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All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Transformative Impacts of Laser-Induced Breakdown Spectroscopy on Environmental and Biological Research at Oak Ridge National Laboratory

This manuscript will present an advancement of transformative research that has been conducted at Oak Ridge National Laboratory (ORNL) over a 25-year period (2000–2025) on a variety of environmental and biological matrices. These investigations derived a fundamental understanding of how elemental detection and analysis of these matrices led to the knowledge and discovery of natural processes in plants and the environment. Each project led to the initiation of a new research area which unearthed awesome and novel breakthroughs. Highlights are listed below: 1. The preliminary research at ORNL centered on the detection of aerosols utilizing Laser-induced Breakdown Spectroscopy (LIBS) technology. The Clean Air Act Amendment (CAAA) of 1990 highlighted the importance of identifying hazardous air pollutants (HAPs) due to their impact on environmental and human health, thereby underscoring the need to detect various toxic elements. Research in aerosol chemistry aimed to identify these harmful elements released by factories during periods of increased emissions in their manufacturing processes. LIBS emerged as the most effective method for real-time, in situ measurements of metal species in both gaseous and aerosol phases. 2. An understanding of the presence of total carbon in soils gives perspective on how to develop carbon sequestration strategies. The recognition that carbon sinks can evolve back to carbon sources to emit back to the atmosphere was an important consideration. Also, the concentration of carbon in soil indicates the health of land areas for growing crops successfully. 3. The direct detection of most of the elements in a wood sample in a single emission spectrum, without sample preparation, encouraged the research to use the LIBS technique for preservative treated wood coupled with use of multivariate statistical methodology. Additionally, it encouraged the researchers to try to differentiate natural woods from different parts of the country, and it was successfully demonstrated that LIBS coupled with MVA analysis could differentiate wood of different species from each other and of similar species grown in different environments based on their elemental spectra. This was a breakthrough since it revealed a systematic approach to connect elemental scarcity and abundance to either drought or typical rainfall conditions for the hardwood trees grown in specific areas. 4. Furthermore, the research progressed to reveal physiological and developmental processes contributing to biomass production such that the variation in leaf elemental composition increases our understanding of terrestrial nutrient cycles, as well as tracking the transfer of toxic elements from soils to living organisms. 5. Recently another breakthrough viz., ionomics initiated the correlation of elements to specific genes, uncovering the function that the element performed in the plant. More recently, this has been extended from plants to fungi as well as fungi growing in symbiotic relations with plants.

09 BIOMASS FUELS↗
DOE OSTI2022

The pursuit of net-positive sustainability for industrial decarbonization with hybrid energy systems

We report signatories of the Paris Agreement are set to miss their climate targets. The net-zero pledges announced to date across many countries and private industries are insufficient to achieve carbon neutrality, which requires implementation of far-reaching and significantly scaled-up climate-positive actions. All technology options that pertain to deep decarbonization and carbon removal must be part of the mitigation portfolio. Transformative action plans must be established in which every individual/organization around the globe is an actor of changes in relation to net-zero goals. Such plans must involve governmental policy support but also encourage voluntary efforts to boost innovations, investments, initiatives, and behavioral changes. Recognition of these efforts is made quantifiable with the concepts of carbon handprint and net positivity. This paper presents a carbon handprint perspective on characterizing the environmental benefits of hybrid energy systems (HESs)—a widely applicable solution to cleaner production leveraging the capabilities of a portfolio of low-carbon energy sources—that provide heat and electricity to industrial processes. First, the carbon handprint and net positivity concepts and their calculation approach are introduced. The state of the art of HES-enabled industrial cogeneration is then surveyed, and the greenhouse gas emission intensities of different energy sources that power HESs are compared. Next, drawing on a case study about a US chemical facility's voluntary initiative to explore replacing its fossil fuel–based cogeneration infrastructure with a clean energy–generated HES, several technically viable scenarios are evaluated—especially those with small modular nuclear reactors—to illustrate how the positive-thinking handprint approach helps encourage and inform the search for widespread influence pathways in pursuit of net-positive sustainability. Finally, current knowledge gaps in the case study are identified, and opportunities to scale up the proposed handprint-based analysis are outlined with consideration of an expanded role of HESs in fulfilling climate objectives.It is envisioned that like-minded decision makers in the industry sector and beyond will adopt this perspective and act synergistically to enhance their environmental stewardship through voluntary actions and make greater contributions to the planet's climate future.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2022

