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At least 91 records · Page 5

Degradation of Organics in a Glow Discharge Under Martian Conditions

The primary objective of this project is to understand the consequences of glow electrical discharges on the chemistry and biology of Mars. The possibility was raised some time ago that the absence of organic material and carbonaceous matter in the Martian soil samples studied by the VikinG Landers might be due in part to an intrinsic atmospheric mechanism such as glow discharge. The high probability for dust interactions during Martian dust storms and dust devils, combined with the cold, dry climate of Mars most likely results in airborne dust that is highly charged. Such high electrostatic potentials generated during dust storms on Earth are not permitted in the low-pressure CO2 environment on Mars; therefore electrostatic energy released in the form of glow discharges is a highly likely phenomenon. Since glow discharge methods are used for cleaning and sterilizing surfaces throughout industry, the idea that dust in the Martian atmosphere undergoes a cleaning action many times over geologic time scales appears to be a plausible one.

Hintze, P. E.

Photoelectron Effects on the Self-Consistent Potential in the Collisionless Polar Wind

The presence of unthermalized photoelectrons in the sunlit polar cap leads to an enhanced ambipolar potential drop and enhanced upward ion acceleration. Observations in the topside ionosphere have led to the conclusion that large-scale electrostatic potential drops exist above the spacecraft along polar magnetic field lines connected to regions of photoelectron production. A kinetic approach is used for the O(+), H(+), and photoelectron (p) distributions, while a fluid approach is used to describe the thermal electrons (e) and self-consistent electric field (E(sub II)) electrons are allowed to carry a flux that compensates for photoelectron escape, a critical assumption. Collisional processes are excluded, leading to easier escape of polar wind particles and therefore to the formation of the largest potential drop consistent with this general approach. We compute the steady state electric field enhancement and net potential drop expected in the polar wind due to the presence of photoelectrons as a function of the fractional photoelectron content and the thermal plasma characteristics. For a set of low-altitude boundary conditions typical of the polar wind ionosphere, including 0.1% photoelectron content, we found a potential drop from 500 km to 5 R(sub E) of 6.5 V and a maximum thermal electron temperature of 8800 K. The reasonable agreement of our results with the observed polar wind suggests that the assumptions of this approach are valid.

Khazanov, G. V.

Discrete-Layer Piezoelectric Plate and Shell Models for Active Tip-Clearance Control

The objectives of this work were to develop computational tools for the analysis of active-sensory composite structures with added or embedded piezoelectric layers. The targeted application for this class of smart composite laminates and the analytical development is the accomplishment of active tip-clearance control in turbomachinery components. Two distinct theories and analytical models were developed and explored under this contract: (1) a discrete-layer plate theory and corresponding computational models, and (2) a three dimensional general discrete-layer element generated in curvilinear coordinates for modeling laminated composite piezoelectric shells. Both models were developed from the complete electromechanical constitutive relations of piezoelectric materials, and incorporate both displacements and potentials as state variables. This report describes the development and results of these models. The discrete-layer theories imply that the displacement field and electrostatic potential through-the-thickness of the laminate are described over an individual layer rather than as a smeared function over the thickness of the entire plate or shell thickness. This is especially crucial for composites with embedded piezoelectric layers, as the actuating and sensing elements within these layers are poorly represented by effective or smeared properties. Linear Lagrange interpolation polynomials were used to describe the through-thickness laminate behavior. Both analytic and finite element approximations were used in the plane or surface of the structure. In this context, theoretical developments are presented for the discrete-layer plate theory, the discrete-layer shell theory, and the formulation of an exact solution for simply-supported piezoelectric plates. Finally, evaluations and results from a number of separate examples are presented for the static and dynamic analysis of the plate geometry. Comparisons between the different approaches are provided when possible, and initial conclusions regarding the accuracy and limitations of these models are given.

Heyliger, P. R.

Electrostatic disruption of a charged conducting spheroid

Electrostatic disruption of elongated parent grains following sudden charging to high electrostatic potentials is proposed as a specific mechanism for the appearance of striae or pseudosynchronic bands which have been observed in several comets. The polar and equatorial electrostatic tension for axis ratios between 0.01 and 1000 are calculated, and the polar pressure is found to be larger than the equatorial pressure for prolate spheroids. The electrostatic polar pressure profile along the polar axis for prolate spheroids is calculated, and the pressure is found to increase monotonically from a minimum at the center to a maxima at the ends. This indicates that as a prolate spheroid of uniform tensile strength is charged up, it will continue to chip off at the ends when the electrostatic pressure there exceeds the uniform tensile strength of the grain. The result can be a prolate grain or a grain which continues chipping until it explodes.

