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Results for “correlates of protection”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

An evaluation of candidate oxidation resistant materials

Ground based testing of materials considered for Kapton solar array blanket protection, graphite epoxy structural member protection, and high temperature radiators was performed in an RF plasma asher. Ashing rates for Kapton were correlated with rates measured on STS-8 to determine the exposure time equivalent to one year in low Earth orbit (LEO) at a constant density space station orbital flux. Protective coatings on Kapton from Tekmat, Andus Corporation, and LeRC were evaluated in the plasma asher and mass loss rates per unit area were measured for each sample. All samples evaluated provided some protection to the underlying surface but ion beam sputter deposited samples of SiO2 and SiO2 with 8% polytetrafluoroethylene (PTFE) showed no evidence of degradation after 47 hours of exposure. Mica paint was evaluated as a protective coating for graphite epoxy structural members. Mica appears to be resistant to attack by atomic oxygen but only offers some limited protection as a paint because the paint vehicles evaluated to date were not resistant to atomic oxygen. Four materials were selected for evaluation as candidate radiator materials: stainless steel, copper, niobium-1% zirconium, and titanium-6% aluminum-4% vanadium. These materials were surface textured by various means to improve their emittance. Emittances as high as 0.93 at 2.5 microns for stainless steel and 0.89 at 2.5 microns for Nb-1 Zr were obtained from surface texturing. There were no significant changes in emittance after asher exposure.

Rutledge, Sharon↗
DOE OSTI2021

Identification of Preferential Recharge Zones in Karst Systems Based on the Correlation between the Spring Level and Precipitation: A Case Study from Jinan Spring Basin

The Jinan spring basin is located in the karst area of northern China, where springs serve as important sources of water supply. Several studies on spring protection and water supply have been carried out, and scholars have developed some laws on local groundwater flow dynamic and characteristics of aquifer structures. Unfortunately, there is a lack of detailed research on preferential recharge zones, which are the main recharge pathways of springs. Therefore, this research focuses on identifying preferential recharge zones based on the correlation between the spring level and precipitation. The results show that when precipitation is more intense or lasts longer, there is a stronger correlation between spring level and precipitation. It has been established that the precipitation at Donghongmiao station has the closest relationship with the dynamic of Baotu spring, which is found to be the most significant contribution to spring preservation. Two potential preferential recharge zones in the Jinan spring basin are detected through correlation analysis and geological exploration data. These findings support spring protection and water supply projects in karst regions.

58 GEOSCIENCES↗
DOE OSTI2024

Microbial Proxies for Anoxic Microsites Vary with Management and Partially Explain Soil Carbon Concentration

Anoxic microsites are potentially important but unresolved contributors to soil organic carbon (C) storage. How anoxic microsites vary with soil management and the degree to which anoxic microsites contribute to soil C stabilization remain unknown. Sampling from four long-term agricultural experiments in the central United States, we examined how anoxic microsites varied with management (e.g., cultivation, tillage, and manure amendments) and whether anoxic microsites determine soil C concentration in surface (0–15 cm) soils. We used a novel approach to track anaerobe habitat space and, hence, anoxic microsites using DNA copies of anaerobic functional genes over a confined volume of soil. No-till practices inconsistently increased anoxic microsite extent compared to conventionally tilled soils, and within one site organic matter amendments increased anaerobe abundance in no-till soils. Across all long-term tillage trials, uncultivated soils had ~2–4 times more copies of anaerobic functional genes than their cropland counterparts. Finally, anaerobe abundance was positively correlated to soil C concentration. Even when accounting for other soil C protection mechanisms, anaerobe abundance, our proxy for anoxic microsites, explained 41% of the variance and 5% of the unique variance in soil C concentration in cropland soils, making anoxic microsites the strongest management-responsive predictor of soil C concentration. Our results suggest that careful management of anoxic microsites may be a promising strategy to increase soil C storage within agricultural soils.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Coherent Erbium Spin Defects in Colloidal Nanocrystal Hosts