Deciphering the Distribution and Crystal-Chemical Environment of Arsenic, Lead, Silica, Phosphorus, Tin, and Zinc in a Porous Ferrihydrite Grain Using Transmission Electron Microscopy and Atom Probe Tomography

Here the interaction of contaminants and nutrients with soil constituents is controlled by processes in intergranular and intragranular pore spaces of organic matter or/and common secondary minerals such as ferrihydrite, ~Fe 3+ 10 O 14 (OH) 2 . This contribution shows that distribution and clustering of the contaminants As, P, Pb, Si, Sn, and Zn in a porous ferrihydrite grain is greatly affected by the heterogeneous size distribution and chemical composition of the pores as well as the ability of their polyhedra to polymerize with the same type of polyhedron. Transmission electron microscopy (TEM) and atom probe tomography (APT) studies are conducted on focused ion beam (FIB) sections extracted from a porous ferrihydrite grain from the smelter-impacted topsoil in Sudbury, Ontario, Canada. The ferrihydrite grain has pore spaces ranging in diameter from tens to hundreds of nanometers. TEM and scanning-TEM studies indicate that the surfaces of the pore walls are enriched in Si. APT data in conjunction with First Near Neighbor (1NN) analyses indicate different degrees of clustering of Pb, As, Sn, Zn, Si, and P within the sample and selected domains. Careful evaluations of 3D atomic plots and 1NN distances indicates the occurrence of polymerized arsenite-, silica-, Sn-, and Zn-polyhedra within pore spaces of the ferrihydrite. Deciphering adsorption, polymerization, and nucleation processes in porous Fe-(hydr)oxides and other soil constituents requires multianalytical approaches and, in this regard, we discuss the advantages and disadvantages of the combination of TEM and APT for characterizing complex environmental samples at the atomic to nanometer scale.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Microbial Community Composition in Deep‐Subsurface Reservoir Fluids Reveals Natural Interwell Connectivity

Abstract The identification of natural fractures and the wells they connect is crucial for the development of geological reservoirs because it may have an important impact on reservoir model construction and hydraulic fracture propagation. In this study we investigated the use of a novel data source, the microbial community composition in the reservoir formation fluids, for identification of interwell connectivity caused by natural fractures. We verified this concept at a newly developed mesoscale enhanced geothermal system (EGS) field testbed located 4,850 ft (1,478 m) beneath ground surface at the Sanford Underground Research Facility in Lead, SD. Fluids produced at or near the EGS testbed were sampled and subjected to high‐throughput 16S rRNA gene amplicon sequencing to analyze the microbial community profile therein. Despite the typically substantial heterogeneity across the community profiles of samples spatially distributed (10 m to 1.9 km apart) throughout the site, samples from two wells at the EGS testbed showed highly similar microbial community composition, suggesting the two wells intersected the same natural fracture. This evidence of natural connectivity between the two wells at the EGS testbed was later corroborated by core log analysis and sewer camera surveys into the boreholes. Besides the field case described in this study, microbial community composition as a reservoir diagnostic tool would be applicable in a much broader context such as unconventional hydrocarbon exploitation, groundwater reservoir characterization, and environmental remediation, adding valuable “hard” data capable of pinpointing the origins of fluids unambiguously.

Zhang, Yuran↗
DOE OSTI2022

Hyphae move matter and microbes to mineral microsites: Integrating the hyphosphere into conceptual models of soil organic matter stabilization

Associations between soil minerals and microbially derived organic matter (often referred to as mineral-associated organic matter or MAOM) form a large pool of slowly cycling carbon (C). Here, the rhizosphere, soil immediately adjacent to roots, is thought to control the spatial extent of MAOM formation because it is the dominant entry point of new C inputs to soil. However, emphasis on the rhizosphere implicitly assumes that microbial redistribution of C into bulk (non-rhizosphere) soils is minimal. We question this assumption, arguing that because of extensive fungal exploration and rapid hyphal turnover, fungal redistribution of soil C from the rhizosphere to bulk soil minerals is common, and encourages MAOM formation. First, we summarize published estimates of fungal hyphal length density and turnover rates and demonstrate that fungal C inputs are high throughout the rhizosphere–bulk soil continuum. Second, because colonization of hyphal surfaces is a common dispersal mechanism for soil bacteria, we argue that hyphal exploration allows for the non-random colonization of mineral surfaces by hyphae-associated taxa. Third, these bacterial communities and their fungal hosts determine the chemical form of organic matter deposited on colonized mineral surfaces. Collectively, our analysis demonstrates that omission of the hyphosphere from conceptual models of soil C flow overlooks key mechanisms for MAOM formation in bulk soils. Moving forward, there is a clear need for spatially explicit, quantitative research characterizing the environmental drivers of hyphal exploration and hyphosphere community composition across systems, as these are important controls over the rate and organic chemistry of C deposited on minerals.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1974

An overview of high temperature metal fatigue: Aspects covered by the 1973 International Conference on Creep and Fatigue

A summary of papers is presented which covers the following broad aspects of high temperature metal fatigue: (1) materials development and characterization; (2) environmental factors, including air, vacuum, helium, iodine, sodium, and radiation environments; (3) general fatigue life relationships; (4) crack growth laws; (5) design code activities; and (6) design and service experience. Illustrative tables accompany the summary.

