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DOE OSTI2025

Long-Term Photovoltaic System Performance in Cold, Snowy Climates

As countries around the world transition towards renewable energy, there is increasing interest in using photovoltaic (PV) technologies to help decarbonize northern and alpine communities due to their scalability and affordability. However, a barrier to large-scale adoption of PV in cold climates is long-term performance uncertainty under snowfall, freeze-thaw cycles, low temperatures, and high winds. In this work, we provide a comprehensive review of published silicon degradation rates in cold Koppen-Geiger climate classifications of Dfb (humid continental), Dfc (subarctic), and ET (tundra). We first analyze the system degradation rates of three subarctic ground-mounted photovoltaic sites in North America using the RdTools year-on-year method: an Al-BSF double-axis tracking site in Fairbanks, Alaska (65degrees N); a PERC and silicon heterojunction bifacial vertical and south-tilted site in Fairbanks, Alaska; and a PERC south-facing fixed-tilt site in Fort Simpson, Northwest Territories (62degrees N). Degradation rates of these newly analyzed sites vary between -0.4%/year and -1.5%/year. Combining these data with previously reported cold climate degradation rates, we show that the distribution of cold climate degradation peaks at -0.1%/year to -0.2%/year but has a large tail with rates above -0.5%/year. The average reported cold climate degradation rate is -0.45%/year, whereas the median value is -0.33%/year. These results suggest that despite frequent freeze-thaw cycles and potential exposure to high wind and snow loads, PV systems in cold climates tend to degrade slower than PV systems in warmer climates. The limited sample size of reported degradation rates in cold climates (27) motivates the need for further data acquisition and monitoring efforts as new technologies are deployed.

14 SOLAR ENERGY↗

DOE OSTI2023

Gas-Liquid Flow Modeling for Renewable Fuels Production

Aerobic/anaerobic and gas fermentation pathways have emerged as promising new technologies for the generation of renewable fuels/chemicals from biomass derived sugars, and mixtures of greenhouse/energy rich gas streams (CO2/CH4/H2/CO) via microbial action. Example pathways include sugars-to-ethanol conversion, biomethanation (CO2/H2 to CH4), biogas upgrading, CO fermentation and wet-waste conversion. Gas and liquid phase transport, mass-transfer, and mixing physics at large length scales can significantly affect microbial conversion rates, particularly when the microbial reaction requires a narrow set of conditions. These phenomena are difficult to study in small-scale bench-top reactors that are typically well-mixed. Predictive computational fluid dynamics (CFD) based simulations can therefore aid in the scale-up, design and optimization of these reactors. This work presents multiphase Euler-Euler CFD simulations of at-scale (~500 m3) bioreactors. Our mathematical model treats the gas and liquid as interpenetrating phases. This approach reduces the computational complexity of tracking individual gas bubbles that are several orders of magnitude smaller than reactor dimensions. We solve the Reynolds averaged Navier-Stokes (RANS) multiphase equations that account for phase and chemical species transport, interphase mass and momentum transfer and uses a phenomenological model for gas uptake by microbes. We use a customized solver derived from open-source CFD toolbox, OpenFOAM [1], to perform these simulations, which has been validated against small-scale reactors in our previous work [2]. There is currently a knowledge-gap regarding bubble-size distributions when using gas mixtures with vastly different properties, which can have a significant impact overall mass-transfer. For example, hydrogen bubbles are more buoyant compared to other relatively heavier gases (CO2/CH4/CO), resulting in a large distribution of residence times and bubble sizes. This work therefore develops a deeper understanding of bubble dynamics and interphase mass transfer in such heterogenous gas mixtures through well-resolved computational models. We use a population balance model (PBM) for bubble-size-distribution modeling that is validated against small-scale experiments in our solver with an uncertainty quantification study for bubble coalescence and break-up model parameters. Results pertaining to multiple simulations of gas-fermentation reactors are presented where gas mixtures with varying compositions of CO2/CH4/CO/H2 are imposed at the sparger boundaries. The spatio-temporal variations in bubble-size distribution and mass transfer coefficient are analyzed for varying superficial velocities and gas-compositions for varying sizes of bubble-column and airlift reactors. This work will also examine the performance of different reactor designs, viz. bubble column reactor, airlift reactor with an internal draft tube, and a stirred-tank reactor with Rushton impellers. Reactor mass-transfer coefficient, gas hold-up, and dissolved gas distribution are critically analyzed among reactors, and sensitivity studies pertaining to gas flow rates and reactor geometry will be presented. [1] Weller, H., Tabor, G., Jasak, H. and Fureby, C., A tensorial approach to computational continuum mechanics using object-oriented techniques, Computers in physics, 12, 6, 620--631, 1998. [2] Rahimi, M., Sitaraman, H., Humbird, D. and Stickel, J., Computational fluid dynamics study of full-scale aerobic bioreactors: Evaluation of gas-liquid mass transfer, oxygen uptake, and dynamic oxygen distribution, Chemical Engineering Research and Design, 139: 283-295.