We demonstrate nearly a microsecond of spin coherence in Er 3+ ions doped in cerium dioxide nanocrystal hosts, despite a large gyromagnetic ratio and nanometric proximity of the spin defect to the nanocrystal surface. The long spin coherence is enabled by reducing the dopant density below the instantaneous diffusion limit in a nuclear spin-free host material, reaching the limit of a single erbium spin defect per nanocrystal. We observe a large Orbach energy in a highly symmetric cubic site, further protecting the coherence in a qubit that would otherwise rapidly decohere. Spatially correlated electron spectroscopy measurements reveal the presence of Ce 3+ at the nanocrystal surface, which likely acts as extraneous paramagnetic spin noise. Even with these factors, defect-embedded nanocrystal hosts show tremendous promise for quantum sensing and quantum communication applications, with multiple avenues, including core-shell fabrication, redox tuning of oxygen vacancies, and organic surfactant modification, available to further enhance their spin coherence and functionality in the future.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
NASA NTRS2011

The Potential Impact of CO2 and Air Temperature Increases on Krummholz's Transformation into Arborescent Form in the Southern Siberian Mountains

Trees in the southern Siberian Mountains forest-tundra ecotone have considerably increased their radial and apical growth increments during the last few decades. This leads to the widespread vertical transformation of mat and prostrate krummholz forms of larch (Larix sibirica Ledeb) and Siberian pine (Pinus sibirica Du Tour). An analysis of the radial growth increments showed that these transformations began in the mid-1980s. Larch showed a greater resistance to the harsh alpine environment and attained a vertical growth form in areas where Siberian pine is still krummholz. Upper larch treeline is about 10 m higher than Siberian pine treeline. Observed apical and radial growth increment increases were correlated with CO2 concentration (r = 0.83-0.87), summer temperatures (r = 0.55-0.64), and "cold period" (i.e. September-May) air temperatures (r = 0.36-0.37). Positive correlation between growth increments and winter precipitation was attributed to snow cover protection for trees during wintertime.

Kharuk, V. I.↗
DOE OSTI2026

When Do Band Gap Calculations Agree with Experiments in Monolayer-Protected Cu 14 and Au 20 Atomically Precise Nanoclusters? A (TD)-DFT Comparison of HOMO–LUMO, Fundamental, Optical, and Electrochemical Energy Gaps

In view of the tremendous progress in atomically precise metal nanoclusters where electrochemical and optical energetics are routinely supported by computations to establish structure−function correlations, we explore the relationship between different protocols for measuring and computing band gaps of two distinct organic ligand-protected nanoclusters: [Cu 14 H 10 (MBN) 3 (PPh 3 ) 8 ] + and Au 20 (TBBT) 16 . Through UV/visible spectroscopy and differential pulse voltammetry, we measure optical and electrochemical band gaps in those systems. We then compare these experimentally determined gaps to HOMO−LUMO gaps, fundamental gaps, vertical excitation energies, and E o ox − E o red potentials computed using different density functional theory (DFT) or time-dependent DFT (TDDFT) methods. Specifically, in both copper and gold nanoclusters, we test the effect of truncating inert ligands from the model and compare density functionals with varying degrees of Hartree−Fock (HF) exchange from 0 to 50%, range-separated hybrids with a varying long-range tuning parameter, different correlation functionals, basis sets, and (equilibrium and nonequilibrium) continuum solvation models. Despite having different frontier orbital characters (the copper nanocluster has a metal-to-ligand charge transfer character while the gold nanocluster has metal-centered frontier orbitals), both nanoclusters display a similar sensitivity of the HOMO−LUMO gap to the HF exchange that is partially mitigated when computing the fundamental, optical, and electrochemical gaps. Other factors, such as the nature of the correlation functional, basis set, and geometry relaxation, have a considerably smaller effect on computed band gaps in these systems. Overall, this work provides guidelines for factors of varied importance for correlating computed and experimental band gap values.