Manson, S. S.↗
NASA NTRS1984

Evaluation of high temperature structural adhesives for extended service

High temperature stable adhesive systems were evaluated for potential Supersonic Cruise Research (SCR) vehicle applications. The program was divided into two major phases: Phase I 'Adhesive Screening' evaluated eleven selected polyimide (PI) and polyphenylquinoxaline (PPQ) adhesive resins using eight different titanium (6Al-4V) adherend surface preparations; Phase II 'Adhesive Optimization and Characterization' extensively evaluated two adhesive systems, selected from Phase I studies, for chemical characterization and environmental durability. The adhesive systems which exhibited superior thermal and environmental bond properties were LARC-TPI polyimide and polyphenylquinoxaline both developed at NASA Langley. The latter adhesive system did develop bond failures at extended thermal aging due primarily to incompatibility between the surface preparation and the polymer. However, this study did demonstrate that suitable adhesive systems are available for extended supersonic cruise vehicle design applications.

Hendricks, C. L.↗
NASA NTRS1985

High Temperature Polymer Matrix Composites

These are the proceedings of the High Temperature Polymer Matrix Composites Conference held at the NASA Lewis Research Center on March 16 to 18, 1983. The purpose of the conference is to provide scientists and engineers working in the field of high temperature polymer matrix composites an opportunity to review, exchange, and assess the latest developments in this rapidly expanding area of materials technology. Technical papers are presented in the following areas: (1) matrix development; (2) adhesive development; (3) characterization; (4) environmental effects; and (5) applications.

Source record↗
NASA NTRS1987

Nickel hydrogen low Earth orbit test program update and status

The current status of nickel-hydrogen (NiH2) testing ongong at NWSC, Crane In, and The Aerospace Corporation, El Segundo, Ca are described. The objective of this testing is to develop a database for NiH2 battery use in Low Earth Orbit (LEO) and support applications in Medium Altitude Orbit (MAO). Individual pressure vessel-type cells are being tested. A minimum of 200 cells (3.5 in diameter and 4.5 in diameter) are included in the test, from four U.S. vendors. As of this date (Nov. 18, 1986) approximately 60 cells have completed preliminary testing (acceptance, characterization, and environmental testing) and have gone into life cycling.

Badcock, C. C.↗
NASA NTRS1987

High temperature polymer matrix composites

These are the proceedings of the High Temperature Polymer Matrix Composites Conference held at the NASA Lewis Research Center on March 16 to 18, 1983. The purpose of the conference is to provide scientists and engineers working in the field of high temperature polymer matrix composites an opportunity to review, exchange, and assess the latest developments in this rapidly expanding area of materials technology. Technical papers are presented in the following areas: (1) matrix development; (2) adhesive development; (3) Characterization; (4) environmental effects; and (5) applications.

Serafini, Tito T.↗
NASA NTRS1997

Habitats and Surface Construction Technology and Development Roadmap

The vision of the technology and development teams at NASA Ames and Johnson Research Centers is to provide the capability for automated delivery and emplacement of habitats and surface facilities. The benefits of the program are as follows: Composites and Inflatables: 30-50% (goal) lighter than Al Hard Structures; Capability for Increased Habitable Volume, Launch Efficiency; Long Term Growth Potential; and Supports initiation of commercial and industrial expansion. Key Habitats and Surface Construction (H&SC) technology issues are: Habitat Shell Structural Materials; Seals and Mechanisms; Construction and Assembly: Automated Pro-Deploy Construction Systems; ISRU Soil/Construction Equipment: Lightweight and Lower Power Needs; Radiation Protection (Health and Human Performance Tech.); Life Support System (Regenerative Life Support System Tech.); Human Physiology of Long Duration Space Flight (Health and Human Performance Tech.); and Human Psychology of Long Duration Space Flight (Health and Human Performance Tech.) What is being done regarding these issues?: Use of composite materials for X-38 CRV, RLV, etc.; TransHAB inflatable habitat design/development; Japanese corporations working on ISRU-derived construction processes. What needs to be done for the 2004 Go Decision?: Characterize Mars Environmental Conditions: Civil Engineering, Material Durability, etc.; Determine Credibility of Inflatable Structures for Human Habitation; and Determine Seal Technology for Mechanisms and Hatches, Life Cycle, and Durability. An overview encompassing all of the issues above is presented.