BIOMASS FUELS↗

NASA NTRS2003

Depth and Distribution of CO2 Snow on Mars

The dynamic role of volatiles on the surface of Mars has been a subject of longstanding interest. In the pre-Viking era, much of the debate was necessarily addressed by theoretical considerations. A particularly influential treatment by Leighton and Murray put forth a simple model relying on solar energy balance, and led to the conclusion that the most prominent volatile exchanging with the atmosphere over seasonal cycles is carbon dioxide. Their model suggested that due to this exchange, atmospheric CO2 partial pressure is regulated by polar ice. While current thinking attributes a larger role to H2O ice than did the occasional thin polar coating this model predicted, the CO2 cycle appears to be essentially correct. There are a number of observational constraints on the seasonal exchange of surface volatiles with the atmosphere. The growth and retreat of polar CO2 frost is visible from Earth-based telescopes and from spacecraft in Mars orbit, both at visible wavelengths and in thermal IR properties of the surface. Recently, variations in Gamma ray and neutron fluxes have also been used to infer integrated changes in CO2 mass on the surface. Measurements made by Viking's Mars Atmospheric Water Detector experiment were sensitive to atmospheric H2O vapor abundance. Surface condensates and their transient nature were detected by the Viking landers. The study here is motivated by recent data collected by the Mars Global Surveyor, affording the opportunity to not only detect the lateral distribution of volatiles, but also to constrain the variable volumes of the reservoirs. We elaborate on a technique first employed by Smith et al. By examining averages of a large number of topographic measurements collected by the Mars Orbiter Laser Altimeter (MOLA), that study showed that the zonal pattern of deposition and sublimation of CO2 can be determined. In their first approach, reference surfaces were fit to all measurements in narrow latitude annuli, and the time dependent variations about those mean surfaces were examined. In their second approach, height measurements from pairs of tracks that cross on the surface were interpolated and differenced, forming a set of crossover residuals. These residuals were then examined as a function of time and latitude. The initial studies averaged over longitude to maximize signal and minimize noise in order to isolate the expected small signal. In this follow-up study we now attempt to extract the elevation change pattern also as a function of longitude, and we focus on the crossover approach.

Aharonson, Oded↗

NASA NTRSDate not supplied

Analyzing Optical Energy Behavior in Tropical Cyclones During Rapid Intensitication

Forecasting rapid intensification (RI) in tropical cyclones is an unpredictable task taken on by forecasters every year. Hurricane Laura made its way through the Gulf of Mexico in August 2020, undergoing RI on August 26, 2020 and strengthening from a category 1 hurricane to a category 4 hurricane in less than 18 hours. The goal of this project was to use data from the Geostationary Lightning Mapper (GLM) aboard the GOES-16 satellite to track lightning over the Western Hemisphere and investigate optical energy during this period of RI. Data was taken from the entire hurricane using a fixed area that captured Laura from 0000-2359 UTC on August 26 and using Python, the sum of the optical energy, average flash extent density (FED), and average flash area were investigated using time series plots to determine if there were any patterns before, during, and after RI. Variations at the beginning and end of RI point to a change in lightning behavior. Along with time series plots, investigating the distribution of values during RI may be a useful in determining if these parameters have any discernable pattern. Applying this methodology to a larger sample of tropical cyclones can provide a better understanding as to how these parameters vary during RI periods.