Chemical calculations↗
DOE OSTI2021

Quantum Computational Advantage with String Order Parameters of One-Dimensional Symmetry-Protected Topological Order

Nonlocal games with advantageous quantum strategies give arguably the most fundamental demonstration of the power of quantum resources over their classical counterparts. Recently, certain multiplayer generalizations of nonlocal games have been used to prove unconditional separations between limited computational complexity classes of shallow-depth circuits. Here, we show advantageous strategies for these nonlocal games for generic ground states of one-dimensional symmetry-protected topological orders (SPTOs), when a discrete invariant of a SPTO known as a twist phase is nontrivial and -1. Finally, our construction demonstrates that sufficiently large string order parameters of such SPTOs are indicative of globally constrained correlations useful for the unconditional computational separation.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1984

An AOTV aeroheating and thermal protection study

The aerothermodynamics and thermal protection of aerobraking orbital transfer vehicles are studied with a view toward design methodology and technology requirements. A particular class of geometries is investigated: the ellipsoidally blunted raked-off elliptic cone. Discussed are the influence of various geometrical parameters on the trajectory and the heat flux as well as heating prediction methods ranging from an engineering correlation formula to computational solutions of the Navier-Stokes equations. Finite-rate catalytic thermal protection materials and gas radiation are considered. Estimates of the specific mass of possible thermal protection systems indicate that support structure is a large contributor to the aerobrake mass as compared with the thermal protection insulation itself. Sizing curves are included which enable the designer to estimate the size aerobrake required from heating considerations for different mass vehicles having aerobrakes of several specific masses.

Scott, C. D.↗
NASA NTRS1983

Fracture toughness/Young's modulus correlation for low-density fibrous silica bodies

Fracture toughness and static Young's modulus were measured for the low-density silic fiber materials used as tiles in the thermal protection system of the Space Shuttle. The fracture behavior was found to be in excellent agreement with a previously formulated micromechanical model and allowed both (density) classes of tile material to be correlated to a single function. A similar correlation was also found between strength and Young's modulus, which is the basis of a nondestructive evaluation test for these materials. It was shown that the value of Young's modulus determined from a dynamic test can be substantially greater than that determined in a static mechanical test. This effect must be taken into account in the correlation. Finally, it was also determined that these materials have significant variations in Kc, both within and between production units, so that the strength variability in these materials is dependent on both fracture toughness and flaw-size variations.

Green, D. J.↗
NASA NTRS1979

Use of arc-jet hypersonic blunted wedge flows for evaluating performance of Orbiter TPS

Arc-jet tests at NASA/JSC have been conducted recently to evaluate the performance of the Orbiter Thermal Protection System (TPS) on three critical areas of the side and top of the Orbiter fuselage: (1) cargo bay door, (2) crew access door, and (3) LRSI/FRSI joint regions. Test articles corresponding to these three areas on the Orbiter were mounted in an arc-jet test chamber in a blunted-wedge holder and exposed to hypersonic flow at various angles of attack. The effects of flow direction, heating load, and overtemperature were investigated. In addition, the reuse capability of the TPS materials was evaluated, along with the protection of the pressure seals within the test articles. Thermal match model predictions correlated well with primary structure thermocouple data. Heating rate and pressure predictions based on a nonequilibrium flow field computer program showed good agreement with arc-jet test data and existing hypersonic flow theories.

Rochelle, W. C.↗
NASA NTRS2016

Flight Experiment Verification of Shuttle Boundary Layer Transition Prediction Tool

Boundary layer transition at hypersonic conditions is critical to the design of future high-speed aircraft and spacecraft. Accurate methods to predict transition would directly impact the aerothermodynamic environments used to size a hypersonic vehicle's thermal protection system. A transition prediction tool, based on wind tunnel derived discrete roughness correlations, was developed and implemented for the Space Shuttle return-to-flight program. This tool was also used to design a boundary layer transition flight experiment in order to assess correlation uncertainties, particularly with regard to high Mach-number transition and tunnel-to-flight scaling. A review is provided of the results obtained from the flight experiment in order to evaluate the transition prediction tool implemented for the Shuttle program.

