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At least 91 records · Page 5

Compliant Interfacial Layers in Thermoelectric Devices

A thermoelectric power generation device is disclosed using one or more mechanically compliant and thermally and electrically conductive layers at the thermoelectric material interfaces to accommodate high temperature differentials and stresses induced thereby. The compliant material may be metal foam or metal graphite composite (e.g. using nickel) and is particularly beneficial in high temperature thermoelectric generators employing Zintl thermoelectric materials. The compliant material may be disposed between the thermoelectric segments of the device or between a thermoelectric segment and the hot or cold side interconnect of the device.

Firdosy, Samad A.↗

Accelerated Stress Testing of Perovskite Photovoltaic Modules: Differentiating Degradation Modes with Electroluminescence Imaging

Herein, electroluminescence (EL) and thermal imaging are used to examine p–i–n metal halide perovskite (MHP) photovoltaic (PV) mini-modules (MA0.6FA0.4PbI3, 20 cells, 78 cm2) before and after indoor-accelerated stress testing or outdoor deployment. Distinct spatial patterns in the EL images emerge, which depend on the external stress conditions experienced by the mini-module. Imaging results highlight a distribution of dark speckle features that dominate after UV stress, attributed to widespread interfacial contact degradation. Lateral intensity gradients across cells dominate after thermal cycling (TC) stress, attributed to current crowding near scribe defects. While current–voltage analysis alone does not give full insight on the degradation process, this study shows that distinct degradation modes can be further defined by multimodal electro-optical imaging (i.e., EL combined with photoluminescence and dark lock-in thermography). Neither UV exposure nor TC-accelerated stress testing alone replicates the same degradation signatures observed after outdoor deployment, suggesting that multiple degradation modes occur under concurrent stressors outdoors. Finally, spatial characterization of degradation modes in MHP PV mini-modules before and after accelerated stress testing lays the groundwork for developing targeted accelerated stress testing procedures through comparison with outdoor aging.

14 SOLAR ENERGY↗

Impact of control blade insertion on the deformation behavior of SiC-SiC channel boxes in BWRs

This article describes the analysis of distortion of a silicon carbide fiber-reinforced, silicon carbide matrix (SiC-SiC) composite channel box under in-reactor conditions of a boiling water reactor (BWR). The BWR core has significant gradients in the fast neutron flux across the channel box due to the presence of water rods within the fuel assemblies, and these gradients increase further with the insertion of control blades. As a result of the temperature and neutron flux dependent irradiation-induced swelling of SiC, the SiC-SiC composite channel box can undergo distortion. In this work, we evaluate the SiC-SiC channel box distortion for three different control blade positions. This analysis is based on the neutron flux and temperature distributions in the BWR core calculated using the neutronics code MPACT and thermal-hydraulics code CTF. This calculation is coupled through temperature feedback. Subsequently, we have performed structural analysis based on the calculated neutron flux and temperature distributions to determine the deformation and stress development in the channel box. The structural analysis was performed using the fuel performance modeling code BISON and the commercial finite element analysis software Abaqus. The results indicate that large gradients in fast neutron flux (up to 35–40% across a single axial level) will develop across the channel box. Due to these gradients, the channel box will undergo time-dependent bending for all the control blade positions in the assembly. The time-dependent bowing behavior is dominated by the transient swelling of SiC-SiC material under non-uniform neutron flux, and changes with variation in the control blade position. The bending will cause temporary interference between the channel box and control blade, and the interference is expected to be most severe for the fully inserted control blade position. The developed stresses due to differential swelling in the channel box exceed the proportional limit stress of the material, which may cause matrix microcracking in the channel box. However, the stresses remain below the tensile strength of the material, and therefore, development of a full, through-thickness crack in the channel box is not expected. Finally, further work is recommended to explore and evaluate the mitigation strategies.

42 ENGINEERING↗

Chromosome-scale Genome Assembly of the Most Abundant Ectomycorrhizal Fungus Cenococcum Geophilum Reveals Massive TE Expansion and RIP Defense Mechanism