Kiahna Mollette↗

DOE OSTI2024

Responses of summer mesoscale convective systems to irrigation over the North China Plain based on convection-permitting model simulations

Extensive irrigation activities in the North China Plain (NCP) significantly influence regional weather and climate. However, previous studies focusing on the NCP were primarily based on coarse-resolution models, which are unable to explicitly resolve convection systems, causing large uncertainty in precipitation simulations. In this study, a convection-permitting model coupled with a dynamic irrigation scheme is utilized to investigate the impacts of irrigation on summertime mesoscale convective systems (MCSs) over the NCP. Sensitivity experiments with irrigation off and on are conducted for 5 summers and an MCS identification and tracking algorithm is applied to both satellite observations and model simulations. We find that incorporating irrigation in the model increases MCS precipitation, which agrees more with observations. The probability distributions of MCS lifetime, area, propagation speed, and intensity are all better simulated with irrigation. Irrigation increases the occurrence frequency of MCSs throughout the entire day. The nighttime increase is partly because of more frequent local initiation of MCS developed from isolated deep convection, while the daytime increase is mainly attributed to the changes in MCSs initiating elsewhere and then propagating to the NCP. On average, irrigation induces additional moisture that is more thermodynamically favorable for precipitation, but this effect is partially offset by the weakened ascending air motion primarily caused by irrigation surface cooling. Compared to weak MCS precipitation events, strong MCS precipitation events experience greater enhancement in precipitation intensity when including irrigation because the offset effect from the change in large-scale ascending air motion is insignificant. In addition, irrigation makes the variation of MCS precipitation intensity more correlated with the variation in ascending motion but less correlated with that in atmospheric moisture. Our results suggest the pronounced impacts of irrigation on MCSs over the NCP which should be included in numerical models to improve regional precipitation simulation and prediction.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS2014

A Revised Calibration Function and Results for the Phoenix Mission TECP Relative Humidity Sensor

The original calibration function of the R(sub H) sensor on the Phoenix Thermal and Electrical Conductivity Sensor (TECP) has been revised in order to extend the range of the valid calibration, and to improve accuracy. The original function returned non-physical R(sub H) values at the lowest temperatures. To resolve this, and because the original calibration was performed against a pair of hygrometers that measured frost point (T(sub f)), the revised calibration equation is also cast in terms of frost point. Because of the complexity of maintaining very low temperatures and high R(sub H) in the laboratory, no calibration data exists at T is greater than 203K. However, sensor response during the mission was smooth and continuous down to 181 K. Therefore we have opted to include flight data in the calibration data set; selection was limited to data acquired during periods when the atmosphere is known to have been saturated. T(sub f) remained below 210 K throughout the mission(P is greater than 0.75 Pa). R(sub H), conversely, ranged from 1 to well under 0.01 diurnally, due to approximately 50 K temperature variations. To first order, both vapor pressure and its variance are greater during daylight hours. Variance in overnight humidity is almost entirely explained by temperature, while atmospheric turbulence contributes substantial variance to daytime humidity. Likewise, data gathered with the TECP aloft reflect higher H2O abundances than at the surface, as well as greater variance. There is evidence for saturation of the atmosphere overnight throughout much of the mission. In virtually every overnight observation, once the atmosphere cooled to T(sub f), water vapor begins to decrease, and tracks air temperature. There is no evidence for substantial decreases in water vapor prior to saturation, as expected for adsorptive exchange. Likewise, there is no evidence of local control of vapor by phases such as perchlorate hydrates hydrated minerals. The daytime average H2O pressure does not change substantially over the course of the mission, although the H2O column abundance varies by a factor of 2. Column abundances calculated from TECP data are lower than orbital measurements if one assumes that H2O is uniformly mixed through a single scale height. These results argue that the vertical distribution of H2O begins to change well in advance of surface concentrations as northern autumn approaches.