Hill, J. R.

Electrostatic dry powder prepregging of carbon fiber

Ultrafine, 5-10 micron polymer-matrix resin powders are directly applied to carbon fiber tows by passing then in an air or nitrogen stream through an electrostatic potential; the particles thus charged will strongly adhere to grounded carbon fibers, and can be subsequently fused to the fiber in a continuously-fed radiant oven. This electrostatic technique derived significant end-use mechanical property advantages from the obviation of solvents, binders, and other adulterants. Additional matrix resins used to produce prepregs to date have been PMR-15, Torlon 40000, and LaRC TPI.

Throne, James L.

Steady-State Solution of a Solar Wind-Generated Electron Cloud in a Lunar Crater

We formulate an analytic description of a steady-state electron cloud and affiliated surface charge, formed in the plasma wake generated as the solar wind flows horizontally over a lunar crater. The solution is complementary to the well-known self-similar plasma expansion formulation, which breaksdown at the plasma wake front and thus fails to capture a substantial region of the crater interior. The present model establishes a theoretical basis for existing simulation results, which suggest that the cavity formed below the wake front is populated mainly by electrons, resulting in a substantial negative surface charge. The electrostatic potential throughout this subwake region is determined by solving Poisson'sequation for a Maxwellian electron cloud, bounded above by the self-similar plasma expansion front and below by the electrostatically charged surface.

Rhodes, Dov J.

Evaluating the De Hoffmann-Teller Cross-Shock 2 Potential at Real Collisionless Shocks

Shock waves are common in the heliosphere and beyond. The collisionless nature of most astrophysical plasmas allows for the energy processed by shocks to be partitioned amongst particle sub-populations and electromagnetic fields via physical mechanisms that are not well understood. The electrostatic potential across such shocks is frame dependent. In a frame where the incident bulk velocity is parallel to the magnetic field, the deHoffmann-Teller frame, the potential is linked directly to the ambipolar electric field established by the electron pressure gradient. Thus measuring and understanding this potential solves the electron partition problem, and gives insight into other competing shock processes. Integrating measured electric fields in space is problematic since the measurements can have offsets that change with plasma conditions. The offsets, once integrated, can be as large or larger than the shock potential. Here we exploit the high-quality field and plasma measurements from NASA’s Magnetospheric Multiscale mission to attempt this calculation. We investigate recent adaptations of the deHoffmann-Teller frame transformation to include time variability, and conclude that in practice these face difficulties inherent in the 3D time-dependent nature of real shocks by comparison to 1D simulations. Potential estimates based on electron fluid and kinetic analyses provide the most robust measures of the deHoffmann-Teller potential, but with some care direct integration of the electric fields can be made to agree. These results suggest that it will be difficult to independently assess the role of other processes, such as scattering by shock turbulence, in accounting for the electron heating.

Steven J Schwartz

The Spacecraft Potential of Wind Over Time

In a space plasma, exposed to ionizing radiation, a conducting object like a spacecraft will generate a net charge as the relevant currents from the plasma and photoelectrons attempt to reach equilibrium over time. This net charging is measured (or inferred from particle measurements) as an electrostatic potential, called the spacecraft potential. The Wind spacecraft will be 30 years old on November 1, 2023 and as such, has one of the longest baselines of continuous spacecraft potential measurements of any space mission. We determine the spacecraft potential from observations of photoelectrons in the thermal particle data. We examine the variations over time finding oscillations that correlate with solar rotation. This preliminary study examines for other effects but is ultimately for the purpose of generating a properly calibrated velocity moment dataset for the entire Wind mission.

Lynn B. Wilson III

Pyrotechnic hazards classification and evaluation program. Electrostatic vulnerability of the E8 and XM15/XM165 clusters, phase 2

An investigation into the electrostatic phenomena associated with the manufacturing and handling of explosives is discussed. The testing includes measurement of the severity of the primary charge generation mechanism, triboelectric effects between dissimilar surfaces; refinement of equivalent circuits of the XM15/XM165 and E8 fuse trains; evaluation of the electrostatic spark discharge characteristics predicted by an equivalent circuit analysis; and determination of the spark ignition sensitivity of materials, components, junctions, and subassemblies which compose the XM15/XM165 and E8 units. Special studies were also performed. These special tests included ignition sensitivity of the complete XM15 fuse train when subjected to discharges through its entire length, measurement of electrostatic potentials which occur during the E8 foaming operation during fabrication, and investigation of the inadvertent functioning of an XM15 cluster during manufacturing. The test results are discussed and related to the effectiveness of suggested modification to reduce the electrostatic ignition sensitivity.