Transposable elements (TEs) play crucial roles in genome evolution and ecological adaptation in fungi, yet their dynamics in ectomycorrhizal species remain poorly understood. Cenococcum geophilum, the most widespread ectomycorrhizal fungus in boreal and temperate forests with its large, repeat-rich genome, represents an ideal system to investigate TE-mediated adaptation to the physical environment and symbiotic lifestyle. However, previous studies have been limited by fragmented genome assemblies that prevented the resolution of repeat-rich regions. We assembled a telomere-to-telomere reference genome of C. geophilum strain 1.58 using PacBio HiFi and Hi-C datasets, resulting in a 178.54 Mbp genome with seven contiguous chromosomes. We identified 14,145 genes and over 78% of the genome consists of transposable elements (TEs). Of these, 94% are affected by repeat-induced point mutations (RIP), a genome defense mechanism that acts during the sexual reproduction phase, indicating cryptic or ancient sexual reproduction in this putatively asexual fungus. Long terminal repeat retrotransposons, LINEs, and DNA transposons dominate, with three TE families (Ty3, Ty1, and Tad1) contributing over 60% of the genome size, indicating recent transposition bursts. Screening of 15 additional C. geophilum strains revealed recent and lineage-specific TE expansions, implying that several TEs escaped the RIP machinery and retained potential activity. Supporting TE activity in the context of symbiosis, we found 56 TEs differentially transcribed between ectomycorrhizal and free-living mycelium tissues. An even higher number (n = 66) of TEs were differentially expressed between stress resistance morphology (i.e. sclerotia) and free-living mycelium. This supports that TEs are differentially regulated as a response to symbiotic and stress-related conditions. Our results demonstrate that the C. geophilum genome expansion was driven by a few lineage-specific TE families in recent history, with high RIP activity attesting to sexual reproduction. We also provide insights how TEs could respond to lifestyle transitions and traits associated with desiccation resistance.

Cenococcum geophilum↗

Differential rotation and turbulent convection: A new Reynolds stress model and comparison with solar data

In most hydrodynamic cases, the existence of a turbulent flow superimposed on a mean flow is caused by a shear instability in the latter. Boussinesq suggested the first model for the turbulent Reynolds stresses bar-(u(sub i)u(sub j)) in which the mean shear S(sub ij) is the cause (or source) of turbulence represented by the stress bar-(u(sub i)u(sub j)). In the case of solar differential rotation, exactly the reverse physical process occurs: turbulence (which must pre-exist) generates a mean flow which manifests itself in the form of differential rotation. Thus, the Boussinesq model is wholly inadequate because in the solar case, cause and effect are reversed. Since the Boussinesq model is inadequate, one needs an alternative model for the Reynolds stresses. We present a new dynamical model for the Reynolds stresses, convective fluxes, turbulent kinetic energy, and temperature fluctuations. The complete model requires the solution of 11 differential equations. We then introduce a set of simplifying assumptions which reduce the full dynamical model to a set of algebraic Reynolds stress models. We explicitly solve one of these models that entails only one differential equation. The overall agreement with the data is obtained with a model that is neither phenomenological nor one that requires a full numerical simulation, since it is algebraic in nature. The new model can play an important role in understanding the complex physics underlying the interplay between solar differential rotation and convection, as many physical processes can naturally be incorporated into the model.

Canuto, V. M.↗

Assessment of Turbulence Models for a Single-Injector Cooling Flow

This work assesses the ability of Reynolds-averaged Navier-Stokes turbulence models to predict a fundamental thermal cooling flow configuration. This geometry consists of a plate with a single cooling hole positioned downstream of a heated exhaust nozzle. The linear Shear Stress Transport (SST), non-linear Quadratic Constitutive Relation (QCR), and differential SSG/LRR Reynolds Stress Model (RSM) turbulence models were investigated for flow conditions with a blowing ratio of 1.0 and 2.0. Despite significant differences in turbulence model complexity, the results miss important details observed in the data and large eddy simulation (LES). Injection penetration is over-predicted. Mixing and centerline wake recovery is too slow. Temperature predictions are worse than velocity, suggesting that perhaps the simple gradient diffusion approximation used to model the turbulent heat flux may be to blame. These observations are put into context using other studies to identify shortcomings in the modeling of both the turbulent stress and turbulent heat flux.

Film Cooling↗

Assessment of Turbulence Models for a Single-Injector Cooling Flow

This work assesses the ability of Reynolds-averaged Navier-Stokes turbulence models to predict a fundamental thermal cooling flow configuration. This geometry consists of a plate with a single cooling hole positioned downstream of a heated exhaust nozzle. The linear Shear Stress Transport (SST), non-linear Quadratic Constitutive Relation (QCR), and differential SSG/LRR Reynolds Stress Model (RSM) turbulence models were investigated for flow conditions with a blowing ratio of 1.0 and 2.0. Despite significant differences in turbulence model complexity, the results miss important details observed in the data and large eddy simulation (LES). Injection penetration is over-predicted. Mixing and centerline wake recovery is too slow. Temperature predictions are worse than velocity, suggesting that perhaps the simple gradient diffusion approximation used to model the turbulent heat flux may be to blame. These observations are put into context using other studies to identify shortcomings in the modeling of both the turbulent stress and turbulent heat flux.

