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All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Processing Meteorological Data for the CAP-88 PC Model at Los Alamos National Laboratory

The Environmental Protection and Compliance-Compliance Programs (EPC-CP) group at Los Alamos National Laboratory (LANL) uses the Clean Air Act Assessment Package 1988 (CAP-88, Littleton 2020) PC model (Version 4.1) to estimate radiological doses for a set of areal sectors surrounding a release location, in order to satisfy the Environmental Protection Agency (EPA) National Emission Standards for Hazardous Air Pollutants (NESHAP) dose calculation requirement in 40 CFR 61 Subpart H. Among several types of data that must be prepared for CAP-88 input is a text file of meteorological data (“WIND” file), consisting of the joint frequency of wind direction, wind speed, and atmospheric stability categories. EPC-CP produces customized WIND files by running a CAP-88 utility program on a user generated text file of wind data in a different format, known as a STability ARray (STAR) file (Turner, 1964). At LANL, EPC-CP meteorologists prepare customized STAR files with data over desired time periods at selected meteorological towers. A custom program written in Precision Visuals -Workstation Analysis and Visualization Environment (PV-WAVE), a commercial Fortran-like language, is used to read LANL meteorological data and write a STAR file; the executable filename is “Star.out”. However, the outdated PV-WAVE utility program is being phased out by EPC-CP, due to the inefficient process to run it and an inability to modify the code. To preserve the ability to create customized meteorological data for CAP-88 in a way that will be easy to use and maintain, a new replacement utility program, written in the Python programming language, has been developed. The new, improved program reads a data file from any LANL meteorological tower, and at each desired observation time, determines the wind direction, wind speed, and stability categories defined in the CAP-88 documentation. The frequencies of all combinations of the three sets of categories are calculated and written to a file in the STAR format, which can later be converted to a WIND file for input into CAP-88.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2001

Canaveral National Seashore Water Quality and Aquatic Resource Inventory

Mosquito Lagoon is a shallow, bar-built estuary located on the east central Florida Coast, primarily within the KSC boundary. The lagoon and watershed cover approximately 327 sq km (79422 acres) .The Lagoon occupies 159 sq km (37853 acres). Water depths average approximately 1m. The lagoon volume is approximately 1.6 x 10(exp 8)cu m. Water quality in Mosquito Lagoon is good. Salinity data typically range between 20 ppt and 35 ppt. The lowest value recorded was 4.5 ppt and the highest value was 37 ppt. Water temperatures fluctuate 2 - 3 C over a 24 h period. Cold front passage can rapidly alter water temperatures by 5 - 10 C or more in a short period of time. The highest temperature was 33.4 C and the lowest temperature was 8.8 C after a winter storm. Dissolved oxygen concentrations ranged from a low of 0.4 mg/l to a high of 15.3 mg/l. Extended periods of measurements below the Florida Department of Environmental Protection criteria of 4.0 mg/l were observed in fall and spring months suggesting high system respiration and oxygen demand. Metals such as antimony, arsenic, molybdenum and mercury were report as below detection limits for all samples. Cadmium, copper, chromium, silver, and zinc were found to be periodically above the Florida Department of Environmental Protection criteria for Class II and Class III surface waters.

Hall, C. R.↗
DOE OSTI2020

Using the CAP88 Plume Model & Dose Assessment Code for the FTWC Project

The Environmental Protection & Compliance Division (EPC) uses the Clean Air Act Assessment Package – 1988 (CAP88) plume model and dose assessment code to evaluate measured emissions or projected emissions of airborne radionuclides from Los Alamos National Laboratory (LANL) facilities. This software package will use facility data (e.g., stack height and exit velocity), emissions parameters (chemical form and quantity), and environmental data (wind speed and direction) to predict downwind concentrations of radioactive material and subsequent dose to a member of the public at that location. The United States Environmental Protection Agency (EPA) has approved CAP88 for use in demonstrating compliance with the Radionuclide NESHAP2, that portion of the Clean Air Act addressing emissions of airborne radioactive material from Department of Energy facilities. EPC Division has two procedures which discuss the use of CAP88.

