Electron probe microanalyses of minerals and glasses in Apollo 11 lunar samples
Apollo 11 lunar igneous rocks minerals and glassy phases characteristics, using electron probe microanalysis
Lovering, J. F.↗
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Mineralogy and petrology of some Apollo 11 igneous rocks
Apollo 11 lunar igneous rock mineralogy and petrology, emphasizing ferrobasalt minerals microanalysis electron probe
Bottinga, Y.↗
Cu-Ni diffusion - Electron microprobe study of effects of voids and discontinuities
Cu-Ni diffusion couples voids and edges effect on concentration gradients measurement by electron probe microanalysis
Lewis, B. W.↗
Mineralogy and petrology of some Apollo 11 igneous rocks
Electron probe microanalysis of minerals of lunar igneous rocks from Apollo 11 flight
Bottinga, Y.↗
Methods of analyzing microsize particulate aerosols and contaminants.
Methods for analyzing atmospheric aerosols and particulate contaminants from natural and industrial sources are briefly described. Their development was spurred by interest in cosmic dust investigations. These methods make it possible to analyze individual particles ranging in size from 0.01 to 1000 microns for elemental and mineralogical content. The described methods include transmission electron microscopy, scanning electron microscopy, electron probe microanalysis, X-ray diffraction, optical mineralogy, and density measurement.
Blanchard, M. B.↗
Lunar polymict breccia 14321 - A petrographic study
A detailed description is given of the petrology and mineralogy of lunar polymict breccia 14321, which was returned from the Fra Mauro formation on the Apollo 14 mission. Electron probe microanalysis and microscopic studies were made of seven petrographic thin sections of the rock. Three broad genetic classes were found in the thin sections: (1) rounded fragments of pre-existing microbreccia with microscopically recognizable crystal and lithic fragments incorporated in a dark matrix; (2) igneous rock fragments of basaltic composition; and (3) a light colored, somewhat friable matrix which cements the other two classes. The components are classified according to chemical, mineralogical textural, and chronological criteria.
Grieve, R. A.↗
Structure and properties of solid surfaces
Difficulties in experimental studies of crystalline surfaces are related to the fact that surface atoms have an intrinsic tendency to react with their environment. A second problem is connected with the effective thickness of surfaces, which ranges from one to several atom layers. The phenomenology of surface interactions with gases are considered, taking into account physical adsorption, chemisorption, and the oxidation of surfaces. Studies of the surface structure are discussed, giving attention to field emission microscopy, field-ion microscopy, electron diffraction techniques, Auger spectroscopy, scanning electron microscopy, electron probe microanalysis, ion microprobe methods, and low-energy backscattering spectroscopy. Investigations of semiconductor surfaces are also described.
Gatos, H. C.↗
Cathodoluminescence of Al/x/Ga/1-x/As grown by liquid-phase epitaxy
Small-area contrast fluctuations observed in cathodoluminescence-mode SEM images of thin Al(x)Ga(1-x)As layers grown by liquid-phase epitaxy on GaAs:Cr substrates are attributed to local variations in alloy composition. Quantitative estimates of the composition excursions are obtained from the variations in CL intensity by calibration against compositions known from electron-probe microanalysis. In a typical sample, the CL variations are shown to correspond to peak-to-peak fluctuations of about 1 at. % of Al and occur over irregular regions generally in the range 6-20 microns in diameter.
Levin, E. R.↗
Provenance of Apollo 15 deep drill core sediments
Modal analysis and electron probe microanalysis were performed on polished thin sections prepared from Apollo 15 deep drill core soils in an effort to characterize their provenance. The particles were in the 0.25-1.00 mm size range. The particles were classified into mineral fragments, agglutinates, glasses, rock fragments, and breccias. The results show that highland and mare material occur in the core in an approximately 60:40 ratio, with mare component generally increasing from bottom to top in the core. Quartz-normative basalts are nearly twice as abundant as olivine basalts. Nonmare sources include KREEP basalt flow units from some depth in the crust, excavated by cratering events and supplied to the site as 'rays'.