Source record

On the origin of striae in cometary dust tails

It has been argued by Sekanina that the so-called striae or pseudo-synchronic bands observed in the dust tails of several comets are a consequence of the sudden disruption of elongated or chainlike parent grains in the tail. The present paper offers a specific mechanism for this disruption process, that is, electrostatic disruption following sudden charging to high electrostatic potentials. Assuming the grains to be prolate spheroids, it is shown that they can attain potentials in the range -60 V to -300 V when subject to energetic electron beams (1-10 keV). The energy source for these electrons is the interaction of the solar wind with the cometary ionosphere producing currents and associated electrostatic double layers.

Hill, J. R.

A satellite investigation of energy flux and inferred potential drop in auroral electron energy spectra

The relationship between auroral electron energy flux and the inferred accelerating potential drop for accelerated Maxwellian distributions is investigated on the basis of Atmospheric Explorer D spectral measurements. An analytical approximation for the total downward energy flux carried by an isotropic Maxwellian electron population accelerated by a field-aligned electrostatic potential drop is derived which is valid for values of the electron energy/characteristic accelerated Maxwellian distribution energy which are less than the difference between the ratio of the magnetic field strengths at the altitude of observation and the altitude of potential drop, and unity. Data from the Low Energy Electron Experiment on board AE D obtained on both the dayside and the nightside during periods of significant inverted-V type electron precipitation shows that the 455 energy spectra considered, 160 of them, obtained between 60 and 85 deg invariant latitude, could be fit to accelerated Maxwellian distributions. The 160 Maxwellian spectra are then shown to be in agreement with the predictions of the accelerated Maxwellian model. Finally, analysis of individual spectra suggests that the altitude of the inferred potential drop is at a maximum near the center of the inverted-V structures.

Menietti, J. D.

Surface potential of the water liquid-vapor interface

An analysis of an extended molecular dynamics calculation of the surface potential (SP) of the water liquid-vapor interface is presented. The SP predicted by the TIP4P model is -(130 + or - 50) mV. This value is of reasonable magnitude but of opposite sign to the expectations based on laboratory experiments. The electrostatic potential shows a nonmonotonic variation with depth into the liquid.

Wilson, Michael A.

Potential drops above pulsar polar caps - Ultrarelativistic particle acceleration along the curved magnetic field

The paper calculates the acceleration of a nonneutral stream of charged particles from the surface of an isolated rotating magnetized neutron star in the case where the particle stream flows along the open field lines of a curved poloidal magnetic field. It is shown that very large electrostatic potential drops can occur in steady unidirectional space-charge-limited flow along the curved open field lines. The explicit incorporation of magnetic field line curvature is the essential element leading to this new result, assuming that all the charges are supplied by emission from the surface. It is emphasized that the current flow and charge density are unique if all of the assumptions are met, with the result that the accelerating electric field near the stellar surface is quite small compared to the vacuum field.

Scharlemann, E. T.

Direct comparison of gyrokinetic and fluid scrape-off layer simulations

Typically, fluid simulations are used for tokamak divertor design. However, fluid models are only valid if the scrape-off layer (SOL) is highly collisional. This assumption is valid in many present-day experiments but is questionable in the upstream SOL of some high-power scenarios envisioned for burning plasmas and fusion pilot plants. This paper reports on comparisons between fluid and kinetic simulations of the SOL for upstream parameters and geometry representative of the Spherical Tokamak for Energy Production fusion pilot plant. The SOLPS-ITER (fluid) and Gkeyll (gyrokinetic) codes are operated in a two-dimensional axisymmetric mode, which replaces turbulence with ad-hoc diffusivities. In kinetic simulations, we observe that the ions in the upstream SOL experience significant mirror trapping. This substantially increases the upstream temperature and has important implications for impurity dynamics. We show that the mirror force, which is excluded in SOLPS’s fluid equations, enhances the electrostatic potential drop along the field line in the SOL. We also show that the assumption of equal main ion and impurity temperatures, which is made in commonly used fluid codes, is invalid for the regimes explored here. The combination of these effects results in superior confinement of impurities to the divertor region in kinetic simulations, consistent with our earlier predictions [Kotschenreuther et al., in 29th IAEA 29 Fusion Energy Conference (IAEA, London, UK, 2023)]. This effect can be dramatic, reducing the midplane impurity density by orders of magnitude. These results indicate that in lower collisionality SOL’s the tolerable downstream impurity densities may be higher than would be predicted by fluid simulations, allowing for higher radiated power while avoiding unacceptable core contamination. Our results highlight the importance of kinetic simulations for divertor design and optimization for fusion pilot plants.