61 RADIATION PROTECTION AND DOSIMETRY↗
DOE OSTI2024

Minimizing Toxicity and Optimizing Lubricity of Ionic Liquids for Eco-Friendly Lubrication

As much as 60 million liters of lubricating fluids end up in the environment annually, and thus, the environmental impact of lubricants is increasingly recognized in addition to meeting the rheological and tribological requirements. Although US Environmental Protection Agency-approved environmentally acceptable base fluids are available, there is a lack of additives that are both nontoxic and effective in wear protection. Here, this study reports the successful development of a new class of ionic liquids (ILs) with demonstrated significantly lower aquatic toxicity and superior friction reduction and wear protection capabilities compared with a commercial lubricant additive and some ILs reported in the literature. Specifically, ammonium phosphate and phosphonium phosphate ILs with four-carbon alkyls have been identified with balanced oil solubility, thermal stability, toxicity, and lubricity, which provide fundamental insights for future development of eco-friendly ILs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Air Pathway Dose Modeling for the E-Area Low-Level Waste Facility

The US Department of Energy (DOE) Order 435.1 performance assessment (PA) process (USDOE 1999) prescribes a performance objective (10 mrem y -1 ) for evaluating atmospheric releases of radionuclides from DOE low-level waste (LLW) disposal facilities. The potential dose to an individual from exposure to radionuclides released into the atmosphere from LLW disposals can be estimated by application of radionuclide-specific dose-release factors (DRFs) (mrem Ci -1 ) to estimated flux rates (Ci y -1 ) at a particular time and location. In Revision 0 of this report, Lee (2006) calculated DRFs for potential atmospheric releases of 15 volatile radionuclides from seven ELLWF disposal units in support of the 2008 ELLWF PA (WSRC 2008). The mainframe version of the US Environmental Protection Agency’s (EPA) dose model CAP88 was used in the Revision 0 assessment. In Revision 1 of this report (Dixon and Minter 2017), the site-specific Savannah River National Laboratory (SRNL) atmospheric dose models MAXDOSE-SR version 2013 (Stone and Jannik 2013a) and MAXINE version 2017 (Bell 2017) were used to calculate DRFs for ten radionuclides. Revision 2 provided updated DRFs using the current version of the US Environmental Protection Agency’s (EPA) dose model CAP88-PC Version 4.1. After Revision 2 was finalized, DRFs were requested for Ar-37, Ar-39, Kr-83m, and Hg-206. Revision 3 provides the additional DRFs calculated using the same methods as used in Revision 2 of this document. The method for estimating new DRFs for the ELLWF disposal units is described in this report.

61 RADIATION PROTECTION AND DOSIMETRY↗
NASA NTRS1997

Suitlock Docking Mechanism

An environmental protective suit used for hazardous clean-up or space applications includes a suitlock docking mechanism that allows for easy egress and ingress of a crew member between a sealed vessel and a possibly contaminated environment. The suitlock docking mechanism comprises a single actuator that controls latches which, in turn, respectfully control rack and pinion assemblies that allow for easy removal and attachment of a life support equipment enclosure shell to the environmental protective suit or to the vehicle from which the operator performs his/her duties.

Culbertson, Philip, Jr.↗
NASA NTRS1997

Methyl Chloroform Elimination from the Production of Space Shuttle Sold Rocket Motors

Thiokol Space Operations manufactures the Reusable Solid Rocket Motors used to launch America's fleet of Space Shuttles. In 1989, Thiokol used more than 1.4 Mlb of methyl chloroform to produce rocket motors. The ban placed by the Environmental Protection Agency on the sale of methyl chloroform had a significant effect on future Reusable Solid Rocket Motor production. As a result, changes in the materials and processes became necessary. A multiphased plan was established by Thiokol in partnership with NASA's Marshall Space Flight Center to eliminate the use of methyl chloroform in the Reusable Solid Rocket Motor production process. Because of the extensive scope of this effort, the plan was phased to target the elimination of the majority of methyl chloroform use (90 percent) by January 1, 1996, the 3 Environmental Protection Agency deadline. Referred to as Phase I, this effort includes the elimination of two large vapor degreasers, grease diluent processes, and propellant tooling handcleaning using methyl chloroform. Meanwhile, a request was made for an essential use exemption to allow the continued use of the remaining 10 percent of methyl chloroform after the 1996 deadline, while total elimination was pursued for this final, critical phase (Phase II). This paper provides an update to three previous presentations prepared for the 1993, 1994, and 1995 CFC/Halon Alternative Conferences, and will outline the overall Ozone Depleting Compounds Elimination Program from the initial phases through the final testing and implementation phases, including facility and equipment development. Processes and materials to be discussed include low-pressure aqueous wash systems, high-pressure water blast systems- environmental shipping containers, aqueous and semi-aqueous cleaning solutions, and bond integrity and inspection criteria. Progress toward completion of facility implementation and lessons learned during the scope of the program, as well as the current development efforts and basic requirements of future methyl chloroform handcleaning elimination, will also be outlined.