Basu, A.↗
Petrography of lunar soil 15601
Lunar soil 15601 has been studied petrographically using grain size analysis, modal analysis, and electron probe microanalysis of monomineralic fragments in the 90-150-micron size fraction. The soil is immature; the grain size distribution is unimodal and very symmetrical, indicating that the soil is a homogeneous product of a single set of processes. It is concluded that 15601 is mostly a simple Apollo 15 mare basalt soil, and its properties can be used to approximate an end product of the array of complex soils that the lunar sample missions have returned.
Basu, A.↗
Mineral chemistry and origin of spinel-rich inclusions in the Allende CV3 chondrite
The present electron probe microanalysis of 20 spinel-rich inclusions in Allende indicates that the mineralogy of spinel-rich Allende inclusions is similar to that of fine grained Ca, Al-rich inclusions (CAIs) in ALH-77003 and rims on coarse grained CAIs in Allende. The mineralogy, mineral chemistry, and bulk chemistry of the inclusions indicate that they are not primitive aggregates of crystalline nebular condensates, but rather aggregates of minute concentric objects that are presently interpreted to be a fractionated distillation residue that lost Ca, Si-rich partial melt. It is suggested that interstellar dust aggregates were melted or distilled into Allende inclusions by aerodynamic drag heating, in regions of the nebula where the dust/gas ratio was so enhanced that the local oxygen fugacity was raised by several order of magnitude and liquids became thermodynamically stable.
Kornacki, A. S.↗
Antarctic Meteorite Newsletter, volume 9, no. 2
Preliminary description and classifications of meteorites that were completed since publication of the February issue are contained. Most large (greater than 150 g) specimens (regardless of petrologic type) and all pebble sized (less than 150 g) specimens of special petrologic type are represented by separate descriptions. However, specimens of nonspecial petrologic type are listed only as single line entries. For convenience, new specimens are also recast by petrologic type. Each macroscopic description summarizes features that were visible to the eye at the time the meteorite was first examined. Classification is based on microscopic petrography and resonnaissance-level electron-probe microanalysis. The pairing list was updated.
Gooding, J. L.↗
The interface in tungsten fiber reinforced niobium metal-matrix composites
The creep resistance of tungsten fiber reinforced niobium metal-matrix composites was evaluated. The interface region between the fiber and matrix was characterized by microhardness and electron probe microanalysis measurements which indicated that its properties were between those of fiber and matrix. However, the measured properties of the composite exceeded those calculated by the rule of mixtures even when the interface zone was assumed to retain all the strength of the fiber. The composite structure appeared to enhance the strengths of both the fibers and the matrix above what they exhibited in stand-alone tests. The effect of fiber orientation and matrix alloy composition on the fiber/matrix interface were also evaluated. Small alloying additions of zirconium and tungsten to the niobium matrix affected the creep resistance of the composites only slightly. A decrease in the creep resistance of the composite with increasing zirconium content in the matrix was ascribed to an increase in the diffusion rate of the fiber/matrix interdiffusion reaction, and a slight increase in the creep resistance of the composite was observed with an addition of 9 w percent tungsten to the matrix. In addition, Kirkendall void formation was observed at the fiber/matrix interface; the void distribution differed depending on the fiber orientation relative to the stress axis.
Grobstein, Toni L.↗
Petrology and provenance of Apollo 15 drive tube 15007/8
The petrology of submillimeter fractions of soils from 13 levels of Apollo 15 drive tube 15007/8 have been studied through grain size analysis, modal analysis of the 90-150 micron sieve fraction, and electron probe microanalysis of monomineralic fragments of olivine, pyroxene, and plagioclase from the soils. It is shown that core 15007/8 does not contain distinct lithologic units and probably contains soils of mixed maturity in which mixing has greatly dominated in situ reworking. No petrologic layering is found in the core. Abundances of KREEP basalts correlate with mare basalts and not with anorthosite, norite, and troctolite components from the Apennine Front. Some olivine and pyroxene fragments with mare basalt affinity are found to be optically and chemically unzoned, suggesting that they may have been derived from unusual source rocks.