Berry, Scott A.↗
NASA NTRS2008

Supersonic/Hypersonic Laminar Heating Correlations for Rectangular and Impact-Induced Open and Closed Cavities

Impact and debris damage to the Space Shuttle Orbiter Thermal Protection System tiles is a random phenomenon, occurring at random locations on the vehicle surface, resulting in random geometrical shapes that are exposed to a definable range of surface flow conditions. In response to the 2003 Final Report of the Columbia Accident Investigation Board, wind tunnel aeroheating experiments approximating a wide range of possible damage scenarios covering both open and closed cavity flow conditions were systematically tested in hypersonic ground based facilities. These data were analyzed and engineering assessment tools for damage-induced fully-laminar heating were developed and exercised on orbit. These tools provide bounding approximations for the damaged-surface heating environment. This paper presents a further analysis of the baseline, zero-pressure-gradient, idealized, rectangular-geometry cavity heating data, yielding new laminar correlations for the floor-averaged heating, peak cavity endwall heating, and the downstream decay rate. Correlation parameters are derived in terms of cavity geometry and local flow conditions. Prediction Limit Uncertainty values are provided at the 95%, 99% and 99.9% levels of significance. Non-baseline conditions, including non-rectangular geometries and flows with known pressure gradients, are used to assess the range of applicability of the new correlations. All data variations fall within the 99% Prediction Limit Uncertainty bounds. Importantly, both open-flow and closed-flow cavity heating are combined into a single-curve parameterization of the heating predictions, and provide a concise mathematical model of the laminar cavity heating flow field with known uncertainty.

Everhart, Joel L.↗
DOE OSTI2022

Estimating the population level impact of a gonococcal vaccine candidate: Predictions from a simple mathematical model

Neisseria gonorrhoeae cross-protection was suggested in a New Zealand meningitis B vaccine. We modeled the potential impact of similar vaccines on gonorrhea prevalence in heterosexuals in the United States. Here, our mathematical model incorporated infection, behavior, and vaccination dynamics. Approximate Bayesian Computation calibrated our model to US prevalence. Primary analyses assumed New Zealand vaccine characteristics: 30% efficacy and 2-year duration of protection. We estimated impact under two vaccine coverages (20%, 50%). Reduction in gonorrhea prevalence ranged from 4.8 to 39.4%, depending on vaccine coverage. Vaccine impact was correlated with both size of the highly sexually active subpopulation and sexual mixing between high and low activity subpopulations. A meningitis vaccine providing low efficacy cross-protection against gonorrhea acquisition and short duration of protection could result in a large reduction in gonorrhea prevalence in the United States. Potential dual protective effects can be considered when making vaccine recommendations.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2026

Spontaneously Broken Noninvertible Symmetries in Transverse-Field Ising Qudit Chains

Recent developments have revealed that symmetries need not form a group, but instead can be noninvertible. Here we use analytical arguments and numerical evidence to illuminate how spontaneous symmetry breaking of a noninvertible symmetry is similar yet distinct from ordinary, invertible, symmetry breaking. We consider one-dimensional chains of group-valued qudits, whose local Hilbert space is spanned by elements of a finite group 𝐺 (reducing to ordinary qubits when 𝐺=ℤ 2 ). We construct Ising-type transverse-field Hamiltonians with Rep⁡(𝐺) symmetry whose generators multiply according to the tensor product of irreducible representations (irreps) of the group 𝐺 . For non-Abelian 𝐺 , the symmetry is noninvertible. In the symmetry broken phase there is one ground state per irrep on a closed chain. The symmetry breaking can be detected by local order parameters but, unlike the invertible case, different ground states have distinct entanglement patterns. We show that for each irrep of dimension greater than one the corresponding ground state exhibits string order, entanglement spectrum degeneracies, and has gapless edge modes on an open chain—features usually associated with symmetry-protected topological order. Consequently, domain wall excitations behave as one-dimensional non-Abelian anyons with nontrivial internal Hilbert spaces and fusion rules. Our Letter identifies properties of noninvertible symmetry breaking that existing quantum hardware can probe.

1-dimensional spin chains↗
DOE OSTI2021

Hydroxyl radical mediated damage of proteins in low oxygen solution investigated using X-ray footprinting mass spectrometry