Golde, Rick P.↗
NASA NTRS2010

The Assurance Challenges of Advanced Packaging Technologies for Electronics

Advances in microelectronic parts performance are driving towards finer feature sizes, three-dimensional geometries and ever-increasing number of transistor equivalents that are resulting in increased die sizes and interconnection (I/O) counts. The resultant packaging necessary to provide assemble-ability, environmental protection, testability and interconnection to the circuit board for the active die creates major challenges, particularly for space applications, Traditionally, NASA has used hermetically packaged microcircuits whenever available but the new demands make hermetic packaging less and less practical at the same time as more and more expensive, Some part types of great interest to NASA designers are currently only available in non-hermetic packaging. It is a far more complex quality and reliability assurance challenge to gain confidence in the long-term survivability and effectiveness of nonhermetic packages than for hermetic ones. Although they may provide more rugged environmental protection than the familiar Plastic Encapsulated Microcircuits (PEMs), the non-hermetic Ceramic Column Grid Array (CCGA) packages that are the focus of this presentation present a unique combination of challenges to assessing their suitability for spaceflight use. The presentation will discuss the bases for these challenges, some examples of the techniques proposed to mitigate them and a proposed approach to a US MIL specification Class for non-hermetic microcircuits suitable for space application, Class Y, to be incorporated into M. IL-PRF-38535. It has recently emerged that some major packaging suppliers are offering hermetic area array packages that may offer alternatives to the nonhermetic CCGA styles but have also got their own inspectability and testability issues which will be briefly discussed in the presentation,

Sampson, Michael J.↗
DOE OSTI2025

Developing a Prototype Methodology to Rank CO2-EOR Wells and Assess Their Reuse Potential for Geologic Carbon Storage

This paper presents a prototype methodology to assess the possible transition of Class II carbon dioxide-enhanced oil recovery (CO2-EOR) wells to Class VI wells. The focus is on wellbore construction materials—casing, cement, tubing, and the packer—and includes comprehensive workflows to evaluate these materials, with primary emphasis on compliance with Environmental Protection Agency (EPA) Class VI well construction and conversion guidelines. These workflows systematically assess material properties and performance criteria to ensure regulatory compliance and optimize long-term wellbore integrity and functionality. Utilizing Python scripts and JavaScript Object Notation (JSON) representations, the study automates checks on digitized Texas Railroad Commission (TRRC) data to rank wells based on workflow criteria. By emphasizing critical factors such as casing integrity, cementing techniques, tubing compatibility, and packer selection, the methodology helps well owners and operators prioritize wells for potential reuse as CO2 injection wells. Given limitations in digitized data, manual user verification is required in some sections. Future improvements include integrating non-digitized data through web scraping and machine learning techniques. This research serves as a practical guide for stakeholders, supporting environmental compliance and sustainable well operations.