Basu, Abhijit↗
Surface migration and volume diffusion in the AgGaSe2-Ag2Se system
Surface migration and volume diffusion in the Ag2Se-AgGaSe2 system were investigated using reactive diffusion couples which were analyzed by X-ray diffraction, optical microscopy, and electron probe microanalysis. The surface diffusivities of all mobile species are found to be much larger than volume diffusivities. The results of the study suggest that Se moves together with Ag and Ga to maintain binary (Ag2Se and Ga2Se3) stoichiometry and electroneutrality. The dominance of surface migration kinetics can account for the uniform annihilation of second-phase precipitates during heat treatments.
Kim, N.-H.↗
Microstructural evolution of NARloy-Z at elevated temperatures
Microstructural evolution was studied in samples of wrought and vacuum plasma sprayed (VPS) NARloy-Z exposed to temperatures up to 970 C (1,780 F) for up to 60 h. Samples were heated in a vacuum furnace, followed by rapid quenching in helium (He) gas at a cooling rate of 166 C (300 F) per second. Microstructural analyses were conducted using optical microscopy, scanning electron microscopy (SEM), and electron probe microanalysis (EPMA). In both the wrought and VPS conditions, precipitates rich in silver (Ag) and zirconium (Zr) were present in the matrix and at the grain boundaries even after long exposure to elevated temperatures. Islands rich in oxygen (O2) and Zr were also observed, as well as incipient melting at the grain boundary triple points. Results indicated that the alloy cannot be homogenized by heat treatment at elevated temperatures.
Singh, J.↗
Preparation and Thermoelectric Properties of the Skutterudite-Related Phase Ru(0.5)Pd(0.5)Sb3
A new skutterudite phase Ru(0.5)Pd(0.5)Sb3 was prepared. This new phase adds to a large number of already known materials with the skutterudite structure which have shown good potential for thermoelectric applications. Single phase, polycrystalline samples were prepared and characterized by x-ray analysis, electron probe microanalysis, density, sound velocity, thermal-expansion coefficient, and differential thermal analysis measurements. Ru(0.5)Pd(0.5)Sb3 has a cubic lattice, space group Im3 (T(sup 5, sub h)), with a = 9.298 A and decomposes at about 920 K. The Seebeck coefficient, the electrical resistivity, the Hall effect, and the thermal conductivity were measured on hot-pressed samples over a wide range of temperatures. Preliminary results show that Ru(0.5)Pd(0.5)Sb3 behaves as a heavily doped semiconductor with an estimated band gap of about 0.6 eV. The lattice thermal conductivity of Ru(0.5)Pd(0.5)Sb3 is substantially lower than that of the binary isostructural compounds CoSb3 and IrSb3. The unusually low thermal conductivity might be explained by additional hole and charge transfer phonon scattering in this material. The potential of this material for thermoelectric applications is discussed.
Caillat, T.↗
A Comparison of Experimental EPMA Data and Monte Carlo Simulations
Monte Carlo (MC) modeling shows excellent prospects for simulating electron scattering and x-ray emission from complex geometries, and can be compared to experimental measurements using electron-probe microanalysis (EPMA) and phi(rho z) correction algorithms. Experimental EPMA measurements made on NIST SRM 481 (AgAu) and 482 (CuAu) alloys, at a range of accelerating potential and instrument take-off angles, represent a formal microanalysis data set that has been used to develop phi(rho z) correction algorithms. The accuracy of MC calculations obtained using the NIST, WinCasino, WinXray, and Penelope MC packages will be evaluated relative to these experimental data. There is additional information contained in the extended abstract.
Carpenter, P. K.↗