Marc Cohen↗
NASA NTRS2001

Not Your Ordinary GEM

Through Small Business Innovation Research (SBIR) funding from NASA's Stennis Space Center, Geophex devised a new design for broadband electromagnetic sensors. Geophex developed a patented sensing technology, capable not only of coastal monitoring, but also a variety of other functions, including environmental pollution characterization, groundwater contamination detection, archaeological study, and mineral detection. The new technology is offered in several of the company's products the GEM-2, GEM-2A, and the GEM-3. The Geophex products consist of two primary electromagnetic coils, which are stimulated by alternating currents that generate a magnetic field in the object targeted for investigation. GEM-2 is a handheld, lightweight, programmable, digital device. GEM-2A is an airborne version of the sensor. Suspended from a helicopter, the GEM-2A is used to search for mineral deposits and to survey large tracts of land. The GEM-3 is capable of detecting buried landmines and other active munitions. GEM-3 identifies landmines by their brand names. Because each landmine has its own unique electromagnetic response to the broad frequency band emitted by the GEM-3, bomb identification and disposal strategies are made easier.

Source record↗
NASA NTRS2004

Development and Characterization of a Low-Pressure Calibration System for Hypersonic Wind Tunnels

Minimization of uncertainty is essential for accurate ESP measurements at very low free-stream static pressures found in hypersonic wind tunnels. Statistical characterization of environmental error sources requires a well defined and controlled calibration method. A calibration system has been constructed and environmental control software developed to control experimentation to eliminate human induced error sources. The initial stability study of the calibration system shows a high degree of measurement accuracy and precision in temperature and pressure control. Control manometer drift and reference pressure instabilities induce uncertainty into the repeatability of voltage responses measured from the PSI System 8400 between calibrations. Methods of improving repeatability are possible through software programming and further experimentation.

Green, Del L.↗
NASA NTRS2005

Mapping Weathering and Alteration Minerals in the Comstock and Geiger Grade Areas using Visible to Thermal Infrared Airborne Remote Sensing Data

To support research into both precious metal exploration and environmental site characterization a combination of high spatial/spectral resolution airborne visible, near infrared, short wave infrared (VNIR/SWIR) and thermal infrared (TIR) image data were acquired to remotely map hydrothermal alteration minerals around the Geiger Grade and Comstock alteration regions, and map the mineral by-products of weathered mine dumps in Virginia City. Remote sensing data from the Airborne Visible Infrared Imaging Spectrometer (AVIRIS), SpecTIR Corporation's airborne hyperspectral imager (HyperSpecTIR), the MODIS-ASTER airborne simulator (MASTER), and the Spatially Enhanced Broadband Array Spectrograph System (SEBASS) were acquired and processed into mineral maps based on the unique spectral signatures of image pixels. VNIR/SWIR and TIR field spectrometer data were collected for both calibration and validation of the remote data sets, and field sampling, laboratory spectral analyses and XRD analyses were made to corroborate the surface mineralogy identified by spectroscopy. The resulting mineral maps show the spatial distribution of several important alteration minerals around each study area including alunite, quartz, pyrophyllite, kaolinite, montmorillonite/muscovite, and chlorite. In the Comstock region the mineral maps show acid-sulfate alteration, widespread propylitic alteration and extensive faulting that offsets the acid-sulfate areas, in contrast to the larger, dominantly acid-sulfate alteration exposed along Geiger Grade. Also, different mineral zones within the intense acid-sulfate areas were mapped. In the Virginia City historic mining district the important weathering minerals mapped include hematite, goethite, jarosite and hydrous sulfate minerals (hexahydrite, alunogen and gypsum) located on mine dumps. Sulfate minerals indicate acidic water forming in the mine dump environment. While there is not an immediate threat to the community, there are clearly sources of acidic drainage that were identified remotely.

imaging spectroscopy↗
NASA NTRS2020

LCF Life of NiCr-Y Coated Disk Alloys After Shot Peening, Oxidation and Hot Corrosion