geologic carbon sequestration↗
DOE OSTI2024

Carbon Management Projects (CONNECT) Database and Explorer

Overview The Carbon Management Projects (CONNECT) Toolkit is an online exploratory visualization tool developed by the U.S. Department of Energy's (DOE) Office of Fossil Energy and Carbon Management (FECM) with support from other federal agencies such as the U.S. Environmental Protection Agency (EPA) and the U.S. Department of Transportation (DOT). It provides a single point of access to authoritative information on federal agency investment in a portfolio of research, development, and demonstration (RD&D) projects that have been publicly announced to advance technologies for point source carbon capture, carbon dioxide removal, transport, storage, and conversion, collectively referred to as carbon management. The RD&D programs covered in this tool are authorized by annual congressional appropriations ("Base Program") and the 2021 Infrastructure Investment and Jobs Act (IIJA). The tool also incorporates public information on other federal initiatives, such as the Regional Clean Hydrogen Hubs, and public information released by other government agencies, such as the Environmental Protection Agency's (EPA) and Primacy States’ Underground Injection Control Class VI permits and EPA’s facility level greenhouse gas (GHG) emissions. Developed in a geographic information system, the tool organizes carbon management projects into five groups based on the primary technology that a project aims to advance, each visually represented as a digital layer ("carbon management project layer"). Only federally funded projects are included, which can be awarded projects that are completed or ongoing, or projects that have been selected but are currently under negotiation. Project information can be viewed in the map or in the attribute table below it when turned on. In the map view, each project is displayed at either its host site (for field work), where available, or its performer site (project lead's location, further explained in the table below). Host sites and performer sites are represented in distinct icons. Several reference layers offer additional public information on infrastructural and natural resource environment for carbon management. These reference layers, combined with multiple geographical basemaps, enable users to visualize the carbon management project layers in context. Carbon management project information will be updated monthly based on feedback and information availability. Carbon management project layers Point Source Carbon Capture (PSC) This layer contains DOE-funded projects focused on capturing carbon dioxide (CO2) from power plants or industrial facilities. Carbon Dioxide Removal (CDR) This layer contains DOE-funded projects focused on capturing CO2 from the atmosphere, including direct air capture (DAC) and DAC hubs, direct ocean capture, enhanced mineralization, and biomass carbon removal and storage. For projects with multiple host sites, each of the sites are displayed individually with the project cost and cost sharing information representing the total for the entire project. Carbon Transport This layer contains DOE- and DOT-funded projects focused on CO2 transport. The Transport Research and Development sublayer contains projects that do not involve physical infrastructure; the Proposed Transport Corridor sublayer contains projects for which either a route for the transport infrastructure has been proposed or a general area for the transport infrastructure has been identified. Carbon Storage This layer contains DOE-funded key projects focused on CO2 storage. For projects with multiple field-work sites, each of the sites are displayed individually on the map with the project cost and cost sharing information representing the overall total for the entire project. Carbon Conversion This layer contains DOE-funded projects focused on converting CO2 into economically valuable products. Reference layers The following layers provide additional information in the geographic proximity of carbon management projects. Users should reference the original sources for more details (weblinks provided below and in pop-up windows on the map). Regional Clean Hydrogen Hub and Facility These layers illustrate the approximate areas of the Regional Clean Hydrogen Hubs announced by DOE's Office of Clean Energy Demonstrations (OCED) and the approximate locations of individual facilities that constitute the hubs (see "Where are the H2Hubs located?" on the webpage linked above). EPA Facility Level GHG Emissions (direct emitter) This layer shows direct CO2 emissions from stationary sources in 2022, using data extracted from EPA's Facility Level Information on GreenHouse gases Tool (FLIGHT). Captured and injected CO2 are not deducted from direct emitters’ total emissions. Contact EPA for additional details. Underground Injection Control Class VI permit/permit application This layer shows the locations of CO2 injection wells that are granted or in the process of applying for an Underground Injection Control Class VI permit by EPA or a Primacy State (currently Louisiana, North Dakota, and Wyoming). The URLs for the permits or permit applications are provided in the pop-up windows associated with the well locations. Contact EPA for additional details. Carbon Storage Resource This layer contains information on prospective CO2 storage resources in saline formations and oil and gas reservoirs provided by the National Carbon Sequestration Database and Geographic Information System (NATCARB) spatial database. Contact NETL for additional details. Existing CO2 pipeline This layer shows active CO2 pipelines based on information digitized from the map issued by the Pipeline and Hazardous Materials Safety Administration (PHMSA). Contact PHMSA for additional details.

Carbon Conversion↗
DOE OSTI2021

Environmental Performance Report 2020 (Annual Site Environmental Report per the U.S. Department of Energy Order 231.1B Chg 1)

The National Renewable Energy Laboratory's (NREL's) Environmental Performance Report provides a description of the laboratory's environmental management activities in 2020, including information on environmental and sustainability performance, environmental compliance activities and status, and environmental protection programs, highlights, and successes. The purpose of this report is to ensure that the U.S. Department of Energy (DOE) and the public receive timely, accurate information about events that have positively affected or could adversely affect the health and safety of the public or workers, the environment, or the operations of DOE facilities. This report meets the DOE requirements of the Annual Site Environmental Report (ASER) and has been prepared in accordance with DOE Order 231.1B Chg 1, Environment, Safety and Health Reporting.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2019

Potential Improvements to the Nuclear Safety and Launch Approval Process for Nuclear Reactors Utilized for Space Power and Propulsion Applications

