using experimental PLV maps of methanol and E00 sprays issued from the ECN Spray M injector. The results highlight a significantly different morphology of the methanol spray compared to the E00 one under late injection conditions. Under stratified combustion, low-volatile fuels are likely to be ignited first, and the flame propagates toward the high-volatile fuels. In conclusion, the spray collapse was also correctly reproduced, inducing the presence of a low-pressure zone and modifying the spray morphology.

E00↗