Phoenix Thermal and Electrical Conductivity Sensor↗

NASA NTRS1988

Lidar observations of the fine-scale variability of marine stratocumulus clouds

An Nd:YAG lidar system was flown aboard NASA's ER-2 high altitude aircraft. Observations of cloud top height were made with 70 m along-track and 7.5 m vertical-height resolution. The lidar data observed from an East Pacific stratocumulus cloud height deck revealed large cloud variability on 1-5 km scales. The cloud deck sloped upward from 700 to 1000 m in a northeast-southwest direction over a distance of 120 km. Vertical cloud top distributions were negatively skewed indicating flat-topped clouds. The dominant spectral peak of the cloud top variations was found at 4.5 km, which is 5 to 7 times the depth of the local boundary layer. No other peaks were significant in the average spectrum. The cloud layer was stable with respect to cloud top entrainment instability. The southwestern region of the study area was more prone to shear instability at cloud top than the northeastern region. The results of this study show that a lidar system is ideal to provide the topography of clouds and local boundary layer depth. This information is useful in the study of cloud top radiation and parameterization of clouds in numerical models.

Boers, Reinout↗

NASA NTRS1993

Ultrastable reference frequency distribution utilizing a fiber optic link

The Frequency Standards Laboratory at the Jet Propulsion Laboratory (JPL) is responsible for the generation and distribution of ultra-stable reference frequency in NASA's Deep Space Network (DSN). Certain assemblies and components of the Radio Science and VLBI systems are located in the cones of tracking antennas hundreds of meters from the Frequency and Timing Subsystem's frequency standards. The very stringent requirements of these users challenge the performance of state-of-the-art frequency sources as well as the associated signal distribution system. The reference frequency distribution system described is designed around a low temperature coefficient of delay (TCD) optical fiber. On-site measurements of the fiber optic link alone indicate 100 MHz phase noise performance on the order of -120 dBc at 1 Hz from the carrier and Allan deviation on the order of parts in 10(exp 16) at 1000 seconds averaging time. The measured phase noise and stability of the link indicate that the performance characteristics of the hydrogen maser frequency standards are not degraded by the distribution system. Thus, optical fibers and electro-optic devices as distribution media appear to be a viable alternative to the classical coaxial cable distribution systems.

Calhoun, Malcolm↗

NASA NTRS1994

The effects of correlated noise in phased-array observations of radio sources

Arrays of radio telescopes are now routinely used to provide increased signal-to-noise when observing faint point sources. However, calculation of the achievable sensitivity is complicated if there are sources in the field of view other than the target source. These additional sources not only increase the system temperatures of the individual antennas, but may also contribute significant 'correlated noise' to the effective system temperature of the array. This problem has been of particular interest in the context of tracking spacecraft in the vicinity of radio-bright planets (e.g., Galileo at Jupiter), but it has broader astronomical relevance as well. This paper presents a general formulation of the problem, for the case of a point-like target source in the presence of an additional radio source of arbitrary brightness distribution. We re-derive the well known result that, in the absence of any background sources, a phased array of N indentical antennas is a factor of N more sensitive than a single antenna. We also show that an unphased array of N identical antennas is, on average, no more sensitive than a single antenna if the signals from the individual antennas are combined prior to detection. In the case where a background source is present we show that the effects of correlated noise are highly geometry dependent, and for some astronomical observations may cause significant fluctuations in the array's effective system temperature.