This study examines potential improvements that could be made to the nuclear safety and launch approval process for fission reactors to reduce the associated uncertainties in cost and schedule while continuing to ensure public safety and environmental protection. It concentrates on the launch approval and mission safety of fission power and propulsion applications of nuclear energy. Improvements to the launch approval process for radioisotope power systems (RPSs) are being considered elsewhere but are acknowledged throughout the report. The study considered technical, process, and organizational improvements to the launch approval processes. The study exclusively evaluated reactors that would not be started up prior to achieving a “sufficiently high orbit,” per United Nations (UN) Resolution 47/68.Potential criticality accidents were considered that could occur during a launch failure or abort or during reentry. Numerous scenarios were examined that might involve one or more Earth flybys as well as potential transportation missions that could intentionally return an active, or previously active fission reactor to Earth orbit. The Study Group was guided in its deliberations according to a number of fundamental principles. These included the paramount importance of adequate and appropriate levels of public safety and environmental protection as well as the importance of the inclusion of independent scientific, engineering, and safety reviews of the applications and proposals as a critical part of the process. Also considered was the need for the development of launch approval processes that might be different, depending upon the source of the application for launch approval, whether it be derived as a governmental launch, a commercial launch, or a hybrid/combination of the two. It is clear that all launches of nuclear reactors into space should have similar safety requirements; however, the safety review effort and the details of the analysis that are required should be commensurate with the potential hazards and the actual risk, which may differ based on the reactor design and its intended purpose. Finally, the study aimed at ensuring that whatever processes and procedures are developed should maximize the sufficiency, simplicity, and transparency of the processes. The Study Group reached five Conclusions and makes thirteen Recommendations. The Conclusions and Recommendations presented here are extensions of those presented previously in other studies. This report attempts to add specificity to the actions that need to be taken in order to move forward with successful space fission reactor programs. Without action to address the perceived and real problems in the launch approval process, designers and mission managers will be reluctant to commit the resources necessary to make space fission reactors a reality.

Camp, Allen↗
NASA NTRS2024

Launch Complex 39A, SWMU 008 2023 Long-Term Monitoring Report Kennedy Space Center, Florida

The 2023 Long-Term Monitoring (LTM) Report (LTMR) presents the annual and semi-annual groundwater monitoring results for Launch Complex 39A (LC39A), Solid Waste Management Unit (SWMU) 008, at Kennedy Space Center (KSC), Florida. The reporting period covered under this LTMR is from January to December 2023, and represents the first year of site-wide monitoring following Air Sparge (AS) system shutdown at the end of 2022. AS system operation at LC39A began operation in 2015. The AS system consisted of a total of 173 AS wells ranging in depth from 11 to 37 feet below land surface. The overall remedial objective for the AS Interim Measure was to actively decrease concentrations of COCs to less than their respective Florida Department of Environmental Protection Natural Attenuation Default Concentrations, so that LC39A can transition into an LTM program. This objective was achieved in 2022, with 2023 marking Year 1 of the LTM program to monitor the residual groundwater plume. VOC results indicate that COC concentrations have continued to decrease or stabilize, with no rebound observed since AS system shutdown. Vinyl chloride was the only COC detected above its GCTL, with the highest concentration detected at 8.0 μg/L. PFAS results detected 15 different PFAS compounds (out of 32 analyzed) between the six monitoring wells sampled. Two PFAS compounds, perfluorooctanesulfonic acid (PFOS) and perfluorooctanoic acid (PFOA), currently have FDEP Provisional GCTLs of 70 nanograms per liter (ng/L). PFOS was detected in one of the six samples above the FDEP Provisional GCTL at a concentration of 200 ng/L. PFOA was not detected above the FDEP Provisional GCTL in any of the six samples. PFOS and PFOA also currently have United States Environmental Protection Agency (USEPA) Maximum Contaminant Levels (MCLs) of 4 ng/L. PFOS was detected in all six samples above the USEPA MCL. PFOA was detected in three of the six samples above the USEPA MCL. Three other PFAS compounds, perfluorohexanesulfonic acid (PFHxS), perfluoro-n-nonanoic acid (PFNA), and hexafluoropropylene oxide dimer acid (GenX), currently have USEPA MCLs of 10 ng/L. PFHxS, PFNA, and GenX were not detected at concentrations greater than their respective USEPA MCLs in any of the six wells. Additional PFAS sampling will occur as part of a PFAS Site Assessment to be conducted in the future. Based on Year 1 LC39A LTM results, recommendations for 2024 are to continue with the second year of LTM in 2024 with the same monitoring well network as Year 1 (18 wells). The three wells that were on a semi-annual schedule will transition to an annual schedule to align with the remaining wells. The next annual event is scheduled for May 2024. The three wells that were found to be inadvertently destroyed will be properly abandoned and a replacement well in the vicinity of former monitoring well 21ST-MW0030I will be installed. This new well will be added to the LTM sampling plan upon installation.