In a prior companion study (Ref. 1), three different Ni-Cr coating compositions (29, 35.5, 45 wt% Cr) were applied at two thicknesses by Plasma Enhanced Magnetron Sputtering (PEMS) to two similar Ni-based disk alloys. One coating also received a thin ZrO2 overcoat. The low cycle fatigue (LCF) life of each coating was determined at 760 °C and was less than that of the uncoated specimens. In this followon effort, shot peening was examined as a means to improve the as-deposited coating morphology as well as impart a residual compressive stress in the near-surface region. After evaluating the effect of the shot peening on the LCF life, the effectiveness of the shot-peened coating in protecting the disk alloy from oxidation and hot corrosion attack was evaluated. This evaluation was accomplished by exposing coated and shot-peened specimens to 500 h of oxidation followed by 50 h of hot corrosion, both at 760 °C in air. These exposed specimens were then tested in fatigue and compared to similarly treated and exposed uncoated specimens. For all cases, shot peening improved the LCF life of the coated specimens. More specifically, the highest Cr coating showed the best LCF life of the coated specimens after shot peening, as well as after the environmental exposures. Characterization of the coatings after shot peening, oxidation, hot corrosion and LCF testing is presented and discussed.

James A Nesbitt↗
NASA NTRS2021

Acoustic Sensor Network for Planetary Exploration

This paper investigates the concept of an acoustic sensor network that can monitor a variety of geophysical processes occurring on other planetary bodies. In many cases sound is naturally omnidirectional and travels at known speeds which depend on the composition and density of the atmosphere. The differences in the time of flight of signals received by a distributed microphone network can be used to locate the source of the sound. We suggest this property is ideal for mobile planetary robots and can be used to expand the exploration envelope considerably by directing camera pointing or rover path planning thus extending beyond line-of-sight exploration. Acoustic signatures have been used in a variety of fields (e.g., sonar, heavy machinery) to identify and catalog sounds associated with a specific vessels and malfunctioning machinery. Our ears have cataloged hundreds of sounds and we continuously use these sounds both consciously and subconsciously to extract information about our surroundings. This paper investigates the use acoustic measurements on other planetary bodies that could be used to characterize specific environmental parameters such as rain droplet size, wind speed, thunder, or dust devil vortex diameter. The paper identified other important sound sources that are thought to occur on other bodies in our solar system include; booming or singing dunes, waves, rivers, streams, fluidfalls, geysers, hurricanes, tornados, ice flow, volcanoes, planetary quakes, avalanche, rock slides and ice cracking. In addition, this paper focused on issues associated with the development of appropriate sensors for the network including the specification of the sensitivity, frequency response, and directional response of each of the microphones in the network in order to aid in localization of sound sources. We also presented our initial development of the transducers for potential mission targets including Mars and Titan and investigated the use of signal processing techniques including windowing, time frequency plots and correlation techniques to resolve phase differences between sensors in the network to aid in localization. We also identified additional benefits of these sensor networks in that they could used as engineering sensors to diagnose mechanical malfunctions on a rover or lander actuators or mechanisms. We also noted that they could also enhance public outreach by adding sound to videos.

Malaska, Mike↗
NASA NTRSDate not supplied

Combustion and Emissions Analysis of Alternatives

NASA’s Aeronautics Research Mission Directorate requested an analysis of alternatives (AoA) study on the following three competencies in 2020: subsonic transport acoustics, combustion and emissions, and aircraft icing. This presentation will address details specific to the combustion and emissions analysis of alternatives study. The basic process used for during the AoA study in shown in Figure 1. Figure 1. Flow chart of the Analysis of Alternative process used in this study. The combustion study team was multidisciplinary, including a wide range perspectives and areas of expertise. Inputs were collected from within NASA and a wide range of external stakeholders, including aircraft engine companies, aircraft airframe companies and other government agencies. Eight future realities for aviation were developed in preparation for the applying the AoA process, such as future realities with increased or decrease airline traffic, greater emissions stringency, or a revolution in energy infrastructure (such as hydrogen usage). Based on the inputs collected, over seventy technical elements applicable to combustion and emissions research were developed. To rank the importance of these technical elements for each future reality, a set of evaluation criterion were developed that can be generally characterized as environmental impacts, technologies enabling reduced fuel burn, and elements requiring significant NASA involvement or having significant industry pull. Using in-house codes to apply the TOPSIS (Technique for Order Preference by Similarity to Ideal Solution) methodology, as well performing consistency checks and other analysis by the study team, a ranked set of technical elements was generated. Several research needs were identified and analyzed to determine the highest priorities for potential research by NASA in the combustion and emissions area. Results from the study will be presented.

combustion↗