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At least 91 records · Page 5

Electron scattering by highly polar molecules. I - KI

Electron-impact energy-loss spectra of KI were studied experimentally in the 15- to 130-deg angular range at impact energies of 6.7, 15.7, and 60 eV. The spectra reveal a number of excitation features which have not been detected previously and indicate that KI is a strong photon absorber in the vacuum-UV region. From the spectra, differential and integral electronically elastic and inelastic cross sections have been obtained by normalizing the experimental data to theoretical results at low scattering angles. Rotational excitation cross sections corresponding to delta j = 0, plus or minus 1, have been calculated using a dipole-plus-repulsive-core interaction potential and the distorted-wave approximation. For comparison, the rotational excitation cross sections have also been calculated in the Born point-dipole approximation.

Rudge, M. R. H.↗

SCF treatment of charge polarization effects in intermediate-energy electron scattering calculations with applications to N2

Converged rotational close coupling calculations of differential, integral, and momentum-transfer cross sections are obtained for seven model potentials for electron-N2 scattering at an impact energy of 30 eV. The model potentials involve a static potential calculated by the INDO/1s or INDOXI/1s method, and exchange potential calculated by the semiclassical exchange approximation from the INDO/1s or INDOXI/1s unperturbed electron density and a polarization potential. The polarization potentials used include the Buckley-Burke semiempirical one and various modifications of the INDOXI and INDO SCF (self-consistent-field) adiabatic polarization potentials. Without adjustment of parameters, good agreement is obtained with the angle dependence of the experimentally measured sum of the elastic and rotational excitation differential cross sections; however, the absolute value of the calculated cross sections is about 20-30% larger than the measured values in the best case, perhaps indicating that the model potentials are too strong or should have a nonzero imaginary part.

Onda, K.↗

A study of pseudoresonances in the application of the Schwinger variational principle to electron scattering from atomic hydrogen

The Schwinger variational principle is applied to s-wave electron-hydrogen atom scattering. Computationally, consistent with a recent paper by Apagyi et al. (1988), there are pseudoresonances at the static exchange level of approximation, but not at the static level. The T-matrix as well as the K-matrix version of the Schwinger principle is used with a real Slater basis, and the same results are obtained in both. The origin of the pseudoresonances from singularities in the separable potential that is effectively employed in the Lippman-Schwinger equation from which the Schwinger variational principle can be derived. The determination of the pseudoresonance parameters from the separable potential is computationally inexpensive and may be used to predict the pseudoresonance parameters for the scattering calculations so as to avoid them.

Weatherford, Charles A.↗

Electron scattering by laser-excited barium atoms

Inelastic and superelastic scattering of 30- and 100-eV electrons by laser-excited 6s 6p 1P and subsequent cascade-populated 6s 6p 3P, 6s 5d 1D, and 6s 5d 3D Ba atoms have been observed. Absolute differential cross sections for the singlet and relative scattering intensities for the triplet species have been determined in the 5 to 20 deg angular region. Under the present conditions excitations dominate over deexcitations.

Register, D. F.↗

Absolute elastic differential electron scattering cross sections in the intermediate energy region. IV - CO

Using a crossed electron beam-molecular beam scattering geometry and a relative-flow technique, ratios of elastic differential cross sections of CO to those of He have been measured at electron impact energies of 3, 5, 7.5, 9.9, 15, 20, 30, 50, 75, and 100 eV. At each energy, an angular range of 15 to 130 deg has been covered. These ratios have been multiplied by previously known He elastic differential cross sections to obtain elastic differential cross sections for CO. Since pure rotational excitations were not resolved, the elastic differential cross sections are a sum of elastic and pure rotational excitations at room temperature. From a knowledge of differential cross sections (DCS), integral and momentum transfer cross sections have been calculated. Both the DCS and integral cross sections are compared at 50, 75, and 100 eV to a recent two-potential theory of e-molecule scattering. Present results show that the isoelectronic molecules CO and N2 have very similar magnitudes and shapes of their differential cross sections.