Deborah M. Wilson↗
DOE OSTI2023

Convergence and divergence in science and practice of urban and rural forest restoration

Forest restoration has never been higher on policymakers' agendas. Complex and multi-dimensional arrangements across the urban–rural continuum challenge restorationists and require integrative approaches to strengthen environmental protection and increase restoration outcomes. It remains unclear if urban and rural forest restoration are moving towards or away from each other in practice and research, and whether comparing research outcomes can help stakeholders to gain a clearer understanding of the interconnectedness between the two fields. This study aims to identify the challenges and opportunities for enhancing forest restoration in both urban and rural systems by reviewing the scientific evidence, engaging with key stakeholders and using an urban–rural forest restoration framework. Using the Society for Ecological Restoration's International Principles as discussion topics, we highlight aspects of convergence and divergence between the two fields to broaden our understanding of forest restoration and promote integrative management approaches to address future forest conditions. Our findings reveal that urban and rural forest restoration have convergent and divergent aspects. We emphasise the importance of tailoring goals and objectives to specific contexts and the need to design different institutions and incentives based on the social and ecological needs and goals of stakeholders in different regions. Here we discuss the challenges of achieving high levels of ecological restoration and the need to go beyond traditional ecology to plan, implement, monitor, and adaptively manage restored forests. We suggest that rivers and watersheds could serve as a common ground linking rural and urban landscapes and that forest restoration could interact with other environmental protection measures. We note the potential for expanding the creative vision associated with increasing tree-containing environments in cities to generate more diverse and resilient forest restoration outcomes in rural settings. This study underscores the value of integrative management approaches in addressing future forest conditions across the urban–rural continuum. Our framework provides valuable insights for policymakers, researchers, and decision-makers to advance the field of forest restoration and address the challenges of restoration across the urban–rural continuum. The rural–urban interface serves as a convergence point for forest restoration, and both urban and rural fields can benefit from each other's expertise.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2004

NASA Data for Water Resources Applications

Water Management Applications is one of twelve elements in the Earth Science Enterprise National Applications Program. NASA Goddard Space Flight Center is supporting the Applications Program through partnering with other organizations to use NASA project results, such as from satellite instruments and Earth system models to enhance the organizations critical needs. The focus thus far has been: 1) estimating water storage including snowpack and soil moisture, 2) modeling and predicting water fluxes such as evapotranspiration (ET), precipitation and river runoff, and 3) remote sensing of water quality, including both point source (e.g., turbidity and productivity) and non-point source (e.g., land cover conversion such as forest to agriculture yielding higher nutrient runoff). The objectives of the partnering cover three steps of: 1) Evaluation, 2) Verification and Validation, and 3) Benchmark Report. We are working with the U.S. federal agencies including the Environmental Protection Agency (EPA), the Bureau of Reclamation (USBR) and the Department of Agriculture (USDA). We are using several of their Decision Support Systems (DSS) tools. This includes the DSS support tools BASINS used by EPA, Riverware and AWARDS ET ToolBox by USBR and SWAT by USDA and EPA. Regional application sites using NASA data across the US. are currently being eliminated for the DSS tools. The current NASA data emphasized thus far are from the Land Data Assimilation Systems WAS) and MODIS satellite products. We are currently in the first two steps of evaluation and verification validation. Water Management Applications is one of twelve elements in the Earth Science Enterprise s National Applications Program. NASA Goddard Space Flight Center is supporting the Applications Program through partnering with other organizations to use NASA project results, such as from satellite instruments and Earth system models to enhance the organizations critical needs. The focus thus far has been: 1) estimating water storage including snowpack and soil moisture, 2) modeling and predicting water fluxes such as evapotranspiration (ET), precipitation and river runoff, and 3) remote sensing of water quality, including both point source (e.g., turbidity and productivity) and non-point source (e.g., land cover conversion such as forest to agriculture yielding higher nutrient runoff). The objectives of the partnering cover three steps of 1) Evaluation, 2) Verification and Validation, and 3) Benchmark Report. We are working with the U.S. federal agencies the Environmental Protection Agency (EPA), the Bureau of Reclamation (USBR) and the Department of Agriculture (USDA). We are using several of their Decision Support Systems (DSS) tools. T us includes the DSS support tools BASINS used by EPA, Riverware and AWARDS ET ToolBox by USBR and SWAT by USDA and EPA. Regional application sites using NASA data across the US. are currently being evaluated for the DSS tools. The current NASA data emphasized thus far are from the Land Data Assimilation Systems (LDAS) and MODIS satellite products. We are currently in the first two steps of evaluation and verification and validation.