Film Cooling↗

Calculation of turbulent flow in complex geometries with a second-moment closure model

A full Reynolds stress turbulence model is applied to calculate the flow in various channels with complex cross-section. The model is shown to be more robust and to produce more consistent results than algebraic stress models. The relationship between various versions of the latter is provided. It is shown that differential or algebraic stress models derived from a direct application of a popular linear approximation for the pressure-strain terms in the Reynolds stress equations will always underpredict the secondary motion, and hence the accompanying distortion of other flow properties. A simple approximation which leads to better predictions is presented and related to previous practice.

Demuren, A. O.↗

Modeling of SiC Lateral Resonant Devices Over a Broad Temperature Range

Finite-element analysis (FEA) modal results of 3C-SiC lateral resonant devices anchored to a Si substrate are presented as resonant frequency versus temperature. The suspended elements are etched from a 2 micron, 3C-SiC film grown at 1600 K on a 500 micron-thick, Si substrate. The analysis includes, temperature-dependent properties, shape change due to volume expansion with temperature, and thermal stress caused by differential thermal expansion of different materials. Two designs are considered: type I has anchor locations close to the geometric centroid and a small shuttle; type 11 has a large shuttle with anchors far from the centroid, The resonant frequency decreases approximately 3.5% over a 1000 K temperature increase for the type-I device, and behaves according to theory. The resonant frequency of the type-11 device decreases by 2% over the first 400 K, then rises slightly over the remaining 600 K. This device deviates from theory because of the high thermal stress induced in the beams. The thermal stress is caused by the differential thermal expansion of the suspended element relative to the substrate. The results show that the device geometry must be properly chosen if the resonant frequency of that device will be used to calculate the temperature coefficient of Young's modulus. These results apply only to resonators of one material on a substrate of a different material.

DeAnna, Russell G.↗

An experimental and analytical investigation of the rail shear-test method as applied to composite materials

This report presents the results from an experimental and analytical investigation of the stress distributions occurring in a rail shear test. The effects of non-uniform stresses induced by differential thermal expansion, rail flexibility and specimen aspect ratio on measured shear modulus and ultimate strength of composite laminates are shown. A two-dimensional linearly elastic finite element model was used to analytically determine how various geometric parameters influenced the magnitude and distribution of inplane normal and shear stresses in a tensile rail shear specimen. Rail shear tests were conducted at room temperature and 589 K (600 F) on selected graphite-polyimide composite laminates using two titanium rail configurations. The analysis and test methods are discussed, and the results of the effects of the various parameters on shear modulus and ultimate strength are presented.

Garcia, R.↗

Origin of fractures, Martian polygonal terrain

It has been proposed that the origin of the polygonally fractured terrain on Mars is due to stress caused by differential settling of material deposited over an irregular base topography. The eventual goal of this study is to evaluate this proposal by construction of mathematical models for this process. These models will attempt to determine what combinations of base topography, covering material composition, and depositional rate would cause the fractures observed. Because fracture formation would largely be a function of generated stress, the first step in modeling is calculation of stresses created during settlement.

Hills, L. Scott↗

The effect of physical aging on the time-dependent properties of carbon-fiber-reinforced epoxy composites

Annealing in nitrogen below the glass transition temperature T(g) is found to affect the matrix-dominated physical properties of postcured, (+ and -45)2s specimens of Thornel 300 carbon fiber/Fiberite 934 epoxy composite as well as neat Fiberite 934 epoxy resin. The damping behavior, stress-relaxation rate and enthalpic state of the matrix material are found to decrease as functions of annealing time. The time-dependent change in physical properties is explained on the basis of free-volume collapse related to the physical aging of the nonequilibrium glassy network of epoxy. Such physical aging in network epoxy has been demonstrated to be thermoreversible through the monitoring of its kinetics by differential scanning calorimetry, stress relaxation tests, and dynamic mechanical analysis.

Kong, E. S. W.↗

Influence of physical aging on the time-dependent properties of network epoxies and epoxy-matrix composites

The matrix-dominated properties of a network epoxy and its carbon fiber-reinforced composite are noted to be affected by sub-glass transition temperature T(g) annealing in a nitrogen atmosphere. The damping behavior, stress relaxation rate, and enthalpic state of the matrix material were found to decrease as functions of sub-T(g) annealing time. This time-dependent change in physical properties is explained on the basis of a free-volume collapse which is related to the recovery process of the nonequilibrium glassy network of the epoxy. The physical aging in network epoxies has been demonstrated to be thermoreversible. Aging kinetics are studied by means of differential scanning calorimetry, stress relaxation tests, dynamic mechanical analysis, and thermomechanical analysis.