Dewey, Rachel J.↗

DOE OSTI2022

Avalanche gain and its effect on energy resolution in GEM-based detectors

Here, we present avalanche gain and associated resolution measurements recorded with a 4 He:CO 2 (70:30) gas mixture and pure SF 6 , a Negative Ion (NI) gas. SF 6 is of particular interest to the directional dark matter detection community, as its low thermal diffusion helps to retain recoil ionization track features over long drift lengths. With the aid of a general form of the reduced first Townsend coefficient (RFTC), multiple GEM-based detector data sets are used to study the high-gain behavior of the 4 He:CO 2 gas mixture. The high-gain data is well described purely in terms of the reduced electric field strength and the number of GEMs, and the robust relationship between the RFTC and the average, reduced, electric field strength across the GEMs is emphasized. The associated (pulse-height) resolution measurements are used to discuss the variance of the avalanche distribution and to describe and estimate the lower limits of energy resolution one should expect to measure using a simple relationship with the RFTC. In the end, a description of avalanche gain, its effect on energy resolution, and the contributing experimental parameters in GEM-based detectors is developed over a broad parameter space for further use.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

NASA NTRS2017

An Investigation of Dust Storms Observed with the Mars Color Imager

Daily global imaging by the Mars Color Imager (MARCI) continues the record of the Mars Orbiter Camera (MOC) and has allowed creation of a long-duration record of Martian dust storms. We observe dust storms over the first two Mars years of the MARCI record, including tracking individual storms over multiple sols, as well as tracking the growth and recession of the seasonal polar caps. Using the combined 6 Mars year record of textured dust storms (storms with visible textures on the observed dust cloud tops), we study the relationship between textured dust storm activity and meteorology (as simulated by the MarsWRF general circulation model) and surface properties. We find that textured dust storms preferentially occur in places and seasons with above average surface wind stress. Textured dust storm occurrence also has a modest linear anti-correlation with surface albedo (0.43) and topography (0.40). Lastly, we perform an empirical orthogonal function (EOF) analysis on the distribution of occurrence of textured dust storms and find that over 50 of the variance in textured dust storm activity can be explained by two EOF modes. We associate the first EOF mode with cap-edge storms just before Ls = 180deg and the second EOF mode with flushing dust storms that occur from Ls = 180-210deg and again near Ls = 320deg.

Guzewich, Scott D.↗

NASA NTRS2003

Limits to the Indirect Aerosol Forcing in Stratocumulus

The indirect radiative forcing of aerosols is poorly constrained by the observational data underlying the simple cloud parameterizations in GCMs. signal of cloud response to increased aerosol concentrations from meteorological noise. Recent satellite observations indicate a significant decrease of cloud water in ship tracks, in contrast to an ensemble of in situ measurements showing no average change in cloud water relative to the surrounding clouds. Both results contradict the expectation of cloud water increasing in polluted clouds. We find through large-eddy simulations of stratocumulus that the trend in the satellite data is likely an artifact of sampling only overcast clouds. The simulations instead show cloud cover increasing with droplet concentrations. The simulations also show that increases in cloud water from suppressing drizzle by increased droplet concentrations are favored at night or at extremely low droplet concentrations. At typical droplet concentrations we find that the Twomey effect on cloud albedo is amplified very little by the secondary indirect effect of drizzle suppression, largely because the absorption of solar radiation by cloud water reduces boundary-layer mixing in the daytime and thereby restricts any possible increase in cloud water from drizzle suppression. The cloud and boundary layer respond to radiative heating variations on a time scale of hours, and on longer time scales respond to imbalances between large-scale horizontal advection and the entrainment of inversion air. We analyze the co-varying response of cloud water, cloud thickness, width of droplet size distributions, and dispersion of the optical depth, as well as the overall response of cloud albedo, to changes in droplet concentrations. We also dissect the underlying physical mechanisms through sensitivity studies. Ship tracks represent an ideal natural laboratory to extricate the

Ackerman, Andrew↗

DOE OSTI2022

Velocity Profiling of a Gas–Solid Fluidized Bed Using Electrical Capacitance Volume Tomography