Computational fluid dynamics

Next-Generation Microshutter Arrays for Large-Format Imaging and Spectroscopy

A next-generation microshutter array, LArge Microshutter Array (LAMA), was developed as a multi-object field selector. LAMA consists of small-scaled microshutter arrays that can be combined to form large-scale microshutter array mosaics. Microshutter actuation is accomplished via electrostatic attraction between the shutter and a counter electrode, and 2D addressing can be accomplished by applying an electrostatic potential between a row of shutters and a column, orthogonal to the row, of counter electrodes. Microelectromechanical system (MEMS) technology is used to fabricate the microshutter arrays. The main feature of the microshutter device is to use a set of standard surface micromachining processes for device fabrication. Electrostatic actuation is used to eliminate the need for macromechanical magnet actuating components. A simplified electrostatic actuation with no macro components (e.g. moving magnets) required for actuation and latching of the shutters will make the microshutter arrays robust and less prone to mechanical failure. Smaller-size individual arrays will help to increase the yield and thus reduce the cost and improve robustness of the fabrication process. Reducing the size of the individual shutter array to about one square inch and building the large-scale mosaics by tiling these smaller-size arrays would further help to reduce the cost of the device due to the higher yield of smaller devices. The LAMA development is based on prior experience acquired while developing microshutter arrays for the James Webb Space Telescope (JWST), but it will have different features. The LAMA modular design permits large-format mosaicking to cover a field of view at least 50 times larger than JWST MSA. The LAMA electrostatic, instead of magnetic, actuation enables operation cycles at least 100 times faster and a mass significantly smaller compared to JWST MSA. Also, standard surface micromachining technology will simplify the fabrication process, increasing yield and reducing cost.

Moseley, Samuel

pyEF: A Python Framework for QM and QM/MM Atom-Wise Electric Field Analysis

We introduce pyEF, a software package for computing molecular electric fields, electrostatic interaction energies, and electrostatic potentials from quantum mechanical (QM) atom-centered multipole expansions with atom-wise decomposable contributions. We demonstrate the computational efficiency and accuracy of this QM-derived electric field evaluation tool through several tests. To assess the influence of the underlying QM method and charge partitioning scheme on these electrostatic quantities, we analyze over 250 configurations of an acetone solute molecule in five solvents of variable polarity. We find that electric field calculations are highly sensitive to the choice of charge partitioning method. Even among real-space charge schemes, acetone Stark tuning rates differ by up to a factor of 2. Benchmarking computed solvent dipole moments against experimental bulk values, we conclude that the CM5, ADCH, and Hirshfeld-I charge schemes most reliably capture solvent electrostatics and therefore provide a more faithful foundation for computing electric fields. When constructed from these real-space charges, electric fields are nearly insensitive to basis set size and monotonically increase in magnitude with higher Fock exchange. We also demonstrate efficient convergence of QM electrostatics when more distant molecules are represented solely by MM point charges, reducing computational overhead. Leveraging these findings, we demonstrate the use of pyEF to deduce environmental effects on a transition metal complex from a Ga 4 L 6 12– nanocage and quantify the dominant role of organic linkers in orchestrating electrostatic preorganization.

electric fields

Observations of inverted-V electron precipitation

The energy and pitch angle distributions of inverted-V electron precipitation fluxes predominantly determined from Atmosphere Explorer satellite observations are shown to be in general agreement with acceleration by a parallel electrostatic potential. The characteristics of secondary electrons are examined, and the effects of beam plasma instabilities on these electrons are discussed. It is found that plasma sheet electrons are continuously accelerated to form inverted-V structures in the premidnight hemisphere, independent of substorm phase. The acceleration processes are probably related to large scale, electrostatic wave turbulence observed at altitudes of a few thousands km. It is suggested that narrow bursts of intense electron precipitation possess characteristics which may cause auroral arcs in the atmosphere.

Lin, C. S.

Electron heating and the potential jump across fast mode shocks

Two different methods were applied to determine the cross-shock potential jump in the de Hoffmann-Teller reference frame, using a data set that represented 66 crossings of the terrestrial bow shock and 14 interplanetary shocks observed by various ISEE spacecraft, and one crossing each of the Jovian bow shock and the Uranian bow shock made by the Voyager spacecraft. Results for estimates of the electrostatic potential based on an estimate of the jump in electron enthalpy correlated well with estimates based on Liouville's theorem, although the Liouville-determined values were systematically the higher of the two, suggesting that significant irreversible processes contribute to the shape of the downstream distribution. The potential jump corresponds to approximately 12-15 percent of the incident ion ram kinetic energy, and was found not to be controlled by the Mach number, plasma beta, shock geometry, or electron to ion temperature ratios.

Schwartz, Steven J.