Kong, E. S. W.↗

Analytical Predictions of Thermal Stress in the Stardust PICA Heatshield Under Reentry Flight Conditions

We performed finite element analyses on a model of the Phenolic Impregnated Carbon Ablator (PICA) heatshield from the Stardust sample return capsule (SRC) to predict the thermal stresses in the PICA material during reentry. The heatshield on the Stardust SRC was a 0.83 m sphere cone, fabricated from a single piece of 5.82 cm-thick PICA. The heatshield performed successfully during Earth reentry of the SRC in January 2006. Material response analyses of the full, axisymmetric PICA heatshield were run using the Two-Dimensional Implicit Ablation, Pyrolysis, and Thermal Response Program (TITAN). Peak surface temperatures were predicted to be 3385K, while the temperature at the PICA backface remained at the estimated initial cold-soak temperature of 278K. Surface recession and temperature distribution results from TITAN, at several points in the reentry trajectory, were mapped onto an axisymmetric finite element model of the heatshield. We used the finite element model to predict the thermal stresses in the PICA from differential thermal expansion. The predicted peak compressive stress in the PICA heatshield was 1.38 MPa. Although this level of stress exceeded the chosen design limit for compressive stresses in PICA tiles for the design of the Orion crew exploration vehicle heatshield, the Stardust heatshield exhibited no obvious mechanical failures from thermal stress. The analyses of the Stardust heatshield were used to assess and adjust the level of conservatism in the finite element analyses in support of the Orion heatshield design.

Squire, Thomas↗

Shallow moonquakes - Depth, distribution and implications as to the present state of the lunar interior

The observed seismic amplitudes of HFT (high-frequency teleseismic) events do not vary with distance as expected for surface sources, but are consistent with sources in the upper mantle of the moon. Thus, the upper mantle of the moon is the only zone where tectonic stresses deriving from differential thermal contraction and expansion of the lunar interior are presently high enough to cause moonquakes. The distribution of shallow moonquake epicenters suggests a possible correlation with impact basins, implying a lasting tectonic influence of impact basins long after their formation. The finite depths now assigned to these shallow moonquakes necessitate further revision to the seismic structural model of the lunar interior.

Nakamura, Y.↗

High-Quality, Thin-Film Germanium Single Crystals

Germanium (Ge) has crystallographic characteristics similar to GaAs and compatible with heteroepitaxial growth of GaAs. Further, since efficient heteroface cells already grown on thick Ge single crystals, Ge is excellent substrate candidate for thin-film cells. Required is single-crystal Ge thin film. Method developed for epitaxially growing highquality 10-um Ge thin films on ,100. NaCl substrates by plasma-enhanced chemical-vapor deposition (PECVD) and then separating Ge films by either melt-away or differential-thermal shear stress techniques. Free-standing films used for growth of AlxGa1-xAs/GaAs heteroface cells by similar techniques.

Outlaw, R. A.↗

Theoretical and experimental studies in support of the geophysical fluid flow experiment

Meteorologists and astrophysicists interested in large scale planetary and solar circulations have come to recognize the importance of rotation and stratification in determining the character of these flows. In particular, the effect of latitude-dependent Coriolis force on nonlinear convection is thought to play a crucial role in such phenomena as differential rotation on the Sun, cloud band orientation on Jupiter, and the generation of magnetic fields in thermally driven dynamos. The continuous low-gravity environment of the orbiting space shuttle offers a unique opportunity to make laboratory studies of such large-scale thermally driven flows under the constraint imposed by rotation and sphericity. This is possible because polarization forces in a dielectric liquid, which are linearly dependent on fluid temperature, give rise to an effectively radial buoyancy force when a radial electrostatic field is imposed. The Geophysical Fluid Flow Cell (GFFC) is an implementation of this ideal in which fluid is contained between two rotating hemispheres that are differentially heated and stressed with a large a-c voltage. The experiment, to be flown on Spacelab III (currently set for launch April 29, 1985), will explore non-linear mode selection and high Rayleigh number turbulence in a rotating convecting spherical shell of liquid. Experiments will be carried out in a low driving parameter range where some limited numerical experimentation is currently feasible, as well as in a parameter range significantly beyond numerical computation for many years.

Hart, J.↗