In this study, a method of producing velocity profile maps from electrical capacitance volume tomography (ECVT) measurements by reconstructing displacement from measured changes in capacitance is developed and applied to fluidized bed systems. The mapping of the reconstruction leverages the gradient of the sensitivity distribution of the ECVT sensor to circumvent the need for image cross correlation techniques. Experimental data of both bubbling and slugging fluidized beds are collected in a cold flow model. Adaptation of the technique is discussed in detail, and velocity profiles are obtained for a range of gas flow rates. The produced velocity maps are compared against the established methods of cross correlation and against empirical correlations from the literature and are found to agree well in tracking slug and bubble velocity. The exception is when the tracked object is large relative to the ECVT sensor dimensions, a scenario that can be avoided through proper sensor design. The quantities of average velocity, momentum, and solid and gas volume fraction are derived from the image and velocity profiles. The results demonstrate and extend the power of ECVT as a measurement tool for the study and monitoring of gas–solid fluidized beds by providing a computationally cheaper alternative to 3-D cross correlation for deriving velocity profiles.

47 OTHER INSTRUMENTATION↗

NASA NTRS1996

Numerical Investigation of Two-Phase Flows With Charged Droplets in Electrostatic Field

A numerical method to solve two-phase turbulent flows with charged droplets in an electrostatic field is presented. The ensemble-averaged Navier-Stokes equations and the electrostatic potential equation are solved using a finite volume method. The transitional turbulence field is described using multiple-time-scale turbulence equations. The equations of motion of droplets are solved using a Lagrangian particle tracking scheme, and the inter-phase momentum exchange is described by the Particle-In-Cell scheme. The electrostatic force caused by an applied electrical potential is calculated using the electrostatic field obtained by solving a Laplacian equation and the force exerted by charged droplets is calculated using the Coulombic force equation. The method is applied to solve electro-hydrodynamic sprays. The calculated droplet velocity distributions for droplet dispersions occurring in a stagnant surrounding are in good agreement with the measured data. For droplet dispersions occurring in a two-phase flow, the droplet trajectories are influenced by aerodynamic forces, the Coulombic force, and the applied electrostatic potential field.

Kim, Sang-Wook↗

NASA NTRSDate not supplied

Analysis and Prediction of VFR Vs IFR Traffic Behavior to Support Uncrewed Aircraft Flight Operations at Regional Airports

Uncrewed Aircraft flight operations at a regional airport will be affected by the uncertainty in the Visual Flight Rules traffic around. This paper analyzes Visual Flight Rules traffic behavior, compares it with Instrument Flight Rules traffic and develops traffic prediction methods to support uncrewed aircraft flight operations. The spatio-temporal distribution of traffic operating under Visual Flight Rules and Instrument Flight Rules was analyzed from one month of historical track data around Fort Worth Alliance airport as a representative regional airport. The traffic behavior was visualized as occupancy maps generated at different altitudes. The Instrument Flight Rules traffic was concentrated in fewer regions of the airspace along structured routes where the risk of interacting with one or more flights reached close to fifty percent in some areas. Visual Flight Rules traffic was spread over more regions, mostly segregated from the Instrument Flight Rules regions, and the risk of interaction was lower reaching up to twenty-five percent on average over the month in some regions. The interaction risk was predicted using predictive occupancy maps over multiple time horizons and conditioned on time and partial observation of traffic in the vicinity. The month-to-month predictability of Visual Flight Rules risk was lower than that of the Instrument Flight Rules traffic, consistently over all the conditions analyzed. However, the prediction and its accuracy were demonstrated to be sensitive to the conditions used. The predictive models generated can be used to support both strategic planning and in-flight decision-making by uncrewed aircraft during flight operations while maintaining an acceptable risk of interacting with other traffic.