In the method of X-ray footprinting mass spectrometry (XFMS), proteins at micromolar concentration in solution are irradiated with a broadband X-ray source, and the resulting hydroxyl radical modifications are characterized using liquid chromatography mass spectrometry to determine sites of solvent accessibility. These data are used to infer structural changes in proteins upon interaction with other proteins, folding, or ligand binding. XFMS is typically performed under aerobic conditions; dissolved molecular oxygen in solution is necessary in many, if not all, the hydroxyl radical modifications that are generally reported. In this study we investigated the result of X-ray induced modifications to three different proteins under aerobic versus low oxygen conditions, and correlated the extent of damage with dose calculations. We observed a concentration-dependent protecting effect at higher protein concentration for a given X-ray dose. For the typical doses used in XFMS experiments there was minimal X-ray induced aggregation and fragmentation, but for higher doses we observed formation of covalent higher molecular weight oligomers, as well as fragmentation, which was affected by the amount of dissolved oxygen in solution. The higher molecular weight products in the form of dimers, trimers, and tetramers were present in all sample preparations, and, upon X-ray irradiation, these oligomers became non-reducible as seen in SDS-PAGE. The results provide an important contribution to the large body of X-ray radiation damage literature in structural biology research, and will specifically help inform the future planning of XFMS, and well as X-ray crystallography and small-angle X-ray scattering experiments.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2023

Determining the influence of temperature and pressure on the structural stability in a polyurea elastomer

The structural response of amorphous elastomers to applied pressure and temperature is of significant interest given their potential for blast and impact protection applications. While understanding disordered structures is often challenging, this study focuses on the ordered correlations that are present at the atomic level even in amorphous materials. This local order was characterized in polyurea elastomers with two molecular weights up to 6 GPa and ~280 °C using in situ energy dispersive X-ray diffraction at the Advanced Photon Source via total scattering techniques. The resulting structure factors and pair distribution functions indicate that the applied pressure reduced the free volume but had little effect on covalent bonds for both molecular weights. Temperature-induced order-disorder transitions that occur readily at ambient pressures within the temperature range studied here were not observed, their onset likely delayed by the limited chain mobility associated with the free volume reduction. In conclusion, this study demonstrates that total scattering offers insights into the high-pressure structure of disordered polymers that are otherwise inaccessible using more conventional X-ray scattering techniques.

42 ENGINEERING↗
NASA NTRS2009

The Prediction of Long-Term Coating Performance from Short-Term Electrochemical Data: Comparison of Electrochemical Data to Field Exposure Results for Coatings on Steel - Part 2

The pace of coatings development is limited by the time required to assess their corrosion protection properties. This study takes a step f orward from Part I in that it correlates the corrosion performance of organic coatings assessed by a series of short-term electrochemical measurement with 18-month beachside exposure results of duplicate pan els. A series of 19 coating systems on A36 steel substrates were test ed in a completely blind study using the damage tolerance test (DTT). In the DTT, a through-film pinhole defect is created, and the electro chemical characteristics of the defect are then monitored over the ne xt 4 to 7 days while immersed in 0.SM NaCl. The open circuit potentia l, anodic potentiostatic polarization tests and electrochemical imped ance spectroscopy were used to study the corrosion behavior of the co ating systems. The beachside exposure tests were conducted at the Ken nedy Space Center according to ASTM D610-01. It was found that for 79 % of the coatings systems examined, the 18 month beachside exposure r esults could be predicted by two independent laboratory tests obtained within 7 days.

Contu, F.↗
NASA NTRS2015

Thermal Protection System Mass Estimating Relationships For Blunt-Body, Earth Entry Spacecraft

Mass estimating relationships (MERs) are developed to predict the amount of thermal protection system (TPS) necessary for safe Earth entry for blunt-body spacecraft using simple correlations that are non-ITAR and closely match estimates from NASA's highfidelity ablation modeling tool, the Fully Implicit Ablation and Thermal Analysis Program (FIAT). These MERs provide a first order estimate for rapid feasibility studies. There are 840 different trajectories considered in this study, and each TPS MER has a peak heating limit. MERs for the vehicle forebody include the ablators Phenolic Impregnated Carbon Ablator (PICA) and Carbon Phenolic atop Advanced Carbon-Carbon. For the aftbody, the materials are Silicone Impregnated Reusable Ceramic Ablator (SIRCA), Acusil II, SLA- 561V, and LI-900. The MERs are accurate to within 14% (at one standard deviation) of FIAT prediction, and the most any MER can under predict FIAT TPS thickness is 18.7%. This work focuses on the development of these MERs, the resulting equations, model limitations, and model accuracy.

Spacecraft↗