Toll, David↗
DOE OSTI2023

Chemical durability assessment of enhanced low-activity waste glasses through EPA method 1313

In this work, we report the progress of the Glass Leaching Assessment for Durability (GLAD) program on the implementation of the United States Environmental Protection Agency (EPA) Leaching Environmental Assessment Framework pH-dependent leach test (EPA Method 1313) to low-activity nuclear waste (LAW) glasses. The GLAD program seeks to develop new strategies to understand the chemical durability of nuclear waste glasses for the disposal in near-surface conditions. A series of 16 high-waste loading LAW glasses, currently under development, were selected using machine learning methods to study the corrosion behavior using EPA Method 1313. Reacted glass powders were examined using scanning electron microscopy and the eluate compositions were examined using inductively coupled plasma-optical emission spectroscopy. Compositional modeling was used to fit the measured elemental releases from EPA Method 1313. The compositional models demonstrated that elements such as Si reduce elemental release while B can increase elemental release (consistent with elemental modeling of the Product Consistency Test and Vapor Hydration Test) while other elements, such as Fe, exhibit pH-dependent behavior. The amount of acid added during the EPA testing was found to significantly impact the observed result, which was only apparent after preforming the present matrix study. The overall titration curves were able to be compositionally modeled for future process optimization.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS2003

Ultra-Efficient Engine Technology Project Continued to Contribute to Breakthrough Technologies

The International Civil Aviation Organization (ICAO), the U.S. Environmental Protection Agency (EPA), local environmental groups, and the public have become increasingly concerned over damage to local air quality from aircraft emissions and the impact of producing greenhouse gases. The NASA Glenn Research Center has been working to develop revolutionary technologies to minimize environmentally harmful engine emissions, such as nitrogen oxides, carbon dioxide, aerosols, and particulates. The two objectives of UEET are (1) to develop technologies to reduce nitrogen oxide (NOx) emissions by 70 percent below 1996 ICAO regulations and (2) to decrease carbon dioxide emissions (CO2) by dramatically increasing performance and efficiency. High temperature engine materials, ultra-low-NOx combustor designs, efficient, highly loaded turbomachinery, and propulsion-airframe integration analysis are technologies being developed at Glenn to meet these goals. Technology developed in the previous Advanced Subsonic Technology Program is being put into commercial production for large and regional aircraft to reduce NOx emissions 50 percent below 1996 ICAO regulations for landing and takeoff cycles. UEET will take the technology to the next quantum leap-reducing emissions to 70 percent below the ICAO regulations level. In addition, NASA-developed research will significantly reduce carbon monoxide, unburned hydrocarbons, and corresponding cruise NOx levels for the next generation of aircraft engines. Glenn's UEET research will be useful across the whole range of flight: subsonic, supersonic, and hypersonic. It will improve the subsonic transportation that the public depends on, contribute to supersonic commercial aircraft, improve military aircraft, and contribute to the design of a future hypersonic vehicle. These technologies are contributing to a better quality of life on Earth.

Shaw, Robert J.↗
NASA NTRS2009

Coated silicon comprising material for protection against environmental corrosion

In accordance with an embodiment of the invention, an article is disclosed. The article comprises a gas turbine engine component substrate comprising a silicon material; and an environmental barrier coating overlying the substrate, wherein the environmental barrier coating comprises cerium oxide, and the cerium oxide reduces formation of silicate glass on the substrate upon exposure to corrodant sulfates.

Hazel, Brian Thomas↗