VFR↗

NASA NTRSDate not supplied

Analysis and Prediction of VFR Vs IFR Traffic Behavior to Support Uncrewed Aircraft Flight Operations at Regional Airports

VFR↗

DOE OSTI2024

A Clean Energy Deployment Baseline for the Energy Community and Low-Income Tax Credit Bonuses [Slides]

The Inflation Reduction Act of 2022 introduced, for the first time, place-based federal tax incentives for projects sited in “Energy Communities,” potentially changing the economic calculus of where projects are best sited. Storage projects can qualify for a 10-percentage-point bonus to the Investment Tax Credit (e.g., from 30% to 40%), while wind and solar projects may qualify for either the ITC bonus or a 10% bonus to the Production Tax Credit (e.g., from $\$27.5$ to $\$30.25$/MWh). Energy Communities are areas with historical ties to fossil fuel industries and above average unemployment levels (FFEU), with closed coal mines or power plants, or contaminated properties. They seek to identify locations across the US that could especially benefit from economic revitalization. This report explores how the new federal tax credit incentives are impacting clean energy deployment patterns and establishes historical baselines against which future changes can be compared. We include a few case studies of clean energy projects going specifically to areas that were recently impacted by coal power plant closures to provide concrete examples of investments in Energy Communities. However, this publication does not assess how much of the incentive benefits pass from clean energy developers to hosting communities, nor does it offer a comprehensive view of the economic effects of clean energy deployment on Energy Communities. Key highlights include: - As clean energy projects take multiple years to conceptualize and develop, it is likely too early to see shifts towards Energy Community locations either among newly built projects or those that entered interconnection queues in 2023. - Approximately 35% of onshore wind, 50% of solar, and 60% of storage capacity built in 2023 and the first half of 2024 are located in Energy Communities, making them likely eligible for bonus incentives. While these bonus incentives were not available to projects coming online before 2023, we used 2023 Energy Community definitions to classify whether past projects were built in what is now considered an Energy Community. The deployment levels for 2023-2024 are similar to recent years (2020-2022) for solar and storage but slightly lower for wind. - Clean energy capacity has surged in the interconnection queues over the last few years, with about 45-50% of both recently proposed and total queued capacity being located in Energy Communities. While the amount of capacity in Energy Communities has also grown, its relative share is either stable (solar and storage) or slightly lower (wind) among projects that entered the queue in 2023. - Clean energy projects can be built at lower costs in Energy Communities. The levelized cost of energy after incentives was on average $\$9$/MWh (24%) lower for solar projects and $\$2$/MWh (6%) lower for wind projects built in 2023, relative to projects not located in Energy Communities. Wholesale electricity values at Energy Community locations relative to the rest of the market vary by region. The average value was often higher for wind projects (-$\$3$ to $\$11$/MWh) but lower for solar projects (-$\$6$ to 0/MWh). - Distributed solar that is owned by commercial entities is eligible for the Energy Community bonus and also, potentially, a Low-Income Community bonus. Residential solar installations in qualifying Energy Communities that are third-party owned represent about 10% of the total residential market. Larger commercial and industrial solar installations in Energy Communities make up 17% of the total market in 2023. Nearly 2 GW of distributed solar was built in areas qualifying as Low-Income Communities in 2023, exceeding the available annual program cap of 700 MW. Continued tracking of these trends will be important for system planners, investors, and local communities.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

DOE OSTI2025

Nonlinear Scaling of Water–Ion Interactions and Dynamics in Alkaline Solutions

Water-ion interactions govern many solvent properties critical to solution-phase chemistry and the behavior of liquid water. The water-ion interactions in alkaline conditions were probed using two-dimensional infrared spectroscopy (2D IR), small-angle x-ray scattering (SAXS), and nuclear magnetic resonance spectroscopy (NMR). Energy transfer between the donor molecule KSeCN, used as a 2D IR probe, and the acceptor molecule NaOD was used to track the average separation distance of ions in a D 2 O solution, while SAXS measurements showed effects in the bulk D 2 O solvent. Here, we observe consistent nonlinear scaling in the SeCN - and OD - average separation distance as a function of NaOD concentration while bulk solution D 2 O-to-D 2 O average separation distance remained highly linear. Ultrafast measurements of solution dynamics via 2D IR and polarization-selective pump-probe spectroscopy show consistent scaling in correlation times as a function of concentration. These results suggests that the SeCN - and OD - anions participate in a water-ion network that significantly reduces the degrees of freedom for the distribution of ions in solution below the standard stochastic for ion distribution.

2D IR Spectroscopy↗