Tanaka, H.↗

Calculation of a mirror asymmetric effect in electron scattering from chiral targets

A dynamical calculation is presented of the helicity induced in an initially unpolarized electron beam after elastic scattering from an optically active medium, a process analogous to the circular polarization induced in unpolarized light following Rayleigh scattering from chiral targets. The calculation is based on the bound helical electron model of a chiral molecule, according to which the major contribution to the helicity is provided by the perturbation of the electron bound state by the spin-orbit interaction of the bound electrons moving in the electric field of the molecular core. The net helicity acquired is found to depend directly on a molecular asymmetry factor and the square of the atomic number of the heaviest atom in an asymmetric environment. For the case of carbon, the induced helicity is on the order of 0.00001, which would account for its lack of observation in a recent experiment. Results may have implications for the origin of optical activity in biological molecules by the differential ionization of D and L isomers by beta-decay electrons.

Rich, A.↗

Elastic and inelastic electron scattering at 20 and 60 eV from atomic Cu

Normalized differential and integral electron-impact cross sections are presented for elastic scattering and for specified excitation levels of atomic copper at 20 and 60 eV. For some excitation levels, an unexpectedly large cross section was found, which at certain angular and energy ranges surpasses the cross section for elastic scattering.

Williams, W.↗

Energetic electron scattering from the lunar remanent magnetic field

Description of a new technique for the detection of surface remanent magnetic fields from lunar orbiting spacecraft. Energetic (approximately 14-keV) electrons in the particle population surrounding the moon are observed by the Apollo 15 and 16 Subsatellite particle experiments to be scattered back up from the lunar surface by remanent magnetic fields. The regions of intense lunar remanent magnetization discovered by the Apollo 15 and 16 Subsatellite magnetometers are observed to strongly scatter the 14-keV electrons. In addition, several previously unreported regions of surface remanent magnetization on the lunar near-side are evident from the electron observation.

Howe, H. C.↗

Positronium and Electron Scattering on Helium

A recent work [1] establishes experimentally that Positronium scattering by atoms of various elements is surprisingly close in total cross-section to that of an isolated electron of the same velocity. In this work we will look at the scattering of Ps on Helium and compare it to a determination of the scattering of an e- with the same element. For both the Ps scattering and the e- scattering on He, we assume the symmetrization of the e- with the closed shell He electrons is the dominant interaction. A local effective potential employed in [2] and [3] is used to model the electron exchange and cross- sections are determined for a set of partial waves. For the Ps scattering we include as a secondary effect the Van der Waals interaction. For single e- scattering of He, we also employ a short range Coulomb potential and dispersion as contributing effects. Results of the cross-sections determined in each case are then compared

DiRienzi, Joseph↗

Absolute Inelastic Differential Electron Scattering Cross Sections for He, Xe, N2, and CO at Near Threshold Impact Energies for 90(deg) Scattering Angle

There is a great deal of need for accurate differential cross sections (DCSs) associated with electron impact excitation of various atomic and molecular species. These cross sections are needed for modeling of various plasma systems (ranging from lasers and material processing plasmas to planetary and astrophysical plasmas) and for guiding development of theoretical and computational schemes.

DCS beam scattering beam-beam scattering↗

Level shifts and inelastic electron scattering in dense plasmas

A completely quantum mechanical formalism has been developed to describe the high density plasma effects on fundamental atomic parameters. Both the bound and free electrons are treated by a method which in principle is similar to Hartree's self-consistent field method. The free plasma electrons' wavefunction is obtained from the Schroedinger equation with the effective potential representing the spherically averaged Coulomb interaction with bound and free electrons. Results are given for level shifts, coefficients of transition probabilities, and electron collision cross sections of Ne(9+) for temperatures of 200 and 500 eV for an electron density range of 1-6 x 10 to the 24th per cu cm.

Davis, J.↗